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By A. Tonejc, A. Bonefacic

As can be seen from the phase diagram A1-W1 the equilibrium solubility of tungsten in aluminum is practically nil at room temperature. By quenching from the liquid state (50,000°C per sec), Varic, Burov, and Kolesnicenko2 obtained A1-W solid solutions up to 0.15 at. pct W. The quenched alloys were in the form of foils, 0.2 to 0.3 mm thick. Considering the results of Duwez and Willens,3 it is obvious that this thickness, which makes impossible a sufficiently rapid quenching, was the main reason for the relatively low content of tungsten dissolved in aluminum found by varic.2 he present note shows that the metastable solubility of tungsten in aluminum can be appreciably extended in aluminum-rich A1-W alloys. The quenching technique and the procedure employed for the preparation of the alloys have been described previously.475 The resulting quenched flakes varied in thickness from 1 to 20 µm from experiment to experiment. However, the measurements of the lattice parameters were carried out only with flakes thinner than 5 µm. The areas of quenched flakes were between 0.1 and 15 mm2. The quenched flakes were placed into a 0.3-mm glass capillary tube which was then mounted in a 114.6-mm-diam Debye-Scherrer camera. Straumanis asymmetric film position and nickel-filtered CuKa radiation were used. The lattice spacings were computed taking X(CuKa1) = 1.54050A for resolved and ?(CuKa) = 1.54178A for unresolved doublets. All specimens were rotated at room temperature, 26o +2°C. The lattice parameters were estimated from extrapolation against the Nelson-Riley function. It was estimated that the error in the lattice parameter of the measurements on a single film lies within +0.0004A for lower and about +0.001A for higher concentrations of tungsten. The lattice parameters of the metastable solid solutions A1-W are plotted vs the concentration of tungsten in Fig. 1 together with the parameters measured by previous investigators.' Each point of the present measurements represents a determination of the lattice spacing on different quenched flakes, for a given concentration of tungsten. With experimental accuracy, the lattice parameters of the metastable solid solutions fall on the straight line passing through the already known data.' As estimated from the uncertainties in the lattice spacings of the solid solutions, the alloys were homogeneous within 0.1 at. pct W. The solubility of tungsten in aluminum-rich A1-W solid solutions obtained by a very rapid quenching technique is increased to about 0.95 at. pct W. This value is 6 times greater than the amount known up to now. -he lattice parameters of the resultant aluminum solid solutions with higher concentrations of tungsten than 0.95 at. pct W did not remain constant AUGER electron spectroscopy has been used to clarify the role of impurities in the embrittlement of AISI 3340 steel. Analysis of fracture surfaces has shown that the embrittled condition is correlated with appreciable antimony segregation at grain boundaries. The low temperature (400" to 600°C) temper embrittlement of low alloy steels containing various combinations of Cr , Ni , Sb , Mn , P , Sn , and As has been examined extensively for many years. General reviews of the area have been made by McMahon1 in 1968, LOW' in 1959, woodfine3 in 1953, and Holloman4 in 1946. Recent work by Low, Stein, Turkalo, and LaForce5 has done much in separating the alloy and

Jan 1, 1970

By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

To address the safety of programmable electronics-based mining systems before this technology proliferates in the mining industry.

Jan 1, 1999

By E. P. Youngman

Gold and precious stones were mined in Egypt in prehistoric times. This mining, carried on at intervals, extended over thousands of years, until about 1300 A. D. Then ensued a dormant period of several hundred yoars. In the mean- time Europe made great rogress in mining practice, metallurgy, and geology and sent out various expeditions during the nineteenth century to investigate ancient mines. But the exploratory work produced no material results, and not until the beginning of the present century did actual mining recommence. The reopening of old gold mines in Rhodesia aroused interest in London and Paris, and these cities provided the capital necessary for the investigation of the ancient minee in West Africa and Egypt. Speculation resulted in the division of most of the uncultivated area of Egypt and the Sudan into huge concessions, and a number of expeditions were made; but after an unprecedented activity in West Africa, roaction set in, and the flow of capital ceased. The concession- aires, mostly individuals with insufficient capital and with a misconception of the initial difficulties of communication, water supply, and labor, allowed

Jan 1, 1932

By Arthur Dubé

An account is given of the developments brought about in the last fifteen years by metallurgical research in the field of heat treatment of steels. The practical aspects of these developments are especially emphasized. Methods of representation of the phase-change during austenitizing and sub-critical transformation of austenite are described and the importance of time-temperature-transformation charts for the planning of heat treatment cycles is shown. Special copies such as retained austenite and internal stresses developed on quenching are also discussed in some detail. Due to the interest shown currently in these problems, it has been thought advisable to describe briefly the underlying principles and present some of the results already available.

Jan 1, 1945

By Yi Luo

In a shearer longwall mining operation, the longwall bits are responsible for breaking into and chip-ping the broken coal blocks away from the coal face. However, underground observations have found that a large number of longwall bits are always working under various degrees of wear. Reduction of the bit wear could be realized by using better designed longwall bits and properly selected shearer operating parameters. A computer program has been developed to simulate the performance of the longwall bits. The shape of the bit head, the installation of the bits on the drum and the operation parameters are the information required by the program. Through the simulations, the main factors affecting the bit wearing process are identified. Suggestions are also made for improving the design of the longwall bits.

Jan 1, 1996

By Brian L. Beninger

This paper discusses the application of the computer to coal preparation process predictions. In broad terms, the computer is used to perform two main functions. Firstly, the given float-sink analysis is interpolated and extrapolated to cover the entire actual range of raw coal specific gravity. Assumptions based on historical data must be made at times. Secondly, the partition curve, which, from historical data, defines the efficiency of a specific coal washing process, is applied to the washability data in order to determine the expected clean coal yield and quality. The vast amount of numerical work which is required to make a prediction of this type exhibits the need for computer methods in this area.

Jan 1, 1979

By Herbert D. Drechsler, James B. Stephenson

"AbstractThe paper identifies the major components of price change which affect the determination of the internal rate of return of a mining project. It illustrates several price indexes which may be used to measure general price increases, identifying techniques which might incorporate them into mine valuation procedures. The ""hurdle rate"" for new investment is discussed.IntroductionDECISIONS regarding the value of an orebody and whether or when to mine an orebody are based on an estimate of the cash flows which would be associated with its exploitation. These pro-forma cash flows represent cash in or out of a possible mineable deposit and include exploration and construction costs, sales revenues, operating expenses, taxes, debt borrowings, interest and debt repayment. It has long been recognized that when combining the cash flows occurring over the life of the mine, dollars received or paid out early have greater value than those received or paid out later. This time value of money has been incorporated into mine evaluation calculations through the use of present-value or discounting techniques. Another factor affecting mine valuation, inflation, is not accounted for by valuation techniques now in use. In recent years, price changes have become more volatile. In the past, price change could easily be ignored when evaluating potential mines. Today, the combination of larger investments and greater price volatility leads to great concern about the effects of price change on mine valuation."

Jan 1, 1977

By C. Jay Hodgson, P. J. MacGeehan

"The gold ore zones of the Campbell and Dickenson mines occur within a km-wide, 2 km-long zone of highly altered and anomalously fissile and deformed volcanic and subvolcanic intrusive rocks, cut by a series of mainly post-deformation mafic and quartz-feldspar porphyry felsic dykes.Three main periods of gold ore-forming hydrothermal activity are recognized. In the first, the mine rocks were extensively altered and gold and arsenic enriched; syn-volcanic auriferous veinlet and low-grade chemical sedimentary ores were deposited in what was a major discharge zone of a submarine hydrothermal system. The chemical sedimentary ores are closely associated spatially and temporally with domal rhyolitic extrusions. Because of its mechanical and chemical properties, this synvolcanic alteration zone became the locus of later deformation, and the site of the generation of auriferous hydrothermal solutions, perhaps by pressure solution processes at depth. These solutions deposited, synchronously with deformation and metamorphism, the second and most economically important type of ore zones in the mine: large foliation-parallel and foliation-oblique banded carbonate- 'chert' Rssure-filling veins.In the third and final mineralizing event, high-grade, pipeshaped zones of siliceous replacement-type mineralization, and quartz-arsenopyrite-gold veins, were superimposed on the previous mineralization types after most of the deformation, but before the emplacement of the late dykes. The source of heat and also possibly the fluids for the third mineralizing period may have been the dyke-forming igneous activity. The textures and mineralogy of the banded carbonate- 'chert' veins suggest a near-surface (<3 km) environment of deposition, but their relationship to the fabric of their host rocks indicates they were emplaced in an environment, presumably at considerable depth (5-10 km?), in which the rocks were undergoing intense penetrative deformation. This anomaly is unresolved."

Jan 1, 1982

By H Weitz

Bateman Engineering provided process technology and engineering design to China Yunnan Metallurgical Company (CYMCO) for a 30 MW DC furnace for the production of high-grade titanium dioxide slag.Following the successful commissioning of the furnace during the latter part of 2009 and the first quarter of 2010, a period of adverse circumstances resulted in having to operate the furnace without feed and at a low power input for a period of time. When normal feed resumed, a layer of solid material was detected on the slag-iron interface during sounding measurements. The condition of the iron was also significantly altered. The iron temperature was much higher than the design value, but the carbon content had decreased to such an extent that a large amount of iron solidified in the furnace, which made iron tapping very challenging. The slag temperature was increased in order to melt the solidified iron. However, severe sidewall damage resulted, which finally led to a burn-through. A number of samples were taken from the slag that remained in the furnace. These samples were analysed to determine the chemistry and phase profile throughout the slag bath. The mechanisms of formation of the high melting-temperature phase on the slag-iron interface are discussed, as well as procedures that can be applied to prevent a recurrence of this phenomenon. Some recommendations are made for instances when furnace feeding is interrupted for an indeterminate period.

Oct 5, 2011

By M. P. Roy, P. K. Singh, A. K. Mishra, Ashish K. Vishwakarma, Vivek K. Himanshu

Ground vibration is one of the major hazards produced by rock-blasting operation. The accurate prediction of vibration is necessary for designing controlled blasting parameters. The existing vibration predictors consider maximum explosive charge weight per delay and distance as the parameters responsible for ground vibration. These predictors are based on the assumption that the geometrical parameters of the blast will be constant for a site. However, the mining sites with bigger production targets have varying geometrical parameters to suit the excavator utility. Accordingly, the other blast design parameters will also have an impact on ground vibration intensity. A principal component analysis is a dimension reduction technique. This technique along with multivariate logarithmic regression has been used in this paper to predict the ground vibration. The technique has classified the blast design parameters into four principal components. The regression with the scores from these principal components has been carried out. The evaluation of the model performance of predictors along with the existing empirical predictors has been carried out using R2 and RMSE values. The evaluation suggests that the predictor with logarithmic regression followed by principal component analysis gives better performance with respect to the existing empirical predictors.

Jul 30, 2022

By D. -A Tremblay

Dynamic wetting spread factors and interfacial heat transfer coefficients were determined for aluminum droplets solidifying on copper substrates, The spread factors were determined from the droplet geometries while the heat transfer coefficients were obtained by solving inverse heat conduction problems, 1-D and 2-D heat transfer models are presented and the results they provided are compared, For the latter, a sensitivity analysis was also performed to determine the influence of thermophysical properties and boundary conditions. Experiments were alternatively carried out with three different gaseous atmospheres and the dynamic wetting spread factors were correlated to the interfacial heat transfer coefficients.

Jan 1, 2005

By K. G. Baxter, D. G. Dixon

The Sepon process plant utilises an autoclave to oxidize a flotation concentrate containing pyrite, residual copper minerals, and sulphur. The concentrate is produced from the residue of a preceding atmospheric copper leaching circuit. The function of the autoclave is to provide iron and acid for that atmospheric copper leaching circuit. The key issues in the operation of the autoclave are to maximise the production of acid and ferric ions and to avoid scaling issues related to sulphur balling in the autoclave. Scale control in the autoclave was examined using various dispersants and residue recycle without success. Operation of the autoclave at high temperature and high acidity addressed the scale issue through rapid oxidation of the sulphur and produced a ferric sulphate precipitate in the residue that could be re-leached to provide ferric iron. This paper presents the development steps followed, through batch and continuous piloting that resulted in an autoclave circuit design that addressed the above process requirements. Following definition of the process design basis, modelling of the autoclave operation was carried out to assist with engineering design. The model included thermodynamics and kinetics of oxidation of pyrite, elemental sulphur and covellite and also considered gas/liquid mixing, oxygen solubility as a function of temperature and solution composition, ferrous to ferric oxidation, gangue reactions with acid and precipitation/re-dissolution of basic ferric sulphate and alunite.

Jan 1, 2004

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

The Role of the Drilling Contractor BY FERRIS E. SAINSBURY Ron Haxby, Occidental Minerals What is the best method for drilling a 12-in. diam hole to a depth of 1200 ft and maintaining the deflection within 25ft from vertical? Ferris Sainsbury: In order to drill a 12-111. hole down to 1200 ft, In most places you would have to employ a rotary tricone bit With a down-the-hole hammer, I expect by that depth significant Inflows of water would be experienced Even with foams, we would not be able to get the water out of a hole of that diameter So the down-the-hole tricone method of drilling would be best. To keep it straight, we would probably employ the largest square drill stem compatible with the diameter of the hole. Ron Haxby: Is it common in drilling contracts to put in a vertical hole clause? Ferris Sainsbury: You can put in the vertical hole clause Ron Haxby: Does it cost more? Ferris Sainsbury: Normally, if the hole deviates, the driller can correct it with deflection wedges and will charge it back to you at cost, plus 10% or somewhere along that range Any drill hole has a tendency to go perpendicular to the dip, and there are times when stabilization systems are not successful in preventing the hole from turning into the dip of the formation. The only solution, in this situation, is to go in with an oriented wedge and kick the hole back out.

Jan 1, 1979

By Harold J. Schock

The cases of no auxiliary ventilation and ventilation with tubing were mathematically modeled, using a turbulent dispersion model. The scooptram that is used to load is modeled as a variable-speed, variable-strength source of pollutants moving in and out of the dead-ended drift. Model predictions are compared to experimental measurements. A parametric analysis was performed to determine the effect of exhaust pipe location and time spent out of the drift, as well as to determine if a relationship existed between CO2 and NO levels. It was concluded from this analysis that when modeling a load-haul-dump cycle, it is necessary to use a model that has the capability of predicting changes in source strength as well as source location. It was also determined that four relevant factors include effective heading height, apparent longitudinal diffusion coefficient, transverse concentration gradient at the face, and average dispersion width of the exhaust jet. As these factors change with heading geometry and ventilation configuration, they were determined experimentally, Carbon dioxide was used as a tracer to calibrate the model; since, knowing the fuel flow rate, it is possible to calculate CO2 production. The above four factors in the computer model were calculated using a regression analysis, comparing predicted local concentrations to measured local concentrations. The model was then verified after this calibration process using additional experimental results. With the calibrated model, it is possible to predict pollutant concentrations at any location in the heading using an engine map and the previously calculated flow field. A parametric analysis shows that the exhaust pipe location can have a significant impact on operator exposure to exhaust gases. It was also shown that NO concentration varies directly with C02 levels. Predictions using the dynamic model are contrasted with constant source strength (pollutant flow rate) results. An analysis of these predictions for computing time-weighted average NO shows the dynamic model predictions of operator exposure to this pollutant to be less than one-half of the value predicted using a constant source model.

Jan 1, 1981

By Elipio Pérez Coronado

El presente trabajo describe la aplicación del método de corte y relleno descendente mecanizado y el método de almacenamiento provisional en la mina Santa Bárbara, ubicada en Cerro de Pasco. Para el primer método, son mayores e intedependientes las operaciones unitarias, limitando la producción y generando mayores costos en el relleno chancado. Mientras que el segundo método, es aplicable en los cuerpos "Vasconia" y "Manuel", siempre que cumpla con tres condiciones principales que hacen posible su efectividad en la mina: la primera, señala que la explotación se realice en los pisos superiores y luego, en los inferiores; la segunda, refiere que la explotación son mayores las se haga en retirada y la tercera indica que el espacio no debe ser rellenado. En este sentido, el método de almacenamiento provisional resulta ser el más idóneo para la explotación de cuerpos irregulares en la mina Santa Bárbara puesto que su capacidad al término del acarreo de mineral es ilimitada.

Nov 8, 1984

By Richard D. Miller

This publication contains routine analyses and related source data for 350 natural gas samples from 19 States collected during calendar year 1362 as part of a continuous survey of the United States for occurrences of helium in natural gas. This survey has been conducted by the Helium Activity of the Bureau of Mines since 1917. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus. Four previous publications have been made to present the results of 5,648 gas analyses made by the Bureau of Mines, Helium Activity, prior to 1962. The first, Bulletin 486, 3/ contains analyses and data on 2,195 gas samples collected during the period 1917-47. Bulletin 576, 4/ the second publication, includes data and analyses for 1,575 samples collected from 1947 through May 1956. The third bulletin contains 1,444 analyses and source data of samples obtained from May 1956 to January 1, 1961.

Jan 1, 1964

By T. T. Chen

This mineralogical study is based on samples from typical "wet" nickel laterites of humid tropical to sub-tropical regions. An in-situ nickel laterite sample from Goro and a transported laterite sample from Plaine des Lacs, New Caledonia, are predominantly limonitic. Two-thirds of the particles in the Goro sample are <10 um in size; they consist of skeletal goethite and serpentine, as well as minor amounts of talc, gibbsite, chlorite, quartz and clay minerals. The coarser grains are mainly Cr-spinel, serpentine, gibbsite and Mn oxide. Nickel occurs mainly in goethite, serpentine and Mn oxide; cobalt occurs in goethite and Mn oxide. The Plaine des Lacs sample is finer-grained and contains more Al and CO3, but less Mg and Si than the Goro material. The sample contains more kaolinite, chlorite, siderite and feldspar, but less serpentine and gibbsite than the Goro material. Nickel is detected mainly in goethite, serpentine, Fe-Mg silicate and Fe-Mn oxide. The Indonesian ore from Sorowako, as sampled from the reduction kiln feed containing some reverts, is predominantly saprolitic, with apparent particle sizes ranging from <100 um to > 1 cm. The sample of reduction kiln feed is rich in Mg silicates, Mg-Fe silicates and goethite, and exhibits complex alteration textures. The nickel contents vary from particle to particle. Nickel is present mainly in serpentine, olivine, chlorite and amphibole, and in subordinate amounts in goethite and Mn oxide. Cobalt is detected in the Mn oxide. Keywords: Nickel Laterite; Mineralogy; Nickel Carriers; Goro, New Caledonia; Plaine des Lacs, New Caledonia; PT Inco., Sorowaki, Indonesia

Jan 1, 2004

By Jim Clark

Tunnel boring machine (TBM) tunneling is an ever-increasing prospect for underground construction, and, with each new tunnel bored, there are unknown elements. When boring through the earth, even extensive geotechnical baseline reports can miss fault lines, water inflows, squeezing ground, rock bursting and other types of extreme conditions. This article draws on the consider-able field service experience within Robbins to analyze successful methods of dealing with the most challenging conditions encountered. Many tunnel projects are located in areas with relatively poor access along the tunnel alignment and bored under extremely high overburden. These two factors often result in limited geological information. It would be reason-able to state that the deeper the tunnel, the greater the lev-el of uncertainties. When faced with these uncertainties everyone involved with the project including the owner, the contractor and the machine supplier must be prepared to tackle geological surprises. This article describes the problematic geological conditions and associated difficulties faced on three separate projects and the measures that were taken to overcome these difficulties.