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By G. Y. Liu

The structure-activity relationships for four thionocarbamate collectors are discussed in this pa-per. These collector classes are alkyl alkyl thionocarbamates, allyl alkyl thionocarbamates, acyl al-kyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates. The main emphasis will be to highlight the differences between collectors and their affinities for copper and iron sulfide minerals on the basis of data on electronic-structure properties obtained by vacuum and solution density functional calculations, flotation experiments and analysis measurements. The mechanism of interaction of these collectors with sulfide minerals is also discussed with perturbation theory. The theoretical study results indicate that acyl alkyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates have best performance in these agents as flotation collectors with improved collecting power for copper sulfide minerals and excellent selectivity against iron sulfide minerals, which are consistent with the experimental data reported in the literature.

Jan 1, 2014

By Diane Reid, Antonio Marinucci, Robin Mao

Super Cells are an innovative, open-shaped bi-directional static load testing device used to promote concrete flow during placement while utilizing greater cross-sectional area of the pile to achieve large applied axial loads at relatively low hydraulic pressures (≤ 250 bar). This paper describes the results of multi-level load testing performed on a sacrificial drilled shaft that was 3.8 m (12.7 ft) in diameter and 110.6 m (363 ft) in length for the Jiaxing-Shaoxing River Crossing Bridge that spans Hangzhou Bay in Shaoxing, China. The test shaft was instrumented with embedded strain gauges and telltale rods along with displacement transducers at the top of the pile to measure the load-induced displacements along the length of the shaft. Load testing was performed twice using a Super Cell placed near the tip of the shaft, prior and subsequent to tip post-grouting, and then again using a Super Cell placed higher in the shaft. The axial resistance for the tested conventional drilled shaft was more than 5 times greater than the estimated axial resistance. In addition, the axial resistance after tip post-grouting (347,100 kN (39,033 ton)) was about 5.3% greater than the ungrouted axial resistance (329,600 kN (37,050 ton)). INTRODUCTION During the past few decades, the magnitude of axial, lateral, and flexural loading has considerably increased due to updated design codes, larger superstructures, and the manner in which extreme event loading (e.g. seismic and scour) is incorporated into design. The diameter and depths to which bored piles or drilled shafts are constructed have increased considerably during the last three decades due to the advancements in equipment technology and capabilities. In addition, monoshaft foundations have become increasingly used, as one large drilled shaft is able to replace a group of smaller diameter piles connected by a cap. Correspondingly, adequate strata, for both side and end resistance, must be discovered/determined as well as achievable to be able to construct the required foundations to support the greater design demands. As design demands have increased, the need to ensure integrity, quality, and performance of a constructed drilled shaft has become ever more crucial. Load tests are essential to validate design assumptions of side and end resistances, to assess the behavior and load transfer characteristics of the constructed drilled shafts, and to evaluate construction methods. Load tests utilizing a bi-directional static load testing (BDSLT) device can achieve considerably large applied axial loads and can be performed more economically, in less time, and in a much safer manner than conventional top-down static load testing methods.

Jan 1, 2019

By Muhammad I. Kabir

The streamline method of recovery prediction reduces a two-dimensional problem to a bundle of one-dimensional ones. This paper presents the development and application of a novel scaling technique which, when used with a streamline model, causes s bundle of one-dimensional problems to further reduce to a single one-dimensional calculation. The one-dimensional calculation accounts for chemical-rock interactions and the streamline model for areal sweep. The scaling technique significantly reduces computation time, is readily modified to desk-top calculations, and can be applied to both absorbing and reacting species. The work was sponsored by the Interior Department's Bureau of Mines.

Jan 1, 1984

By Rongjie Kong, Shiwei Wang, Guomin Wei

Owing to the selective oxidation and uneven combustion that occur on the surface of carbon anode, some carbon particles detach and form carbon residue, which is defined as spent anode slag (SAS). The highly graphitized and toxic impurities such as fluorite ( CaF2), corundum (α-Al2O3), and cryolite ( NaAl11O17) are crucial components of SAS resource but are difficult to separate from graphite. This study developed a method of using water-soluble (emulsified) kerosene to separate the carbon particles from the toxic impurities in the SAS resource. The flotation purification approach of utilizing conventional kerosene was experimentally investigated and compared with that of using water-soluble kerosene. The results showed that with the use of emulsified kerosene, the maximum combustible matter recovery of the carbon particles was 89.86% while that of using traditional kerosene was 80.30%. The emulsified kerosene was comprehensively examined by various instruments to clarify its adsorption mechanism on the carbon particle surfaces. Because of the superior dispersibility of emulsified kerosene, it effectively envelops carbon particles with a smooth surface, oxygen-containing functional groups, and hydrophilic C–F bonds, thereby increasing the surface hydrophobicity and flotation responses of targeted carbon particles.

Feb 6, 2024

By Matthew Preedy, Anthony Pooley, Mike Wongkaew, Dirk Bakker, Raghu Bhargava

Sound Transit’s ST3 program will add 62 miles of light rail to the Puget Sound area, including connections to the neighborhoods of West Seattle currently anticipated by 2031 and Ballard by 2036. These connections include considerations for both elevated and tunnel alternatives, as well as a new downtown tunnel for which different configurations are being considered with potentially very different construction logistics and risk profiles. This paper describes the latest developments in the ongoing evaluation process that will inform the consideration of different tunnel and station construction methods, technical and operational challenges and contracting methodologies, including construction of deep stations in dense urban environments.

Jun 13, 2021

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By Roy L. Soderberg

The Bureau of Mines has conducted substantial research on the design, construction, and operation of metal and nonmetal tailings ponds. This design guide, like related Bureau publications that preceded it, is produced to assist the industry in the management of mill tailings disposal. It covers the site selection, sampling, laboratory testing, design, construction, operation, and inspection of tailings embankments. The effects of environment, topography, and hydrogeology are also included, and various methods of stability analysis and factors affecting stability are reviewed. Because of the diversity of problems encountered in tailings embankments, specific solutions are not intended. The guide is, however, a useful checklist for designers, operators, and inspectors of this type of structure.

Jan 1, 1977

By J. R. Nettle

A method has been developed in the laboratory for successfully electro-refining titanium metal. Refining is accomplished in e fused-salt electrolyte using offgrade metal as the anode and collecting the purified metal at the cathode. The characteristics and requirements of the various alkali chlorides tested as electrolytes are discussed in relation to relative ease of purification and serviceability. The various types of cells designed and tested for electrorefining are illustrated and their method of operation discussed. The individual advantage of each cell and the purpose for which it was designed are reviewed. The magnitude of the cathode current density was found to depend largely upon the quantity of soluble titanium chloride in the electrolyte. The physical condition of the anode also greatly affected the cathode current density.

Jan 1, 1957

By M. Saghaeian, R. Hejazi, A. Dehghani Ahmadabadi, M. Zare

"In the most iron ore beneficiation plants, reverse flotation is the best method for removing silicate gangues from final iron ore concentrate. Many previous studies show, if the major portion of impurities include quartz minerals, the flotation process is simple, but if iron silicates are dominant, reverse flotation is so complicated and mostly not very effective. In this study which was performed on the Sangan iron ore concentrate, the performance using of reverse flotation and magnetic flotation separator for elimination of silicate gangues from the magnetic iron concentrate was investigated. The operational parameters for reverse flotation are considered as: collector and frother types and dosages and also modifiers. But for magnetic flotation separator parameters were magnetic field intensity as well as overflow and underflow water rates. Results showed that reverse flotation has not a significant effect on the elimination of impurities. Because of the silicate gangues of Sangan concentrate including a mixture of quartz and iron silicates (amphibole, pyroxene and feldspar), so downgrading of the SiO2 content for the flotation concentrate was rather low and only average reduces of 20.60% were possible. But the findings of using magnetic separator was more satisfactory. Results of the weight recovery, iron grade and also SiO2 and S grades of final concentrate were better with magnetic flotation device. So at the best and optimum condition, we could reduce 51.01% of the total silicate (SiO2~ 2.19%) along with 74.66% of sulfur content (S~ 0.076%) and concentrate weight and Fe recoveries of 92.04% and 94.51% respectively, final Fe grade of 68.73%.INTRODUCTION Chemical/traditional flotation is one of the most effective methods for separating valuable particles from waste minerals, which is used in most mineral processing industries. In the iron ore processing industry, the major impurities present in iron ore concentrate include sulfur, silica and phosphorus (Bruckard et al, 2015), which are often carried out by reverse flotation methods for the removal of sulfide and oxide impurities (Donald, 1967: Araujo et al., 2005: Ma, 2012)"

Jan 1, 2018

By John C. Machisak

Employment and related injury experience of the coking industry in the United States for 1957 contained in this publication is summarized under three general sections: (A) General injury experience: Tables 1 to 9: Current and comparable statistics on operating data, number, frequency, and degree of severity of injuries and major accident agencies involved in the cause of Injuries. Data are presented for the industry as a whole, for each type of oven, and for the States in which coke was produced.

Jan 1, 1959

By Dielle Cristine Toledo Costa

Os aços austeníticos 304L quando processados tem suas propriedades mecânicas afetadas pelas transformações martensíticas induzidas pela deformação plástica (efeito TRIP). O objetivo deste trabalho foi avaliar esse comportamento em corpos de prova que sofreram deformações gradativas por meio de ensaios de tração uniaxial a partir de diferentes técnicas de análises microestruturais e mecânicas, a saber: ferritoscopia, difração de raios-x e ultramicrodureza. Os resultados obtidos foram satisfatórios e permitiram estimar o efeito da deformação na transformação martensítica e comparar as técnicas utilizadas.

Aug 8, 2018

By G. E. McElory

"INTRODUCTION The subject of mine and tunnel ventilation has two broad aspects - (1) what atmospheric conditions to obtain in underground openings and (2) how to maintain the desired conditions efficiently. The first relates primarily to quantity requirements of ventilating systems, whereas the second relates more particularly to pressure requirements. Both, therefore, determine power requirements, which is the deciding factor in any system of mine or tunnel ventilation.Both divisions of the subject have received considerable attention from the Bureau of Mines since its inception in 1910 in the form of research, service, and correlation and dissemination of information. Numerous papers on various Phases of the subject have been published, of which a selected list, numbered and arranged in chronological order by type of publication, will be found at the end of this Paper. One of these, Technical Paper 705 (25) 2/ gives a complete bibliography of Bureau of Mines publications dealing with health and safety. As indicated by the selected list of publications accompanying this paper, the health and safety aspects have received most of the attention devoted to this work, chiefly because these have been dominant factors in Bureau policy, but partly because these aspects lend themselves to laboratory research and small-scale field studies. Although considerable attention has also been devoted to the engineering aspects of mine and tunnel ventilation, there has been, in the opinion of the author, who has been engaged on this phase almost continuously for the last 30 years, only sporadic recognition of the vital effect this phase of the work could have on improving health and safety conditions. As a matter of fact, ventilation activities have constituted but a very minor part of the total work of the Bureau of Mines, as, except for a few years in the nineteen twenties, there have been only a few short intervals when more than two or three men were engaged in field work and a similar number in laboratory research directly related to mine gases or mine air."

Mar 1, 1950

By S. Brunauer

The hydration of portland cement is treated as a chemical reaction and the changes in matter, in energy and the rate of change of the process are discussed, Portland cement is a mixture of four major and at least as many important minor constituents. In the hydration process, the four major compounds (trical-cium silicate, dicalcium silicate, tricalcium alumi-nate and tetracalcium aluminoferrite), plus gypsum and water form five or six new compounds. In spite o the great complexity of the reaction, considerable progress has been made in its understanding, primarily with the help of such research tools as X-ray diffraction and electron microscopy. The rate of the reaction can be followed by direct and indirect methods of measurements. The effects o composition, particle size (or specific surface), temperature and water-cement ratio on the rates of hydration are discussed. The hydration of portland cement is a chemical reaction accompanied by such highly important physical phenomena as heat evolution, setting and hardening. It is a vast and complex subject, on which hundreds of papers have been published. At the time of the writing of this paper, in October 1962, a two-volume book, which alone contains dozens of papers pertaining to cement hydration appeared in print.' The present paper deals with a few aspects of this vast subject, and the selection was not easy. The work reported here deals with some of the most recent investigations in the field. In any chemical reaction, the physical chemist is primarily interested in three things: changes in matter, changes in energy and the rate of change of the process or the speed of the reaction. This is true also of the chemical reaction between portland cement and water, and all three aspects of the reaction will be discussed. These three aspects are of vital interest to the engineer as well. Portland cement is not a cementing material — the hydration products, the new materials which form in the reaction, have the cementing action. The energy changes manifest themselves in a considerable evolution of heat, which may be useful or harmful. It is useful, for example, in winter concreting, but in very large concrete structures like dams, a large evolution of heat, which cannot be easily dissipated, may produce distress in the structure. Primarily for such a purpose was the Type IV or low heat portland cement developed. The speed of the chemical reaction is important because it determines the time of setting and hardening. The initial reaction must be slow enough to permit placing of the concrete before setting occurs. On the other hand, after the placing of concrete it is often highly desirable to obtain as rapid chemical reaction as possible. For this purpose the Type 111 or high early strength portland cement was developed. CHANGES IN MATTER Portland Cement: In a basic investigation, before one begins to study a reaction, one either knows the quantities and compositions of the starting materials, the reactants, or one determines them. This is obvious; the chemist expresses the changes in matter that occur in a reaction by a chemical equation, which has the quantities and compositions of the reactants on the left side of the equation and the quantities and compositions of the reaction products on the right side. The first question is then what to put on the left side of the equation in the reaction between portland cement and water? It is not very easy to answer this question. Portland cement is not a single chemical compound but a mixture of many compounds. Four of these are considered the major compounds, and at least four of the minor compounds also play important roles in the hydration reaction. In order to avoid complicating matters, the present discussion will be restricted primarily to the four major compounds, which constitute usually more than 90% of a portland cement. The relative amounts of these compounds vary from cement to cement. Actually not only the amounts but the compositions of these constituents also vary to some extent, but the variation in composition of the individual components will be neglected for simplicity.

Jan 1, 1963

By D A. Bowman, S Schafrik

With the goal of reducing injuries and fatalities related to haul truck accidents, this research investigates technologies and intervention strategies for improving worker training using a virtual environment (VE). Funded by the National Institute for Occupational Safety and Health (NIOSH), this research specifically focuses on training workers in preshift inspections of haul trucks to avoid preventable defects from causing worker injuries and expensive equipment damage. Improved training in these inspections is expected to increase uptime. The VE developed to train workers for preshift inspections consists of three phases: the virtual tour, the virtual inspection and the shift simulation. The virtual tour introduces information necessary to conduct a preshift inspection by guiding the worker around a haul truck, identifying parts to be inspected and explaining defects to look for. The virtual inspection assesses retention as the worker navigates around a haul truck and identifies defects. During the shift simulation, the worker is shown a simulation of the work shift, which animates severe consequences of any overlooked defects to emphasise the importance of preshift inspections. To provide multiple training platforms, desktop and CAVEÖ versions of the training VE were created. Flux Studio was used to model the environment and to produce Virtual Reality Modelling Language (VRML) files for the desktop version. DIVERSE, an application programming interface, was then used to implement a more realistic version of the VE in a CAVEÖ, a room-sized visualisation system. Initial feedback from mining colleagues indicates that the training VE may replace normal classroom training for preshift inspections in the future. As opposed to PowerPoint presentations and instructional videos, the training VE provides better spatial understanding of the location of parts and incorporates interactive features to actively engage drivers in the learning process, which may result in better retention. Initial feedback also indicates that minor improvements can be made to the virtual tour and virtual inspection phases.

Jan 1, 2008

By Weibai Hu

Four methods to assess the relative flotability of fine coal have been tested: flotation with frother only, flotation with frother and collector, salt flotation, and timed-release analysis. A practical and simple criterion which combines the separation efficiency (capacity factor and kinetic rate constant (intensity factor) has been suggested. Five coal samples are chosen and tested. Based on test results, it is concluded that the flotability test with collector and frother is closer to practice, and, according to the suggested flotability criterion, coal fines can be classified into four categories of relative flotability: very easy, easy, moderate, and difficult.

Jan 1, 1987

By J. A. Hudson

"The paper begins with a brief summary of Professor Müller’s formation of the ISRM and the contents of the previous six Müller lectures with their emphases on rock fractures. The geological origin of fractures is described via a deformational spectrum diagram and a matrix characterising the consequences of a sequence of superimposed deformational events. The different fracture frequencies encountered along lines in all directions through a fractured rock mass are explained. The value of computer modelling and simulation is demonstrated through an example of the effects of fracture zones on the distribution of the in situ stress field. The need to establish the validity of computer programs, i.e., that the modelling/simulation, does actually represent the rock reality, is discussed with reference to the work of the DECOVALEX project. Finally, examples are given of the effects of rock fractures on engineering design and construction, from pre-split blasting to caverns.INTRODUCTIONIt is a great honour to have been chosen as the recipient of the ISRM 7th Müller Award and I am grateful to the representatives of the International Society for Rock Mechanics (ISRM) National Groups who voted for me. In addition, I am especially pleased because my working life in rock mechanics and rock engineering has been devoted to understanding the geometry and mechanical properties of rock fractures and rock masses—which were the key subjects that Professor Müller promoted. In the ISRM 50th Anniversary Commemorative Book, Hudson and Lamas (2012), Professor Charles Fairhurst notes that on 24 May 1962, i.e., the day before the constitutional meeting of the ISRM took place in Salzburg, a reporter asked Professor Müller, “Do we know the strength of rock?”, to which Professor Müller replied, “For rock tested in the laboratory, yes. For a rock mass, no. This is what we need to determine. This is why we need an International Society for Rock Mechanics”. Also, in his Opening Address at the 1st ISRM Congress in Lisbon, Professor Müller, as the then ISRM President stated,“Many experts agree with me that discontinuity and anisotropy are the most characteristic properties of the material rock and that the properties of jointed media depend much more upon the fabrics bond of the unit rock block system than upon the rock material. Therefore any theoretical investigation of that material has to go its own ways, in the same way as the construction material of soils years ago suggested to soil mechanics its own methods, which differ greatly from the way of thinking of technical mechanics”."

Jan 1, 2015

By W. L. Acherman

Molybdenum, tungsten, and vanadium were found by the Bureau of Mines to possess generally superior chemical and galvanic corrosion properties in many aqueous corrosive media at temperatures up to the boiling point. The corrosion resistance of vanadium in certain solutions was further improved by alloying it with such metals as columbium, tantalum, and titanium. was susceptible to a type of crevice corrosion in mercuric chloride solutions, but no other instances of crevice corrosion were encountered. With few exceptions, molybdenum, tungsten, and vanadium were not adversely affected when coupled with dissimilar metals in galvanic corrosion experiments; in some cases one or both members of a couple were protected by contact. When exposed to aqueous ammonia spray at 60° C, all three metals were attacked, but they were moderately resistant in spray environments of substitute ocean water and ammonium dihydrogen phosphate.

Jan 1, 1966

By John Freeman

THE tensile properties of steels at elevated temperatures have been studied by numerous investigators,1 primarily for the purpose of determining their suitability for structural uses. Tests with this objective have been confined largely to the temperature range of approximately 20° to 500° C., because of the rapidly decreasing tensile strength at the latter temperature. Tests have also been extended to higher temperatures for the purpose of determining the most suitable forging range. This temperature range is also of theoretical interest. The phenomenon of increased tensile strength and decreased ductility in the so-called "blue-heat" range, approximately 200° to 300° C., is well known. It was suggested to the Bureau early in 1926 that a study of the properties of rail steels in this temperature range might prove of interest in relation to the studies of transverse-fissure failures in rails. There were available from another investigation3 several new rails from several different heats made to approximately the same specification requirements, the complete manufacturing histories of which were known. It was decided to determine, at least in the preliminary series of tests, only the ultimate tensile strength, elongation and reduction of area, because of the difficulty, time and cost involved in determining the proportional limit and yield point at elevated temperatures.

Jan 1, 1930

By Robert C. Gabler

Evaluation of incinerated sewage sludge as a secondary resource for aluminum, phosphorus, and minor constituents such as copper and zinc was initiated as part of the Bureau of Mines secondary resource program. The elemental composition of sludge ash for 14 plants in 11 U.S. cities was determined. Comparing industrialized cities with cities where most of the sewage is domestic, significant differences in heavy metal content were noted. Various parameters were investigated affecting the extraction of metals and phosphorus from a typical industrial city sludge ash and from a Palo Alto, Calif., sludge ash with a high precious metal content. Three extraction-recovery procedures for metals and phosphorus using sulfuric acid leaching, ion exchange, and various precipitation techniques were investigated. The last procedure developed was a combination approach using a three-stage countercurrent sulfuric acid leach that recovered most of the economic values from the sludge ash and also removed the leachable fraction of elements of environmental concern.

Jan 1, 1979

By Jonathan K. Hrica, Brianna M. Eiter

The ability to identify hazards during a workplace examination is a critical skill for mineworkers to have in order to maintain a safe workplace. While research suggests that being able to successfully recognize hazards requires a complex set of competencies, it is unclear which competencies are most critical to adequately perform a workplace examination. This paper presents a hazard recognition competencies framework as an explanation of the competencies that affect mineworker hazard recognition. To better understand how the industry is selecting and preparing workplace examiners, researchers fromthe National Institute for Occupational Safety and Health (NIOSH) interviewed nine health and safety (H&S) professionals at surface stone, sand, and gravel mine sites throughout the USA. A primary purpose of these interviews was to verify the competencies included in the hazard recognition competencies framework and to understand why these competencies are critical. Finally, the results of this study are presented within the context of current NIOSH research findings related to hazard recognition.

Jul 27, 2020