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By S. Kelebek, S. O. Fekete

The flotation process developed at Falconbridge laboratories utilizes sulphur dioxide and diethylenetriamine (DETA) reagent combination in the depression of pyrrhotite to allow its separation from pentlandite and chalcopyrite. DETA by itself has failed to produce flotation selectivity with samples from plant and pilot plant streams which showed relatively high redox potentials. However, DETA was found to function effectively on laboratory-generated samples under certain conditions. The results of poor depression are in keeping with thermodynamic calculations which indicate that in the presence of sufficient xanthate and DETA, the formation of ferric dihydroxy xanthate and dixanthogen is possible under oxidizing conditions. The use of sulphur dioxide alone has also resulted in a rather poor depression of pyrrhotite. However, the combined use of these reagents has resulted in an efficient and consistent separation of pyrhotite from pentlandite and chalcopyrite. Various aspects of this selective flotation system are presented along with a discussion on possible operating mechanisms.

Jan 1, 1995

By A. W. Khair, J. A. Organiscak, M. Ahmad

This paper describes research that seas conducted on bit wear and respirable-dust generation. The investigation was performed by the US Bureau of Mines (USBM) and West Virginia University (WVU), a member of the Generic Technology Center on Respirable Dust. The USBM investigated wear, energy and dust characteristics of various conical bit designs when cutting rock. WVU studied the functional relationships between wear, cutting force, energy and dust of one type of conical bit cutting coal. The objective of the USBM study was to identify qualitative bit-selection guidelines. The objective of WVU's research was to determine optimum bit-replacement guidelines. Both research studies found that bit geometry (a function of bit design and wear) influences energy consumption and dust generation. Bit selection and replacement recommendations are given.

Jan 1, 1996

By D. W. Fuerstenau, J. Vazquez-Favela

This paper shows how the efficiencies of size-reduction processes depend on the mode of particle constraint and energy transfer within the comminution device: namely, whether the process consists of single-particle loading, confined-particle-bed comminution or loose- (unconstrained-) particle grinding. The relative efficiency of single-particle comminution, ball-mill grinding and particle-bed comminution in the recently invented high-pressure roll mill is evaluated by making use of the self-preserving nature of the size distributions of comminuted products. The highest energy efficiency can be achieved by utilizing a hybrid two-stage system in which the material is first ground in the high-pressure roll mill and then the ball mill.

Jan 1, 1998

By K. A. Natarajan, M. K. Yelloji Rao

The effect of galvanic interactions among sulfide minerals such as chalcopyrite, galena, and sphalerite in the presence and absence of a grinding ball material on the flotation recovery of chalcopyrite has been studied. X-ray photoelectron spectroscopy (ESCA) studies were carried out to identify the reaction products on the sulfide minerals after different apes of galvanic interactions. Galvanic contact with active minerals such as galena and sphalerite, either alone or together, significantly affected the floatability of chalcopyrite mineral, such an effect being more severely felt in the additional presence of a grinding medium as well as oxygen. Surface analysis studies revealed the presence of oxyhydroxide species of iron on all the sulfide mineral samples which were in prior contact with the grinding medium. The formation of such oxyhydroxide species of iron was found to be dependant on the relative electrochemical activity of the mineral. Probable electrochemical reaction mechanisms are discussed.

Jan 1, 1990

By Isobel Clark

Geostatistical methods of estimating ore reserves and other spatial phenomena are becoming increasingly wide spread in their use. Properly applied, Geostatistical estimation falls into two stages -- the "modelling" of the spatial variability within the study area; and the use of this spatial model to provide an appropriate estimation technique. The first stage usually consists of construction and interpretation of semi-variogram graphs, and the second is the development of the corresponding Kriging method. Because of the apparent subjectivity inherent to the first stage of a geostatistical analysis, attempts have been made to provide methods of "testing' whether a particular semi-variogram model (say) adequately represents the study area. Increasingly, the choice of model is being justified by a process known as "Cross Validation'. With this approach, the analyst uses a partial data set to estimate values at actual sampled positions. "Real" and "estimated" values are then compared in such a way that the model can be accepted or rejected. This paper discusses the process of cross validation in some detail, using case studies as examples. Some problems with the technique are illustrated and discussed.

Jan 1, 1986

By D. C. Seidel, W. K. Tolley

Supercritical water alters the structure of common sulfide minerals by partially removing sulfur from the mineral structure. This discovery has been applied to the treatment of pyritic gold ores to improve precious metal recovery without generating or utilizing environmentally sensitive products such as S02, chlorine, or cyanide. Pretreating pyrite concentrates in supercritical water under mildly oxidizing conditions provided by certain metal oxides or oxygen improved gold leaching using thiourea. The pretreatment differs from chlorination or roast pretreatments in that elemental sulfur rather than sulfuric acid is the major product. A pyritic ore containing 58 g/mt Au was pretreated with oxygenated supercritical water at 24 MPa and 400°C, then leached with 20 g/L thiourea. With pretreatment, gold recovery was 90%; by contrast, gold recovery was below 10% without pretreatment.

Jan 1, 1990

By H. Polat, S. Chander

Relatively large amounts of hydrocarbons such as fuel oils are often needed in the flotation of low rank coals. The amount of oil can be decreased considerably by using surfactants as promoters. The reagents that are good candidates as surfactants to promote hydrophobicity can also act as emulsifying and wetting agents. Because the physical and chemical variables influence various subprocesses in different ways, their influence on the performance parameters is complex. The results of laboratory tests are presented to show that the dual role of reagents can be judiciously exploited to increase both the recovery and grade of the clean coal. The mode and order of reagent addition is critical in enhancing their efficacy as flotation promoters. The results demonstrate the benefits of proper conditioning of the pulp prior to flotation.

Jan 1, 1999

By F. N. Kissell, C. D. Litton

This study ranks the factors impacting survival during a coal mine fire. It has already been established that reducing time delays is the most important factor in saving lives. Consequently, every event during afire is measured in terms of its duration, and the effectiveness of any action taken to improve survival is measured in terms of the time it saves. By ranking actions according to time saved, these authors found that a combination of actions was most effective. This combination was: •installing lifelines, •moderately decreasing air leakage and •decreasing the fire growth rate. Changing ventilation leakage alone was much less effective, as was altering the CO (carbon monoxide), sensor alarm threshold. These results confirm an earlier fault-tree study on escape from mine fires. The fault-tree study had shown that, with the exception of delays, single-factor changes have minimal impact. Significant reductions in fire fatalities only take place with multiple factor changes.

Jan 1, 1994

By F. Michael Jenkins, Elaine T. Bowers

Longwall systems are used to mine approximately 50 pct of the world's total coal production. Single entries are the predominate method of longwall development in Europe and Asia where mining conditions are much more severe than those encountered in the United States. During the 1970's and early 19801s, the Bureau of Mines and the coal mining industry invested nearly $20 million in single entry and related research. This report reviews the accomplishments of single-entry research in the United States. Two U.S. single-entry field projects are described; the Sunnyside Single-Entry Project conducted in central Utah, and the Tunnel Boring project conducted in northern West Virginia. Two other important studies are discussed, the Single-Entry Study by NAMCO and the Single-Entry Design Study by Ketron. Inc. This review compares the resulting technology with European counterparts to further assess the utility and efficiency of the U.S. systems, and final1 y, it discusses future research and development options which would lead to safe and productive single-entry longwall development in this country.

Jan 1, 1986

By S. A. Diatchkov

Introduction There is a misconception that mineral-project economic evaluations in the former Soviet Union are either nonexistent or very limited. This is not the case. In fact, there are at least two basic methods that can be utilized to evaluate the vast mineral resources of the Commonwealth of Independent States (CIS). Evaluation procedures are based either on a comparison to known projects, which may rely on limited available data, or on potential-profit calculations, which generally uses more extensive databases. Significant philosophical differences between these systems and those utilized in the Western world include the following: •Under the centralized-government system, the economic evaluation of a mineral project was based on artificially determined mineral prices and costs. Every ten to 12 years, prices for concentrates and metals were established by the Council of Ministers and remained unchanged until the next reconsideration of prices . •The time value of invested money was not considered to be important under these "stable" prices, and inflation was assumed to be nonexistent in the planned economy. •An overestimation of the value of social and economic factors such as keeping the local population employed and providing the country with strategic minerals biased the economic evaluations of projects. Sequence of exploration Geological exploration in the CIS countries typically includes two major phases: prospecting and exploration. Prospecting consists of the following: •Regional geological studies. •General prospecting. •Prospecting. •Prospect evaluation. Regional geological studies are conducted within large territories and utilize satellite images, deep seismic zoning and other state-of-the-art methods. Geological and geophysical maps on a scale of from 1:200000 to 1:1000000 are developed to help identify regional anomalies and mineral prospective areas. The areas of primary interest are then subjected to general prospecting, beginning with geological mapping of the area at 1:50000 (1:25000) scale. The prospecting phase determines mineral potential based on further geological mapping (mostly 1:10000 scale), surface geophysics and geochemistry. Finally, the most attractive targets are subjected to further detailed evaluation (prospect evaluation) to help identify "possible" projects by means of trenching and wide-spaced drilling. The results of the prospect evaluation are analyzed and conclusions regarding the economical potential of the project are drawn. If the initial-prospecting phase results are positive and the prospect is recognized as economical, it then moves into preliminary exploration, which is followed by detailed exploration. Preliminary exploration determines the feasibility of the project on the basis of limited data. For example, in some underground projects, the initial exploration drilling and tunneling is done at two or three times wider spacing than would be required by the assumed mining method. Detailed exploration focuses on preparing the project for mining development, such as completing drilling and tunneling, particularly in the portion of the ore body to be first mined. During the project's mining phase, further exploration is usually conducted along the flanks of the mineralized structures and deeper sections of the ore body. Finally, during exploitation, it is sometimes necessary to delineate the ore body within the mining-block limits. A comparison between the United States (US) sequence of exploration activities and the CIS system is given in the Table 1. There is no "additional" and "exploitation" exploration shown in the US system, but it is common knowledge that all mineral projects are subjected to "additional" and "exploitation" exploration while being mined. An economic evaluation should be performed after the [ ]

Jan 1, 1996

By Euler De Souza, Jason Chew, Aldrich Philip Dirige

Sillmats are structural elements upon which the safety and economics of underfill mining or sill pillar recovery in stopes of moderate width with steeply dipping ore zones, depend. The traditional stability design of cemented sillmats appears to have developed from experience and from standard static physical model tests such as uniaxial and triaxial compression. Such standard static physical model testing approach arrives at some approximate parameters, normally used to describe or predict the behaviour of sillmats in analytical or numerical models. This approach offers inherent limitations and generally results in conservative designs. Centrifuge modeling studies are combined with numerical modeling in this paper to provide insights into sillmat strength behaviour. The results of both modeling techniques suggest that, in stopes with smooth rock wall conditions, sillmat failure is driven by the fill self-weight and has minimum dependency on the fill binder content. In stopes with rough rock wall conditions, however, the wall roughness contributes significantly to the stability of the sillmat during underfill mining. This study indicates that the stability of paste fill sillmats can be designed with confidence using centrifuge physical modeling in combination with numerical modeling.

Jan 1, 2001

By S. K. Mishra, S. B. Kanungo, D. Biswal

Jigging of the -2.8 +0.7-mm size fraction of a friable, low-grade manganese ore sample from Andhra Pradesh increased the Mn content of a concentrate by 7% to 8%, with an average recovery of 57%. The jig concentrate was mixed with the unjigged -0.7-mm size fraction and ground to -150 µm. The sample was then subjected to wet high-intensity magnetic separation (WHIMS). The magnetic fraction thus obtained showed an increase in Mn content of 6%, but with an overall recovery of only 50%. The results of hydrocyclone classification of -150- µm ground ore indicated that the method is not capable of upgrading the manganese content, as both ferromanganese oxides and aluminosilicate gangue minerals constitute the fine size fraction. However, when the nonmagnetic fraction obtained from the WHIMS of -150- µm ore is subjected to hydrocyclone classification and the underflow obtained is subjected to WHIMS again, an overall recovery of about 50% to 52% is obtained with at least a 7% to 8% increase in the Mn content of the product. The phosphorus content in the product is not reduced by either of the two combinations of methods. The complex association of phosphorus with all the major phases in the ore has been clearly demonstrated from the linear correlation between the distribution ratios of major constituent phases and phosphorus.

Jan 1, 2000

By Robert A. Wilson

Los primeros pasos básicos para determinar los valores reales y los minerales concernientes, que son la base para las pruebas metalúrgicas, son presentados en este capítulo. A continuatión, eligiendo el proceso o los procesos indicados para el tratamiento de un mineral, son expuestos los temas. Todo esto es seguido por los procedimientos utilizados, el resultado de los cuales indicará la viabilidad para el tratamiento. Estas pruebas de procedimiento han sido desarrolladas, utilizadas y de probada efectividad en laboratorio con evaluaciones relativas al procesamiento de la planta. Los procedimientos especiales y poco comunes se encuentran fuera de la finalidad de este capítulo. La evaluatión de los resultados de las pruebas y su incorporatión dentro del flujograma preliminar y final para el diseno de la planta son temas igualmente expuestos. El valor de un flujograma, con balances de material y agua para el diseño de la planta, es asimismo mostrado.

Jan 1, 1982

By B. P. Mohanty, D. A. Shores

During the induration of fluxed taconite pellets, alkali salts deposit on the grate support bars, causing severe corrosive degradation of these alloys. To determine the source of these deposits and to understand the mechanism by which the salts are conveyed to the grate bars, a study of the reactions between fluxed pellets and combustion gas was carried out. The study focused on the thermodynamics and kinetics of several processes associated with induration; namely, oxidation of magnetite, calcination of flux, and the formation and gaseous transport of various alkali salt species. Both theoretical and experimental techniques were used. It was concluded that the principal source of alkali salt deposits is alkali chlorides, which are present as contaminants in the flux and/or residue from contaminated washwater. The pathway from pellet to grate bar involves the following steps: evaporation of chloride salts within the pellet; diffusion of salt vapor out of the pellet, aided by the outflow of CO2 from calcination of the flux; convective transport by the combustion gas with concurrent (partial) conversion to alkali sulfates by reaction with residual SOX in the combustion gas; and condensation of salts on the grate bars.

Jan 1, 1998

By L. F. Barrett, D. E. Cameron, J. C. Wilson

Exploration by Anaconda Minerals Co. in the Rico area from 1978 through 1983 resulted in dis¬covery of the Silver Creek molybdenum deposit. The drill-indicated resource is 40 Mt (44 million st) of 0.31% Mo, and projections suggest that the deposit may exceed 182 Mt (200 million st). No source intrusion has been intersected by drilling, but its presence is sugested by intramineral silicic alkali-alaskite porphyry dikes observed at the surface and in drill holes. Age dates and fluid inclusion studies indicate that the deposit was formed 5.2 ± 0.2 m.y. ago and that more than 1200 (3937 ft) of cover has since been removed by erosion. The deposit is hosted by Precambrian quartzite and greenstone, and Paleozoic sediments. Three prominent faults intersect in the vicinity of the molybdenum deposit, and one of these, the Last Chance fault, strongly influenced the shape and location of the deposit. The juxtaposition of host rocks across the Last Chance fault reflects significant offset spanning at least three different periods. Wallrock alteration associated with the deposit includes potassic, phyllic, and propylitic zones in noncalcareous rocks and garnet and anhydrite-diopside zones in the carbonates. All +0.2% Mo mineralization is within the potassic and garnet zones. Premineral faults that intersect the deposit contain the only surface molybdenum, tungsten, and fluorine anomalies. Dispersion halos of the indicator elements were defined by drilling in the discovery phase of exploration, and are particularly well-developed in the hanging wall of the Last Chance fault.

Jan 1, 1987

By G. L. Bloomsburg, E. G. Zahl

INTRODUCTION During the past decade, disposal of mine and mill waste material has become an increasingly important issue. Problems of structural stability and seepage effects on stability have been well addressed, and significant technological advances have been achieved [(1-4)]. The primary problem currently facing industry in the waste disposal area is environmental protection. The greatest environmental concern is over the amount of seepage or leachate entering the ground or surface water systems. Methods to determine the quantity of water seeping from a tailings pond have also been covered in the literature [(5-23)]. However, much further work is necessary to fully implement these techniques to evaluate tailings pond performance and accurately predict the various influences of disposal management on seepage from mill tailings. This study is an effort to develop those necessary techniques. The partially saturated method of analysis which is discussed here is applicable to most situations involving seepage from waste piles. In a conventional type of tailings pond, a slime layer is ordinarily built up under the ponded area. This material will consolidate slowly from capillary pressures and the weight of material deposited above it. In situations where this consolidation results in a slime layer of lower permeability than the native foundation soil, a partially saturated flow condition will usually exist in the native soil. This will result in a smaller quantity of water entering the ground-water system than would be predicted by saturated flow analysis. The finite-element program used in this study was originally developed by Neuman [(17)] and is called UNSAT2. The program will analyze problems of saturated or unsaturated, steady or nonsteady flow and can be used with a variety of boundary conditions such as constant flux, constant pressure, maximum flux, minimum pressure, and with infiltration, evaporation, and seepage surfaces. The maximum conditions are controlled by exterior factors such as atmospheric conditions; but the actual flow in the porous media is determined by properties of the porous media. In this test, the computer code was used

Jan 1, 1980

By E. J. Garrison

Discussion by E.J. Garrison A.C. Noble presents a clear and concise summary of the factors pertinent to a competent reserve evaluation of a mineral occurrence. However, I believe that he confuses the difference between a resource and a reserve. By definition, a reserve estimate includes all known economic, legal, mining, metallurgical and environmental factors impacting the recovery of the product(s) found in the deposit. A resource estimate, however, is an estimate of what is there - what is available for exploitation and should not include economic and other considerations. Only after defining the resource, its extent, location, physical and chemical properties, can an intelligent selection process begin of the extraction and processing technologies most appropriate to the circumstances encountered. The early and almost certainly inappropriate application of these often cookbook choices has probably lead many companies to walk away from good properties. (How many mines have been found in others rejects?) An example of the process is the early selection of metallurgical samples, after encouraging values are found in a few holes or surface samples, in an attempt to determine the economics of the prospect. Unfortunately, the sampler does not know how representative of the occurrence the sample is because he does not know what the deposit looks like. As a consequence, the property becomes saddled with a bad metallurgical sample that is often inappropriately used in evaluating the deposit which it does not represent. Reply by A.C. Noble E.J. Garrison asserts that I confuse the difference between a resource and an ore reserve. In fact, this paper was motivated by the observation that resources and reserves are almost universally confused throughout the industry. While Garrison is concerned that too-early consideration of engineering, metallurgical and economic factors will result in dropping properties too soon, some issues that must be considered include: •The purpose of exploration is to discover ore reserves, not to discover resources. •Ore reserves are always smaller than resources. • Decisions on exploration expenditures must be made based on the expectation of the quantity of ore reserves that will ultimately be defined. Noble's Fig. 2 can be used to give guidance as to when it is appropriate to begin reserve calculations. When exploration enters the "flat" portion of the curve, representative samples can be selected for metallurgical studies and appropriate mining methods chosen. It is at this stage that we know enough about the deposit to make intelligent choices of representative samples and recognize constraints on mining caused by the deposits shape, environment and physical properties. Once the appropriate technologies have been chosen, then their cost can be estimated with reasonable accuracy. Early entry of economic and process factors gives the false appearance of reserve status to the resource estimation. It would be more informative and less subject to abuse and misunderstanding if resource calculations were made at a number of cutoff grades. The cutoff grades should be chosen to cover the range of grades found in practice in existing operations of similar type. This would emphasize the open nature of resource estimates and encourage creative evaluation of mining and process technologies. It does not preclude the use of economic, environmental and recovery technology factors in deciding the advisability of continuing exploration expenditures, but would highlight their speculative nature. It is thus hoped that decisions on the future of the deposit would not be made on the presumed suitability of a given technology but on the actually known reality. I agree that resource estimates should be reported as a range of cutoff grades. Since reporting at a cutoff implies application of underlying economics (even by analogy to similar properties), however, it should be clearly stated that resources do not consider economic, mining or cost factors, and that ore reserves will be substantially less. The dilemma of the explorationist is that until the continuity and limits of ore-grade mineralization have been established, it is difficult to make quantitative estimates of either resources or ore reserves. Further industry discussion is needed regarding standards for disclosing early exploration information in such a way as to fairly represent the potential of an exploration property.

Jan 1, 1995

By Jerry C. Tien

This paper investigated the airflow pattern in the working face area during a cross-cut development. The study used a 10:l scale face model and a mock continuous miner. Results showed that keeping up the line curtain is essential in order to avoid recirculation and to control respirable dust and methane, in the face area.

Jan 1, 1989

By Alan M. Ritchie, Paul Miskelly

The 2-D code FIDHELM has been used to simulate conditions in piles of pyritic material with vertical dimensions of 20 to 70 m and a horizontal dimension of 500m. Those properties of the pile and its external environment (wind, temperature) important in determining the time and space dependence of sulfide oxidation, have been identified. A prescription to evaluate the overall sulfide oxidation rate in a pile of known volume but variable geometry has been developed.

Jan 1, 2000

By I. W. Farmer, R. E. Finky

Design of structures in rock based on ultimate limit states or strength criteria is unrealistic. The fracture process which inevitably occurs in rock around an underground structure is an energy release phenomenon. The development of fractures and associated displacements around a structure may therefore be more logically described using strain energy concepts and design may sensibly be based on serviceability limit states.

Jan 1, 1986