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By Erich U. Petersen, J. B. Hiskey, William J. Tafuri, Donald M. Hausen, X. H. Jiang, Douglas N. Halbe, G. Ramadorai

The extraction of gold from chloride solutions with activated carbon is examined. It is shown that the uptake of gold by activated carbon from chloride solution follows a mechanism whereby gold is reduced to the metallic state. Metallic gold appears as deposits both on the carbon surface and in pore space within the carbon particle. The deposition rate is dependant on the carbon particle size and pH. At low initial gold concentrations, the initial rate is insensitive to gold concentration. Sodium hypochlorite exhibits an adverse effect on the reduction reaction. The overall loading and initial rate of reduction are both decreased in the presence of NaC10. The effect of iodide on the loading of gold was also examined in an attempt to overcome the superficial deposition of gold on carbon.

Jan 1, 1990

By Meliton M. Garcia, Satya Harpalani

This paper discusses the results of an investigation carried out in an underground mine to characterize the volatile by-products adsorbed on airborne particulates following the detonation of four common explosives including ANFO. The primary objective of this study was to determine if any organic amine compounds, particularly nitrosamines, and any polycyclic aromatic hydrocarbons were produced and trapped in the dust that a miner might inhale during the workday. The production of these substances is of great concern because of their suspected carcinogenic nature. The results of the study indicated that a large variety of the by-products are adsorbed on the particulates generated, and thus remain airborne following the detonation of explosives. The major by-products retained by the dust were bis(2-ethylhexyl) phthalate, and aliphatic hydrocarbons with carbon chains ranging from C12 to C28. One explosive, a water gel, produced the polycyclic aromatic compound, trimethylnaphthalene. No nitrosamine compounds were detected.

Jan 1, 1989

By James A. Jones

The Doe Run Co. emerged from the depressed lead market of the mid-1980s as North America's leading lead producer. Doe Run was lean and mean but quickly recognized that technology had advanced while the company was held to the belt tightening slump. With the 1990s approaching, Doe Run moved quickly to update its technology and control equipment to ensure its position as an industry leader. Doe Run was formed in 1986 when Fluor Corp. and Homestake Mining Co. combined their lead-zinc-copper assets in Missouri to form a joint venture. Doe Run is now owned by Fluor Corp. A rich history of mining, milling and smelting started in Missouri in 1862 when the St. Joseph Lead Co. was founded. Subsequent acquisitions led to the formation of St. Joe Minerals, which was later purchased by Fluor Corp. Six mines, four concentrators and two smelters are presently being operated, and a secondary lead smelter was recently commissioned. The Viburnum, Buick and Fletcher operations are lead, zinc and copper flotation concentrators, while the Brushy Creek plant is set up to process high copper-low lead ores. This article looks primarily at the process control installation at the Fletcher concentrator.

Jan 1, 1991

By K. N. Han

The leaching behavior of palladium in ammoniacal solutions was investigated by using the rotating-disk technique in an autoclave. The study included the effects of rotation speed, temperature, oxygen pressure, composition of ammoniacal solutions and catalysts on the overall leaching rate. The dissolution of palladium in ammoniacal solutions was discussed in terms of the thermodynamics and a kinetic model. Even though the Eh-pH diagram suggests that palladium metal can dissolve in ammoniacal solutions at room temperature, it was found that the dissolution was very slow at temperatures below 100 °C but was significantly improved at higher temperatures. It was also found that the rotating speed of the palladium disk had no effect on the leaching rate. The apparent activation energy was found to he 69.7 kJ/mole. Based on the results obtained, it was concluded that the dissolution of palladium is controlled by chemical reaction.

Jan 1, 1999

By M. S. Enders

The McDonald gold deposit is located in the upper Blackfoot Valley in Lewis and Clark County in west-central Montana, about 65 km (40 miles) northwest of Helena and 13 km (8 miles) east of Lincoln (Fig. 1). The McDonald project area covers about 20.7 km2 (8 sq miles) of elevated terrain on the north side of the Blackfoot Valley. The Blackfoot River lies 1 km (0.6 miles) south of the McDonald deposit. East Butte and West Butte rise 300 m (985 ft) above the Blackfoot Valley to an elevation of 1,750 m (5,740 ft). They conveniently divide the area into two parts. The Seven-Up Pete Joint Venture (SPJV) is a partnership between Phelps Dodge Mining (72.25%) and CR Montana, a subsidiary of Canyon Resources (27.75%). SPJV controls about 83 km2 (32 sq miles) of mineral and surface rights in the Lincoln area. The McDonald project is on state-owned and private land. The joint venture has conducted exploration since 1989 at the Seven-Up Pete, McDonald and Keep Cool areas (Fig. 1).

Jan 1, 1995

By C. K. Blair, V. J. Hucka, E. P. Kimball

In central Utah, a coal mining operation is taking place under an 0.5-m (20-in.) pressurized natural gas pipeline. The room-and-pillar method with pillar extraction is being used to extract the coal from the seams. The pillars beneath the pipeline will not be extracted; however, there is a possibility that some subsidence may occur due to pillar failure. To assess possible damages on the pipeline, an attempt has been made to predict subsidence in the area where pillars may collapse. The resultant values of subsidence strain and slope have been used to determine the magnitude of strain, stress, and shear induced in the pipeline. Also, a network of survey points has been installed along the pipeline to detect ground move¬ment that would indicate excessive subsidence.

Jan 1, 1987

By R. A. * Russell, J. R. * Brooks, E. J. Griffith

In 1967, a major impoundment to contain phosphate tailings was built near Columbia, TN. Precise records were maintained on the behavior of the impoundment throughout its 20-year active life. The volume of the impoundment was determined. The DNT (dry net tons) of solids added to the impoundment were continuously measured. The rise of the mud line in the impoundment was measured monthly. The density of the settled strata was determined, as required to understand the behavior of the settled tailings. And experiments were per formed to increase the settled density of the clays. The impoundment is currently being retired and stabilized. It covers more than 400 acres and the settled muds are almost 200 ft thick. The clays have been sufficiently solidified with electroendosmosis to support the growth of cypress trees. More than three milllion trees are being planted.

Jan 1, 1992

By John G. Reid

Geologists, employed by the Australian Company, Metals Exploration Limited, discovered nickel laterite enrichment at Greenvale in 1967. A joint venture was arranged with the Freeport Minerals Company who had gained early experience with nickel laterite ores when building and operating the Nicaro and Moa Bay Treatment Plants in Cuba. A 5 tonne/day Pilot Plant at the Freeport research facilities at Belle Chasse, Louisiana, verified the amenability of the ore to treatment by the reduction and ammonia-ammonium carbonate leaching process used at Nicaro. A 5 800 tonne/day Treatment Plant was constructed on the coast at Yabulu, North Queensland. This paper describes the ore body, the mining operation and the stages of treatment required to produce nickel oxide products and a mixed nickel/cobalt sulphide product at Yabulu.

Jan 1, 1979

By D. Robert Weir, Roman M. G. S. Berezowsky

Pressure oxidation can virtually always render refractory auriferous sulphidic ores and concentrates amenable to cyanidation. Its effectiveness as a pretreatment of refractory gold feedstocks is reflected by the successful startup and operation, over the past four years, of four commercial plants. At least three more are scheduled to come on stream during the next three years. Over the past eight years, a variety of ores and concentrates have been subjected to integrated miniplant testing and process demonstration by Sherritt, and data derived from these studies have been used in the design and construction of several of the commercial facilities. Some factors affecting the selection of pressure oxidation in gold recovery processing are discussed.

Jan 1, 1989

By J. Hanna, J. Jung, I. J. Anazia

Electrothermal production of elemental phosphorous (P4) generates substantial amounts of highly toxic phossy water and sludges. Because of their high phosphorous contents and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations. To date, the sludges are stored in ponds or above ground in special containment vessels at various locations around the country. Two samples of electric furnace phosphorous sludge (obtained from the Tennessee Valley Authority (TVA) in Muscle Shoals, AL and FMC Corporation in Pocatello, ID) were investigated using physical separation techniques to recover the elemental phosphorous and to render the residual material nonhazardous. The techniques tested include sizing, froth flotation and dispersed air oxidation. Flotation and sizing produced concentrates containing 69% - 90%P4, with recovery in the range of 60% - 87%. Dispersed air oxidation of the fines and tailings products was effective in the removal of an additional 10% - 15% of the P4 in the sludge.

Jan 1, 1993

By Serkan Saydam, Ercument Yalcin

This paper presents the results of Caldagi Nickel-Cobalt Ore Deposit's, located in Turkey, reserve and ultimate pit limit design analysis. Reserve analysis of any deposit requires two steps. First one is to constitute of block model of the deposit and second step is to generate ultimate pit limit. The block model of the Caldagi ore deposit has been created by means of geostatistics. The reserves of nickel and cobalt in this block model are defined as resource, approximately 12 million tons of nickel and 1 million tons of cobalt with average grades of 0.9% Ni and 0.03% Co, respectively. Ultimate pit limit analysis has been performed by considering economic, technical and legal factors. In this paper, the ultimate pit limits are generated by Lerchs & Grossmann (L&G) algorithm. As a consequence of ultimate pit limit design, total amount of tonnage to be excavated is 1.4 billions of tons, 700 million of which contains ore and 747 million of which is the tonnage of waste.

Jan 1, 2002

By N. J. Themelis

It is a pleasure to introduce this session on frontier technology and present an overview of pyrometallurgical technology, as it is today and where it may be heading. While there have been many advances in hydro-metallurgical processing in our times, pyrometallurgy has not been still, and more novel processes have been introduced in the last four decades than in all previous ages of humanity put together. As a result, pyrometallurgy has managed to remain the predominant mode of producing metals from ores and concentrates: over 95% of the world primary metals production, including iron, manganese, copper, lead, chromium and nickel, is obtained via the high temperature route. Some of the characteristics of pyrometallurgy, along with the corollary industrial advantages are shown in [Table 1]: [ ] On the other hand, the necessity of operating at high temperatures also entails special problems and it is unfortunate that research on how to overcome these problems has not, in most cases, kept up with the development of these wonderful novel processes. We shall first speak of the important developments in pyrometallurgy which have brought us to the current state of the technology, and subsequently on the problems still encountered and the kind of research and development that will be necessary to bring pyrometallurgy on a par with other late twentieth-century technological developments.

Jan 1, 1985

By G. J. Melvin

Mines the world over tend to face a common range of problems. They begin life by trying to determine if there is sufficient product, usually under tons of earth, of sufficient quality to justify the operation. Once such a determination is made the mine must then be planned and brought into operation. Once operating most mines find that they are far away from suppliers, using very expensive equipment. Hence the three most common mining problems are, what does my ore body look like and how can it best be mined, how can I get sup- plies to my mine in the most cost effective way, and how do I control the vast dollars required to keep it all operating. Mincom started life by providing technical mining software to address the first of these problems and was very successful, particularly in the coal mining industry. However the company soon realized that if it was to become a significant provider of mining industry software it must also address the other major problem areas. Hence started what is now Mincom's largest business which is the provision of fully integrated mine management software with strong emphasis on materials and maintenance management to control costs. Mincom not only supplies the software but also provides a comprehensive implementation package using its own staff of experienced mining industry specialists. This papaer highlights some of Mincom's international implementation experiences.

Jan 1, 1989

By Samuel Frimpong

In this paper, the authors present a typical mine profitability model. The method of generating system moments is used to examine the sensitivity of the profitability function to changes in the dependent variables, and to express the expected risk associated with undertaking the project in a predicted economic and technical environment. Profitability of a mining venture is a function of many variables ore grade, capital and operating costs, milling efficiency, ore reserve tonnage and annual tonnage, equity - loan structure, tax regime, etc. Estimates of the expected value and the variance of the profitability function are obtained by calculating the partial derivatives of the function with respect to the dependent variables, using the Taylor series expansion method to the second order. Sensitivity analysis is carried out by examining the effects of each variable on the profitability function, which is determined by the magnitude of the product of its partial derivative and variance. An appropriate probability density function, based on the expected value and the variance of the profitability function, is assumed to estimate the expected risk associated with the project. This expected risk is a measure of the area under the profitability density function below the appropriate, selected discount rate or the cut-off net present value (NPV). The results are compared with those obtained by using the Monte Carlo simulation technique, and they show that either of the two methods could be used to evaluate the probability of project failure or success with no significant difference.

Jan 1, 1992

By Ora H. Rostad

The sequence of events preceeding the discovery of the Mount Emmons molybdenite include some inadvertent near misses by several groups. The events are given in general chronological order to bring out the essentially contemporaneous, but different activities by several groups in two areas on opposite sides of Mount Emmons. The Mount Emmons molybdenite deposit lies in the Elk Mountain mining district. The west edge of the deposit is near the boundary between the Elk Mountain and Ruby mining districts as shown by the USGS map included (see Fig. 1). Considerable history regarding the Keystone silver-lead-zinc mine is given because of its proximity to the Mount Emmons molybdenite deposit which is on the other side of the mountain from Redwell Basin and where other significant activities took place. It should be noted that there was no documentary evidence available to me that would indicate that molybdenite was recognized to be present on, or under, any part of Mount Emmons, including Redwell Basin, before 1970. Veins containing silver-lead-zinc minerals were discovered in the Elk Mountain and Ruby mining districts about 1872. Some discoveries on the south flank of Mount Emmons about 1880 were developed into the Keystone mine. The Keystone has the largest cumulative production of metal ores of any of the mines in these districts. Most of the 413 Mt (455,473 st) of ore produced from the Keystone mine through August 1967 was produced after 1950. The ore averaged 175.4 gt (5.64 oz per ton) Ag, 2.62% Pb, 5.56% Zn, and 0.72% Cu.

Jan 1, 1991

By S. J. Ripke

To pelletize fine moist magnetite concentrate, a 40% water slurry must be dewatered to about 10% by filtration, before it can be agglomerated into pellets. Slurry pH, typically ranging from 8 to 11, gives the magnetite particle surface a strong negative charge and thus causes two adverse effects. First, this negative charge attracts calcium and magnesium cations, which strongly retard the effectiveness of the bentonite clay binder added during agglomeration. Second, a repulsive force created by the negative charge functions as a dispersant that reduces filtering production rates. Tests were conducted to remove these cations during filtration, by rinsing the moisture remaining in the filter cake with a small amount of water adjusted to pH 6 with HCl. Laboratory work was also conducted at Michigan Technological University (MTU) and at Cliff’s Mining Services Company (CMSC) to corroborate the plant tests. In some cases HCl caused filter bag blinding, therefore CO2was investigated to reduce pH. The CMSC lab tests showed that using carbon dioxide to reduce slurry pH from 7.6 to 7.0 improved filtering production rates by 11%. Plant-scale filtering rates were improved by 23.7% when carbon dioxide addition reduced the slurry pH from 8.6 to 6.7.

Jan 1, 2004

By J. Trouw, W. de Bruijn, A. van Sandwijk, R. H. Heerema

Differential reduction and expansion or shrinkage of hematite under the influence of intimately associated foreign oxides may be a source of stress formation and sinter degradation during blast furnace reduction. To study specific effects, synthetically prepared hematite powder evenly doped with 1 % by weight of several elements present as oxides, was pressed into tablets and sintered at high temperature prior to reduction. Continuous theimogravimetric and dilatometric analyses were performed on the sintered tablets as these were being subjected to reduction under simulated blast furnace time/temperature/gas composition conditions up to 1183 K. These findings were coupled with observations on the microstructure of tablets removed from various stages of the reduction process. The results indicate that the degree of expansion or shrinkage of hematite during reduction is highly dependent upon impurities associated with the original material; marked differences in reduction rate and microstructure were observed as well. An important finding is that the influence of a particular additive can also strongly vary from one reduction stage to the next. The reduction behavior appears to be affected by the physical and chemical nature of the associations formed by the added elements.

Jan 1, 1990

By Shahid A. Pirzada, Milton Manrique, Patrick R. Taylor

Microsilica or silica fume is a waste material generated from silicon or silicon-containing alloys producing electric furnaces. One of its usage is as an additive in the concrete production. This investigation describes a process to use microsilica as a feed material to produce fine silicon carbide. A thermal plasma reactor is used to convert this waste material into a value added ceramic. Details of the theoretical considerations, experimental work, and characterization are presented in this work

Jan 1, 1995

By D. Y. Jiang, X. S. Tan, S. S. Peng

Expansion strain and stress that exist in floor rocks and that are due to the presence of water, were derived from a basic theory of mechanics. The results indicate that water stress and strain are the important factors that cause failure of the floor rocks and induce floor heave.

Jan 1, 1994

By V. Y. Kirillin, V. A. Rumjantsev, S. A. Tchesnokov, Yu A. Veksler, V. F. Kalmykov, A. N. Telgarin, A. T. Shakirov

Mining in outburst hazard seams may be safe and effective if some preventive measures, such as lowering gas and rock pressure as well as speed regulating of a continuous miner in cutting the seam would be practised. The driving speed should be optimal as the low speed lowers labour productivity but the high speed may cause gaso-dynamic phenomena. At this mine the driving speed is regulated by seismo-acoustic control of the seam condition.

Jan 1, 1985