Search Documents

By C. Liu, F. Ye

"To extend the variety of lump ores that are used in the COREX shaft furnace and to optimize iron ore blending, the original evaluation method for iron ores that was proposed by Voestalpine AG has been improved. Physicochemical and metallurgical properties of iron ores, including Sishen lump ore and CVRD pellets, which are currently used in the COREX process, and three other lump ores, were assessed and compared. Ore matching principles were proposed and five optimized iron ore blending schemes designed and verified by laboratory experiments to prove the effectiveness of the improved evaluation method. The replacement of Sishen lump ore by the alternative L2 and L3 lump ores without varying the proportion of CVRD pellets could improve the degree of reduction and rate of metallization, and decrease the bonding index. Based on the results of laboratory test work and industrial- trials, an ore blending scheme of 60% CVRD, 20% L2, and 20% L3 is recommended for use in the COREX process. IntroductionIn recent years, problems such as environmental pollution and a shortage of coke and coal resources for blast-furnace ironmaking have become increasingly apparent. Based on sustainable developments in the iron- and steelmaking industries, the environmentally friendly COREX smelting-reduction process with low energy consumption was developed and introduced (Zhou and Du, 2013; Song, Lv, and Yin, 2015; Xu et al., 2016; Kurunov, 2010). The evaluation system for lump ore that was proposed by Voestalpine AG recommends that only Sishen lump ore from South Africa be used in the COREX process, because of the stringent physicochemical and metallurgical property requirements. This situation significantly hampers improvements to the technical and economic aspects of the COREX ironmaking process, especially in China (Eberle, Siuka, and Bohm, 2006). No theoretical or technical basis has been provided for the evaluation system, and the assessment approach for iron ores also presents problems that need to be discussed and resolved.The COREX process consists of two reactors: the prereduction shaft furnace and the melting gasifier as shown in Figure 1 (Wu et al., 2017). Pellets and lump ores which are charged to the prereduction shaft should have a good reducibility and metallization with a low degradation index (Li et al., 2016; Wu et al., 2011; Kumar et al., 2009; Kang, Gupta, and Sahajwalla, 2007). The properties and microstructure of the iron ore pellets which are required to achieve a high productivity and a lower fuel rate in the COREX process have been investigated (Umadevi et al., 2011). Some efforts have also been made to investigate the behaviour of lump ores in the COREX shaft furnace, including the disintegration characteristics and the reduction degradation (Umadevi et al., 2011; Zhou et al., 2015; Xu et al., 2013; Li, Feng, and Zou, 2013; Hou et al., 2014). However, few studies have focused on the optimization of ore blending for partial or total substitution of the expensive Sishen lump ore by other, cheaper lump ores to reduce the production cost. The technology for the utilization of blended lump ores in the COREX process is still in its early development stages (Zhou et al., 2017; You et al., 2017)."

May 1, 2019

By M. M. Masood, G. Y. Raju, T. Verma

The inverse velocity method has proven to be an effective approach for predicting slope failures in surface mines by analysing displacement monitoring data. However, the accuracy of inverse velocity method predictions is significantly affected by instrumental noise and natural environmental variations, which influence the identification of different deformation stages. To enhance predictive accuracy, this study applies and evaluates three filtering techniques to velocity time series data: Exponential smoothing filter, short-term smoothing filter, long-term smoothing filter and also compares it to raw data (no filtering). A refined prediction framework, that is, filtered inverse velocity method analyser, is proposed to improve slope failure forecasting in surface mining operations. The results demonstrate that filter selection plays a crucial role in optimising failure time predictions, offering valuable insights for geotechnical monitoring and early warning systems in surface mines.

Sep 1, 2025

By J. Preussner, U. Glatzel, R. Völkl, S. Prins, M. Wenderoth

Platinum base alloys are very corrosion resistant and have got a high melting point. Similar to Ni-base superalloys, which are used for jet turbines, the hardening effect of the intermetallic L12Pt3Al phase is used to receive a material that is creep resistant at high temperatures. Chromium is added to the alloy system to stabilize the L12phase down to room temperature. With the right amount of nickel the misfit and shape of the precipitates can be controlled. Various alloy compositions have been melted and analysed. With scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) a microstructure can be observed, which is very similar to the one in Ni-base superalloys. To support alloy development with simulations, a thermodynamic database of the Pt-Al-Cr-Ni system is about to be established. The SEM and EDS measurements provide useful input to the thermodynamic optimization. Also many data from the literature have been used to receive the best approximation. The Cr-Pt binary phase diagram has been reassessed and the latest results of thermodynamic modelling are presented.

Jan 1, 2006

By M. Gomo, L. S. Mokhahlane

"Underground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for electricity generation. Residue products from UCG have the potential to leach into surrounding groundwaters. The geochemistry and leaching dynamics of these products are explored in this study. The products include char, ash, and the heat-affected zone in the surrounding rocks. Core samples from the pilot plant at Majuba are the first ever to be recovered from a UCG cavity in Africa, and they give key insights into the geochemistry of the gasification zone. Mineralogical and chemical analyses were performed on the samples, and acid-base accounting (ABA) was used to predict the acid-producing capacity of the gasification zone, particularly for char samples. Some of the char contained pyrite, although not all samples were acid-producing as determined by the ABA analysis. The ABA results showed that some of the unburned coal has moderate levels of sulphur, which could be the driving medium for acidic conditions. The ABA analysis indicated that water in contact with the gasification zone would eventually have a pH lower than 7, which could lead to acid rock drainage. These results form part of a preliminary investigation into the geochemistry of the reaction zone, post gasification. IntroductionUnderground coal gasification (UCG) is an unconventional mining method that converts coal in situ into a fuel gas that can be used for industrial purposes, including electricity generation. The gasification process leads to the formation of a cavity composed of char, rubble, and void space (Bhutto, Bazmi, and Zahedi, 2013). Residue products from UCG have the potential to leach into groundwater. These products include char (devolatilized coal), which can generate acid rock drainage (ARD). ARD is caused by the oxidation of sulphide minerals, which acidifies the leachate, thus increasing the solubility of some environmentally toxic metals (As, Cd, Hg, Pb, Zn, etc.) (Bouzahzah et al., 2015).The main source of ARD is oxidation of sulphide-bearing minerals due to interactions with oxygen, water, and microorganisms (Simate and Ndlovu, 2014; Kefeni, Msagati, and Mamba, 2017; Bouzahzah et al., 2015). Although ARD occurs naturally, it can be enhanced by mining activities that escalate exposure of sulphide minerals to water, air, and bacteria (Simate and Ndlovu, 2014). At the Majuba pilot plant, the unburned coal remaining in the cavity has been in contact with groundwater since the gasifier was shut down in 2013. It is possible that in a commercial UCG plant, most of the coal will be consumed and no unburnt coal will be left in the cavity. Most of the sulphur will be converted to H2S during the gasification process and transported with the syngas to surface, where it can be removed and captured as elemental sulphur."

Oct 1, 2018

By R. Perlman

This paper describes the various new computer-aided techniques being used by economists in the construction of economic models. It discusses the relevance of these techniques to mining industries. In particular, it describes their role in making it possible to obtain better estimates of future price and demand developments on the markets on which metals are sold, and how these estimates can be used to improve forward planning by mining companies.

Jan 1, 2014

By J. Saunders, N. Pretorius, G. Krafft, T. P. Katakwa

Imagine being able to see all the future planned mining activities in real time. This is exactly what SIMS (Short Interval Management System) will enable you to do. SIMS is a real time short interval control system that continuously measures and sets optimised plans for mining production processes. The system utilises algorithm-based software that takes resources (people, equipment, tasks, and workplaces) and gives you the best achievable plan. The algorithm was developed using methods found in the field of metaheuristics. A metaheuristic is a strategy to designed to efficiently search for optimal or near optimal solutions to problems that are very complex computationally. (Glover, 1986) There are several algorithms that have been developed to solve optimisation problems which are difficult to solve using traditional techniques. This has given rise to a field called evolutionary computing. (Simon, 2013) Examples of these techniques are genetic algorithms, particle swarm optimisation, and ant colony optimisation. These methods are used to solve problems in a variety of fields. As an example, Kok and Lane (2012) used particle swarm optimisation for equipment allocation in a mechanised underground mining environment. The first SIMS deployment took place in a platinum underground tabular mechanised mine near Burgersfort (province?) from 2017-2019. This included the development from a paper-based system to a fully operational online system. SIMS then moved to a second site and is currently being tested in a second platinum underground tabular mechanised mine in South Africa. Full deployment of the system is currently being phased in. SIMS was built in response to issues that have been plaguing the mining industry for years. These issues are all aligned into one major problem statement: how can we optimise mining production processes without compromising safety? This product was developed by combining years of mining experience with software development. SIMS is based on a four-pillar concept. Safety, productivity, accountability, and business improvement. SIMS uses a set of pre-configured mining and production rules, and with the resources that are available, to determine valid short term production plans. A background algorithm then determines the optimum plan to be executed. The system continuously produces a set of job cards that are pushed to respective operators on their allocated tablets. The management portal component allows you to view and manage all current and planned work on any connected device available. This allows real time visibility of completed, current, and planned work to operators, service departments and management, i.e., seeing into the future.

Sep 1, 2021

By D. K. Chibwe, P. Taskinen

"Typical operation of industrial Peirce-Smith converters (PSCs) used in copper smelting results in several common phenomena such as excessive splashing, slopping, tuyere blockage, and low converter campaign life due to high tuyere line refractory erosion. These phenomena give rise to an inefficient operation from both a process and an energy perspective.This investigation presents numerical and physical models of flow patterns, mixing, solid-liquid mass transfer, and slag-matte phase distribution in a slice model of an industrial PSC. For physical simulations, a 0.2-scale cold model was developed. Water, kerosene, air, and sintered benzoic acid compacts were used to simulate matte, slag, injected gas, and solid additions into the PSC. The two- and three-dimensional numerical simulations of the three-phase system were carried out using volume of fluid (VOF) and realizable k- e (RKE) turbulence models to account for the multiphase and turbulence nature of the flow respectively. These models were implemented using the commercial computational fluid dynamics numerical code FLUENT.Both numerical and physical simulations were able to predict, in agreement, the mixing and dispersion characteristics of the system in relation to various blowing conditions employed in the investigation. Measurement of mass transfer characteristics conclusively indicated that fluid flow in the PSC is stratified. Both blowing configuration and volume of slag in the converters were found to have significant effects on mixing propagation, wave formation, and splashing.The splashing and wave motion in these converters are known to cause losses of metal/matte and potential production time due to the requirement for intermittent cleaning of the converter mouth, resulting in reduced process throughput. To prevent these losses and hence to increase process efficiency, we propose a combined blowing configuration using top lance and lateral nozzles. The numerical simulations were conducted on combined, as well as lateral, blowing conditions. In comparison, the recent results of the combined blowing concept were found to be encouraging."

Jan 1, 2014

By F. M. L. Mulaudzi

Metal dusting is a corrosion phenomenon that occurs in strongly carburizing gas atmospheres at elevated temperatures. Reaction kinetics and product characterizations of Alloys 602CA and 800 were examined by scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX) and X-ray diffraction (XRD).The results showed that Alloy 602CA is more resistant to metal dusting than Alloy 800. Visual examination and SEM surface analysis showed that Alloy 800 suffered metal dusting attack after a relatively short exposure period. The amount of coke deposits increased on Alloy 800 with increased exposure from 96 to 336 hours. X-ray diffraction on the reacted surfaces identified graphite and austenite in both alloys and some iron oxides/spinel for Alloy 800.

Jan 1, 2012

2nd CONGRESS OF THE INTERNATIONAL SOCIETY FOR ROCK MECHANICS The 2nd Congress of the International Society for Rock Mechanics will be held in Belgrade, 21-26 September, 1970. The Congress will include: working sessions, study tours, receptions, excursions introduced in the working sessions and post-congress excursions and special programme for accompanying persons. Anyone interested in rock mechanics and its applicarion may take part in the 2nd Congress. Official languages of the Congress are: English, French and German. Simultaneous translation service will be provided during the Congress. All the correspondence concerning the 2nd Congress of the International Society for Rock Mechanics should be addressed to: Sekretarijat 2. kongresa Medjunarodnog drustva za mehaniku stena Institut za vodoprivredu "Jaroslav Cerni" Bulevar vojvode Misica 43, Postanski fah 530 Beograd - Jugoslavija NINTH INTERNATIONAL SYMPOSIUM TECHNIQUES FOR DECISION MAKING IN THE MINERAL INDUSTRY The Symposium which is to be held in Montreal during the week of June 14-19, 1970, follows the Computer Symposium held in Salt Lake City this year. The purpose of the Symposium is to define the role of decision making techniques within the mineral industry and to stimulate the development of specific applications. The subject of the Symposium-mathematics, operations research and computers as applied to the mineral industry-allows a complete picture of the mineral industry in its public policy, corporate, financial and technological environment to emerge. This is another of the series of symposia on this and related subjects started in the early 1960's at the University of Arizona. Sponsorship has included a number of Universities and the Society of Mining Engineers of the American Institute of Mining. This 1970 symposium is the first to be held outside of America, and is being sponsored by the Canadian Institute of Mining, McGill University and Ecole Polytechnique. A number of delegates from South Africa have participated in these symposia and several have already arranged to attend this symposium in Montreal. Enquiries should be directed to: Secretariat, The 9th International Symposium, Department of Mining Engineering, Ecole Polytechnique, P.O. Box 50l, Snowden, Montreal 248, Quebec, Canada. 24th INTERNATIONAL GEOLOGICAL CONGRESS This Congress is to be held in Montreal, Canada, from August 21 to 30, 1972. A very detailed and extensive programme has been proposed, and includes a number of excursions. Copies of the first circular are obtainable from: The Organizing Committee, 24th International Geological Congress, 601 Booth Street, Ottawa 4, Ontario, CANADA. SYMPOSIUM ON THE RECOVERY OF PYRITE The proceedings of the Symposium on the Recovery of Pyrite, held in Johannesburg on 12th to 13th June 1969 are now available. Copies may be ordered from the Secretary, S.A.I.M.M., P.O. Box 61019, Marshalltown, Transvaal at a cost of R10.00. Papers and addresses presented at the Symposium were: Opening Address by Mr J. K. E. Douglas (President). 'The world sulphur position,' by W. C. J. van Rensburg (Member). 'The South African sulphur position,' by D. L. Taylor (Member). 'The recovery of pyrite at Government Gold Mining Areas Limited,' by R. J. Westwood (Member), G. S. Stander (Affiliate) and H. R. Carlisle (Member). 'Recovery of pyrite concentrates from colliery-waste discards-A preliminary assessment,' by W. A. Gilbert (Visitor) and E. A. Nugent (Member). 'The role of pyrite in upgrading the uranium content of Witwatersrand conglomerate ores by means of the heavy-medium separation process,' by D. J. Tutt (Associate Member). 'Pyrite recovery by jigs at Durban Roodepoort Deep Limited,' by E. J. Dominy (Affiliate), F. Diamond (Affiliate) and A. D. Graham (Affiliate). 'The storage of pyrite concentrates,' by Joan C. Campkin (Visitor) and P. J. Lloyd (Member). 'The flotation plants of the Anglo- Transvaal Group,' by L. A. Bushell (Member). 'Pyrite flotation with amines and cyanidation of the products,' by E. H. D. Carman (Member). 'Gold recovery by cyanidation from mill products obtained after pyrite flotation,' by P. G. Mrkusic (Graduate), M. Sciarone (Visitor) and H. E. Simonsen (Visitor). 'The influence of sulphydral and cationic flotation reagents on cyanidation of native gold,' by K. G. Ashurst (Visitor) and W. P. Finkelstein (Member). 'Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collector,' by J. Levin (Member), and M. L. Veitch (Visitor). Closing Address, by Dr R. E. Robinson (Director, National Institute for Metallurgy).

By J. de V. Lambrechts

A critical comparison of specific cooling power and the wet kata thermometer in hot mining environments By J. de V. Lambreehts. D.Sc. (Eng.) (Rand) A new formula for the wet kata thermometer has been established in place of the currently used one which is believed to be fundamentally wrong and the new formula is compared with the recently proposed specific cooling power concept. Apart from a constant multiplier, it is concluded that the difference between. the two concepts lies solely in the value of 'n' in the function vn and that this value for the cooling power of air on the sweating human body remains to be established reliably. The kata thermometer might yet be found to be a reliable predictor of heat stress in hot environments.

By F. T. Cawood

The new mineral royalty regime for South Africa was signed into law in November 2008, with its main objective being to compensate the State for the depletion of public minerals through a royalty charge payable from 1 March 2010. The aims of this paper are to establish the potential impact of mining royalties on State revenues, industry affordability, and explore whether the dual formula system is likely to encourage miners to become refiners. It also measures the royalty dispensation against economists? tax standards in an attempt to make a judgement on the ?equity? of the new system. This paper argues that most stakeholders should be comfortable with most of the requirements of the Act for most of the time. However, the new regime is unlikely to motivate miners to become refiners, as the benefit of the reduced rate on refined minerals appears to be insufficient to justify the additional costs to refine the mineral resource to the prescribed states of beneficiation.

Jan 1, 2011

By V. V. Getman, V. A. Chanturiya, T. N. Matveeva

Most of the Au and PGM ores in Russia are characterised by a thin mineral impregnation of noble metals in sulfide minerals, and a large variety of mineral forms that lead to high loss of precious metals with fine fractions during flotation. In modern flotation technology, the rational choice of reagents is one of the main trends for selective separation of minerals and effective metals recovery. New data on the selectivity of the thermo-sensitive polymer with specific functional groups (TMPPh) as a flocculant and collector of Au and Pt fine fractions are available. The selective modified collector (DEDTCm) for the recovery of Au and Pt from complex ores is discussed in this paper. Scanning electronic microscopy (SEAM), laser SIM and AFM microscopy, UV and IR spectroscopy were applied to study the adsorbed layer of new reagents on the mineral surface. Flotation tests of TMPPh on the gold-bearing ore of the Olimpiada deposit showed an increase in Au extraction and Au content in the concentrate of the rougher flotation. Using a combination of reagents TMPPh and ButX, the quality of the Au and Pt concentrates increased in 1.7 time with an increase in recovery up to 15 % compared with the traditional reagent mode. Testing of TMPPh polymers in flotation of Pt-Cu-Ni ore at Norilsk Nickel has shown the ability to obtain a concentrate with a higher Pt content. Recovery of platinum is 17% higher than recovery in an experiment without polymer. Application of DEDTCm helped to achieve higher technological parameters in flotation of lowgrade Rt-Cu-Ni ore. Compared to the basic mode Pt recovery was plus 13%, Pd recovery was plus 9% and the content of precious metals in the rougher flotation concentrate increased in 2,5 - 4 times. The studies have been supported by Grants of the President of RF “Scientific School of Academician V.A. Chanturiya” NSh-220.2012.5, NSh-748.2014.5. Keywords: Au and Pt complex ores, flotation, flocculation, thermo-sensitive polymer TMPPh, modified collector

Jan 1, 2020

By Y. G. Zhu, G. B. Zheng, X. X. Hu

Reverse flotation by cationic collectors is the classical method to reduce the silicon content in magnesite. But because of the low selectivity, there is a large loss of magnesite in the reverse flotation froth. To improve the efficiency of the collector, a novel collector named BK433 was developed in this paper. In order to determine the performance of the BK433 collector, a systematic experimental study was carried out with a high silicon magnesite in China. The suitable pH environment of slurry was confirmed, the depression effect of different depressants was investigated, and the flotation effect was compared with commonly used traditional collectors. The results show that the BK433 shows remarkable good selectivity and collection ability. After the 4 stages reverse flotation, the SiO2 content decreased from 3.76% to 0.25%, SiO2 impurity removal rate reached 94.69%. Meanwhile, the MgO content increased from 45.06% to 46.73%，the recovery of obtained concentrate (calculated by MgO) was 82.79%. Keywords: Magnesite, Desilicication, Reverse flotation, Collector

Jan 1, 2020

By I. V. Filippova, Y. Foucaud, M. Badawi, L. O. Filippov, S. Lebègue

To optimize the flotation of Ca-minerals, their separation contrasts were investigated by coupling experimental and theoretical techniques. We showed that they mainly rely on structural properties such as the Ca-Ca distance on their exposed surfaces but also on the ability to control the intermolecular interactions. An optimized composition of the carboxylic collector by calculating the collector-mineral and the intermolecular interactions was developed. Blending the saturated acids and non-ionic molecules with a fatty acid collector significantly increases the flotation selectivity between scheelite (CaWO4) and fluorite (CaF2). The theoretical results were validated by experimentally improving the separation contrast between Ca-minerals. After the tests of several depressants and collectors, the best depression of gangue Ca-minerals (fluorite, apatite and vezuvianite) was found by combining sodium silicate and sodium carbonate. Keywords: Ca Minerals, Fluorite, Scheelite, Carboxylic acids, Unsaturated Acid, Fatty acids

Jan 1, 2020

By P. Cowx, L. Els, P. Smith, R. Nordhagen

"Tapping operations at ferroalloy smelters generate a significant amount of fume. Effective capture of fumes is required to meet the obligations of environmental, as well as occupational, legislation.A study was completed on an existing fume extraction system at a ferromanganese furnace tapping area. The area under consideration included the tap-hole, launder, and ladle area. The study consisted of site test work as well as computational fluid dynamics (CFD) modelling to identify and evaluate solutions.Site test work and observations during furnace operation provided a baseline of system performance as well as input parameters for CFD modelling. Gas flow rates and energy contents from each extraction area were measured. Photographs and video footage were taken to evaluate areas of fume leakage.The CFD study was firstly validated against site observations to ensure the accuracy of input parameters. Thereafter several modification concepts were modelled and suitable combinations were investigated to ensure robust solutions. The following concepts were considered:•,Air curtains•,Ladle hood aspect ratio and position•,Increase of ladle extraction volume•,Extension of the length of the tapping garage structureThe paper presents the results of a performance test on a working ferromanganese tapping area fume extraction system and the results of CFD modelling as compared to site test results. Upgrade options are evaluated and an integrated robust upgrade of the system described."

Jan 1, 2014

By A. C. Johnstone

The aim of the study is to determine if pit lakes are a sustainable coal mine closure option in South African. The water balance, chemistry, limnology, and bacterial population of three selected pit lakes were investigated. The lakes are in the three major coal basins of South Africa and are associated with different lithologies and mining methods. The major factors driving the water balance of the pit lakes are direct rainfall, runoff, inflow from old mine workings, and groundwater infiltration, with the major losses being evaporation or discharge onto surface. The study indicated that pit lakes can be designed as ’terminal sinks’ to provide a sustainable mine closure option. The pit lakes sampled have an alkaline pH, and mostly a sodium/calcium sulphate water with total dissolved solids content of less than 3000 mg/l. The phytoplankton and microbiological data indicates that the pit lakes support aquatic life. The study shows that correctly designed pit lakes can be an environmentally sustainable closure option for South Africa’s coal mines. A suggested design manual has been developed to assist mine owners and regulators in developing sustainable coal mine pit lakes as a closure option.

Oct 1, 2021

By N. Mangadoddy, M. Padhi

The simulation of multi-component classification with modified viscosity model is the key focus in the current study. The classification of the ores using hydrocyclone is a renowned process and has a convoluted flow separation phenomenon. The highly turbulent flow inside hydrocyclone depends on the operating and design parameters apart from the feed mixture. Slurry viscosity also plays a dominant role in the classification of solid particles under the centrifugal settling action. A heterogeneous mixture with different components would result in different settling and rheological behaviour of particles’ suspension in the water medium. The newly proposed multi-component viscosity model (Mandakini et al. 2020) is implemented as a user-defined function to define the material property during the CFD study of the mixture rheology inside hydrocyclone classifier. The multiphase and turbulence model is solved using the modified Algebraic Slip Model and Large Eddy Simulation model. A comparison of the predicted component performance curves is evaluated with and without the corrected viscosity model. The density and size effect on the particle phase distribution inside the classifier are compared, where the misplacements of the finer particles are carefully assessed. Validation of the component classification in hydrocyclone with the laboratory experiments found a close agreement with the rheology based CFD data. Keywords: Dual-component, multi-component viscosity model, double-gap rheometer, computational fluid dynamics, high solids concentration

Jan 1, 2020

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By H. S. Sichel

This study deals with the development of some new theory concerning the bias which will result from the employment of the t-estimator if in fact the underlying distribution of ore values is not lognormal. It is found that the t-estimator is robust as long as the logarithmic variance is small and the shape factors of the transformed distribution are not unduly large. The choice of the threshold parameter [t] for the t-estimator is important, and some hints are given how to estimate it if the sample size is small, as en- countered in borehole valuation problems.

Jan 1, 1987

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluoridesl.2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02?SiO2) with the ammonium acid fluoride (NH4F?XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo-dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012