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By Ralph L. Brown

As a preliminary step in a recent study4 of the phenols present in a low-temperature tar, the writers prepared the hydroxyacetic derivatives of the simpler available members of the phenol series in order to obtain material to assist in fixing the identity of similar derivatives obtained from the phenols of the tar. When comparing the melting points of the pure derivatives we had made with those given in the literature we were unable to find the characteristics of one of the xylenol derivatives which we had prepared--namely the 1, 3 dimethyl-2-phenoxyacetic acid, In the belief that the compound does not appear in the literature we are presenting these notes on its preparation and its melting point. The hydroxyacetic derivatives are easily prepared and in good yield, and are useful in studying mixtures of phenols. The 1, 3 dimethyl-2-phenoxyacetic acid makes the fifth of the six isomeric derivatives to be reported in the literature. Gluud and Breuer report the preparation of the 1, 3, 4, the 1, 4, 2, and the 1, 2, 4 derivatives. A fourth isomer-¬the symmentrical 1, 3, 5--has been reported by Schutz6, although no record of it occurs in the indexes. The remaining derivative--the 1, 2, 8-has not, been found and it is now being synthesized in the Organic Chemistry Laboratory of the. Pittsburgh Experiment Station. It is true, however, that from a phenolic fraction boiling 215.9 to 2180 isolated from natural petroleum, Tanaka and Kobayashi7 obtained a hydroxyacetic derivative melting at 103.3°. They state that this is the 1, 2, dime ethyl-3-phenoxyacetic acid but present no evidence for the assertion. The known derivatives are summarized in Table 1 following;

Jan 1, 1929

To provide a simple means for rapidly checking methane concentrations at working faces in coal mines while remaining under permanently supported roof. The Approach: A light telescopic probe, through which a gas sample can be pumped Into a methanometer, has been developed. See Figure 1 [ ] How It Works: The telescopic probe consists of sections of small stainless steel tubing encased in sections of lightweight fiberglass tubing. When fully extended the probe is almost 19 ft. long; fully closed it is approximately 5-1/2 feet long. It can be used In either of these positions as well as at intermediate extensions. An approved methanometer is clamped to the probe by a support bracket.

Jan 1, 1975

By H. Kenneth Sacks

The Bureau of Mines has developed hardware for electromagnetic (EM) detection and location of miners trapped in underground coal mines. This report describes a technique for using the developed equipment for locating uncased boreholes underground. Results of several field and laboratory experiments are described.

Jan 1, 1978

By Michael S. Wieland

Recognizing the dynamic nature and possible range of toxic concentrations in the impending fume cloud prior to undertaking explosive blasting can reduce potential hazards and mitigate related incidents. The scaled cloud model was formulated to predict the relevant (major) toxic components in fume clouds released by nonideal mining explosives used for surface blasting. Natural turbulence unceasingly disperses the toxic molecules, widening (inflating) the fume cloud while diluting the concentrations, ultimately rendering nonhazardous conditions. The threshold cloud size depends upon the type and quantity of total explosives used and the cloud's thermodynamic condition. Though the scaled theory works for fume clouds with irregular (odd) shape, an equivalent upright cylindrical form is useful for rendering simple riskhazard scenarios. The cylinder's projection downward on the underlying terrain yields a circular 'shadow' marking the region threatened, thereby permitting a rough estimation of the potential hazards, were the cloud to settle down there. Wind causes the cloud to drift while it expands, so the shadow travels while it grows, until the risk hazard process is truncated at the nonhazardous threshold. The overall relative fume toxicity (RFT) is taken from the traditional Russian RFT rule, which utilizes only the two fume components that tend to dominate the resultant toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). Tabulated constants that characterize the fume spectrum in the cloud model were resolved for ammonium nitrate (94%) with fuel oil (6%), ANFO-94/6, using a refined thermodynamic work-principle. Comparable results were found with the reduction factor technique, when test results from the underground fume chamber were readjusted to reflect nominal field shooting conditions.

The National Institute for Occupational Safety and Health (NIOSH) recommends that occupational exposures to respirable coal mine dust and respirable crystalline silica* be controlled by complying with the provisions presented in this document. These recommendations are designed to protect the health and provide for the safety of workers exposed to respirable coal mine dust and respirable crystalline silica for up to 10 hr/day during a 40-hr workweek over a working lifetime. The information presented in this document demonstrates that underground and surface coal miners are at risk of developing simple coal workers' pneumoconiosis (CWP), progressive massive fibrosis (PMF), silicosis, and chronic obstructive pulmonary disease (COPD). Adherence to the recommendations in this document should prevent or greatly reduce the risk of adverse health effects in workers exposed to respirable coal mine dust and respirable crystalline silica. NIOSH recommends that preventive efforts be focused primarily on reducing worker exposures. Effective health and hazard surveillance and medical screening are also useful components of a comprehensive prevention effort.

Jan 1, 1997

By R. H. Grau, S. B. Robertson, R. B. Krog, T. P. Mucho

Stone mines represent the highest percentage of operating underground nonmetal mines in the United States. With the introduction of stricter Diesel Particular Matter (DPM) regulations, large-opening underground room-and-pillar stone mine operators are faced with implementing one or more alternative methods to reduce concentration levels including: install and maintain an effective ventilation system; install lower DPM emission diesel engines; the adding of DPM filters. The National Institute for Occupational Safety and Health (NIOSH) is actively researching various aspects of fan and stopping designs in an effort to improve the ventilation of these mines. NIOSH has identified and further developed three alternative ventilation methods for use in large-opening underground mines: split-mine, perimeter, and unit-ventilation. This paper describes the implementation of the three methods with respect to their use in mines of various levels of development.

To devise an economical, environmentally acceptable method for recycling scrap lead-acid batteries. Approach A combination electrorefining-electrowinning method for recycling lead metal and sludge from scrap batteries was devised which produces a 99.99 + percent pure lead product and eliminates the lead and sulfur oxide emissions that are the normal by-products of high-temperature smelting processes. How the Method Works Lead metal grids and lugs are separated from the battery sludge by washing and screening, and are melted and cast into anodes for electrorefining by the Betts process. The electrolyte used is fluosilicic acid, a large volume waste product generated during the production of phosphate fertilizer. During the electrorefining process, impurities in the anode are trapped and held in an adherent slime blanket on the surface as the anode dissolves while pure metallic lead is deposited on a lead cathode. The major problem in the past has been to recover the lead from the battery sludge which consists of approximately 60 percent lead sulfate, 21 percent lead, and 19 per-cent lead dioxide. In the flow sheet developed by the Bureau

Jan 1, 1983

By William H. Schiffbauer

This paper details the computer hardware and software integrated to provide computer-assisted control and monitoring of four different coal mining machines. The backbone of each system is a U. S. Bureau of Mines integrated distributed microcomputer control network called BOM/NET. The network provides connections for intelligent sensors and systems that provide for navigation, diagnostics, and computer control. Many different computer systems using various operating systems (including RMX I, UNIX, VXWORKS, DOS and DCX51) have been connected to the network and each have had complete network functionality. A description of the network's integration to Joy' 16CM, a Joy 14CM, a Jeffrey 102, continuous mining machines, and a custom built auger machine is provided. The networks for the Joy 16CM, the Joy 14CM, and the Jeffrey 102 have been installed and extensively tested at the Bureau's surface test facility. The Jeffrey 102 system has also been tested in a highwall coal seam. The Joy 14CM will soon be tested underground.

Allow miners to communicate via the pagerphone system when they are not near one of the phones. Approach A small lightweight pagerphone, having crocodile clips which pierce the phone line insulation, was developed. How It Works The Portable Telephone/Intercom is temporarily clipped onto an existing pagerphone line at any location, and operated like an intercom. It is riot necessary to strip the insulation from the pagerphone line to make the connection. In addition to the clips for connecting to pagerphone line, the Portable Telephone/Intercom consists of a small belt-carried control box, an ear-phone, and a bone-conduction microphone which is attached to the webbing in a miner's helmet. All together, these components weigh only 20 ounces including the batteries

Jan 1, 1977

By R. T. Stull, L. E. Geyer

"Previous Work:As outlined in previous papers* ond clays for graphite crucibles have been tested at the plants of the Detroit Lubricator Co., and the Detroit Copper and Brass Rolling Mills, Detroit, Mich.These tests indicated that there were two American clays (Missouri pot clay and Illinois kaolin) that tested better than the Klingenberg (German) clay. Dorset (English) ball clay was tenth in the list.Making the Crucibles:After it had been determined that American clays can be used successfully in graphite crucible manufacture and service, the next step in the investigation was to determine the value of American graphites as compared to the foreign, These final tests were carried out at the plant of the Detroit Lubricator Co., through the courtesy of Mr. G. B. Duffield. The crucibles, as previously. were made at the plant of the Vesuvius Crucible Co., Swissvale, Penna., from a formula compiled by the Bureau of Mines and under the supervision of Bureau engineers.The graphites to be tested were given an initial to indicate their source. The number of crucibles made and shipped are set forth in Table 1."

Nov 1, 1923

Provide means for rapidly re-establishing ventilation control in metal mines after blasting, for emergency applications, and for routine temporary use. Approach Two quickly-installed, parachute-like stoppings have been developed and tested by the Bureau's Pittsburgh Mining and Safety Research Center. How the Parachute Stopping Works The parachute stopping can be fastened to an existing anchor point, opened, and effectively block the air flow, in less than two minutes. Because the parachute stopping tends to be self-scaling, its performance is generally better than that of conventional fabric stopping. However, the periphery of the parachute stopping must be longer than the periphery of the mine opening, Figure 1 shows the parachute stopping deployed in a mine entry. To reduce leakage during routine use, the cloth at the periphery of the parachute stopping can be adjusted and then anchored at several points as necessary. This extra adjustment can also be done after the initial installation during mine rescue or mine recovery.

Jan 1, 1977

Improve the accuracy of commonly-used mine air velocity measurement techniques. Approach The Bureau of Mines, through a contract with Ketron, Inc., conducted a detailed study to establish appropriate, generalized correction factors for commonly-used air velocity measurement techniques. The techniques used were centerline readings, continuous traverse and split traverse vane anemometer readings, and smoke cloud readings (see Bureau of Mines Bulletion 589 for details on the proper use of these techniques). The various measurement techniques were used at different mine test sites to measure different air velocities. The data collected from the test sites were used in a statistical analysis which determined a generalized correction factor for each measurement technique. The correction factor multiplied by the measured velocity was used to provide the true velocity.

Jan 1, 1984

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 6 Listing The following is a listing of the Mine Evacuation Simulation Program

Jan 1, 1976

By Dorsey A. Lyon

At the main experiment station of the U. S. Bureau of Mines , situated in Pittsburgh, Pa . , three phases of its work in behalf of the safety of the coal miner are the establishment of permissible explosives for use in gaseous and dusty mines , the development of electrical equipment that can be used with safety in mines of this character , and improvement in the safety of mechanical devices used in and about the mines . Also That these efforts are beginning to have a cumulative effect in lives. saved is evident from the fatality statistics of the industry . Although nearly 80,000 more men are employed in coal mining than ten years ago and much more coal is mined , the fatalities each year are considerably less than ten years ago . the amount of coal mined in a year for each life lost has risen between 60,000 and 70,000 tons . In 1909 , the year before the Bureau was created , the production of coal for each life lost was 174,416 tons . In 1920 , the production for each life lost was 285,000 tons .

Mar 1, 1921

By J. Brad Seymour, Mark K. Larson, Richard L. Rains, Douglas R. Tesarik

For several years, researchers from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health (NIOSH) have been using geotechnical instruments in underground mines to study ground control problems and develop means of reducing accidents and fatalities caused by ground falls. This paper describes many of the different types of instruments, sensors, and data acquisition equipment that have been used for these studies; briefly explains the advantages and disadvantages of various sensor technologies; provides practical recommendations regarding the use of specific instruments and data acquisition systems; and outlines a general approach to the design and implementation of a successful instrumentation plan. A wide variety of instruments are commercially available for measuring deformation, strain, stress, and/or load. If used correctly, these instruments can provide important quantitative information regarding the mining-induced behavior of the host rock, the performance of ground support systems, and the safety and stability of underground workings. Data collected from these instruments can warn mine staff of impending ground control failures or hazardous working conditions, as well as provide valuable information for the design of ground support systems and the configuration and sequencing of mining excavations. We hope that the practical information presented in this paper will encourage a more widespread use of geotechnical instruments in underground mines and lead to reliable measurements that aid the engineering decisions affecting the safety of miners.

Jan 10, 2000

Reduce the number of accidents caused by slips and falls from large mining equipment. Approach A powered lift was developed that provides operators with a safer way of getting on and off large machines. How It Works The powered step is designed to lift personnel and materials to working levels on large machines. It eliminates hazardous blind steps and makes it unnecessary to climb on irregular surfaces made slippery by mud, ice, snow, and accumulations of grease. The step is powered by a self-contained electric/hydraulic unit which is connected to a vehicle's auxiliary power supply. When in the "down" position, the step rests about 15 inches above ground level. When the power unit is activated with an electrical switch located on the step, a Single cylinder attached between two lifting arms smoothly lifts the step. In conjunction with the lifting motion, a linkage and bearing arrangement on the mounting end of the lift arms causes the step to rotate towards the machine, so that the step moves in an arc from ground to platform level. When the machine Is operating, the step is automatically locked in the "up" position, protecting it against any damaging contact with obstructions. The step is lowered by activating a pressure release solenoid. An in-line orifice controls downward speed and prevents free fall. On most machines, additional control switches are conveniently located at ground level and in the operator's cab. Visual alarms and machine interlocks are provided where necessary to prevent machine operation when the step is In the "down" position. The powered step can be easily adapted to any type or model of large machinery.

Jan 1, 1981

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

MINE VENTILATION NETWORK ANALYSIS

Jan 1, 1977

To reduce the possibility of injury to operators and damage to equipment caused by collision of mining vehicles during coal loading. Approach An energy-absorbing bumper was developed and tested underground on a continuous miner. How It Works The bumper, a long box-like weldment backed by five energy absorbers, is attached to a continuous mining machine by a hinge behind the cab. See Figure 1. When a shuttle car collides with the bumper, or when it is otherwise struck, the energy absorbers are compressed. This absorbs and dissipates part of the kinetic energy of the colliding vehicle, thereby reducing or eliminating its destructive effects. Each energy absorber consists of two chambers separated by a freely-moving piston. One chamber (Figure 2) contains hydraulic fluid. The second chamber contains a gas. When a collision causes the absorber to compress, the hydraulic fluid in the first chamber is forced past a metering pin and through an orifice. The hydraulic fluid then pushes against the piston, compressing the gas in the second chamber.

Jan 1, 1978

By A. T. Iannacchione

Underground stone mining represents an emerging sector for the U.S. mining industry. As this expansion takes mines under deeper cover and as more efficient mining methods are utilized, adequate stone pillar design methods will become more important. It is the purpose of this paper to examine current design practices and to discuss issues for safe mine layouts so that a rational first approach towards balancing the demands for increased production can be weighed against increased risk to worker safety from rib instabilities and pillar failures. Seventy-two stone mine pillar designs were examined. Pillars with width-to- height ratios below 1.5 and subjected to excessive stress levels appear more likely to fail. When width-to- height ratios fall below 1 .O, defects in the pillars, such as through-going discontinuities, can have a significant influence on stability. Discontinuity persistence, dip, material properties, and orientation are important factors controlling pillar strength. The influence of discontinuity dip, a characteristic easily identified in the field, was examined so that its presence could be accounted for in developing generalized guidelines for pillar design.

By Peter F. R. Altounyan, Paul B. Cartwright, John W. Cassie

This paper describes measured data on strata behavior obtained in recent years from sites in the United Kingdom and the implications for pillar design. The data include results from overcoring stress measurements adjacent to coal mine roadways and deformation monitoring related to longwall extraction. The stresses adjacent to mine roadways or entries have been measured at a number of coal mine sites in the United Kingdom. The results are analyzed with regard to the information they provide on pillar behavior and strength estimates. A reduction in stress consistent with yielding of the strata adjacent to the roadways is evident. This is consistent with the confined core model for pillar behavior. The pillar strength is dependent on the rate atwhich vertical stress can increase with distance from the pillar edge and hence the confinement provided to the yielded material. The measured data indicate a wide range in pillar strengths. Two groups of results are identified that show significantly different behavior corresponding to differing effective pillar strengths. Estimates of pillar strengths derived from the measured data for these two groups are compared with established equations used for pillar design. The differing behaviors and strengths are attributed to variations in the amount of yielding and deformation in roof and floor strata and hence in the amount of confinement they provide to the coal seam. Numerical modeling is used to provide a comparison with the measured data and to indicate that this provides a feasible mechanism to account for the measured data. As the depth of mining increases, pillars tend to become increasingly wide and squat. In such cases, it is possible for the surrounding roadways to become badly deformed and damaged while the pillars remain stable. The criteria of comparing pillar strengths and loads to establish pillar stability become less applicable in these circumstances; rather, considerations of roadway stability may be the limiting factor in determining suitable pillar dimensions. This is the case for pillar dimensions typically employed around longwall panels in the United Kingdom. Depending on the properties of the site and what are deemed to be satisfactory roadway conditions, this can lead to wide variations in required pillar dimensions. Measured data for deformations in roadways influenced by adjoining longwall workings are presented. These show that in some circumstances the influence of longwall extraction can be transmitted over large distances and confirm the variability in required pillar sizes depending on site properties.

Jan 5, 1999