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By Monica M. Jimenez Correa, Jorge A. Soares Tenorio, Denise Crocce Romano Espinosa, Paula Aliprandini

The surface zone of nickel laterite ore is generally considered as residue. However, because of the depletion of ore sources and the increase in demand, this previously discarded zone may now be processed economically for nickel and cobalt. After leaching and removal of the impurities, the solution contains cobalt, magnesium, manganese and nickel. Solvent extraction is a hydrometallurgical technique used in the separation of metals from aqueous solutions. Cyanex 272 and D2EHPA are extractants used to separate nickel from cobalt. The mixture of extractants can change the performance during the metals extraction. This work aims to evaluate the solvent extraction of nickel and cobalt when Cyanex 272 and D2EHPA are mixed. The results showed that the increased concentration of D2EHPA in the organic phase increased the extraction of nickel and magnesium. However, cobalt extraction was reduced and the manganese extraction was not altered.

Mar 1, 2018

By Yao Dun-Pu

Solution mining, sometimes also refered to as chemical mining or bacterial mining, is an innovative technology which, by making use of proper chemical reagents and taking advantage of bio-chemical action of some micro-organism species, can dissolve effectively most. desirable metallic values from ores and then extract them profitably from the resultant metal-bearing solution by suitable means to form the metal product it is more preferable to the conventional mining methods, not only because of its capability to improve working conditions and minimize environmental problems either underground or on surface, but also for its amenability in particular, to exploit low-grade or submarginal ore bodies, or those deposits which are too deep-seated to be mined out economically. Furthermore, it also provides a potential approach to win metals directly from their ores or ore-deposits in-situ by more simplified methods and at a lower cast than the conventional mining-milling-smelting process would do previously. Hence, in developing countries such as China, it will most, probably become a new mining tool of great promise. (1)

Jan 1, 1981

By William G. Pariseau

A small displacement-small strain finite element technique utilizing the constant strain triangle and incremental constitutive equations for elastic-plastic media that are nonhardening and obey a Coulomb yield condition has been applied to the analysis of gravity flow initiation in a V-shaped hopper containing a powder under lunar environmental conditions. Three methods of loading were examined. Of the three, the method of computing the initial state of stress in a filled hopper prior to drawdown by adding material to the hopper layer-by-layer is superior (as expected). Results of the analysis of a typical hopper problem show that the initial state of stress, the elastic moduli, and the strength parameters have an important influence on material response subsequent to the opening of the hopper outlet.

Jan 1, 1971

By R. F. Linfield

Figure 1-1 shows the basic transmitter design concepts used for the pulse system, the half-wave CW system, and the full-wave CW system. The antenna current waveform is also shown for each transmitter for typical operating frequencies and antennas. The switches shown in Figure 1-i were actually implemented using solid state devices. In all three systems the signaling format may be interrupted to conserve power and thereby extend battery life. Frequency accuracy and stability is achieved using a tuning fork oscillator in the transmitters and tuning fork filters in the receivers for all three systems. This provides the narrow reception bandwidths needed to enhance signal detectability. All three systems also use frequency assignment for identification purposes. The location schemes employed are likewise identical, each being based on detecting the null (signal minimum) of the horizontal magnetic field on the surface. Since these systems are basically similar, the primary purpose is to select the system which gives the maximum signal detectability on the surface from a manpack transmitter operating in the mine. Both the pulse and half-wave C W systems use a d. c. pulse to energize the loop antenna. However, with the pulse system, this pulse duration is short compared to the pulse repetition rate (prf), whereas with the half-wave C W system the pulse duration equals one-half the period of the switching frequency. In the pulse system, energy from the battery is stored in a capacitor so that during the switching interval the internal resistance of the power source can be considered almost negligible. Both transmitters must drive a loop antenna which is a reactive load having inductance, L, and resistance, Ra.

Jan 1, 1973

By Bruno Deves Flores

O presente estudo visou avaliar em escala laboratorial os efeitos da substituição de carvão importado por nacional em misturas típicas para fabricação de coque metalúrgico. Carvão da camada Barro Branco foi amostrado, beneficiado e caracterizado. Misturas entre carvões coqueificáveis importados, coque de petróleo e o carvão brasileiro foram produzidas de modo a permitir a avaliação da influência do carvão nacional na qualidade do coque. O coque gerado no estudo foi produzido em escala de laboratório e posteriormente avaliado a partir de testes de resistência mecânica e reatividade. Os resultados do estudo apontam que a substituição parcial de carvão importado por nacional é viável tecnicamente sem que ocorram prejuízos importantes à qualidade do coque gerado. As diferenças de qualidade dos coques produzidos com ou sem carvão nacional foram menores para misturas com alto teor de inertes, onde as características termoplásticas da mistura passam a controlar a qualidade do coque gerado.

Oct 30, 2017

By H. Scott Swinden

"ForewordA symposium on base metal deposits was held in Bathurst, New Brunswick, from June 10-13, 1990, sponsored jointly by the Geological Surveys Branch of the New Brunswick Department of Natural Resources and Energy, the New Brunswick Prospectors and Developers Association, and the Geology Division of the Canadian Institute of Mining, Metallurgy and Petroleum . Papers prepared for the symposuim are being published as a series of articles in the CIM Bulletin. This second paper (the first was by Fyffe, et al., in Vol. 83, No. 938) in the series presents an overview of the paleotectonic settings of massive sulphide deposits in the Dunnage Zone of Newfoundland with emphasis on volcanic geochemistry.ABSTRACTCambrian and Ordovician volcanic sequences of central Newfoundland, which record the history of the Iapetus Ocean, are prolific hosts to volcanogenic massive sulphide (VMS) deposits. Geochemical, isotopic and geochronological studies show that the vestiges of Iapetus in Newfoundland probably record a complex series of island arcs and back-arc basins that were marginal to, rather than part of, the main ocean basin of Iapetus. The geochemical and isotopic data provide a means of characterizing the tectonic environment of individual volcanic sequences, and allow us to identify a number of distinct tectonic environments in which VMS depositiontook place.Four tectonic environments have been identified as being associated with VMS deposition: (I) back-arc environments hosting VMS deposits include both N-MORB-type ophiolites (e.g. Skidder?) and volcanic sequences with oceanic island (or within plate) tholeiite characteristics (e.g. Great Burnt Lake); (2) primitive arc environments include both supra-subduction zone (SSZ) ophiolites (e.g. Betts Cove, Rambler) and volcanic/epiclastic sequences (e.g. Point Leamington, Duck Pond) and are characterized by abundant arc tholeiites, with lesser refractory lavas and rhyolites; (3) mature arc environments comprise dominantly thick felsic and mafic volcanic piles in the Buchans - Robert's Arm Belt (including the Buchans camp) and are characterized by dominantly calc alkalic basalt and andesite; and (4) continental rift environments occur in the Hermitage Flexure area (e.g. Strickland deposit) and are characterized by dominantly felsic volcanic sequences.Island arc environments are by far the most prolific hosts to VMS deposits. Patterns of VMS distribution in central Newfoundland show that similar tectonic settings may be recorded by very different stratigraphic sequences (e.g. both ophiolites and thick volcanic/ epiclastic sequences may record primitive arc rifting) and emphasize the importance of the rifting in VMS generation, irrespective of the details of the tectonic or stratigraphic setting. The ability to judge the prospectiveness of a volcanic sequence by using whole rock geochemistry to evaluate its tectonic environment may prove useful in area selection at the grassroots exploration level."

Jan 1, 1991

By F. P. Haver

Because State and Federal agencies have limited the amount of sulfur oxides that can be discharged to the atmosphere, most copper smelters plan to convert the S02 in offgases to sulfuric acid. In some cases, however, it might be preferable to use a nonsmelting method to fix the sulfur in the form of a discardable product. Research by the Federal Bureau of Mines has shown that sulfur in copper concentrate can be converted into insoluble anhydrite (CaS04) by roasting the concentrate with lime (CaO). After leaching the calcine to recover metal values, the residue may be discarded without harm to the environment. The process can use a rougher flotation product, thus reducing separation costs and saving valuable minerals (for example, molybdenite) that are now lost in making cleaner concentrate. In tests, rougher concentrate was pelletized with the theoretical amount of lime and roasted for 1 hour in a 6-1/2-inch-ID by 11-foot-long rotary kiln at 700° C. Sulfur retention was about 97 percent. Leaching the calcine with 20 percent RCI extracted approximately 99 percent of the copper, 73 percent of the iron, and 91 percent of the molybdenum. After the molybdenum was removed from the leach solution by adsorption on activated carbon, copper with a purity in excess of 99 percent was obtained by cementation on sponge iron. The strip solution then could be spray-roasted at 500° C to recover the RCI for recycle and obtain F2O3 as a byproduct.

Jan 1, 1975

By D Bertoldi, C Haines

"The Waihi Gold Mine (WGM) operated by OceanaGold New Zealand Limited is a wholly owned subsidiary of the OceanaGold Corporation of Australia. Traditionally WGM has stockpiled and processed separate campaigns of open pit and underground ore. The ore is processed via a conventional semi-autonomous grinding (SAG) / ball circuit (SABC). The low aspect SAG mill operates in a closed circuit with two 20" cyclones, whilst the ball mill is also a closed circuit with a 10" cyclone cluster. A major wall movement in April 2015 ceased open pit operations indefinitely, 18 months ahead of the mining plan. This immediately reduced the forecast mill tonnage leaving two options: begin campaign milling or change the operating strategy and target lower throughput. Additional cost pressures necessitated improved milling cost efficiency. The immediate ore restriction limited processing alternatives to within the existing major infrastructure. Available comminution circuit survey data laid the foundation for developing a comminution model using the JKSimMet™ software package (version 6, created by KJTech). A number of flow sheet variants were then evaluated based on predicted throughput and efficiency. The comminution models suggested opportunities for improved efficiency lay in reducing throughput and increasing utilisation rather than on/off campaign milling under the existing operating philosophy. A series of process alterations followed, delivering new cost efficiencies that maintained the current $/t processing cost. This paper aims to review the change in circuit performance and examine the decisions and challenges faced following the transition from a high tonnage SABC circuit to lower tonnage SABC circuit.Citation:Haines, C and Bertoldi, D, 2016. The Transition from Semi-autogenous to Autogenous Milling at Waihi Gold, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 303–312 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By O. M. Bishop

From October 1943 to March 1944, the Bureau of Mines conducted core drilling at the Victory fluorspar mine, Hardin County, Ill. to test the Fredonia limestone and the included sub-Rosiclare sandstone zone beneath the existing stopes. Twenty-one vertical holes were drilled to an average depth of 60 feet. Ore was penetrated in six holes. Since its discovery in 1927, the Victory mine has produced approximately 5 percent of the total fluorspar mined in the United states after that date. The ore discovered in the early mine development is now exhausted, except that contained in pillars drifting to the northeast has partly developed one substantial ore body, and company drilling has indicated another nearby. The increasing need for fluorite for war use in 1943 suggested the desirability of mining the pillars, provided it could be established that no ore beds existed below the stopes or in areas to which access would be obtained through the present workings. This work describes the work accomplished during the project and presents the data obtained.

Jan 1, 1948

By Henrique Silva Furtado

This paper presents the results obtained on the exchange of an original old blow charge model for a new up-to-date state of art global model, employing optimization techniques and process modelling, and, the results obtained in terms of fluxes consumption reduction and the introduction of user friendly tools and practices.

Aug 17, 2017

By AIME AIME

IN many countries the lack of liquid petroleum supplies has centered interest upon the hydrogenation of coal and coal tars for the preparation of motor fuel. In the United States, hydrogenation has been of greater interest for grading up low-value petroleum fractions to the more valuable volatile fuels and for the preparation of a variety of premium products, including aviation gasolines, solvents, Diesel fuels, and lubricating oils. Chemically, the basic reason for this process is that, as shown in Table 1, the ratio of hydrogen to carbon (H/C ratio) in available raw materials is quite different from that characterizing the products sought.

Jan 1, 1936

By Andre Vien, Frank Laroche, David Di Sandro

Back in 1994, Claude Bazin presented a novel method for linking size data from milling models to the feed input of flotation models. It was achieved with the simple addition of a metal/mineral distribution—size distribution relationship. This allows grade and recovery predictions from a varying mine plan via product size distribution predictions. This paper presents a case study where this elegant method has been used to build a very powerful forecaster at a process plant, built from historic operating data. The methodology has been used by this operation to forecast production on a quarterly, annual, and life-of-mine basis since the late 1990s. It has been upgraded several times to incorporate new drivers as the complexity of feedstocks has increased over the years.

By I. Barin

The thermodynamics of cyclone smelting of sulphidic copper ores is described using as example the production of copper matte with 75 wt % Cu. Equilibrium calcualtions and material and energy balances show that an increase in process temperature from 1600 K to 1900 K results in the extensive transfer of minor elements such as As, Sb, Bi, Pb, Zn,.... to the gas phase. A pilot plant for carrying out the cyclone smelting process is described. Calculations of material and heat transfer for the reaction of ZnS show that the smelting reactions of sulphides in the cyclone take place very rapidly at high temperatures. The dissociation of the sulphides with subsequent oxidation reactions in the gas phase plays an important part in. the process and is mainly controlled by heat transfer.

Jan 1, 1983

By M. M. Wong, J. E. Klosterman

Scrap beryllium chips ( nominally 96 to 97 percent Be ) were electrore fined in a prototype cell with 408 lb of electrolyte composed of 52.4 mole - percent LiCl , 36.3 mole - percent KC1 , and 11.3 mole - percent BeCl2 . The cell temperature was 500 ° C. In a typical 10-3 /4 - hour deposition cycle , 0.415 pound of metal was produced ; the metal contained impurities in parts per million as follows : C , 700 ; 0 , 610 ; Al , 34 ; Ca , 32 ; Cu , 20 ; Fe , 25 ; Mg , 9 ; and Mn , 23 . Operation of the prototype cell for 2 years demonstrated that adapting the electrorefining process to an enlarged scale of operation presented few difficulties in mechanical functions , maintenance of optimum operating conditions , and control of product purity . After the spent anode feed was leached in a 5 - percent nitric acid solution and the fine - sized particles were removed , it was recycled in some tests . The metal produced was somewhat higher in impurities than metal from the fresh scrap chips .

Jan 1, 1964

By P. T. O'Kane

The PLATSOL® process, initially developed for the treatment of the NorthMet Cu/Ni/PGM concentrate, has seen over the recent years its applicability extended to include numerous other Cu/Ni concentrates of the same type, as well as other precious metals-containing feedstocks. However, several concentrates were found refractory to the typical PLATSOL® conditions, more particularly so the platinum. Attempts to extend those conditions, such as higher temperatures (250°C), longer retention time, increased oxidation conditions, higher chloride additions, were not successful. Detailed mineralogical investigation of those PLATSOL® leach residues indicated the main refractory mineral to be cooperite (PtS). Further metallurgical investigations showed that a thermal pre-treatment of the concentrate effectively unlocked the refractory platinum minerals for the subsequent leach. Temperatures between 400 and 750°C were tested, with the optimum being found around 650°C. The kinetics of the pre-treatment process were fast, and one hour at temperature proved sufficient. Under those conditions, PLATSOL® extractions were re-established around 95% for both platinum and palladium. From a mineralogical examination of the calcine, it was shown that the effect of the pre-treatment was to transform the cooperite and other refractory sulphides into metallic platinum and alloys, amenable to the PLATSOL®. The implications of the pre¬treatment step for the processing of PGM concentrates arc briefly discussed.

Jan 1, 2004

By J. B. Yianatos

A practical an interactive model to describe the operation of a flotation bank of mechanical cells was developed based on the hydrodynamic and metallurgical characterization of large industrial flotation cells. Thus, the mineral grade and recovery, as well as the stream properties along the flotation bank can be described in terms of the operating variables. The model was built considering the flotation bank as a distributed system, so the solution for the water and solids mass balances, per size classes, for each single cell, are sequentially solved. Also, each cell was described by two distinct zones, the collection zone characterized by the flotation rate constant and the froth zone characterized by the froth recovery. The mineral feed was described in terms of the mineral species and particle size classes, using a rectangular flotation rate constant distribution. Also, the effect of changing the actual operating variables (air flowrate, pulp level, pulp density, pulp flowrate, etc.) on the mineral collection process, in the collection (pulp) zone, was considered downstream along the bank. The froth recovery of floatable mineral has been estimated by measuring the mass flowrate of particles entering the froth by true flotation together with the concentrate mass flowrate (ton/h). The mass flowrate of collected particles at the pulp/froth interface level was calculated from direct measurement of bubble load (ton/m3) and gas flowrate (m3/h). Flotation recovery is mainly related to the froth depth and air flowrate. All parameters considered in the model have been adjusted from direct measurements in plant site. Also, the effects of other operating variables such as reagents dosage, top of froth grade, or froth discharge velocity are presently under study. This procedure has been tested using data from industrial rougher operations consisting of flotation banks with 5 cells to 9 cells in series, and different cell sizes, such as 45m3, 130m3, 160m3 and 250m3. Thus, it has been shown that the model approach is a powerful tool for flotation cells diagnosis, operation and development of new control strategies, as well as, to evaluate the effect that de-sign and operating variables have upon the collection and froth zones performance in large flotation cells.

Jan 1, 2014

By Z. R. Llanos

This paper presents a review of industrial and experimental processes for the recovery of molybdenum, vanadium, nickel, cobalt and aluminum from spent hydrotreating or hydrodesulfurization catalysts. Numerous processes have been developed in a laboratory and pilot scale. However, worldwide, there are only four well established commercial facilities currently in operation. The installed capacity of these facilities exceeds the availability of spent catalysts and may be sufficient to assimilate future increases of spent catalysts. Despite liability risks; significant quantities of spent catalysts are still being landfilled. Changing regulations that may affect the future handling and disposal of spent catalysts are also reviewed.

Jan 1, 1995

By C. J. Chindgren

Upgrading of commercial red cake and recovery of vanadium oxide from uranium-vanadium mill solutions were investigated by the Bureau of Mines. Alternative procedures potentially useful for manufacture of high-quality vanadium oxide at the mill site were explored and developed. The simplest and best procedure for converting commercial red cake containing about 10 percent combined sodium and potassium oxides (Na20) (K20) into a 98- to 99-percent vanadium pentoxide (V205 product appeared to be a metathesis in an ammoniacal solution of ammonium sulfate. Molybdenum, as well as the alkali metal oxides, was removed from the red cake by this procedure at a modest expenditure of labor and reagents. When preparing vanadium oxide of higher grade, it was necessary to dissolve the red cake and reprecipitate the vanadium as ammonium metavanadate. Calcination at 450° C, decomposed the metavanadate and yielded oxide of about 99.5 percent V205. By recyrstallizing the metavanadate before decomposition, an oxide product approaching 99.9-percent purity was obtained.

Jan 1, 1962

By Bruno de Paulo Silva

O cobre é um dos metais mais utilizados desde os primórdios da indústria, principalmente para a fabricação de fios e cabos para fins elétricos. Dentre as diversas propriedades do cobre, as mais importantes são: capacidade que o material tem de conduzir corrente elétrica e quantidade de energia utilizada para realizar o recozimento garantindo o alongamento especificado. Essas propriedades são diretamente influenciadas pelo teor de oxigênio adicionado como elemento de liga durante a fabricação do vergalhão de cobre eletrolítico. Neste contexto, o artigo tem o objetivo de apresentar como realizar o controle do oxigênio no processo de laminação e quais as influências desse elemento para diminuir os custos com energia elétrica, reduzir as quebras no processo de trefilação e aumentar a condutividade elétrica dos produtos de cobre.

Aug 17, 2017

By Patrick Tassot

Increased worldwide highly competition in steel market imposes innovative measure for the steelmaker targeting cost reduction and climate-friendly steelmaking process in order to have the ability to withstand the pressure of the market. At the same time the demand for high purity and highest quality steels continues to grow from year to year, especially in the sector automotive in transportation of oil and gas, in the construction Industry and in the manufacture of heavy plate. As they allow producers to be up to the requirements while allowing expanding their product mix, new secondary metallurgical treatments have become a must additionally to standard equipment elements of steel plants modern. Most of these treatments occurs in the steel ladle increasing the pressure to ensure a reliable and as possible neutral reactor. Intelligent solutions for refractory lining ladles should integrate better adaptation to the operational process parameters and the high reliability/availability at the best cost/performance. This challenge has conducted Refratechnik to develop new concepts to overcome the frontier between shaped and unshaped materials and that’s what will be covered in this paper.

Aug 17, 2017