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By C. Hilgendorf, J. Gingerich, J. R. Boniwell, M. Drouin, D. David on, J. Boldy

The initial discovery of gold in the Eastmain River area, 310 km northeast of Chibougamau, was made by Placer Development Limited in 1970. This discovery resulted from the drill testing of an airborne E .M. Target located in an area of extensive glacial overburden, within an unexplored Archean greens tone belt considered prospective for base metal deposits. Intermittent exploration by another company between 1973-1977 failed to obtain promising results and the existing claims were allowed to lapse. In 1981, Placer reactivated the project and initiated intensive exploration during the next two years which included aerial E .M. surveys, claim staking, ground E .M. and magnetic surveys, geological mapping, diamond drilling and attendant borehole P,E.M. surveys. Beginning in 1983, exploration has been conducted on a joint venture basis with Eldor Resources Limited, The greenstone belt under investigation has an arcuate distribution pattern relative to a centrally located granitic core. Occurrences of gold mineralization defined to date are located to the south of the granite along a strike length of 7 km, and appear to be restricted to the lowermost of two mafic volcanic cycles. This lower cycle is dominated by basaltic flows with subordinate rhyolitic flows and pyroclas ties. Concordant, variably magnetic, massive to talcose ultramafic units occur towards the stratigraphic top of the lower mafic volcanic cycle and appear to crudely define areas considered prospective for gold on a regional bases. Economic interest in centered on a s tratabound, siliceous, sulphide-bearing unit hosted in a 15- 25 metre thick sequence of rhyolite tuffs, basalts and intercalated ultramafics, The siliceous ore bearing unit ( interpreted as a recrystallized chert) contains from 10%-30% pyrrhotite and pyrite with subordinate chalcopyri te and minor sphaleri te. Alteration is characterized by mica development, silicification and carbonatization. Garnets are also occasionally present in close proximity to the ore horizon. The sequence is south facing, and overturned to the northeast at 35°-55°. Explora tory drilling in the vicinity of two conductive targets has been on 100 metre centres along a 1 km strike length of the prospective sequence. To the end of 1983, two ore zones (A and B) have been partially drill tested with estimated indicated and inferred geological reserves of 1 million tonnes grading 11.7 g/t gold , 14.7 g/t silver and 0.26% copper. The system is open at depth. This discovery is the result of the effective integration of geophysics and geology with contributions by many over a long period of time. Key events that can be emphasized are: ( 1) initial area selection of a remote greenstone belt in 1969 - albeit for base metal deposits , (2) utilization of an airborne E .M. system which successfully targeted the A Zone in 1970 , (3) the timely reactivation of the project in 1981 and the subsequent recognition that the original discovery represented a sulphide bearing stratabound horizon with implicit volcanogenic connotations , (4) the intensive effort in 1982-83 deploying aerial and ground geophysics coupled to volcanogenic concepts of ore distribution which resulted in the discovery of the B and C Zones in 1982, and (5) the integration of downhole P . E.M. surveys and geology to successfully delineate ore at increasing depths . To the end of 1983 , $2.6 million has been expended, and it is hoped that continued effort will result in the eventual delineation of an economically viable ore deposit for the joint venture partners .

Jan 1, 1984

By J. A. Finch, J. Vergouw

"Flotation selectivity becomes progressively more difficult to achieve with decreasing particle size. One of the possible problems is agglomeration, i.e. particles clustering together. One mechanism derives from the surface charge all particles develop in water. Agglomeration driven by surface charge is known as coagulation. One form is coagulation between particles of two different minerals of opposite charge. Another is coagulation between particles of the same mineral when conditions are such that the charge approaches zero.The paper describes the method of measuring charge and a new automated settling technique for measuring agglomeration. The phenomena are illustrated with galena and pyrite. Methods of assessing the importance of agglomeration in the plant environment are still to be developed.IntroductionFine particles can agglomerate (i.e. adhere to each other) under certain conditions. This is counter-productive for any physical separation process, including flotation. One cause of agglomeration derives from the surface charge that all particles develop in water. Agglomeration due to surface charge effects is referred to as coagulation. There are two forms of coagulation. If the surface charge is brought to near zero then the force of repulsion is lost and particles coagulate. This usually applies to particles of one mineral type and the technical tenn is homocoagulation. On the other hand, if two particles have opposite charge there is an attractive force. Since the particles in this case are usually different minerals this is known as heterocoagulation.Both types of coagulation can cause minerals to be misplaced. In the case of heterocoagulation this is fairly obvious. One example that may be familiar is slime coating (fines of one mineral coating larger particles of another) But even homocoagulation can be a problem an agglomerate of the same mineral particles can entrap particles of another mineral."

Jan 1, 1997

By Peter Bourke, Marc van Olst, Seppo Ronkainen, Natalie Brown

"Since the early days of flotation, process technicians have known that the speed at which the froth is recovered over the lip of the cell has a very direct and consistent influence on the grade and recovery of the circuit. No plant would deny that, even to this day, one of the most important aspects of a process technician’s job is ensuring that the froth is moving at a desired and controlled speed over the lip. Unfortunately, process technicians cannot watch the froth throughout the entire shift, as there are always a lot of other tasks to do.A considerable amount of work has thus been done to develop a “system” that automatically measures the speed of the froth. This measurement would then be used in simple controllers to emulate the steps taken by the process technician in correcting deviations of the froth speed from its desired level. Many of the earlier attempts to measure speed were ineffective, as they were unable to cope with turbulence on the froth surface. The FrothMasterTM instrument makes use of machine vision technologies to measure the speed of the froth over the lip of a cell at a very high sampling rate. This instrument produces an extremely reliable and accurate measurement of the froth speed (as well as other parameters such as bubble size and froth stability). As we will show, the effectiveness of the speed measurement in controlling the performance of the plant is a testimony to its reliability.Three FrothMasterTM units have recently been installed on the Cadia Hills Gold Mine in New South Wales (Australia). The objectives of this installation were:To control the mass-recovery of two Tank Cells in series on the same level where differences in the hydrostatic head between the two cells result in the cells pulling inconsistently with respect to each other.Control of the concentrate grade (%Copper) from the first rougher.Reduction in the frother consumption in the rougher circuit by monitoring the froth speed.A simple controller was designed to react to disturbances in the same way that human operators react. This was done after consultation with the metallurgists and the process technicians at Cadia. The controller had two functions:Stabilisation: The stabilising controller made use of three manipulated variables (level, frother addition rate and aeration rate) to control the froth speed to a setpoint.Optimisation: The optimising controller adjusted the froth speed setpoint based on deviations of the grade (measured in real-time with an OSA) from a setpoint. The plant metallurgist adjusted the grade setpoint based on information about the ore."

Jan 1, 2001

By K. J. R. Ford

"Significant advances in mining and metallurgical operations have occurred over the last two decades, to define ore bodies via geological mapping, mineralogical analyses, geostatistical models and resource reserve modeling. Metallurgical process measurement, controls and modeling have also significantly progressed, with advanced instrumentation, control software, data capture systems and simulation tools. This progress together with development of the science of geometallurgy has allowed geologists, mineralogists, miners and metallurgists to start working together to define geometallurgical ore units and link these to mine planning and projected metallurgical performance. However, application of full geometallurgical programs into existing mine-processing operations or into new “greenfield” projects has been slow. This is mainly due to higher costs, limited dedicated technical resources and little or no corporate leadership. Additionally, life-of-mine cash flow models, the “dollars”, have been largely driven by ore tonnage rates, pay-metal grades and fixed pay-metal percentage recoveries, with few or no geometallurgical parameters included.Here defined, the “electrons” represent intrinsic ore characteristics embracing chemical composition, mineralogy, gangue components and their associated fundamental metallurgical processing phenomena. With its ever expanding treasure chest of measurement and modeling tools, geometallurgy paints a much clearer picture of the “electrons” for the geologist and metallurgist. But to fully understand and realize the real net value of ores over the life of a mine, a comprehensive link of “electrons to the dollars” is essential. Intrinsic characteristics of geometallurgical ore units are by definition linked to their metallurgical processing, but importantly need also to be related to operating costs, capital requirements and revenue.This paper discusses this important linkage under topics of ore geology and mineralogy, metallurgical processing, waste disposal, environmental issues, metal refining, project engineering and lifeof- mine models. Topics are illustrated by multi-metal references and by case examples from gold ore heap leaching and manganese ore smelting projects. 1"

Jan 1, 2013

By H. E. Urtubia, C. W. Bailey

"BHP-Billiton’s Minera Escondida Limitada is one of the world’s largest copper producers. It treats a combined 88 million tons of copper ore per year through its two concentrators: Los Colorados and Laguna Seca. Over the past three years, metallurgical sampling has been performed at the Laguna Seca concentrator to calibrate both the JKSimMet and JKSimFloat grinding and flotation simulators. In the past, the calibrated simulators have been used to predict the effect of changes in operating conditions in the grinding and flotation circuits separately. To assist in the development of future processing options, predictions were required of the effect of changing grinding circuit conditions on flotation performance. This was achieved by using an integrated grinding and flotation simulation. The grinding circuit performance was predicted under different operating conditions (such as tonnage rate and product grind size) using JKSimMet, and these results were then used in JKSimFloat to predict the flotation performance for the new grinding circuit product. This combination of the simulators allows both the effects of residence time and grind size on flotation performance to be investigated.This paper presents the first combined grinding and simulation modelling and simulation case study using JKSimMet and JKSimFloat. The modelling and simulation methodologies for the grinding and flotation circuits are discussed along with the circuit simulations that were performed. The simulator predictions are presented in conjunction with independent laboratory results of the new operating conditions. The ability to predict flotation circuit performance based on changes in grinding circuit performance is also discussed. This methodology provides improved predictions of flotation circuit performance when grinding circuit changes (including grinding capacity increases) are made.INTRODUCTIONOver the past decade, the grinding and flotation research groups at the Julius Krutschnitt Minerals Research Centre - JKMRC (Brisbane, Australia), University of Cape Town (Cape Town, South Africa) and McGill University (Montreal, Canada) have been developing a methodology for optimising grinding and flotation plants using actual plant data together with semi-empirical sub-process models. The project is being conducted as part of the Australian Minerals Industry Research Association (AMIRA) P9 Project, titled “The Optimisation of Mineral Processes by Modelling and Simulation”. The project first commenced in 1962 and is currently in its “Nth” phase."

Jan 1, 2007

By W. Duyvesteyn, B. Sabacky, T. Spitler, D. Verhulst

"The Altair TiO2 pigment process is based on hydrochloric acid leaching of ilmenite at high-acid concentration. Titanium is transferred by solvent extraction into a high-purity aqueous stream with a high titanium concentration. HCl gas is recovered by pressure-swing distillation and is used to regenerate the leaching solution.A new method of TiO2 recovery in dense film with simultaneous dehydration and hydrolysis provides great flexibility in adjusting the characteristics of the TiO2 pigment product.Modifications of this method lead to a flexible, low-cost, high-tonnage process first for the production of nano-sized TiO2, and later for stabilized zirconia-based nanomaterials and nano-sized titanates.IntroductionProcesses for the production of TiO2 from ore by a hydrochloric acid route have been proposed in the past. Most of these processes dissolve impurities and recover TiO2 as a residue or as a hydrolyzed phase in the original solution (Turner, 1948; Berkovich, 1975; Morris, 1982; Judd, 1986; Chao, 1993). Solvent extraction of titanium after leaching in aqueous HCl has also been studied (Tsuchida et al., 1982; Narita et al., 1983) or at least mentioned as an alternative (Ellis, 1963). A number of small-scale studies on leaching and solvent extraction in both sulphuric and hydrochloric systems have appeared recently (John et al., 1999; Lanyon et al., 1999; Sole et al., 1999. As far as we know, only Kerr-McGee (Morris, 1982) and a plant in India and one in Malaysia use a hydrochloric acid route (20 wt% HCl) to commercially produce synthetic rutile.The Altair process originated in a search for an economical method to treat high-magnesium ilmenite deposits, while avoiding the production of a waste metal salt by-product. The first attempts aimed at producing pure TiO2 by leaching out the impurities. Further work centred on completely dissolving the ilmenite in concentrated hydrochloric acid and reprecipitating TiO2. To decrease the impurity level in the product, solvent extraction of titanium into a purified stream was introduced. It also became clear that to take full advantage of the increase in leaching efficiency provided by concentrated acid, it was necessary to regenerate HCl gas."

Jan 1, 2002

By Kenji Koga

In order to derive the population distribution of gold nanoparticle morphologies as a function of size, highresolution electron microscopic (HREM) observations and structural analyses were done for over 4000 particles (3-18 nm) grown by an inert gas aggregation (IGA) source using helium. To obtain structural features threedimensionally and not to skip high-contrast images, twenty photos were taken for each particle by changing tilting angle of a specimen holder in combination with the through-focus procedure. For the reliable structural determinations, HREM images and their tilting sequences were directly compared with multislice-simulation results for icosahedral, decahedral and face-centered cubic morphologies, and finally the population distribution of each morphology was obtained as a function of size. In the present sample, icosahedral particles were dominantly populated over the whole observed size range and decahedral particles with non-spherical truncated bi-pyramid shape were secondly dominant. Even though a large number of sampling has been done, few crystalline particles were observed.

Oct 1, 2003

By P. N. Saavedra, E. A. Salamanca

"The maintenance strategies in the mining industry are changing from operative and periodic inspection strategies to a condition-based, predictive maintenance strategy centred in vibration analysis plus complementary techniques. Condition monitoring can also help to improve availability by being able to pinpoint and diagnose problems on operating machinery at an early stage. This reduces unscheduled downtime and production losses.However, in mining, for shovels operating in transient modes, with variable load and/or speed, the FFT (Fast Fourier Transform) standard approach is not directly applicable for analysis. This work illustrates how spectral order analysis and new transforms, called time-frequency transforms (TFT), allow us to monitor the shovel when it is working. Some practical examples showing the application of these analysis techniques to occasional vibrations measured on hoist and crowd transmission of a shovel are also presented. It is shown that at present, it is possible to carry out the vibration monitoring in the mining shovel while it is working, therefore avoiding the high cost of a loss of production which can occurr in traditional monitoring, where the measurement is taken while the shovel is out of production."

Jan 1, 2002

By Glenn K. Nolan

"Today, more than any other time in recent history, aboriginal communities are looking for ways to be understood as more resource development companies continue to explore and develop Canada's vast resource potential.Recent Supreme Court rulings have affirmed the need to engage aboriginal communities early on in resource development projects. There are many conflicting ideas on how, who, and when to engage. Given the large number of communities and varied cultures, each resource development company must equip itself with a better understanding of the people they are planning to work with.The lecture will begin with a basic historical perspective on treaties and the various societies across Canada. We will also explore the current situation many communities find themselves in today. Building a meaningful relationship with a community is the foundation for a lasting partnership. Every community is unique and every approach to engage communities must be just as unique. The lecture will outline some basic steps that can lead to a better relationship building process between the communities and companies."

Jan 1, 2008

By Fraser Rowe

This paper discusses the philosophies, strategies, goals and pitfalls in automating a mine schedule. The intention of the paper is to give an open and honest view of who could benefit from moving to an automated system, what you can expect from such a system, and what you should be aware of. Many companies feel that moving to an automated mine planning solution will allow the mine scheduling engineer to push a button and walk away, but the reality is that is hardly ever the case. Part of that awareness comes from understanding what is meant by ?automated mine scheduling?, and this paper address that. By contrasting what is meant by ?manual scheduling? and ?automated scheduling? it is hoped that the reader can gain an appreciation of the entire process.

Oct 1, 2009

By P. R. Stephenson

"The Australasian Code for Reporting of Mineral Resources and Ore Reserves (JORC Code) has been operating successfully for 14 years, and has an ancestry dating back over 30 years. Together with complementary developments in stock exchange listing rules, the Code has brought about substantially improved standards of public reporting by Australasian mining and exploration companies. The Code is regarded as a world leader in its field, and has been used as a basis for the development of resource/reserve reporting standards in other countries. The reasons for its success are varied, foremost among them being its adoption in full by the Australian and New Zealand stock exchanges, and the ability and willingness of mining industry organizations to bring Competent Persons to account when necessary.The latest revision of the JORC Code was undertaken in 2002-2003, based in part on releases of upgraded reporting standards in Canada, the United Kingdom/Western Europe, and South Africa, and the 2003 edition is expected to be released mid-year. Two of the more significant changes are: the introduction of a requirement for a Competent Person to be responsible for the documentation upon which Exploration Results are reported; and inclusion in the definition of a Competent Person of a reference to “Recognized Overseas Professional Organizations” being overseas professional organizations to which Competent Persons may belong for the purpose of preparing documentation for the submission of reports to the Australian Stock Exchange."

Jan 1, 2004

By Sylvie Brassard

Available information ?? InfoMine: mineral properties ?? Metals Economics Group: budgeted exploration expenses ?? MineScan: Canadian and American Mining Companies ?? Statistics Canada: Canadian Direct Investment Abroad, by Sector in the world OR all sectors by Country

May 1, 2008

By Sami Hindstrom, Travis Orser, John Starkey

"A great deal of effort has been expended in the last 11 years by the authors and others to identify the correct power required to grind ore in a SAG mill, by developing ore hardness variability functions for the ore body to be mined. This paper describes the next step in the SAG design process, which is choosing a SAG mill to accomplish the required specified design performance.At the test work stage, each ore hardness data point is a unique and discreet bit of information that represents the energy required to grind the ore represented by that sample at optimum SAG conditions. When the design criteria are set, it is now considered necessary that the required power draw in the mill chosen be provided at optimum conditions as well.Based on actual 3-ft diameter pilot plant results, we can now show that the grinding efficiency and throughput drop when the optimum load limit is exceeded. Future work is expected to show a similar reduction in efficiency when exceeding optimum speed. Providing specified power by exceeding these optimum conditions is not adequate and leads to a lower cost but underperforming SAG mill.It is possible in some cases to modify a SAG circuit to force it to perform better, but this often takes time, much effort and costly modifications. In most cases the capital spent on a properly sized SAG mill may prevent production losses that would be many times greater over the extended start up period. This is the direct result of choosing the proper SAG mill at the start.INTRODUCTIONThe sequential steps required for the design of any grinding circuit, have changed dramatically in the last seven years. Previously, it was considered necessary to do six foot diameter SAG mill pilot plant tests on representative samples of minus six inch ore (F80), in order to understand design requirements. It can now be shown that this method is costly and not likely to produce the desired result because it is difficult to recover six-inch material from deep within a new mine. The representative nature of the sample is often compromised when the sample is selected."

Jan 1, 2003

By Leslie F. Sawatsky

Each potential oil sands developer deals with the question of optional sources of raw water to supply large water demands that range from 50 to 80 million cubic metres per year for each of six existing and planned developments. The Athabasca River currently supplies nearly all of the water to the existing mines via conventional bank intakes, which has resulted in some concern over the effects of reduced river flows. This paper describes the various water supply options, and the likely scenario for future oil sands water supply projects. Various water supply options have been suggested including Athabasca River water via infiltration galleries, groundwater, combined Athabasca River water and alluvial groundwater using wells (i.e. bank filtration systems), diversion of tributary rivers, utilization of large lakes in the region and pumping from other large rivers in the region. Investigations show that the size of river catchment needed to support raw water usage by a typical oil sands mines exceeds 5,000 km2 eliminating all tributary rivers that are located in the oil sands region except those rivers with large drainage areas like Firebag and MacKay Rivers. Lakes cannot be used as a source of supply due to large water deficits for smaller lakes and the large cost of sourcing water from a lake as large as Lake Athabasca. A groundwater source alone would not likely meet the large water demands. River intakes on the Athabasca River will likely continue to be the most practical water supply option for oil sands mines north of Fort McMurray, although various types of Athabasca River intakes are possible. Existing intake systems include screened riverbank intakes, forebay intakes, and river bottom intakes. Infiltration galleries are not feasible for most sites, though some bank-filtration-type systems using high capacity wells may be an option if there is sufficient thickness of high-permeability alluvium at a suitable location in the Athabasca River valley.

May 1, 2004

By Phillip Cancilla, Daniel Roy, Frank Rosenblum

"The manual moisture determination methods employed today by mineral processing plants falls short in providing timely information required for automation control. The costs associated with transporting and handling concentrates still represent a major portion of the overall treatment price. When considering the cash flow of a mining operation, that is governed by both the smelter contract, with moisture penalties and the quantity and quality of the concentrates shipped, an efficient method of on-line moisture content would be a welcome tool.A novel on-line determination system for ore concentrate moisture content would replace the normally tedious classic manual procedure. Since the introduction of microelectronic-based control systems, operators have strived to reduce the treatment costs to the minimum therefore a representative and timely determination of on-line moisture content becomes vital for control set points and timely feedback. Reliable sensors have long been on the “wish list” of mineral processors since the problem has always been that you can only control what you can measure. Today, the task of moisture determination is still done in the classical technique of loss in weight by uncontrolled procedures. These same methods were introduced in the earliest base metal concentrators. Generally, it is acceptable to have ore concentrate moisture content vary within a range of 7 to 9%. Many times, delays in manually achieving reliable feedback on the moisture content results in the moisture varying from 5 to 12% before corrective actions can be made.This paper first reviews the traditional and widely available methods for determining moisture content in granular materials by applying physical principals and properties to measure moisture content. All methods are in some form affected when employed on mineral ore concentrates. This paper describes a unique and promising on-line moisture sensor in two mineral processing applications, which not only automates the tedious tasks but also results in reliable moisture feedback that can be used in the optimization of the de-watering process equipment such as pressure or vacuum filters and fuel-fired driers. Finally, two measurement applications will be presented to indicate the usefulness and to summarize the measurement requirements for the proposed method of employing drag force and mechanical properties of the material itself to determine the moisture content."

Jan 1, 2001

By Bryan M. Maybee

The scheduling of underground mining activities is a complex task, in particular because of the requirement to satisfy a large number of constraints. A Schedule Optimization Tool (SOT) for underground mine planning is described, and its use for investigating strategic decisions is illustrated by means of a case study. The main components of SOT include: a genetic algorithm, which searches for optimal schedules; guidance, the application of heuristic rules to guide the genetic algorithm; and sliding, which implements just-in-time development. For the case study, SOT is employed to generate schedules at various ore capacities, accounting for the appropriate financials in each schedule evaluation. The case study finds that preliminary scheduling performed before invoking SOT, intended to provide a good starting point for the search, does not ultimately lead to higher value schedules. Two key uses for SOT are identified. A mine planner can save time by using SOT to produce high-value scheduling alternatives. This process ensures a broader investigation of the value that the deposit can yield. Also, SOT can be used to validate strategic and tactical decisions, by scheduling under alternative scenarios. Both uses produce high value schedules conforming to all imposed resource constraints.

May 1, 2009

By R. Rosenblum, J. Y. Kim, D. Shink, K. G. Stowe

"A small scale continuous flotation cell was designed and constructed at the Noranda Technology Centre to develop a mobile testing flotation circuit located next to the production circuit. This mobile small scale flotation pilot plant can easily and economically be set up at any circuit in a mill and used to evaluate and predict plant performance against a given flotation condition. The main feature of the cell, beside the provisions of automatic pulp level and feed rate control, is to provide a reduced surface to volume ratio approaching to that of an industrial machine.This paper describes the basic design and the results of various testwork carried out to date including aeration, conditioning, reagents, recirculation, flotation gas, etc. are presented in comparison with the plant production results. INTRODUCTIONStudy of the behaviour of an ore during concentration by flotation process starts, in general, with a series of tests in laboratory cells. Given the discontinuous nature of these tests, the information obtained by such a study is somewhat limited. It has long been recognized that laboratory test results are not always reproducible in pilot plant tests and subsequently, the pilot plant results do not always predict plant performance. The differences are often blamed on batch vs continuous operations, grinding media, size distribution, aging (oxidation), water quality, equipment, operator's skills, etc."

Jan 1, 1992

By J. A. Vallejos

Re-entry protocols are a tactical approach for controlling risk after blasts or large events in seismically active mines. Based on the results of a survey on 18 seismically active mines, mostly in Ontario, current re-entry practices are summarized. Over half of the mines in Ontario use event decay rate analysis as their primary re-entry decision making parameter. We study in detail the applicability of the Omori?s law as an equation for describing the event decay rate for more than 250 mining-induced aftershock sequences in seven different environments. Practical guidelines for the use of the Omori equation as a re-entry criterion are proposed.

May 1, 2009

By Jacques Deraisme

The technology of percussion drilling is well mastered. The lower cost of percussion drilling allows more holes to be drilled for the same budget. However significant differences are often observed between percussion and diamond drill assay data. This is due to the increased level of contamination associated with the percussion drilling process. Statistical studies on twinned drillholes show that diamond and percussion assays cannot simply be merged in a traditional kriging approach. The question then arises on how to use both types of data to produce reliable resource estimates. To take into account the lower reliability of the percussion assays, a noise characterized by a variance is added to these data. The methodology consists of two steps: 1. Cokriging of the equivalent diamond value at the percussion assay locations. 2. Block kriging using diamond assays and equivalent diamond values, calculated previously, adding to these data a noise, whose variance is the cokriging variance of step 1. This particular way of achieving kriging is called kriging with variance of measurement error. The paper illustrates this innovative methodology with an application on an iron deposit. The results of this method is compared to block kriging using only diamond assays and the gain in precision is quantified. An extension of that approach to multi-element cokriging is also presented.

Oct 1, 2009

By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016