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By Alana Pereira Ramos

O efeito de memória de forma tem como principal objetivo a recuperação da forma por meio de aquecimento acima das temperaturas críticas de transformação. Fitas da liga Ti43,5Cu37,8Ni18,7 foram preparadas através do processo melt spinnig com velocidade da roda de 21 m/s e 63 m/s. As fitas foram tratadas termicamente numa temperatura de 700°C por 15 minutos em forno e resfriadas ao ar. A caracterização das fitas foi feita por calorimetria diferencial de varredura (DSC) e análise por difração de raios X (DRX). Foi observado que com uma menor velocidade de rotação da roda (21 m/s) a fita apresentou-se totalmente cristalina, e quando aumentou-se a velocidade linear da roda para 63 m/s a fita apresentou-se completamente amorfa. Após o tratamento térmico todas as fitas apresentaram as transformações martensíticas e auteníticas. Observou-se que a velocidade da roda tem grande influência nas temperaturas de transformação, chegando à variação de aproximadamente 7°C. O tratamento térmico remove todos os defeitos produzidos pelo processo de solidificação rápida e produz um rápido crescimento de grão, favorecendo ao aumento das temperaturas de transformação.

Aug 8, 2018

By Fábio Rogério do Carmo

O ar soprado é uma das principais utilidades responsáveis pelo processo de transformação do minério de ferro em gusa no Auto Forno. Para que ocorra o processo de redução o ar soprado é superaquecido nos regeneradores dos autos fornos a uma temperatura de 1.300°C. Este energético é fornecido na CSN-UPV pelos turbos sopradores da Central Termoelétrica nº 2 (CTE#2), área dos Motos Sopradores 1 e 2 e os turbos sopradores n°1 e 3 da CTE#1 que operam com a velocidade reduzida 24 horas soprando para atmosfera e consumindo vapor de 30Bar. Devido à obsolescência do sistema de ar soprado da CTE#1, alto custo de operação e risco para a segurança operacional, este trabalho apresenta o estudo do problema em questão, a metodologia utilizada para desativação do ar soprado da CTE-1 e a redução de custo.

Sep 25, 2017

By Steven Gillgrass

Gerdau Monroe has installed and commissioned the Tallman Supersonic Carbon Injection system (TSCi™) for use in their 135-ton Electric Arc Furnace (EAF) located in Monroe, MI. TSCi™ is an innovative injection system with the primary aim of improving injection carbon delivery to the steel bath by increasing efficiency. It is proven technology with installations at numerous steelmaking facilities all over the world. Results from installation and commissioning of TSCi™ at Gerdau Monroe will be reported as well as on-going trials and optimization efforts. Standard injection systems deliver carbonaceous material from a vessel to the EAF using air where it is injected through a lance pipe or oxy-fuel burner. Using this method, material delivery to the EAF is limited by the pressure and velocity of the transport air. Loss of efficiency can be observed by looking at the quality of the injection carbon stream during operation or by measuring loss on ignition of EAF slag or off-gas system dust. TSCi™ uses a patented design and proprietary technology to improve delivery of carbonaceous material to the EAF. Using this method, savings at Gerdau Monroe were realized by reducing the amount of carbon used in each heat while maintaining or improving upon existing foamy slag practice. As well, significant savings were achieved as a result of reduced FeO content in the slag and improved recovery of iron. Additional savings can be realized by using a smaller mesh material to take advantage of lower material cost and higher injected surface area. Other inherent benefits to improved injection carbon include lower energy and electrode consumption, reduced refractory wear and reduced maintenance cost.

Oct 30, 2017

By Ananda Moreira Vaz Ourique de Avila

High and intermediate temperature fuel cells (FC) are power generators characterized by high efficiency and their use in cogeneration systems. The single fuel cells are connected in series by the use of interconnects to form a fuel cell stack. Ferritic stainless steels have been used in the making of high and intermediate temperature operation solid oxide fuel cells interconnects. However, at high temperatures, on the order of 700-8500C, these steels can present significant oxidation and degradation processes, promoting increased electrical resistivity and corrosion losses that result in contamination of the electrodes and reducing the performance and the useful life of the FC. Intensive R&D activities have been made to minimize these problems and the use of composite coatings on metallic substrate has been considered. This paper evaluates the use of coatings of copper and nickel, with particles of La2O3, Y2O3, CeO2, LaCrO3 and doped chromites applied on ferritic stainless steels AISI 430, AISI 441 and Crofer22APU produced by electrodeposition. The produced samples were evaluated by microscopy techniques, gravimetric analysis and by electrothermal characterization. The most significant results were obtained with chromites coatings (LaCrO3 pure, mono- and multiple-doped) showing the combination of the best features of metal coatings, substrates and ceramic particles with semiconductor properties.

Aug 7, 2018

By Karl Berger

The paper gives a comprehensive overview of the historical development of various metal rolling technologies and also describes the influence to industrial and socio-economic developments. The rolling of steel, in particular of rails, beams, rebar, strip and plate has enabled the large scale transport and travel, the building of bridges and buildings, the manufacturing of ships and cars. All this has changed the face of the world significantly. Further the paper approaches technological highlights in the design, manufacturing, drive and control of modern mills and the various types developed to create industrial economic units for the different markets and customers’ requirements. An outlook of future challenges is as well discussed in the paper. Various solution approaches for the rolling technologies, from continuous improvement of existing plants to more radical new concepts like endless rolling, near net-shape casting and rolling are approached. A positive conclusion is drawn that rolling technologies will remain a valuable area for engineers with scientific and economic challenges, but also a clear vision for positive contribution to further industrial and social development.

Jul 30, 2018

By Shibu John

The COREX® process is beside the FINEX® technology the only industrially realized alternative to the blast furnace route for the production of hot metal. Changes in the raw material sector in respect of decrease in quality, strictly enforced environmental laws and positive operation results of COREX® reference plants make it worth to carefully re-evaluate the COREX® technology in comparison with the traditional blast furnace technology. Integrated Plant concepts based on COREX® offer solutions for future challenges of the iron- and steelmaking industry, which include: economical hot metal production; efficient and highly economic export gas utilization (power generation, DRI production, syngas production for chemical products); lower raw material cost, higher raw material availability; environmental friendly high grade steel production. The economic evaluation of different COREX® gas based plant concepts in comparison with the traditional blast furnace route shows that the COREX® technology is highly competitive in the challenging iron and steel producing environment.

Aug 17, 2017

By Robin Schott

The blast furnace process is the most important process to produce pig iron. The necessary process energy is mainly covered by coke. But the production of coke is connected with CO2-emissions and high costs. A significant measure to reduce the coke rate and with it the CO2-emissions plus costs is pulverized coal injection (PCI) through the tuyeres into the blast furnace. A further increase to substitute coke by coal can be achieved by using the Oxycoal+ technology. This article compares and shows the cost effectiveness and the decrease of CO2-emissions with the help of simplified energy balances for the only coke operation of the blast furnace, the operation using pulverized coal injection and the operation using the Oxycoal+ technology.

Aug 17, 2017

By Fábio Dian Murari, Antônio Adel dos Santos

The effect of reheating temperature of slabs on the precipitates dissolution and mechanical properties of Ti-Nb microalloyed steel was investigated in pilot scale. It was verified, by means of transmission electron microscopy, a significant decrease in precipitates formed during the solidification of the steel as the reheating temperature increased from 1100°C to 1200°C. No significant changes in size and shape of the precipitates were observed with further temperature increase up to 1280°C. In line with the precipitates dissolution behavior, an increase in strength was observed with the elevation of the reheating temperature up to 1200°C, due in part to the reprecipitation of fine Nb-rich precipitates during the hot rolling. At 1200°C the presence of deformed ferrite on the microstructure contributed to the additional increase in strength. After reheating above 1200°C up to 1280°C, a decrease in strength of the rolled plates was noticed. This effect has been credited to the absence of deformed ferrite grains and also to a small increase in the low angle grain boundaries size. The results were in agreement with Thermo-Calc and Dictra simulations.

Oct 1, 2019

By Manuela Arend Prediger

Este trabalho tem como objetivo investigar, através da Espectroscopia UV-Vis, os diferentes estados de oxidação da Polianilina (PAni) obtida pela síntese química, através da reação da anilina em meio ácido e persulfato de amônio como agente oxidante, sob agitação constante e baixa temperatura. A caracterização da condutividade elétrica foi determinada através da técnica de medidas de 4 pontas. Foi possível verificar a obtenção de um polímero com características condutoras, através da observação, nos Espectros UV-Vis, dos picos que caracterizam o sal esmeraldina, sendo este o estado de oxidação da PAni que apresenta propriedades condutoras. Além disso, conseguiu-se obter valores de condutividade elétrica relevantes para confirmar a obtenção da PAni condutora.

Aug 17, 2017

By Robson Ferreira Vargas

No início de Março/2015 começaram a ser notados eventos de oxidação em bobinas armazenadas no pátio de expedição, e naquela época o fenômeno foi creditado às chuvas. Entretanto, passado o período chuvoso, ainda foram notados eventos de oxidação, que ocorriam também em produtos destinados à exportação. Isto mostrou que havia outra causa atuando no problema, e que era necessário descobri-la e tomar ações para sanar o problema. O produto final é a coroação do esforço produtivo anterior à sua obtenção, e leva consigo o nome do fabricante para onde for enviado. Por isto ele não pode ter falhas. A ArcelorMittal Tubarão montou um grupo de trabalho, que atuou em várias frentes, incluindo o condicionamento químico do sistema de resfriamento direto da laminação. Este grupo de trabalho obteve êxito na tarefa e as conclusões obtidas estão mostradas aqui.

Aug 17, 2017

By Benito Barbabela Silva, Michel Garant, Mathieu Dubé

Pellets market challenging scenario has stimulated pelletizing experts to pursue innovative alternatives to process development in order to increase pellets competitiveness vis-à-vis sinter. When it comes to indurating process, pelletizing productivity is still limited and its OPEX inflated by the lower input of carbon into mixes due to quality impairment caused by magnetite formation in pellets core. This obstacle led to the rethinking of carbon distribution strategy within the green balls. To achieve such purposes, COREM through its precompetitive research program dedicated to its members, has proposed the layered pellets®, a two-stage balling technology. Balling in disc and pot-grate tests in COREM’s pilot plant were carried out to proof the concept, support the arising technology and evaluate its potential. According to first results, while CCS strongly improved, tumble and abrasion indexes as well dynamic LTD must be further investigated. Tests on four classes of equivalent carbon content pellets to evaluate layering strategy gave very good perspectives concerning the increase of productivity, and the reduction of fuel consumption and GHG emissions.

Oct 1, 2019

By João Vitor Mokan

O presente trabalho avalia o efeito das camadas de conversão a base de CrVI e CrIII aplicadas na superfície de arames galvanizados por imersão a quente. As bitolas testadas foram 1,24mm, 1,65mm e 3,00mm, utilizando os ensaios de Névoa Salina e Câmara Úmida, avaliando o aspecto superficial dos arames após 1, 3, 6, 24 e 28 horas de exposição ao ambiente agressivo. Pode ser observado que o ensaio de Névoa Salina é pouco indicado para avaliar a oxidação superficial do arame em função de sua agressividade. Os resultados foram melhor interpretados utilizando o ensaio de Câmara Úmida. Inicialmente os arames recobertos por uma camada de conversão a base de CrIII apresentaram desempenho levemente superior àqueles recobertos por CrVI, considerando os mesmos tempos de exposição. Após seis horas os arames galvanizados apresentaram comportamentos semelhantes. O arame galvanizado com maior resistência a oxidação foi aquele protegido com CrIII, porém com o passar do tempo os dois tipos de revestimento se equivalem.

Oct 30, 2017

By Ernesto Furtado de Mello Neto, Eliezer Thuler, Claudio Vano Nunes, Carlos Alberto Cristofari

The Brazilian steel industry is dealing an adverse scenario with direct competition from global emerging markets. In this scenario, the need to improve asset operational performance, makes complex studies involving technical knowledge and asset life behavior, become important tools to support companies strategic accomplish. These studies allow consider performance, costs and operational risks relationship in the decision make process. The Asset Management approach support these studies in order to observe the whole asset life cycle, understand value chain through all company process and optimize the asset economic life. In this context, the present technical work has the purpose to support asset management decision making regarding ArcelorMittal Vega cold rolling drive motors, through the motors fail behavior modelling and estimated the risks involved in asset management decision. Through the Reliability, Availability and Mantenability (RAM) analysis, simulations were performed considering the failure, repair cost data and investments to build options to mitigate the operational risks.

Oct 9, 2019

By Shibu John

Rising energy demand and steadily decreasing quality of raw materials due to the global resource depletion are great challenges to the steel production today. The FINEX® Process has been developed jointly by POSCO, Korea and PRIMETALS Technologies Austria, to provide the iron making sector with the capability to lower hot metal production costs, environmental pollutions and to increase the flexibility in terms of operation and the choice of raw materials. FINEX® is a new technology combining a gas-based reduction in a series of fluidized bed reactors and a reduction smelting in a melter gasifier. Commenced in April 2007, the first 1.5Mtpa commercial plant has demonstrated the competiveness as an alternative iron making route. Another 2.0 Mtpa, third generation FINEX® (3G) plant was recently installed at POSCO, Pohang Works and has been operating satisfactorily since its blow-in in January 2014. Based on the well-proven plant concept, new process features, the highly competitive production costs and environmental advantages, the FINEX® Process can be considered as a competitive alternative to the conventional blast furnace iron making route.

Aug 17, 2017

By Larissa Carolina Ferreira

O impacto das atividades do setor de mineração sobre o meio ambiente tem levado a estudos visando, tanto à utilização racional dos recursos naturais, quanto o tratamento de efluentes gerados durante os processos. A caracterização de efluentes é uma etapa importante, podendo apontar erros nos processos de beneficiamento, parâmetros em desacordo com a legislação ambiental e guiar etapas de desenvolvimento de técnicas do tratamento. Este trabalho consiste na caracterização de um efluente da etapa filtragem de uma mineradora de minério de ferro do quadrilátero ferrífero comparando os valores encontrados com as exigências da norma CONAMA 357/2005 e 430/2011, de forma a enquadrá-los na categoria de águas doces classe 1 e de lançamento de efluentes. O pH encontrado (9,8), turbidez (2133 NTU) e sólidos sedimentáveis (28mL/L), estão fora dos padrões permitidos e mostram grandes problemas em relação aos sólidos presentes na amostra. O diâmetro médio das partículas (8,54µm), indicou a predominância de partículas ultrafinas de difícil sedimentação. Os elementos majoritários Al, Fe, P e S, 0,296; 1,6; 0,218 e 26,5 mg/L, respectivamente, também apresentaram valores acima do permitido para água doce classe I. As análises indicaram que o efluente necessita de tratamento prévio para posterior descarte.

Aug 16, 2017

By Cristiano José Scheuer

Experiments were carried out aiming to study the influence of micro-abrasive wear test variables and plasma treatment parameters, on the tribological characteristics of low-temperature plasma carburized AISI 420 steel. The first part of this study was conducted in order to evaluate the influence of abrasive particle size, normal load and counter body rotation speed on carburized sample wear behavior; and the second part was conducted in order to evaluate the treatment temperature and time effect on carburized samples wear behavior. Plasma carburizing treatments were performed at 8 and 12 h, for temperatures ranging from 350 to 500°C; and at constant temperatures of 400°C for times between 12 to 48h, and for 450°C for times of 4 to 16h. Micro-abrasive wear test were performed by mean of a calowear ball-cratering equipment using a polished ball of AISI 52100 steel rotating at 80, 120 and 160 rpm, for sliding distances from 2.6 to 104.2 m. Alumina abrasive particles with sizes of 0.05, 0.3 and 1.0 ?m were employed. The normal loads applied on this study were 0.1, 0.3 and 0.5 N. Carburized sample was characterized by mean of OM, XRD and hardness measurements. Worn crater characteristics were evaluated by confocal laser microscopy. Results showed that the transient wear regime prevails along the outer layer length (composed by Fe3C and ?’C), and the steady-state wear stabilizes in the diffusion layer region (composed by ?’C). It was verified that the wear rate and wear coefficient decreases with treatment temperature in the range of 350–450°C and increase for 500°C. It was also verified that the wear rate and wear coefficient decreases with treatment time in the range of 12–36 h (for 400°C cycle) and 4–12 h (for 450°C cycle), and increase for larger treatment times due the chromium carbide precipitation. It was also found that the wear coefficient increases with the increase of abrasive particle size, and decrease with the increase in counter body rotation speed and normal load. Lastly, the analysis of the worn craters indicates the occurrence of grooving and micro-rolling abrasion wear mechanisms.

Aug 17, 2017

By Sidiney Nascimento Silva

O presente trabalho teve como principal objetivo avaliar, em escalas laboratorial e industrial, a viabilidade técnica e financeira da aplicação da escória de Aciaria LD (EAC), em combinação com a escória granulada de Alto-Forno (EAF), à produção de Cimento Portland CP III. O projeto de pesquisa em questão foi desenvolvido pela CSN, através de Convênio de Cooperação Técnica e Econômica com a Escola de Engenharia de Lorena, EEL, da Universidade de São Paulo, USP, e compreendeu as seguintes etapas: i) caracterização físico-química e mineralógica da escória de Aciaria LD da CSN; ii) desenvolvimento do processo adicional de beneficiamento da EAC para aplicação na produção de cimento; iii) testes laboratoriais visando a avaliar a viabilidade técnica; iv) testes industriais com a finalidade de validar os testes laboratoriais e selecionar a formulação de melhor desempenho; v) estudo de viabilidade financeira; e vi) implantação do projeto. A aplicação da escória de Aciaria LD da CSN na produção de Cimento Portland CP III, em combinação com a escória de Alto-Forno e clínquer, é viável técnica e financeiramente. Isso traz reflexos positivos para o aumento da competitividade do negócio Cimento, aumenta a recuperação de metálicos para reciclagem nos processos siderúrgicos da UPV (negócio Siderurgia) e reduz passivos ambientais.

Aug 16, 2017

By Fábio de Oliveira Braga

Atualmente, tecidos de fibras sintéticas como a aramida (Kevlar®) e o polietileno (Dyneema®) têm sido os preferidos para proteção balística contra munições leves, e para integrar sistemas de proteção contra calibres superiores, como o 7,62 mm. Porém, por apelos econômicos, ambientais e da disponibilidade limitada destes produtos, materiais alternativos têm sido testados. Neste cenário, destacam-se os compósitos reforçados com fibras naturais, que têm demonstrado bom desempenho balístico. Assim, o objetivo deste trabalho é avaliar o desempenho individual de compósitos reforçados com fibras naturais de curauá, quando submetidos ao impacto balístico com munição 7,62 mm. Foram executados ensaios balísticos, medindo-se a energia do projétil absorvida pelos materais, e os resultados tratados estatisticamente por Anova e teste de Tukey. Mostrou-se que estes compósitos têm potencial para substituir as fibras sintéticas em sistemas de blindagem para proteção pessoal, com a vantagem de serem materiais leves, de baixo custo, nacionais, de ampla disponibilidade e ambientalmente corretos.

Aug 17, 2017

By Heloíza Döering Gasparin

Os efeitos de elevadas temperaturas e do tempo de exposição sobre as propriedades mecânicas de um ferro fundido cinzento hipoeutético foram avaliados em amostras de dois ferros fundidos da classe FC300, de mesma base, com diferentes percentuais de molibdênio. Ensaios de tração até ruptura a quente foram realizados em corpos de prova com diâmetro de 10 mm, usinados de um pino bruto de 30 mm de diâmetro. Os ensaios foram realizados a frio (temperatura ambiente) e a quente (200°C, 300°C, 350°C, 400°C, 450°C, 500°C e 550°C). Os tempos de exposição a elevadas temperaturas, após homogeneização térmica do material, foram de 0, 60, 90 e 120 minutos. As amostras com maior percentual de molibdênio (0,27% em peso) apresentaram melhores propriedades mecânicas para todas as condições ensaiadas. De acordo com a literatura a redução na resistência mecânica com a elevação da temperatura é atribuída à ocorrência de decomposição da perlita, como resultado da difusão do carbono vindo da cementita às lamelas de grafita, que é o responsável pelo aumento da quantidade de grafita no material. As análises metalográficas evidenciam a ocorrência deste fenômeno. Aumentos no tempo de exposição a temperaturas elevadas também contribuíram para a degeneração da perlita.

Aug 7, 2018

By Cristiano José Scheuer

The effect of low-temperature plasma carburizing treatment on the micro-abrasive wear resistance of AISI 420 steel was investigated by mean of a CSM Calowear ball-cratering equipment. Carburized samples were treated at temperatures of 350, 400, 450 and 500°C for a fixed time of 12 h, using a gas mixture containing 99.5% (80% H2+20% Ar)+0.5% CH4. Micro-scale abrasive wear tests were conducted with a 25.4 mm AISI 420 steel sphere, using an abrasive suspension of alumina (Al2O3) with particle size of 1 ?m (abrasive concentration of 0.11 g/cm³). The contact normal force, abrasive flow and ball rotation speed were fixed at: 0.5 N, 0,2 drop/s, and 120 rpm. The wear craters were analyzed using a confocal laser microscope, Olympus OLS 3000. The wear analyses were performed for test times of: 30, 60, 90, 120, 180, 360, 540, 720 and 900 s (equivalent sliding distance: 0.84, 1.68, 2.52, 3.36, 5.04, 10.09, 15.14, 20.19 and 25.23 m, respectively). The results indicate that the wear coefficient in the outer layer and in the diffusion layer are different, being lower in the latter. It was also verified that the wear coefficient on the outer layer region decreases with increasing treatment temperature in the range of 350 to 450 °C, and increase again for 500ºC. The diffusion layer wear coefficient is similar for all the carburized samples. Finally, for all studied conditions, the analysis of the wear craters surface indicates the occurrence of grooving and micro-rolling abrasion wear modes.

Aug 8, 2018