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By J. E. Fraley

This report describes the preliminary results of a Bureau program to develop and test an inexpensive grout for full-column support of roof bolts. Various inorganic grouts were tested in both cartridge and slurry form. Tests were also performed on methods of water packaging and on the effect of fillers on the grout strength. Results showed that some grouts had poor early strength and exceptional mid-to long-term strength. Laboratory tests have shown that rapid-setting inorganic grout could be an economical replacement for resin bolts if the short-term strength could be increased. Further development to improve its early strength would need to be tested in the laboratory and underground to prove its potential for the mining industry.

Jan 1, 1987

By E. J. Matson

Under the investigation for critical and strategic minerals the Kaiser mine, formerly the Baxter fluorspar property, in northeastern Mineral County, Nev., was explored. The work comprised excavating 32 trenches averaging 90 feet in length, 8 feet in width, and 1 1/2 feet in depth. The trenches were excavated across the strike of the ore body to enable the engineer to spot the diamond-drill holes; 7 such holes were drilled, aggregating 3,276 linear feet. A total of 20 core samples and 107 sludge samples was taken. The work under this program indicated that the fluorspar southwest of the deposit extended laterally and also at depth at least 250 feet below the 400-foot level. INTRODUCTION The Kaiser fluorspar deposit is in the northeastern portion of Mineral County, Nev. Mining was begun about 1928, and the property has been a consistent producer of both Acid- and Metallurgical-grade fluorspar. The mineralized zone has been developed along a strike length of about 2,000 feet and to a depth of over 700 feet along the dip.

Jan 1, 1957

By Simón Díaz-Quezada, HUMBERTO ESTAY

The heap leaching process has been widely used for recovering different metals since its first application at the end of the 1960s. In Chile, copper production via heap leaching has accounted for between 30 and 40% of annual copper production over the past 10 years. This level of production has been achieved through and supported by the use of a mathematical relation, known as the leaching ratio (LR) or irrigation ratio (IR), which relates operational parameters with metal extraction in a heap leaching operation. This ratio has been used to develop leaching column tests, to scale up results from the laboratory to industrial operations, to design new heap leaching plants, and in metallurgical control and production estimation. In spite of the widespread industrial use of this relation, few scientific studies mention it. This is due to its simplicity and basic theoretical foundations. This disparity between industrial practice and scientific research could lead to operational decisions which lack substantial theoretical support, and to scientific studies which have limited industrial impact. Against this background, several questions arise about the use of the LR: What are the constraints on the use of the LR? Are there practical advantages with respect to reported kinetic models? What is the main reason that industry prefers the use of the LR over kinetic models, which enjoy greater theoretical support? In order to guide its future use, this paper describes the leaching ratio and its current uses and limitations, through a literature review and case studies.

May 2, 2020

THE progress in lead smelting practice in the United States during 1930 has been along previously defined lines. Since most of the material treated is high-grade concentrate relatively high in zinc, practically all the plants have been forced to adopt double sintering. This generally results in there being' no matte fall, and most of the copper in the charge is recovered in the furnace dross. The furnace dross is . smelted with. scrap iron and flux .in small reverberatories, giving a shipping matte or speiss high in copper and low in lead. Details of this reverberatory. furnace practice vary at the different plants. There is a decided tendency toward moreintensive filtration of blast- furnace and sinter fume. Bag capacity has been in- creased by using higher pressures and more frequent shaking.

Jan 1, 1931

By James S. Browning

The Bureau of Mines conducted laboratory batch and small-scale continuous selective flotation tests of barite-fluorspar ores from two deposits near Marion, Ky., to determine the technical feasibility of recovering commercial grade fluorspar and barite concentrates. The lignin sulfonate-sodium fluoride method of floating the fluorspar successfully produced acid-grade fluorspar concentrates. Flotation of the barite from the fluorspar tailing using petroleum sulfonate collector yielded concentrates suitable for use in compounding oil-well drilling mud. The fluorspar and barite recoveries were about 82 and 85 percent, respectively.

Jan 1, 1963

By Charles W. Huggins

To determine the nahcolite and dawsonite content in oil shales, the Bureau of Mines compared X-ray diffraction, infrared spectroscopy, thermal methods, and a previously published method by Smith and Young based on the selective solubility of sodium compounds. The Smith and Young method and a new method based on the weight of carbon dioxide produced by thermal decomposition are recommended for determining nahcolite. X-ray diffraction and the Smith and Young method are recommended for determining dawsonite. X-ray diffraction, infrared spectroscopy, and differential thermal analysis were useful for identifying other minerals in the samples.

Jan 1, 1973

By J M. Shekiro

In the chloride process to manufacture TiO2 pigment, feedstocks containing higher TiO2 contents (high-grade ores or HGOs) are favoured in order to minimise production of undesirable by-products. Most of today’s HGOs are produced through the smelting or reduction and leaching of ilmenite, processes which consume significant energy and/or produce large volumes of non-titanium materials that may have to be landfilled. In order to improve the economic and environmental sustainability of its TiO2 business, the DuPont Company, working with Kobe Steel Ltd, has developed an innovative process called TiRON for making HGO. Using a rotary hearth furnace, the process reduces ilmenite to a high TiO2 slag and metallic iron granules. The TiO2 slag is suitable for TiO2 pigment manufacture, and the iron is suitable for steel making. TiRON can process sand or rock ilmenite of varying compositions and particle sizes. Fossil fuel instead of electricity supplies the energy for the reduction. Dusts and off-spec materials are recycled. These process attributes, together with capital requirements estimated to be significantly lower, give TiRON substantial economic, environmental, and process flexibility advantages over conventional ilmenite upgrading processes. TiRON has been demonstrated at the semi-works scale, and preparations are being made to bring it to the pilot scale.

Oct 5, 2011

By L. A. Kaufman

"AbstractThe Bureau of Mines, Ottawa, in conjunction with Eldorado Mining and Refining (1944), Limited, has developed an automatic concentrator for uranium ores.A brief review of radioactivity is given which shows the present limitations for obtaining •good results by electronic concentration. The ores after being mined, or at any other stage of a concentrating process, can be analysed for the uranium dissemination and from these results the possibility of an economical concentration can be estimated.The electronic and mechanical parts of the equipment are described. Difficulties in the operation's, and means by which they have •been and are •being overcome, are discussed. The capacity of the units, the results obtained, the man-power required, and other pertinent data are presented. Simple control analysis on the percent U3O8 has been developed.Research is continuing along lines to develop a more completely automatic unit using a scintillation detector, and applying a few new ideas and some devices that have been developed in colour sorting.IntroductionIt is well known how important the Geiger counter is in the field of exploration for uranium. It was in late 1946 that Dr. C. Lapointe, of the Bureau of Mines, Ottawa, first started work on an automatic picking unit to concentrate uranium ores. He used the principle that if a number of pieces of unknown ore, some of which contained uranium, were individually brought up close to a Geiger-Müller tube, then the pieces containing uranium could •be easily picked out due to their activity. Since then a good deal of work has been done by the Bureau of Mines in conjunction with Eldorado Mining and • Refining (1944), Limited, to develop an electronic concentrator."

Jan 1, 1950

By Thomas P. Mucho

Retreat or pillar recovery mining redistributes the overburden weight onto the adjacent coal pillars in a room-and-pillar section. The additional stress and the resultant energy stored in the remaining pillars can become so great that pillars may bump or violently fail. An investigation at the Gary No.2 Mine was conducted to examine the effectiveness of the thin pillar mining method for mitigating bump occurrences. Field observations were made and instruments were installed to monitor pillar behavior during extraction. Stress monitoring instruments and roof-to-floor convergence stations were installed in pillars and entries and crosscuts, respectively. Results indicated that high pillar stress concentrations occurred in these bump-prone geologic conditions. The thin pillar mechanism, the creation and progressive outby movement of an expanded yield zone, was also monitored through the instruments. The expanded yield zone, a result of using thin pillars in a highly stressed pillar line area, mitigates bump risk.

Jan 1, 2010

By L Lorenzen

The selection of samples for metallurgical test work is generally focused on providing geologically representative samples. One of the major problems experienced with metallurgical test work using drill hole data, is the small sample sets selected for metallurgical testing. Major process and financial decisions are being made from results obtained using snapshot samples. Snapshot samples means that samples are basically selected only by grade and spatial location with the assumption that the rest of the orebody or portion of orebody is similar and will respond metallurgically the same way – ie the assumption is that the mineralogy and lithology are basically the same as the test sample. From the test work, algorithms were usually developed and used to describe throughput and recovery using some explanatory variables including grade (mineral chemistry) and ore hardness. These algorithms were then used in the recovery models to determine tonnes produced and plant throughput. However, the metallurgical parameters are a function of many geological factors including grade, lithology, alteration, mineralogy, spatial relationships and SG. In previous years, the limited mineralogical information available was deemed enough for the metallurgist to make decisions as to how many samples are needed to evaluate the metallurgical performance of the ore during processing, and subsequently the basis for the plant design. If the orebody is consistent and not complex or refractory (thus, relative simple lithology), then only spatial and grade samples will be needed to evaluate the throughput and recovery, so limited mineralogical information may be acceptable. There is now, however, an increasing realisation that the mineralogy and geology change, as do the metallurgical characteristics of the orebody, so limited samples may not be sufficient for effective metallurgical test work.It is the purpose of this paper to discuss the effect correct mineralogical information has on the subsequent metallurgical test work program and process selection using a case study. Factors such as type of rock, rainfall and topography are thought to influence the minerals that ultimately form in various orebodies, with the result that different orebodies often react differently during metallurgical test work programs. It is therefore important to obtain accurate mineralogical and elemental deportment data, which will also indicate where the valuable metal containing minerals are located within the orebody. The better you plan and execute your metallurgical test work program during the early phases, the more accurate the decision-making process will be during the selection phase. Improved integration between geology and metallurgy data gathering (geometallurgy) during early phases will result in more accurate predictions with regard to throughput and recovery during modelling and process. Equipment selection will be considerably simpler in later phases with early planning, with improved mine and process scheduling and subsequent net present value (NPV).

Sep 5, 2011

By Jason Ganley, Yingjia Liu, Adam Dekich, William Tilson, Jeffrey Fergus, Dileep Kumar CJ

"Manganese cobalt spinel oxide coatings have been shown to be effective for preventing chromium volatilization from interconnect alloys, and the associated cathode poisoning, in solid oxide fuel cells. During high temperature exposure a reaction layer consisting of chromium containing spine! forms due to reaction with the chromia scale formed on the alloy. The electrical conductivity of this reaction layer is much lower than that of the coating material and thus can increase the overall area specific resistance (ASR) of the system. The approaches to reducing the ASR are to reduce the thickness and/or increase the electrical conductivity of the reaction layer, which includes both the high-chromium spinel phase and the chromia scale. In this paper the effects of transition metal dopants on the amount and properties of reaction products formed during the reaction of spine! oxide coating materials with chromia are presented.IntroductionThe high cost and difficulties involved with the processing of chromia based ceramic interconnect materials for SOFCs are driving the search for metallic interconnects [1, 2]. The reduction in the operating temperature of SOFC has allowed for the use of high chromium alloy steels for this application [3]. However, the volatilization of chromium from the chromia scale, and the associated poisoning of the cathode, remains a problem which needs to be addressed [ 4]. Though the application of manganese cobalt oxide spine! coatings on the alloy surface substantially reduces chromium poisoning of the cathode [5], the low electrical conductivity of the reaction layer formed between the chromia scale and coating affects the performance of interconnect. Incorporating transition metal ions in the reaction layer could alter the electrical characteristics and improve the performance. Copper and nickel doped manganese oxide spinels are widely used as thermistors due to their high electrical conductivity and negative temperature co-efficient of resistance characteristics [ 6, 7]. Hence doping of copper and nickel in manganese-cobalt spine! oxide composition may improve the electrical characteristics of interaction layer as well and is attempted here."

Jan 1, 2012

By F. P. Haver

A method to recover copper and elemental sulfur from chalcopyrite concen¬trate, using a ferric chloride leach, CuFeS2 + 3FeCl3 ? CuCl + 4FeCl2 + 2S, was reported by the Federal Bureau of Mines in 1971 (Report of Investigations 7474). Since that time, additional work has been done to improve certain steps in the procedure; that is, the recovery of sulfur from the leach residue, the recovery of copper and iron from the leach solution, and the regeneration of the leach solution. It was determined that over 99 pct of the elemental sulfur in the leach residue could be extracted at ambient temperature with an ammonium sulfide solution. Heating the pregnant solution precipitated crystals of rhombic sulfur (99.5 pct purity) and liberated ammonia and hydrogen sulfide for recycle. Copper with a purity in excess of 99 pct was obtained from the leach solution by electrolysis, using a diaphragm cell, with an energy requirement of less than 0.7 kW-hr/lb. Metal was deposited as a weakly adherent powder that could be easily dislodged from the cathode and withdrawn continuously from the cell in the form of a slurry. During electrolysis, part of the Fe(II) was oxidized to Fe (III) at the anode so there was no chlorine evolution. The leach solution was regenerated by direct oxidation of the spent electrolyte with air or oxygen in a turboaerator at 80° C. This precipitated the iron dissolved during leaching in an easily filterable form, Fe203.xH20, and converted the remaining Fe(II) to Fe(III).

Jan 1, 1975

By Terry Gerritsen, Sylvain Picard, Bruce MacKay

Virtually all new technologies require a control system. Any intense process has many process variables that react quickly making manual control difficult. Control system design has a significant impact on the success of a plant especially during ramp-up. New technology projects are particularly sensitive to control system design as the process response is unknown. This paper discusses the important factors encountered in the design of a control system for a new technology. Examples are given of successful new technology plant start-ups where tight coordination of the process control system implementation, process design and selection major equipment led to rapid ramp-ups.

Jan 1, 2011

By Robert F. Chaiken

More than 500 fires are now burning in abandoned coal waste banks and coal deposits in the United States. Once established, such fires can burn for decades, and extinguishing them by conventional methods such as surface sealing to exclude air, excavation to remove fuel, or flushing to cool the fire zone is usually difficult and always expensive. Burnout Control, a technique developed by the Bureau of Mines for the control of abandoned fires, involves the accelerated combustion of coal in place with total management of the heat and fumes produced. A burning waste bank or mine is placed under negative pressure relative to the atmosphere, and heat and combustion products are drawn from the combustion zone through an exhaust ventilation system. Heat produced appears as sensible heat in the exhaust, at temperatures as high as 1,000° C (1,832° F), and can be recovered for the production of steam, hot water, process heat, or electricity. The Bureau's first field demonstration of Burnout Control was at Calamity Hollow in Allegheny County, PA (near Pittsburgh). Calamity Hollow was the site of an underground mine in the 1900's and was surface mined in the 1940's. In the winter of 1961-62, a fire of undetermined origin was discovered in the exposed coal. In 1963, the Bureau constructed a trench barrier around the fire and a surface seal over the affected area. The fire was isolated, but not completely extinguished. In 1979, when the Bureau began work on the Calamity Hollow Mine Fire Project, to demonstrate controlled burnout, the fire was still smoldering on the hot side of the trench barrier. The project, which was begun in December 1979 and ended in July 1982, consisted of the design, construction, operation, and subsequent dismantling of a Burnout Control ventilation system. This report is the fourth in a five-part series that describes the Calamity Hollow Mine Fire Project. The first report, part 1, describes the design and construction of the field installation. Part 2 will present the results of a continuous 4-month burnout operation. (Because part 2 involves the analysis of a substantial body of data, it will not be published until after publication of parts 3, 4, and 5). Part 3 describes the instrumentation used to control and monitor the progress of the burnout operation. This part (part 4) and part 5 both deal with the closeout phase of the field demonstration. The quenching of the fire is described in this report, and part 5 will describe the final excavation and backfilling of the heated zones. The reports in this series document the Calamity Hollow controlled burnout demonstration, which showed that (1) controlled in situ combustion is a feasible method for controlling underground fires in abandoned mines, (2) the resultant thermal exhaust output is sufficient for energy utilization, and (3) water injection with fume exhaustion is a potentially effective method for cooling large underground fire zones. Further trials of both Burnout Control and water injection with fume exhaustion are planned.

Jan 1, 1984

By Francisco Necy Alves Júnior

Os aços inoxidáveis superduplex (AISD) aliam boas propriedades mecânicas e resistência à corrosão, possuindo um vasto campo de aplicação na indústria petroquímica. Geralmente, os reparos dos equipamentos são realizados por soldagem, sendo importante a seleção de parâmetros. É de suma importância a obtenção do teor adequado de ferrita no metal de solda, sendo que a variação da energia de soldagem pode influenciar de forma direta a microestrutura e resistência à corrosão. Logo, este trabalho teve como objetivo avaliar os efeitos provenientes da variação de parâmetros de soldagem nas características do AISD UNS S32750. Foi avaliado o balanço de fases, relacionando esse efeito com a resistência à corrosão. Foram realizadas soldagens em chapas pelo processo TIG autógeno em 3 níveis de energia de soldagem (5, 10 e 18 kJ/cm), variando a corrente e velocidade de soldagem, de modo a obter 5 condições e a possibilidade de analisar as variáveis-resposta com essas variações isoladamente. A análise da microestrutura foi realizada por microscopia ótica e o teor de ferrita foi quantificado pela utilização de duas técnicas: ferritoscópio e quantificação por imagem. Foram realizados ensaios de temperatura crítica de pite para análise de resistência à corrosão. Concluiu-se então que o acréscimo de energia pela variação da velocidade de soldagem acarretou no aumento no teor de ferrita, ocasionando a redução da temperatura crítica de pite, sendo estes observados na fase ferrítica.

Aug 7, 2018

Variety among deserts is nearly as great as among other climatic environments. Common to most deserts, and to areas downwind from them, is the dominance of aeolian transport of surface material, at least during some seasons of the year. The result is dilution of local surface materials with varying proportions of chemically uniform fine sand and silt, often imported by the wind from remote areas. Fortunately, desert pavement,.even though separated from bedrock by a meter or more of nearly pure loess, is simply a diluted reflection of nearby bedrock. Infiltration of loess through the surface debris and the rudimentary soil-forming processes in the desert usually preserve the integrity of the pavement. This pavement, or its "downstream" derivatives, provides a suitable sample for exploration geochemistry if proper care is taken to circumvent the aeolian dilution. The simplest and most commonly used method of circumventing the dilution is to use a coarse fraction of soils or stream sediments, discarding or retaining the finer fraction depending upon the magnitude of the dilution. Where the coarse surface debris is composed of rock chips representative of the bedrock sources, the method is successful. Under most circumstances the coarse fraction of the surface material will give a fair representation of gross lithology and will occasionally give an indication of mineral- ization. The major drawback to this approach is that selective weathering and erosion in the vicinity of mineral deposits often lead to the loss of ore minerals into the finer fraction, leaving a coarse residue enriched in feldspar and particularly in quartz; thus, the geochemical signature from a mineral deposit is effectively reduced or completely masked. The second most commonly used method to overcome aeolian dilution, and probably the most effective at present, is to use a heavy- mineral concentrate. This approach presupposes that the chemical signature sought resides in a heavy mineral. Fortunately, the arid weathering cycle is conducive to the formation of a wide variety of secondary ore

Jan 1, 1988

By N. Bahrani

Photogrammetry surveys were used to document a footwall slab failure that occurred at a surface coal mine located on the eastern slope of the Rocky Mountains. Photographs taken before and after the failure provided the pre- and post-failure geometry of the slope and the failed slab. A 2D finite element model was constructed using slope profiles. The model contained joint elements that represented the bedding surface upon which the slab slid and the model was used to analyze the footwall slope. The in situ stresses, rock properties and the bedding surface shear strength and stiffness properties are discussed. The process of mining out a valley and exposing a highwall was modelled. As expected, elastic valley rebound occurred in the model, but shear stress and shear displacement reversals along the slip surface were also observed. The modelling results provided new insight into shear strength degradation that occurs when the pit floor approaches and then passes a specific point in the highwall.

Jan 1, 2009

By P Hodkiewicz

Recent structural interpretations based on historic stope shapes were used to develop a rapid and innovative method to domain and simulate structurally complex, high-grade gold veins at depth in the Edna May deposit. This involved ‘implicit’ modelling of drill hole data using Leapfrog software, which allows complex wireframe domains to be built and updated rapidly, compared to ‘explicit’ manual wireframing methods that are too subjective and time consuming. Conditional simulation was used for resource estimation, in order to simulate the highly variable gold grades associated with the veins. Similar modelling methods could be used to determine the mining potential of other historic gold deposits that are receiving renewed interest because of the high gold price.Gold at Edna May is hosted in the Edna May Gneiss, which is a WNW-striking tonalitic intrusion along a shear zone that dips approximately 45° towards the NNE. Gold occurs in multiple 0.5 - 5 m thick arcuate quartz veins that plunge steeply towards the west. Two phases of historic underground mining at Edna May (1911 to 1922 and 1935 to 1947) produced 360 000 ounces of gold at an average grade 19.5 g/t from seven ‘reefs’ to a depth of 240 m. This established Edna May as one of the highest grade gold mines in Western Australia at the time.Recent drilling by Catalpa Resources confirmed the potential for down-plunge continuity of high-grade veins. New structural interpretations, based on historic level maps and wireframe re-constructions of the arcuate stope shapes, were used as ‘structural trends’ in Leapfrog to model the mineralisation. The resulting wireframes capture the complex distribution of gold in the deposit and were used as domains for resource estimation.Conditional simulation using the Turning Bands method was used to simulate the expected variability of gold grades associated with this mineralisation style and the median of the 100 realisations was used to report an inferred resource. Results of this modelling method are being used to target vein extensions at depth, to consider different underground mining scenarios, and to assess the risks associated with developing and mining this high-grade and high-nugget gold deposit.

Aug 22, 2011

By E. E. Maust

The present work is part of an ongoing Bureau of Mines effort to provide a better understanding of the fundamental phenomena involved in sulfide flotation, the role of oxygen in xanthate adsorption being one essential issue. Galena was chosen as the material around which to develop a conceptual model, partly because of its demonstrated oxygen sensitivity and partly because information on its properties and flotation behavior constitutes the largest part of the fundamental information available on sulfides of commercial importance. The model is formulated primarily in terms of surface electronic energy levels produced by oxygen and xanthate and is further developed using existing experimental evidence and its implications. Four major functions of oxygen are elucidated, and the relationship of these to the formation of lead xanthate, dixanthogen, and a surface compound is discussed. Though yet incomplete, the model provides a useful framework within which the results of diverse experiments can be related to one another in their proper perspective, as shown by a brief discussion and resolution of some apparently discordant results reported in the literature.

Jan 1, 1976

By Michael G. Zabetakis

Investigation of gas explosions usually reveals that the combustible gases have come from transmission and storage facilities or from natural gas or oil wells. However, combustible gases such as methane and hydrogen can derive from biological processes. Hazardous situations have been created in the past by the use of abandoned mines for the disposal of sewage and rainwater, by the interconnection of storm and sanitary sewers, by sealing the openings in manhole covers when repaving the roadway over a sanitary sewer, and by the construction of buildings over or near garbage fill areas without adequately providing for the release of combustible gases.

Jan 1, 1962