Search Documents

By A. M. Kivari

OPERATIONS at the cement plant of the Permanente Corporation, in the hills about 45 miles south of San Francisco and 12 miles west of San Jose, are interesting to the members because of the adoption of modern hydrometallurgical methods for handling and beneficiating raw materials Closed-circuit grinding, classification, hydroseparation, flotation, agitation, and thickening are familiar terms at this cement plant These methods make it possible to process refractory limestone into suitable materials for the manufacture of modern cements Construction of the plant, haying originally a design capacity of 7000 bbl of cement per clay, was started in June 1939, and the first clinker was ground on the following Christmas Day At present the capacity is about 12,000 bbl of finished cement per 24 hr , most of the production being low-heat cement † About 3130 tons of limestone, 620 tons of clay and 100 tons of gypsum are required daily for this output Occasionally iron oxide is added to the clay to obtain the desired composition This, together with the gypsum, is purchased from outside sources Up to the present time, the corporation has produced low-heat, normal, moderate¬ heat, moderate-sulphate-resisting, high-early-strength, oil-well, modified-oil-well, and plastic cements Most of the present production is for Shasta Dam, near Redding, Calif , the told demand being 5,800,000 bbl of cement Following are sonic of the cement requirements of the Shasta D [im] specifications [ ] The average specific surface in the bin s sampled shill be not less Ulan 1800 sq cm per gram and no individual sample less thin 1600 sq centimeters Compressive strength The average compressive strength in pounds per square inch of three mortar cubes composed of one part cement and 2 75 parts fine testing sand, by weight, shall be equal to or greater thin the following

Jan 1, 1941

IT is difficult to judge how much influence the success attained during its first year, 186465, by the School of Mines at Columbia had on developments in education for the mineral industry elsewhere in the immediately subsequent years. The facts are as follows: 1. The Massachusetts Institute of Technology began giving instruction in February 1865, with a mining course included in its curriculum. 2. Early in 1865 the faculty of the Department of Science, Literature and the Arts of the University of Michigan requested permission from the Regents to establish "a course of study to be called the School of Mines . . . Also that the degree of Mining Engineering be conferred on students who should complete the course of study prescribed in the same." A resolution authorizing this was adopted by the Regents on March 28, 1865. 3. Samuel Hooper endowed a Sturgis-Hooper professorship of geology at Harvard in 1865 with the intention of making it a nucleus of a new School of Practical Mining and Geology. 4. Yale appointed Alfred P. Rockwell professor of mining in 1865. 5. Lafayette College appointed Henry S. Osborn professor of mining and metallurgy in 1865. 6. Washington College (as Washington and Lee was then known), rising out of the ashes of Civil War destruction, made a fresh start in 1865, with General Lee as its president, and offered a mining course in the first catalogue thereafter published. 7. Lehigh University, founded in 1866, had a mining curriculum from its beginning. 8. Rensselaer Polytechnic began offering a curriculum in mining and metallurgical engineering in 1867. It would be natural to suppose that these events were a reaction to the success of the school at Columbia, and possibly they

Jan 1, 1941

By C. P. Gazzara and

The modulus of elasticity and yield strength of commercially pure, annealed titanium sheet was investigated at room temperature as a function of strain rate and direction of loading. The value of E varied with direction of measuremeni in the sheet but was unaffected by strain rate in the range 0.04 x 10-to 10-2min-1. The yield strength increased with increase it2 strain rate and varied with specimen orientation. VALUES of the modulus of elasticity, E, in tension for commercially pure titanium have been reported at from 14 to 20Xl06 psi.' Reasons suggested for this variation have been a) composition, b) strain rate, c) texturing, and d) creep. For example, alloys of titanium with aluminum, manganese, and nitrogen have yielded modulus values of from 12.5 to 16.8 x lo6 psi at room temperature.' It was shown by Klier that the modulus in titanium plate was sensi-tive to strain rate. while Dotson and kattus meas- ured variations in E as the strain rate was increased from 3X to 60 min-l. For RC-7OA, 0.040-in. titanium sheet at room temperature Dotson and Kattus found that the average values of E, for specimens in the rolling direction, increased from 14.7 to 16.0 X lo6 psi as the strain rate increased. Simultaneously, the 0.2 pct yield strength increased from 74,700 to 95,700 psi for the same specimens. Differences in yield strength and E have been reported as a function of directionality in titanium sheet.= Dotson and Kattus report such an effect, and Feola6 found in annealed titanium sheet marked anisotropy in tensile strength, yield strength, reduction in area and elongation at room temperature, with

Jan 1, 1961

By Clarence Zener

Theoretical considerations by one of the authors have ledl to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have verified2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are presented to test this extended theory. The physical basis for the type of internal friction that is being investigated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so likewise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal currents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,³ and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal currents accompanying transverse vibrations. Of more fundamental importance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adjacent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

By Clarence Zener

Theoretical considerations by one of the authors have ledl to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have verified2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are presented to test this extended theory. The physical basis for the type of internal friction that is being investigated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so likewise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal currents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,³ and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal currents accompanying transverse vibrations. Of more fundamental importance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adjacent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

By R. G. Treuting, W. C. Ellis

D. Whitwham, M. Mouflard, and P. Lacombe (British Council Research Fellow, Labratoire du Professor Chaudron, Vitry-sur-Seine; Inqenieur de Recherches, Labratoire de Vitry; and Maitre de Recherches, Labratoire de Vitry, Professeur Adjoint de Metallurgie, Ecole des Mines, Paris)—The authors' work is of great interest in bringing out the geometrical relations existing between twinned lattices, and for the notion of a coincidence super lattice developed from this. We should like to point out that a similar idea was put forward by Friedel8 in his book on the subject of lattice merohedrism "merihedrie réticulaire:"—When two crystals A and B are twinned with respect to a mirror plane, there exists a common superlattice, "réseau periode," which is independent of the contact surface between the two crystals. The volume V of this superlattice is a simple multiple of the volume v of the lattice of crystals A, or B, (Fig. 5). This "multiple cell" is defined by the twin plane (p q r) and a row of atoms [h k l] normal to this plane, the base being taken as the smallest unit (two-dimensional) of this plane. Two cases must be considered. First when the multiple cell, as defined, has no atom site at its center nor at the center of its faces other than (p q r), v the twinning index is defined by —. In the second v case, when one of the two above conditions does not v apply, then the twinning index is V 2v A more intuitive definition of the twinning index would be the proportion of atoms of C, which would coincide with those of C1 when the C, lattice is imagined to extend on the other side of the contact surface. In the case of cubic crystals, the twinning index

Jan 1, 1952

These pages may be used as order sheets. Mark the number desired opposite title of pamphlet wanted, add your name and address, tear out the sheets and mail them to us. Single orders 25 c. Pamphlets 10 c. each in lots of three or more. Pamphlets 5 c. each in lots of fifty or more. These prices prevail for orders for pamphlets of the same or different titles, when cash accompanies order. The pamphlets listed on the following sheets are advance copies printed to facilitate discussion at the meetings of the Institute. They are offered for sale at the reduced prices given above as long as-the supply lasts. This list is published in the Bulletin in order that members may have the first opportunity to secure pamphlets, which sometimes are in such great demand that the supply is exhausted before the wants of members can be supplied. The following list includes only a fraction of the pamphlets that have been published by the Institute. Any other paper published by the Institute may be obtained for the price of $1, except those published in Volume XXXI, which are rare. The Institute is still selling back volumes of Transactions at reduced prices, but some of these volumes are becoming rare and members who desire to complete their sets of these very important books on mining and metallurgy are advised to send in their orders as soon as convenient. (See Advertising page 15.) , The attention of members is also called to the bibliographical index of the science of ore, deposits contained in the Emmons Volume which is selling at $3 in paper and $4 in half morocco. The Posepny Volume is already exhausted and members who do not get in their orders for the Emmons Volume at the present reduced price may soon find themselves unable to obtain it on such favorable terms.

Jan 6, 1917

By F. A. Hames, D. S. Eppelsheimer

The ferromagnetic copper-manganese-aluminum and copper-manganese-tin alloys (Heusler alloys) owe their ferromagnetism to the beta phases (body-centered cubic structure) in their respective systems.l,2,3 The ternary beta phase regions in these systems are extensions of the beta fields of the binary copper-aluminum and copper-tin systems into the ternary models of the copper-manganese-aluminum and copper-manganese-tin systems respectively. X ray analysis has indicated the presence of long-range order in the more strongly magnetic alloys.3,4,5 The ideal ordered structure is obtained in alloys of compositions Cu2MnAl and Cu2MnSn; the copper atoms occupy positions at cube centers while the aluminum (tin) and manganese atoms alternate at cube corners. This atomic arrangement is illustrated in Fig 1. The compositions Cu2MnAl and Cu2MnSn are also those that show maximum magnetic saturation moment. 3,4,6,7 Departures from these compositions result in a decrease in the degree of order attainable and a decrease in magnetic saturation moment. In view of the chemical similarities of aluminum, tin, indium, and gallium, and the existence of beta phases in the binary systems copper-indium and copper-gallium, it may be suspected that ternary beta phases exist in the systems copper-manganese-indium and copper-manganese-gallium, and that these are ferromagnetic. The purpose of this investigation was to determine whether ferromagnetic beta phases exist in the systems copper-manganese-indium and copper-manganese-gallium analogous to the ferromagnetic beta phases in the systems copper-manganese-aluminum and copper-manganese-tin. Previous Work At the time this investigation was started no information could be found regarding the constitution of copper-manganese-indium and copper-manganese-gallium alloys, nor of the binary manganese-indium and man-

Jan 1, 1950

By W. E. Bruce, R. J. Morrell, James Paone

This chapter is a partial summary of an investigation by the U.S. Bureau of Mines (USBM) made in response to a recent request by the Assistant Secretary, Water and Power Development of the U.S. Department of the Interior, for a comprehensive review of horizontal boring technology related to underground power-line installation. This review is concerned primarily with 3 to 36-in. diam horizontal holes from several hundred to several thousand feet in length. An electric power system consists of three essential functions: generation, transmission, and distribution. The generation component includes the generating station and step-up substation; the transmission component includes the transmission line and stepdown substation at typical voltage levels ranging from 69 to 345 kv for underground lines and 69 to 500 kv for overhead transmission lines; the distribution component includes the distribution line carrying the commonly used voltages of 120, 208, and 240 v, the distribution transformer, and the line to the service customer.l The Federal Power Commission reports that 1600 miles of underground transmission lines of 60 to 345-kv capacity are now in service in the United States. By 1980, it is estimated that approximately 3000 miles of trans- mission lines will have to be placed underground.2 The cost of burying electric transmission lines underground in metropolitan areas, approximately 30 miles from the center of each of the most populated cities, will exceed $1.5 billion with the methods now available. The wide spread in unit costs of overhead and underground transmission lines narrows as right-of-way costs for overhead transmission in congested areas increase. Improved methods of underground emplacement will certainly reduce this difference in costs and even further favor underground emplacement. Also, in the future, overhead transmission lines will probably not be permitted in highly built-up areas.

Jan 1, 1970

By Fred J. Hurst

In 1934, Irvin Lavine (A), University of North Dakota, stated that the low-rank coals (lignite and subbituminous) of this country represent a vast tonnage of fuel of commercial value and predicted that some day they will play an important role in our economic welfare. Lavine also pointed out that one of the major problems with efficient utilization of the low-rank coals is their high moisture content. Following the discovery of uranium-bearing lignite in the Williston basin of North and South Dakota in 1948 by D. G. Wyant and E. P. Beroni, detailed investigations were conducted (primarily during 1950 to 1954) by members of the U. S. Geological Survey to evaluate the geologic factors and economic possibilities of the radioactive lignites as a source of uranium. The information gained in these studies and summarized in several papers indicated that a large potential reserve of uranium is contained in the subbituminous coal and lignite deposits of the Dakotas and Wyoming (2,3,4). Most investigators concluded that an epigenetic emplacement of uranium in the coal by means of circulating groundwater and the more extensive concentrations of uranium in coal are apparently related to the permeability of the rocks enclosing the coal beds. Breger (5) and others have shown that uranium is readily adsorbed by coal and is held irreversibly as a disseminated adsorbed constituent. Briefly, lignite beds containing 0.1 to 10% uranium have been discovered in the Dakotas and Wyoming. The distribution of uranium was found to be erratic and was usually concentrated in thin layers, which were characteristically 10 to 14 in. thick and occasionally 30 to 36 in. thick. Lignite beds more than 3 ft. thick generally contain more uranium at the top of the bed than at the bottom. Special strip mining techniques are required to mine these thin

Jan 1, 1983

By Charles W. Bauer

Most of the aluminum produced in the United States today is derived from foreign bauxite deposits. Earth Sciences, Inc. initiated a program to evaluate domestic non bauxite sources for alumina in the 1960's. In the initial evaluation of alunite, domestic resources were not sufficient to support development. An exploration program led to the discovery of large deposits of alunite in Utah and several other western states. Identification of alunite is difficult as both its physical and chemical characteristics are similar to the minerals with which it is associated. Most of the significant alunite deposits in the western United States are replacement type deposits. These deposits have formed as a result of hydrothermal alteration of volcanic, sub-volcanic, and igneous rocks. Typical alunite deposits contain between 30 and 50% alunite and 50 and 70% quartz, with minor amounts of other minerals. Four mineralogical zones are common in these systems. They include a siliceous zone, a quartz-alunite zone, a kaolinite zone, and a chlorite-montmorillonite zone. Total US reserves of alunite were estimated at 20 Mt fat 30% alunite) by the US Bureau of Mines in 1941. More recent work by the US Geological Survey estimates reserves of 252 Mt and potential resources at 1.4 Gt. Reserves and resources estimated for 23 properties on which field work has been done by ESI are considerably higher. Most of these properties have reserves and potential resources of several hundred million metric tons. The combined demonstrated reserves of these properties are estimated to be about 650 Mt. Inferred reserves are estimated at 2.5 Gt and potential resources at 8 Gt. It appears that the US has sufficient reserves and resources for alunite to be considered as a potential nonbauxite source of alumina.

Jan 1, 1982

By Milnor Roberts

The Nicola Valley coal-field is small, but it seems likely to become important because of its commanding position in a rich region that is developing rapidly. Bituminous coking-coal in workable quantity has not been found at any other point between the Crow's Nest Pass region, about 400 miles to the east, and Vancouver island, 250 miles westward. The Canadian Pacific railway reached the Nicola valley two years ago ; two other lines, the Canadian Northern and the Great Northern, are building towards the valley. The vast region between the Rocky mountains and the Pacific coast, extending northward for several hundred miles from the international boundary, which has been the scene of extensive mining- and smelting-operations for many years, is filling up with settlers, who are attracted by the wealth of minerals and timber, the rich soil of the valleys, and the fine climate. The Nicola river, flowing westward through the valley of that name in the Yale district, discharges into the Thompson river, which is the eastern branch of the Fraser. The transcontinental line of the Canadian Pacific railway crosses the mouth of the Nicola river at Spence's bridge, 178 miles from Vancouver. From Spence's bridge the Nicola branch line ascends the valley for 40 miles to Merritt, the coal-center, and continues 7 miles farther to the town of Nicola. Thus the haul from the mines at an elevatioiz of 2,000 ft. to salt water is 218 miles down river-grades. The Nicola branch will be continued about 150 miles farther eastward to Penticton, where it will connect with an extension of the line through the rich Kootenay and Boundary districts. The Canadian government has granted a subsidy of $6,000 per mile, to which the provincial government is planning to add $5,000 per mile, to assist in the construction of the Nicola extension. Upon the

Jan 1, 1910

By C. M. Weld

The southeastern coast of China, from Ning-Po to .Macao, represents an element in the continental mass of Asia which has at practically all times in the remote past exhibited a tendency to rise rather than to subside.' This strip of land, 1,000 or more miles long by perhaps 150 miles wide at its widest part, has in fact stood above sea level since at least early Cambrian times, while the great basins to the north and west were receiving their massive accumulations of Sinian (Cambro-Ordovician), Carboniferous, and later deposits. We find, .therefore, a coastal fringe of metamorphic and igneous rocks bordering the huge expanses of sedimentary rocks which occupy the interior. Hong-Kong is situated toward the southwestern extremity of this fringe. Hong-Kong is an island of approximately 30 sq. miles, on the north shore of which is situated the city of Victoria, with its 325,000 inhabitants. This island was ceded to Great Britain in 1842. In 1560 the peninsula of Kowloon (about 5 sq. miles), being that part of the mainland lying directly across from the city of Victoria, was added to Hong Kong. Thirty-eight years later, in 1898, a stretch of territory, including the mainland behind Kowloon and. numerous adjacent islands, was leased to Great Britain for 99 years. This last addition is known as the "New Territory of Hong-Kong" and comprises 376 sq. miles in area. A map of Hong-Kong, Kowloon, and the "New Territory" is shown in Fig. 1. My studies of this total area of over 400 sq. miles were devoted primarily to an investigation of the mineral resources. Systematic mapping of the immensely complex exposures of rocks was not possible in the time at my disposal. However, observations in, this. direction warrant a few generalizations.

Jan 2, 1914

ONE of the interesting-though not unnatural-features of the whole Porphyry Copper development is the way in which the history of each property dovetails with that of one or more of the others. The same names keep cropping up as one digs into the accounts of events from 1900 to 1915. J. Parke Channing made examinations of Nevada, Ray, and Inspiration, as well as of Miami. Henry Krumb did important work in the early stages of the exploitation of Utah, Nevada, Ray, Braden, and Inspiration. Pope Yeatman was favorably impressed with the Braden property before he had ever visited it, when he saw a batch of Braden ore sent to the United States for testing. It reminded him immediately of Nevada Consolidated ore: indeed, he was unwilling at first to believe that it came from South America. And it was while working on the examination at Utah Copper that Philip Wiseman became enthused with the possibilities of the Ray mines. In 1905, Mr. Krumb, under the general direction of A. Chester Beatty, was strenuously engaged at Bingham, Utah, in arriving at an answer to this question: Should or should not the Guggenheim interests back Jackling to the tune of several million dollars to build the big concentrators at Gafield? Seeley W. Mudd was the Guggenheim engineer on the Pacific coast and in that capacity was indirectly responsible for the work at Bingham. At his suggestion Wiseman came up from Los Angeles as one of Krumb's assistants-at $5 per day, incidentally. A little later Mr. Mudd, in Utah on one of his visits, went down to Bingham. That evening in the old Hills Hotel in Markham Gulch he was going over reports with Mr. Krumb. Wiseman and some of the other engineers on Krumb's staff were present. During a breathing spell, Mudd expressed

Jan 1, 1933

By A. M. Gaudin

UNTIL recently little attention has been paid to the effect of particle size on flotation. This has been especially true of material finer than 200 mesh.1 Particles of different sizes must behave differently in a flotation circuit; increased information along this line would be of practical use as well as of theoretical interest. The object of this study has been to determine what effect particle size has on floatability. The problem has been approached in two ways. One method consisted in a study of samples of the final products of several mills. These samples were sized and each size-product was analyzed for its important constituents. Bakelite briquettes2 of some of the products were made and studied under the microscope. This investigation is being continued, with particular reference to quantitative microscopic analysis of intermediate products of flotation plants. M In the other method of study, mixtures of pure minerals were ground to different degrees of fineness and floated. The products were then sized and analyzed. A study of the behavior of mixtures of pure sized minerals would have been illuminating, but after trial it was considered impractical on account of the tediousness of the large amount of elutriation required and the fact that the mineral particles would oxidize while being sized, preparatory to flotation. Broadly speaking, the following conclusions have been reached: 1. Results obtained by the two methods of study are in agreement. 2. The usual notion about the relative ease of flotation of very fine particles does not agree with the facts: 3. There is a time sequence of flotation with regard to particle size, the medium coarse particles floating first. 4. No successful method of floating extremely fine pulps has been found. 5. Recovery is optimum in a certain well-defined size range. 6. Selection is optimum in another well-defined size range.

Jan 1, 1931

By E. Posnjak

IT is rather the general belief that acidified, solutions of ferrous salts are readily oxidized when in contact with air, and often elaborate pre-cautions are taken to prevent it. This, however, is not the case and several statements may be found in the literature expressing surprise at the extreme slowness with which oxidation takes place when air or oxygen is bubbled through such a solution. Thus C. Baskerville and R. Stevenson1 "observed with surprise" that no oxidation apparently took place, as shown by titration with 0.5 N KMnO4, when a stream of air was passed for 3 hr. through an acidified solution of ferrous ammonium sulfate or ferrous sulfate. The same authors state that even the presence of salts such as. cobalt, chromium, copper, manganese, etc., which usually act as oxygen carriers, had "no effect upon the oxidation as was observed by passing air for 3 hr.. through solutions of Mohr's salt acidified with sulfuric acid." While this statement will bee proved further on to be at least partly incorrect the slowness of the oxidation of ferrous salts alone has been previously established by McBain.2 His investigation also showed that the rate of oxidation increases markedly with an increase in the concentration of ferrous sulfate as well as that of oxygen; the concentration of free acid had a comparatively small influence, which in the case of sulfuric acid was to retard slightly the rate of reaction. More recently R. Thomas and E. T. Williams3 investigated the catalytic effect of nitric oxide on the oxidation of ferrous salts, which had been earlier patented by McCulloch.4 They found that the probable mechanism of the catalytic action was the oscillation of the catalyst between two stages of oxidation and its interaction alternately with the oxygen and the ferrous iron.

Jan 12, 1926

By Perry G. Harrison

The first autlientic description of an iron bath for the deposition of iron is probably that of Bottger in 1846, who used a bath containing ferrous sulfate and ammonium chloride. In 1861, Kramer deposited iron from ferrous chloride solution. Electrolytic iron was produced in 1869 by Bietz, who used it for making some magnetic tests. In the same year, Klein is. said to have worked out his process. Jacobil in 1869 described the results obtained in electroplating with iron on copper for making dies and plates for bank notes, by Klein's process. A letter from Klein to Jacobi describes the bath more fully. It consisted of FeS04 + (NH4)2SO4. Lenz2 described some properties of electrolytically precipitated iron. He used Klein's bath, FeS0, + MgSO4 + MgCO3, to neutralize and obtained fine-grained and hard iron. His conclusions were as follows: 1. Electrolytic iron and copper contain gases, notably hydrogen. 2. The volume of gas absorbed by iron varies within wide limits, but it is easy for iron to take up very considerable quantities of gas. 3. The absorption of gas is principally in the first formed layers of iron. 4. When iron is heated, gas begins to come off below 100°, principally hydrogen. 5. Heated to redness, reduced iron oxidizes in water, in part at least at the expense of the oxygen of the water, decomposing it and setting free hydrogen, which is partly or wholly absorbed. Siemens,3 in 1889, was the first to propose a general process embodying a step for leaching a sulfide mineral with ferric chloride or sulfate and a step for regenerating the leach and depositing iron on a cathode in a diaphragm cell. So far as is known, Siemens did not carry out his patent

Jan 1, 1930

By A. J. Fenn

Cananea is located at an elevation of 5,200 ft in the north-central part of the state of Sonora, Mexico, about 135 miles northeast of Hermosillo, the state capital, and about 30 miles south of the United States border. A graded road runs to Cananea from the border town of Naco, near Bisbee, and a branch road turns east to Cananea at Imuris, a town 36 miles south of the border on the Nogales-Hermosillo highway. Railway service is provided by a spur from the Nogales-Naco branch of the Ferrocarril del Pacífico Railroad. Fuel for the power plant, smelter, and town (population approximately 20,000) is natural gas, supplied through a pipeline from the United States. The Compa[n]ía Minera de Cananea generates electric power for its own installations and also supplies both electricity and water to the town. HISTORY The earliest record of mining in Cananea dates back to 1760, when Jesuit fathers worked the Cobre Grande mine for silver in spite of resistance from hostile Indians. About 1800, several mines were worked on a relatively large scale by the House of Guea of Chihuahua. From then until about 1890 when William C. Greene of Fairbanks, Ariz., acquired control of a large group of properties, mining continued in a rather sporadic manner. The mineralized district is approximately 6 miles wide and 15 miles long, and the orebodies are associated with breccia pipes and granitic intrusive rock. In the early days, many small mines operated within the area on high-grade orebodies. In 1899, Greene promoted the building of a mill and smelter and established the present company, The Cananea Consolidated Copper Co., S.A., now Cia. Minera de Cananea (S.A. de

Jan 1, 1969

By George J. Young

The recurrence of mine-fires in Nevada during the past decade is not only a matter of interest, but also one of considerable concern to engineers and mine-managers. The more important fires may be enumerated as follows: Forman Shaft fire, Gold Hill, April 21, 1903; shaft-house, machinery, and shaft destroyed; loss estimated at $50,000; cause unknown. Union Shaft fire, Virginia City, July 14, 1904; shaft-house, machinery,and shaft in part destroyed; loss estimated at $100,-000; cause of fire stated as the careless throwing of a match in the rope-house. Sutro Tunnel fire, Virginia City, Jan. 27, 1909; 700 ft. of tunnel-timbering destroyed, and direct damage of $10,000; cause " probably electric wires." Belcher Shaft fire, Gold Hill, Aug. 9, 1910; shaft-house destroyed, machinery ruined, and upper part of shaft damaged; damage, $25,000; no cause given. Belmont Mine fire, Tonopah, Feb. 23, 1911; fire started ill winze; 17 men killed. Giroux Mine fire, Kimberly, Aug. 23, 1911; fire originated in shaft-station from unknown cause; 7 men killed, and $34,-521 damage caused. (Note 1.—On June 11, 1912, some time after the present paper was written, a fire broke out in the pump-room on the 2475 station of the Ward shaft, Virginia City. This fire was caused by the short-circuiting and exploding of the starting-switch on No. 5 pump. The oil in the switch was scattered about and set fire to the timbers and lagging of the pump-room. The pump-man in charge notified the surface, and the electric current was shut off. A hose was then turned on the fire, but the dense smoke drove the attendant out. Inspection by the electrician and the shaft-foreman, equipped with oxygen-

Jan 1, 1913

By G. R. Speich, R. A. Oriani

The rate of coarsening (Ostwald ripening) of copper precipitate Particles in an a-iron matrix has been studied in three Fe-Cu alloys containing 2.3, 4.0, and 5.4 wt pct Cu in the temperature range 730° to 830°C. The kinetics of Ostwald ripening ohevs the law as deduced by Lifshitz and Wagner so that matrix diffusion controls the process. The equilibrium shape of the particles is that of rods with hemispherical caps, and is due to the BOTH Lifshitz and slyozov and wagner3 have recently solved the complex problem of determining the rate of coarsening of an assembly of precipitate particles. Both workers, although using somewhat different mathematical approaches, arrive at the same equation for the relation between the mean radius 7 of a distribution of spherical particles and the bulk solubility co, diffusivity D in the matrix, large anisotropy in the copper/a iron interfacial free energy (y,/y, = 4). A Lifshitz -Wagner equation, modified for both the nonsphericity of the diffusion field and the reformulation of the Gibbs-Thomson equation for the case of nonsphencal particles, is derived. Using the modified equation, the calculated values of the mean radius are smaller than those observed by a factor of about one -half. absolute temperature T, gas constant R, surface free energy y of the precipitate/matrix interface, and the time t of aging: where V, is the molar volume of the precipitate and v is a stoichiometric factor. Wagner's treatment is restricted to the case of spherical particles growing in a liquid matrix where strain energy is not a factor. Lifshitz and slyozov have discussed the effect of anisotropic particle shapes and internal strains on the rate of coarsening. Oriani4

Jan 1, 1965