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By C. M. Harrer

This paper describes the location, features, qualities, extent, and potential of iron occurrences and some associative resources -limestone and dolomite, coal, petroleum and natural gas, power, and water - in New Mexico. Reconnaissance investigations were made of 118 iron occurrences to deter-mine their extent, attitude, and potential; character samples were analyzed to determine their quality and impurities; and pioneer metallurgical investigations were made on character samples to present their metallurgical problems. Some factors influencing past and potential iron markets are discussed. The most abundant iron minerals are magnetite and hematite. The higher grade deposits are extensive contact-metamorphic and pyrometasomatic replacements in calcareous Paleozoic rocks associated with intrusives. Low-grade deposits of considerable potential are the extensive Cambrian oolitic hematites of sedimentary origin and the Precambrian magnetite-hematite taconite iron formation. Iron occurs also as extensive colluvial and alluvial concentrations. A wide variety of accessory elements are indicated and these pose metallurgical and economic problems.

Jan 1, 1963

By R. J. Leary

Significant improvements in surface conditions or mechanical properties of steels have been attributed by several investigators to ladle additions of small quantities of rare-earth metals or their oxides. To investigate systematically these effects in wrought and in cast plain carbon and alloy mechanical steels containing approximately 0.35 percent carbon, heats of four representative compositions were melted by the Bureau of Mines in a 4-ton open-hearth furnace. Each heat was cast into three sets of ingots to exemplify respectively, treatments with (1) rare-earth metals, (2) rare-earth metal oxides, and (3) an untreated set as a control. The development of melting, casting and rolling practices is described and discussed. Lance injection of oxygen shortly after melt raised the temperature of the metal immediately as much as 500° F., principally because mechanical agitation exposed the high-carbon metal to the flame and furnace root. An exceptional degree of superheat in the metal at the termination of the refining period was attributed to oxygen injection during the refining period. Bath temperatures higher than industrial practice were permitted by the all-basic furnace lining. Rates of carbon elimination as high as 0.036 percent carbon per minute were achieved by oxygen injections.

Jan 1, 1961

By W. H. Zieman

"THIS IS THE THIRD of the consecutive Annual Forums on Grinding that were instituted by Mr. L. E. Djingheuzian in 1957. The first was on the subject of Ball Milling (Transactions, Volume LX, 1957) and the second on The N on-Cataracting Ball Mill (Trans-actions, Volume LXI, 1958). From the discussions at these forums it was evident that one of the most important factors affecting the efficiency of grinding is the shape of the liners. In order to make a study of liners in use, it was •decided to seek the co-operation of operators across the country by sending out questionnaires requesting basic information. Additionally, these operators were urged to set down briefly any pertinent information on the subject acquired through experience and experiments at their own particular plants. A compilation and analysis of these data were to form a basis for discussion at the Forum on Liners at the Annual Meeting in Montreal, April, 1959. The response of the milling fraternity to this solicitation was most gratifying, and clearly indicated the importance attached by the operators to the effect of liner design upon overall grinding performance."

Jan 1, 1959

By E. P. Youngman

Before the World War the use of zirconium and its compounds was largely experimental and confined almost wholly to Germany and Austria . Occasionally small lots of zirconium ore had been produced in the United States ( 1,000 pounds in 1869 , 26 tons in 1883 , and 3,000 pounds in 1903 ) and used (with monazite ) in the manufacture of various lighting devices , especially incandescent gas mantles ; but it was not until 1906 that the discovery of the natural zirconium oxide in large quantities near Sao Paulo , Brazil , first gave promise that a zirconium industry eventually might be developed . Edward Rietz , who worked the Brazilian deposits , interested German chemists in extending the use of zirconium , and by 1911 trade journals were listing German firms as manufacturers of compounds or products derived therefrom . For a time zirconia was one of the various oxides used in the Nernst lamp . It was used also for crucibles and hearths as refractory material ; in the manufacture of chemical utensils ; in enamels ; in the place of bismuth subnitrate for defining Röntgenray pictures of the stomach ; as a pigment ; in medicine ; and in a number of other ways . The Germans were credited also with producing a remarkable zirconium steel , which , it was claimed , was much superior to other alloy steels . During the World War the United States Government investigated the possibilities of zirconium , as well as those of other steel -hardening elements , and a large automobile manufacturer actually purchased a substantial quantity of ore with the purpose of employing zirconium in automobile steels . Immediately after the armistice the Government ceased its investigations ; but despite the difficulties experienced by various investigators in reaching concordant results , interest in the use of zirconium as a steel -hardening agent , as well as in other uses of the element and its compounds , continued . In 1918 the Foote Mineral Co. , which had been interested in zirconium for several years , was exploiting the deposit in Brazil formerly worked by the Germans and was supplying zirconia in the form of ore , brick , and cement for refractory and other purposes . About the same time the Electro Metallurgical Co. , which before the entrance of the United States into the war was experimenting with zirconium alloys , supplied in tonnage quantities the demand for these alloys . In 1919 it was reported that American manufacturers , after several years of research, were producing in commercial quantities pure zirconium oxide , which was finding a place in the manufacture of small refractory articles , scorifying dishes , crucibles , tubes , and one- piece furnace linings . In 1920 the lowering of the price of zirconium metal powder ( because of improved metallurgical methods ) promised the production of the metal on a semicommercial scale . In 1924 the Titanium Alloy Manufacturing Co. introduced a new opacifying agent , " Opax , " made from zircon . A year or two later some of the large pottery manufacturers became interested in the use of zirconium oxide as an opacifying agent , the increased production of titanium pigments having resulted in the production of zirconium as a by-product at a price that could compete with tin oxide . In 1928 it was reported that the industrial use of zirconium oxide was increasing steadily in the manufacture of brick , crucibles , and other refractory products , such as high- temperature cements . However , the reluctance of producers to install additional and more suitable

Jun 1, 1931

By Barry L. Warner

This program involves the evaluation of means for suppressing fires on underground coal mine conveyor belts. Full scale conveyor belt fire tests were conducted to determine the requirements of automatically actuated water sprinkler, high expansion foam, and multi-purpose dry powder extinguishing systems, and of various fire detection devices, necessary to adequately protect underground belt heads. The program included the development of a suitable MI scale conveyor belt test fire, conducting of fire tests in which extinguishing and detection systems and equipment were evaluated, and testing to evaluate the effects of the coal mine environment on detection equipment. Preliminary testing conducted to develop a suitable test fire revealed that fire can propagate on some conveyor belting classified as fire-resistant. New fire-resistant PVC and new non-fire resistant rubber belts were used in the full scale fire tests. These tests indicated that a single branch line sprinkler system with relatively low water pressure provides adequate belt head protection. High expansion foam and multi-"purpose dry powder extinguishing systems as presently specified by regulation were found to be suitable for belt head protection, although care is required with powder systems to assure adequate distribution. Thermal type detection devices were found to be most practical for conveyor belt protection, with combustion products and optical detection methods having serious disadvantages.

Jan 1, 1974

By Norman A. Pace

This paper is one of a series being published by the Federal Bureau of Mines on methods and practices used in mining and preparing crushed stone for market. Performance, in terms of units of work or tons produced per machine and per operator man-hour, is given whenever that information can be obtained. Direct operating costs are useful for comparing different methods and are included, if available. In addition to describing equipment and methods used} the Bureau considered it desirable to discuss the engineering reasons for the choices that have been made. This paper is particularly concerned with operation of the Camak quarry and plant of the Weston-Brooker Co. The quarry and plant are near Cedar Rock, north of State Highway No. 80 and east of Middle Creek in Warren County, Ga., and about 40 miles west of Augusta. Rail access is by a spur line of the Georgia Railroad from Camak, 5 miles southwest. The main office of the company is at Cayce, S. C.

Jan 1, 1959

The ability to track miners and communicate with them while they work in underground coal mines is important during normal daily operations, and critical in emergency conditions. As was evident during recent incidents at underground coal mines worldwide, communication with miners and the knowledge of their location is of great importance for rescue efforts and the preservation of life. Numerous technologies have been developed, adapted, and deployed to meet tracking requirements of the Mine Improvement and New Emergency Response (MINER) Act. Evaluating the performance of these systems has proven to be difficult for mine operators, system manufacturers, and regulatory agencies. The MINER Act of 2006 requires operators to improve accident preparedness by developing an emergency response plan specific to each mine. With the recent implementation of the provisions of the MINER Act of 2006, all underground coal mines in the United States are subject to the mandates of legislation concerning communication and tracking system installation. As of June 2011, 203 new or revised tracking and/or communication systems had been approved by the Mine Safety and Health Administration (MSHA), with nearly 50 other systems or revisions in the approval process (MSHA, 2011). At that time, the available approved systems for underground coal mine use included these types: ? Leaky Feeder Communication Systems ? Fixed Node-Based Communications and/or Tracking Systems ? Wireless Node-Based Communications and/or Tracking Systems ? Medium Frequency (MF) Communication Systems ? Communication System Peripherals Other types of tracking systems have since been developed and some manufacturers are seeking approval for use in this application. Some of the new products include Through-the-Earth (TTE) systems and various radio frequency (RF) adaptations. New technologies that are currently being developed and deployed in other industrial applications should also be considered, including acoustical, optical, inertial, and hybrid technologies To date, no uniform method has been employed in the industry to effectively compare and evaluate the performance of installed systems. Neither industry operators nor regulatory agencies can accurately assess the capabilities of installed systems in the continuously changing mine environment. There is need for a uniform evaluation method that provides the ability to assess how different systems and technologies perform in various mining applications, and whether they can satisfy the regulatory requirements.

Feb 23, 2014

By Philip C. Tully

This bibliography contains 2,072 citations to technical and scientific literature about helium and alpha-particles abstracted by 12 abstract service publications during 1962. Citations are listed by 16 major subject classifications with several subclassifications to minimize areas of literature search. Automatic data processing was used to reduce the time and labor required to compile the bibliography.

Jan 1, 1969

By P. R. Clark, M. D. Gleghorn

"IntroductionAt TransAlta Utilities Corporation's Highvale Mine, located west of Edmonton, Alberta (Fig. I and 2), dragline stripping has proved to be a practical and economical method of overburden removal and future plans have been based upon the continued use of draglines (Fig. 3) as the major stripping equipment (Williams, 1979, Nikols et al., 1986). However, long range planning has shown that the capacity of draglines alone will be exceeded in the early 1990s as mining progresses into deeper overburden cover (Tapics, 1983). Strip ratios will increase from I.3 bank m!/ t of coal in 1985to 4.5 bank m3 / t in 1995. During this period the depth of overburden will increase substantially and the areas to be mined will be characterized by weak soils including glacially displaced overburden. This increased overburden depth in relatively weak soils will make it impractical to _continue side casting by draglines without prestripping in advance. In 1983, a major investigation was initiated to determine what additional overburden removal equipment was appropriate to the Highvale operations, and recognizing the long delivery times of this major equipment. when it would be required. This paper describes studies and tests which were undertaken in 1983 and 1984 to select prestripping methods and equipment for the future operation of the mine.Previous planning studies have shown that with the current burn schedule and with the economies of progressing from low cover to high cover, as has been practiced in the past, overburden volumes will exceed the capacity of the existing draglines in the early 1990s (Fig. 4). These previous studies had placed reliance on (I tandem dragline operation for future overburden removal requirements up to a depth of 45 m throughout the Highvale Mine. New drilling together with the associated geotechnical studies and some detailed planning on the practicality of using tandem draglines, created concerns about their universal application. Even without considering geotechnical conditions there was a depth limitation to tandem dragJines and substantial prestripping would be required to achieve the ultimate depths."

Jan 1, 1987

By Afshin Sadri

Uma das principais razões para o reparo de altos-fornos é a perda do revestimento refratário, principalmente nas regiões da soleira e onde são feitos os furos de corrida. A operação intensa dos altos-fornos pode resultar em desgaste e deteorização extensiva do material refratário. Isto pode, então, afetar a continuidade das operações e a vida útil do forno. Novo-Lipetsk (NLMK) e a Hatch desenvolveram uma abordagem sistemática para monitorar a condição do revestimento da soleira dos altos-fornos usando Acousto Ultrasonic-Eco (AU-E), um sistema de ensaios não-destrutivos desenvolvido pela Hatch. Inspeções contínuas e periódicas dos altos-fornos revelaram áreas com deterioração acelerada do material refratário, formação extensa de “elefant foot” e acelerado desgaste do refratário, assim como fissuras e outras anomalias. Para prolongar a vida do forno, mantendo a intensidade de suas operações, algumas modificações, tais como a melhoria da qualidade do coque e da limpeza das placas de resfriamento e adição de óxido de titânio, entre outras medidas, foram recomendadas e aplicadas. Este trabalho demonstra como esforços coordenados entre a NLMK e a Hatch resultaram no prolongamento da vida útil de um alto-forno

Aug 17, 2017

By V. T. McLemore

"Production of industrial minerals remains important to the rural economy of New Mexico. In 2014, some 240 mines were registered in New Mexico, including 25 industrial mineral operations and 189 aggregate operations. New Mexico leads domestic production of potash, perlite, zeolite, and travertine. Other production includes aggregate, humate, pumice, gypsum, salt, common and fire clay, scoria, limestone, fly ash, cement, magnetite, silica, and decorative stone. New Mexico has potential for additional production of industrial minerals. One company is exploring for garnet. Cretaceous black sandstones in the San Juan Basin have drawn interest for titanium, rare earth elements (REE), and zircon. Other REE deposits are being explored. REE-Th-U veins are found in the Gallinas, Capitan, and Cornudas Mountains and Laughlin Peak-Chico Hills. Recent exploration has occurred for beryllium in the San Mateo Mountains, Iron Mountain, and Victorio districts. Companies also are examining High-Ca limestone and High-Mg dolomite for potential development. Aggregate continues to be important in urban areas and along highways. INTRODUCTION Industrial minerals and rocks are literally the building blocks of our way of life and they are an exceptionally diverse and vital group of raw materials that underpin almost all aspects of human activity, infrastructure, and standard of living. Industrial minerals and rocks are used in the manufacture of many products, from ceramics to plastics and refractories to paper. Although industrial minerals permeate every aspect of daily life, their presence and their role are typically invisible. A widely used definition of industrial minerals and rocks is “any rock, mineral, or other naturally occurring substance of economic value, exclusive of metal ores, mineral fuels, and gemstones: one of the non-metallics” (Bates, 1975). This definition includes the important construction materials sector as well as specialized industrial minerals, but complex interactions between consumer industries produce a number of apparent anomalies to this definition. Some metals are included as industrial minerals because their use is industrial rather than as a metal. Sulfur is now predominantly extracted as a by-product of cleaning natural gas, one of the world's major energy fuels. Production of industrial minerals has been and remains important to the rural economy of New Mexico. Industrial minerals constitute nearly 40% of the more than $2.8 billion generated by mineral production in New Mexico in 2013 (Table 1, see APPENDIX). In 2015, some 240 mines were registered in New Mexico. This total includes 25 industrial mineral operations and 189 aggregate operations. New Mexico leads domestic production in potash, perlite, zeolite, and travertine. Other industrial minerals production from New Mexico includes aggregate, humate, pumice, gypsum, salt, common and fire clay, scoria, limestone, fly ash, cement, magnetite, silica, and decorative stone. Additional production statistics are in Harben et al. (2008). Major industrial mineral districts are shown in Figure 1."

Jan 1, 2016

By P. Diehl, M. David

"As shortage in the supply of mineral commodities become more probable, there is an increasing need for reliable and comparable reserve/resource data. It is therefore necessary to standardize the traditional classification procedure by quantifying the three basic criteria in resource evaluation: economic feasibility, geologic assurance and recovery. For the portion of fairly well documented deposits and as far as their geologic parameters are concerned, geostatistical methods can considerably improve the quality of ore classification. In respect of economic feasibility and recovery, approved geostatistical methods can be introduced directly into the classification procedure. The concept of geologic assurance, however, requires a new interpretation in terms of geostatistical error spread. As the ""risk"" in estimating an ore parameter is also a function of the respective block size, it is reasonable to define not only upper limits for the risk intervals for each class of uncertainty, but also block dimensions which reflect the typical stage of planning associated with the different ore categories. An algorithm has been developed to block out areas inside a mine or a large panel which satisfies the constraints of an ore category in respect of the risk intervals of a parameter and in respect of their size. The method has been computerized and is demonstrated on a massive copper-nickel deposit.IntroductionFacing an uncertain future with respect to the demand and supply of mineral commodities, both governmental authorities and the mining industries show an increasing interest in a useful framework for the assessment and classification of the remaining mineral resources"". This is reflected by the recently published appraisal and classification scheme of the United Nations as well as by the new or revised classification systems of the USA; Canada or Australia. Moreover there are various classification schemes which are currently discussed in major mining companies."

Jan 1, 1982

By S. Kodama

Starting on a small scale, the equipment for processing synthesis gas to form liquid hydrocarbons was expanded to handle 100 m) 3/hr. This reactor was successfully designed and constructed, and a basis for future design methods was established. Because, however, this work was carried out on an empirical basis, it is felt that a more thorough theoretical study should be made in an effort to increase the efficiency of the process, particularly in the development of a simpler converter.

Jan 1, 1951

By Beth Robinson

Central Mexico's mining districts, opened centuries ago during the Spanish conquest, still form the backbone of metal mining in the country today. Beginning at Chihuahua City, the Second Mexican Mining Rail Excursion traveled southeast from camp to camp through this major mining area to Taxco. Improved exploration, exploitation, and beneficiation methods have permitted continuous mining of many old deposits, and led to the discovery of new ones. Minerals not sought by early miners-lead, zinc, copper, and fluorite-now contribute substantially to mining activity in central Mexico. Of Mexico's five physiographic provinces, the rail excursion passed through two: the Mesa Central, and the Sierra Madre Occidental. The Mesa Central province is a wide tableland with basin and range topography, containing important base metal deposits. Mining in this region is primarily of limestone replacement ore bodies. Massive deposits form horizontal mantos or vertical chimneys. In northern Zacatecas, the Santa Eulalia and Naica mines demonstrated this character. The Sierra Madre Occidental lies west of Mesa Central in northern states, then widens to almost the entire width of the country from outside Mexico City to the southern border. The area consists of volcanic beds, several kilometers thick. These intermediate volcanics are primarily andesitic, of Tertiary age. Resting on older strata of adjoining physiographic divisions, the volcanic beds are overlain by a thick series of acidic flows and tuffs. Economic mineralization in the Sierra Madre Occidental is vein-type, primarily gold and silver. Mines at Fresnillo, Guanajuato, Pachuca, and Taxco contribute to the claim that this region is the center for precious metals in Mexico. A third type of mineralization, contact metamorphic deposits, is commercial at Santa Eulalia. First Stop, Santa Eulalia Mine tours began with the Santa Eulalia unit, located 25 km east of Chihuahua City. Mining in the region dates back to the early 1700s. The oxidation zone was worked until 1790, but mining declined until Asarco arrived in the early 1900s, building a selective flotation plant for treating primary sulfides. Asarco still owns 34% of Industrial Minera Mexico, S.A. (IMMSA), operator of the Santa Eulalia mine. Santa Eulalia currently has a milling capacity of 850 t/d. The San Antonio and Buena Tierra mines provide feedstock. Head grades at San Antonio, the mine participants toured, average 80-120 g/t of silver, 1.5-4.5% lead, 4-16% zinc, and 0.1-2.5% copper. Tin and vanadium were also recovered between 1930 and 1940. Estimated proven and probable reserves total about 7.6 Mt, although 1.8 Mt of reserves are located in areas of high water pressure and volume, which makes extraction difficult. Water is a significant production problem at the San Antonio mine. In one area, an AX drill hole encountered 2.6 m3/min (700 gal/min) at a pressure of 2.5 kPa. Precautions are taken to cope with the problem: protective drilling in advance of blasting is performed;

Jan 2, 1982

By C. Overton, R. W. Nice

"With todays economic trials and tribulations we have all become deeply engaged in costs and cost cutting in our field of mineral processing. Grinding is one of the most expensive unit operations. The cost of grinding media is the most expensive item in grinding costs. Therefore, it is only reasonable to attack the cost-cutting area by trying to reduce the consumption of media. This introduces the field of autogenous or rock-on-rock grinding.Rock-on-rock grinding is not new to us. It has been known for many decades;The South Africans used pebble grinding in the '20's for gold.Mr. B. Crocker was prompted for the same reasons to introduce pebble grinding at Lakeshore Mines in Kirkland Lake during the last war.The Buffalo Anchorite used beach pebbles in grinding prior to the war.Autogenous and semi-autogenous grinding is used quite successfully in the iron ore field. Base metals have their examples in Australia at Caba, in Africa at Komato and in Sweden at Aitik.Recently three mills in British Columbia and one in Arizona started with autogenous mills in their circuits. One was originally conceived to utilize a modified autogenous grind with a crusher in the circuit. All except the same mill had contingency plans for converting to semi-autogenous. All four mills have since converted to the semi-autogenous mode. These are Island Copper, Lornex, and Similkameen in B.C. and Pima Mining in Arizona."

Jan 1, 1975

By Wignall. T. K., J. De Geoffroy

Statistical models are fitted to the observed distributions of eighteen characteristics of the population of commercial porphyry deposits of North and South America. The statistical base required for the formulation of the statistical models includes 58 commercial porphyry-copper-molybdenum deposits of the Cordilleran Belt from which geological, geometric and economic data were collected. Predictive and composite models are derived from the statistical study to assist explorat10n. planning, engineering studies and fmanc1al analyses as required for the development of new porphyry deposits in the Cordilleran Belt.

Jan 1, 1973

By Thomas S. Jones

This Bureau of Mines publication reviews characteristics, manufacture, and uses of natural and synthetic iron oxide pigments. Supply and demand trends within the domestic industry and in foreign trade are presented for 1955 through 1976. Iron oxides are expected to continue in demand for traditional uses, and if anything, to be favorably affected by technological developments. Imports have been significant in relation to domestic production, most notably for synthetic oxides from West Germany and Canada.

Jan 1, 1978

By Ebrahim Ghasemi, Mohammad Hossein Kadkhodaei, Mosareza Jalilian

Entry-type mining methods, such as cut and fill method, play a significant role in underground mining, and they are still suitable methods for extracting deposits with irregular shapes and with weak host rocks. In these mining methods, the stability of the open spans is important for improving worker safety and increasing ore recovery. This study focuses on the application of six data mining classification methods, namely multinomial logistic regression (MLR), classification and regression trees (CART), logistic model tree (LMT), decision tree (J48), multivariate adaptive regression spline (MARS), and gene expression programming (GEP), in order to develop predictive models for stability assessment of underground entry-type excavations. For this purpose, a database containing 399 case histories of entry-type excavations from seven Canada underground mines was used. These models predict the stability status of entry-type excavations based on two input parameters, dimensions of the span and rock mass rating (RMR). The performance of developed models was evaluated using six performance metrics namely accuracy (ACC), sensitivity (SE), precision (PR), Matthew’s correlation coefficient (MCC), area under the receiver operating characteristic (ROC) curve (AUC), and performance index (PI). The results showed that all developed models can be used to predict the excavation stability, but the comparison of models indicated that the J48 model provides the highest performance with ACC = 0.900, SE = 0.869, PR = 0.922, MCC = 0.835, AUC = 0.891, and PI = 4.417. Thus, the proposed J48 model can be applied to identify the susceptibility of span instability in the entry-type mining, and if instability has been predicted, the necessary measures, including the use of suitable support systems, can be considered to reduce the casualties resulting from span instability.

Feb 26, 2024

By A. Mitrašinovic, A. Wolf

"The aim of this investigation was to determine the most suitable additive for recovering metals from converter slags generated during Ni extraction. Fluxes analyzed were silica and lime and reductants included pig iron, ferrosilicon and copper-silicon compound. Slag was settled at 1300°C for one hour to simulate the smelting environment. The newly formed matte and slag were characterized by chemical composition and morphology. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with traces of magnetite. Entrained matte was present in the slag mostly as prills of Ni3S2-FeS matrix and a Cu2S-FeS secondary phase below 10µm in diameter. Kinetic parameters of matte formation, valuable metal recovery rates and partition coefficients were deduced. Silica additions generated higher partition coefficients for copper and nickel than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and partition coefficients. Silica additions favoured the formation a higher grade matte while lime additions will hinder metal recovery. Pig iron, ferrosilicon and Cu30Si were the most effective reductants for valuable metals recovery. Cu10Si and coke additions had little to no effect on valuable metals recovery."

Jan 1, 2015

By B. Mishra, W. A. Averill

"The application of various hydrometallurgical, pyrometallurgical and electrochemical processes in the extraction, purification and production of radioactive metals as well as the use of various materials, ego metals and alloys, ceramics, polymers, etc. in the process, construction and handling equipment in the nuclear industry has generated a large stockpile of radioactively contaminated waste material and scrap metal which can not be directly discarded, recycled or considered for long-term storage due to its volume and potential hazards, without the separation of radionuclides. This paper reviews the emerging methods that have been investigated and suggested for dealing with some of these wastes and scrap material.The separation technologies studied for the recovery of radioactive components from the pyrometallurgical and electrochemical processing wastes have been discussed in details with results from some of the recent theoretical and physical modeling work as well as the data obtained from the actual waste treatment. Specific processes shall be described in terms of its advantages and limitations. These emerging separation technologies are being considered by the US Department of Energy as alternatives for dealing with the issues of environmental management [EM] and decontamination and decommissioning [D&D].IntroductionThe high temperature carbothermic or metallothermic smelting reduction methods for metal production are associated with the generation of significant quantity of waste as slags, flue dusts, sludges, residues, effluent salts etc. Certain hydrometallurgical processes also generate lots of aqueous waste due to the inherent nature of the technique. Also, the gas-based reduction processes are not applicable to many stable metal compounds, such as alumina, titania, beryllia, lanthanide and actinide oxides, etc. due to thermodynamic considerations. All these methods cause substantial environmental hazard. There is a need to develop alternative processes which have low waste or ideally a ""zero-waste"" generation.Pyrochemical processes using molten salts provide a unique opportunity for the extraction and refining of many reactive and valuable metals either directly from the beneficiated ore (aluminum, beryllium, neodymium, plutonium, uranium, etc.) or from other process effluent that contain reactive metal compounds. The processes reduce metal compounds electrolytically (A12O 3 and BeCI2) on a carbon anode or by calciothermic reduction (Po, Nd). The by-product, in the latter case, is a calcium oxide saturated halide salt. The waste-treatment to recycle the halide has to be done as a separate step or stored as a contaminated waste. A successful separation technology can provide a new insight to the waste minimization strategy for the nuclear industry."

Jan 1, 1996