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By W. W. Weller

Low-temperature heat capacity measurements were conducted, and entropies at 298.15° K were evaluated for sodium monomolybdate (Na2Mo04), magnesium monomolybdate (MgMo04), and calcium monomolybdate (CaMo04). The 298.15° K entropy values were sodium monomolybdate, 38.1±0.3 cal/deg mole, magnesium monomolybdate, 28.4±0.2 cal/deg mole, and calcium monomolybdate, 29.3±0.2 cal/deg mole.

Jan 1, 1963

By Fred Garcia, William P. Diamond

As part of its mine safety and health research program, the National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, has been investigating the geologic and mining factors influencing methane gas emissions associated with longwall mining. A primary focus of this research has been the consequences of increasing longwall panel dimensions, particularly face width, in gassy coalbeds. Continuous longwall face emission monitoring studies were conducted at two adjacent mines operating in the Pocahontas No. 3 Coalbed, where longwall faces were to be extended from 229 to 305 m (750 to 1,000 ft). Average longwall pass methane emission rates for 229-m (750-ft) wide faces were 61 % (0.072 m31sec (153 cfm)) higher at the VP-3 Mine than at the VP-1 Mine. It was predicted by regression analysis of methane emissions data from 229-m (750-ft) wide faces that extending faces to 305 m (1,000 ft) would increase methane emission rates by only 7%, or 0.009 m3/sec (20 cfm), to 0.144 mysec (304 cfm) at the VP-1 Mine. In contrast, it was predicted that extending faces to 305 m (1,000 ft) at the VP-3 Mine would increase methane emissions by as much as 13%, or 0.029 mysec (65 cfm), to 0.268 dlsec (567 cfm).

Jan 10, 1999

By R. L. Grayson, T. Simonyi, R. A. Andrel

"The purpose or this paper is to disclose analytical, statistical, and observational results relating to mineralogy and trace elements in respirable dust samples collected from two different mines in West Virginia. Samples were taken from longwall panels, and the panels operated in different coal seams, one located in the northern part or the state and the other in the southern region. Mining conditions and equipment arrangements on the panels will be described along with dust control techniques used. Results from sample analyses are summarized with emphasis on relationships between mineralogy, trace elements and mineral particle size to worker locations. Correlations are made between micro x-ray diffraction and energy dispersive x-ray analyses for sample mineralogy.IntroductionThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from harmful exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al, (l) which has been used to establish the 2 mg/m3 exposure limit in the United States. According to the model exposure to respirable dust for 35 years at this level or less could prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP) in a miner. The exposure limit, of course, must be adjusted whenever greather than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mean mass concentration exposure, which generally showed the highest correlation with both incidence and progression of CWP. As Morgan, et al noted, however, the quantity of respirable dust inhaled is not the only significant factor. 2) They noted that although mass of respirable dust correlates highe.st with the incidence of CWP, it is not a causal factor. Admittedly, the insidious processes causing the disease occur at the lund cell-dust particle level."

Mar 1, 1989

By L. M. Demers, D. C. Kuhn

The alveolar macrophage (AM) responds to stimuli such as coal mine dust by releasing inflammatory mediators such as cytokines, growth factors. reactive oxygen species. and eicosanoids. Eicosanoids are synthesized by°AM through the action of cyclooxygenase and lipoxygenase enzymes and serve to modulate the proinflammatory function of this cell as part of the lungs' host defense mechanism. Reactive oxygen species can be generated by AM as a by-product in the biosynthetic pathway of the prostaglandins. AM produces primarily prostaglandin E2, thromboxane A2, and leukotriene B4 as part of the cellular response to an inflammatory stimulus. There is evidence to suggest that eicosanoid production by AM is functionally linked to both surface interaction with mine dust particles like silica and by the phagocytosis of the dust particle itself. In this report, we examined the effects of an antioxidant, vitamin E. on dust-induced synthesis of PGE2 and TXB2 in vitro and in vivo by AM obtained by bronchoalveolar lavage from rats. We also looked at the effects of the surface of silica particles on AM eicosanoid biosynthesis under conditions of calcination, a process that removes exposed hydroxyl groups from the surface of silica particles, thus reducing the likelihood of soluble hydroxyl radical formation. Treatment of AM with vitamin E in vivo and in vitro reduced the augmentation in eicosanoid production usually observed when AM are exposed to mine dusts. These results suggest that vitamin E may effectively reduce the inflammatory and fibrotic response produced by inhalation of mineral dust through an antioxidant mechanism. Silica that has been chemically altered by calcination was unable to activate AM eicosanoid production in vitro when compared to untreated, freshly fractured silica. These findings suggest that the mechanism by which dust particles can activate AM eicosanoid release may involve interaction of surface and/or soluble factors with the cell membrane. Taken together, these studies point to the involvement of AM eicosanoid production as part of the proinflammatory response of this cell to occupational inhalation of mineral dust. - Environ Health Perspect 102(Suppl 10):97-100 (1994)

Dec 1, 1995

By H. Dolezal

An investigation was made on the use of magnesium for the direct reduction of rutile to make low-cost, offgrade titanium which could be upgraded to an acceptable grade of metal by electrorefining. Reductions made with charges containing magnesium chloride under hydrogen yielded products with oxygen con-tests close to the theoretical equilibrium composition. Two reduction products were made from rutile for use in electrorefining amenability tests: (1) a product from reduction in an inert atmosphere which contained 88.9 percent titanium and 4.42 percent oxygen, and (2) a product from reduction in a hydro-gen atmosphere which contained 92.5 percent titanium and 2.40 percent oxygen. Reduction products obtained under both of these conditions were amenable to electrorefining.

Jan 1, 1965

By John M. Devine

The oxygen bomb-is used extensively for determining sulphur in petroleum, although it has been suspected that the results obtained with this method are somewhat lower than the true varies. In this paper are compared the results given by the oxygen-bomb and Carius methods, the latter being generally accepted as the standard procedure for the determination of sulphur in organic compounds. The Carius determinations given hero were made in connection with a special study of this method.4 Only petroleum oils of the less-volatile type are covered in the present work. Summary and Conclusions. When used with oils containing 2.3 to 0.15 per cent of sulphur the oxygen-bomb method gives results that are consistenly if slightly lower than those obtained with the Carius method. This variation, for the oils used, amounts to 3.1 per cent (on tae basis of sulphur present) for the sample containing 2.47 per cent of sulphur, and gradually increases (as the percentage of sulphur in the oils decreases) to 7.3 per cent for the oil containing 0.15 per cent of sulphur. With the oils studied the presence of ammonium nitrate in the bomb does not influence the results materially.

Jan 1, 1928

By Hendrik Gerritsen

The research to be described is directed to the construction of an instrument that detects methane in air. The principle on which it is based is that methane gas absorbs infrared radiation in the wavelength range of about 3.2 to 3.4 micron. Solid state p-n junctions of composition In, .97Ca.03As emitting radiation in a band centered at 3.3 micron were grown by liquid epitaxy on InAs. Fight separate growth cycles and a total of 200 diodes were measured to determine total power, wavelength peak, spectral. half width and reproducibility of the method. In order to compensate for temperature changes, dual emitter systems (one InGaAs, and one InAs diode) mounted on the same TO-5 header were made. These devices were imaged, using a folded optical path cell, on large area InAs detectors, grown by a planar diffusion technique. In the 0-50°C range the primary temperature sensitivity is in the InAs detector rather than in the emitters. Several methods to reduce the overall temperature sensitivity to within acceptable limits were demonstrated. Humidity was shown to have a negligible effect on the measurements.

Jan 1, 1976

By Gregory J. Chekan

As part of the initial investigation and validation of a new boundary-element formulation for stress modeling in coal mines, the underground stresses and displacements at two multiple-seam coal mines with unique stress problems were modeled and predicted. The new program, LAMODEL, calculates stresses and displacements at the seam level and at requested locations in the overburden or at the surface. Both linear elastic and nonlinear seam materials can be used, and surface effects, multiple seams, and multiple mining steps can be simulated. In order to most efficiently use LAMODEL for accurate stress prediction, the program is first calibrated to the site-specific geomechanics based on previously observed stress conditions at the mine. For this calibration process, a previously mined area is "stress mapped" by quantifying the observed pillar and strata behavior using a numerical rating system. Then, the site-specific mechanical properties in the model are adjusted to provide the best correlation between the predicted stresses and the observed underground stress rating. Once calibrated, the model is then used to predict future stress problems ahead of mining. At the two case study mines, the calibrated models showed good correlation with the observed stresses and also accurately predicted upcoming high stress areas for preventive action by the mines.

Jan 5, 1999

By P. Kovalchik

The Bureau of Labor Statistics (BLS) classifies hearing loss as a separate illness category. Hearing loss accounted for 11% of all illnesses in 2005 (U.S. Department of Labor Bureau of Labor Statistics, 2006a). According to occupational data for coal mining provided by the Mine Safety and Health Administration (MSHA) from 2000 to 2005, operators that exceeded 100% noise dosage were from only seven types of machines: auger miners, bulldozers, continuous mining machines, front end loaders, roof bolters, shuttle cars (electric) and trucks (Title 30 CFR Part 62, 2000-2005). Roof bolting machine operators rank second among all underground machine operators that exceed 100% noise dose. There are approximately 600 underground coal mines with 3,930 roof bolting machine operators (U.S. Department of Labor, Mine Safety and Health Administration, 2005; U.S. Department of Labor Bureau of Labor Statistics,

Jan 1, 2008

By W. M. Dressel

A simple field test for detecting the presence of germanium in rocks, coals, and flue dust has been developed by the Bureau of Mines. The method consists of dissolving germanium from the samples by either acid or fusion treatment methods, adding a few drops of hematein or phenylfluorone dye, and extracting the resulting colored complex with carbon tetrachloride. INTRODUCTION Germanium is obtained commercially as a byproduct of zinc production, as a coproduct of base-metal refining from germanium-bearing mineral, and as a recovered product from the ash of some coals. The growing use of germanium in the electronics industry has increased demand for this semiconducting metal to the extent that an intensive search for new sources of supply is necessary.

Jan 1, 1962

Develop personal computer (PC) based software for analyzing and/or filtering time- and frequency-domain attributes of seismic and electromagnetic signals from geophysical surveys for the enhanced interpretation of rock masses and subsurface geologic structure. The Problem Both mining and petroleum geophysicists utilize seismic signals to characterize rock masses for delineating subsurface stratigraphy and structural conditions. However, a vast amount of information available in seismic project evaluation data often is unavailable for interpretation unless these data are enhanced. New processing technology increases the quality of these signals for analysis and interpretation. Comprehensive signal processing software is mostly written for petroleum exploration companies. Commercially available signal processing programs are often limited to a single application or are restricted for use with specific hardware, e.g., a digital oscilloscope or a mainframe computer. The programs may use computer codes that are proprietary, restrict user modification to expand capabilities, or may be hard to interface. They may have insufficient documentation for easy use and be support dependent.

Jan 1, 1990

By James R. Means, George Bowser

A new phone system was developed that provides eight full duplex communications channels over a single twisted shielded phone line, with no central switching station or line amplifiers. This system greatly simplifies installation and maintenance over that required with conventional switching systems. The system is based on microprocessor technology and digital frequency synthesis. Frequency division multiplexing is used over a bandwidth of approximately 300 kHz, and a baseband voice channel (compatible with conventional pager phones) is provided as a backup to assure communication if the multiplex features fail. Multiplex operations are controlled over a 30-kHz digital channel. The system is designed to operate with up to 16 km (10 miles) of cable plant and a maximum phone separation of 8 km (5 miles). The digital techniques permit a limited amount of monitoring and control capability to each phone. This consists of two pair of contact inputs or outputs, to be used as desired. These "flags" may be read or controlled by a dispatcher's phone.

By R. M. Winslow

"The phosphorus content of an iron ore is a determining factor as regards the value of the ore and also its metallurgical treatment. If some method of treatment, such as concentration, leaching, etc., could be used and the phosphorus con- tent of the ore reduced, it would be an important advancement in the iron mining industry towards the utilization of high phosphorus ores. Large bodies of material toe high in phosphorus to be marketable under present conditions would be made available, and a great deal of ore from the Cuyuna Range and other places, which is relatively high in phosphorus but otherwise suitable for making spiegel, could be reduced in phosphorus content sufficiently to permit its use in furnaces producing speigel.The form in which phosphorus occurs in iron ore is a much disputed question and it probably varies with the type and location of the ore. The statement has been made that ore piles on long exposure to the atmosphere often decrease in their phosphorus content. (Emmons, S.F. - Ore deposits, 1913, p. 652; Leith, C.K., Mesabi iron bearing district, U.S.G.S. Monograph 43, 1903, p. 275) There is described below experiments on the leaching of iron ores high in phosphorus, to determine whether it was economically possible to reduce the phosphorus content appreciably by leaching. As the research had a practical as well as a theoretical application, only low concentration of acids and alkalies were used.A number of variables were tried, among these being: (1) The solvent used, (2) strength of the solvent, (3) volume of solution used, (4) time ore was agitated (5) type of ore, and (6) screen size of the ore. The amount of ore taken was kept constant."

Jul 1, 1921

Roof falls continue to be the greatest single safety hazard faced by underground coal miners. During 1996-99, 44 coal miners lost their lives in rock falls, and nearly 2,400 were injured. In addition, nearly 6,000 noninjury roof collapses were reported. Roof supports are installed to protect the miners, but support system failures contributed to most of these incidents. Reducing the terrible toll taken by ground falls continues to be a major goal of research by the National Institute for Occupational Safety and Health (NIOSH). The purpose of these proceedings is to provide the mining community with a comprehensive survey of coal mine roof supports. Drawing on many years of research undertaken by the NIOSH Pittsburgh and Spokane Research Laboratories, this volume describes what types of support are available, how they work, and when they should be used. The major subjects covered include roof bolts, standing roof supports, cable supports, and longwall shields. Some special topics are also addressed, including an analysis of roof fall accident statistics, techniques for better skin control, material handling considerations, and longwall mining through recovery rooms. This proceedings volume also contains information on several important new technologies, which are described here for the first time: •Guidelines for selecting roof bolt length, pattern, and capacity that were derived from statistical analysis of the roof fall experience at 37 underground mines; •A new design method for longwall tailgate supports; and •A technique for measuring loads developed within cable bolts. The papers in these proceedings were presented at open industry briefings conducted by NIOSH on New Technology for Coal Mine Roof Support. The briefings were held in Norton, VA, Charleston, WV, Evansville, IN, Tuscaloosa, AL, Price, UT, Glenwood Springs, CO, and Washington, PA. The papers were also presented at the Mine Safety and Health Administration (MSHA) Preventative Roof-Rib Outreach Program (PROP) Seminar, which was held at the National Mine Health and Safety Academy near Beckley, WV.

Jan 10, 2000

By T. Whitrnoyer, J. Sneckenberger

"The acOustic impedances of seven rat lungs were measured at frequencies between 100 and 6400 Hz. Rats were divided into two groups: a silica exposed group (N=3) and a control group (N=4). The silica exposed group was injected intratracheally with silica solution. Three of the control group were intratracheallyinjected with saline. Between four and six weeks after theinjections, all lungs were excised and degassed. Lungs were,suspended in a pressure Chamber, with the trachea canula attached to the end Of a tapered impedance tube. The lungs were subjected to transpulmonary pressures between -30 cm H2O and 6 cm H2O to simulate deflation and inflation. With transpulmonary pressure being held constant, the impedance tube was excited with random noise. A dual channel analyzer calculated H12(f), the transfer function between the two microphones. This function was used to calculate the lung's impedance at that pressure. The impedance magnitude spectra of both groups typically had peaks at 2000,3500, and 5500 Hz. Statistically significant differences. (90%confidence level or greater) between the two groups occur at the 3500 Hz peak at transpulmonary pressures of 20, 8, 6, 4, and 2 cm of H2O. This fact seems to confirm that this method can detect. lung disease. Further research will indicate whether this method will be able to detect the onset Of coal worker's pneumoconiosis.INTRODUCTIONOne of the first studies of impedance Of the human lung were conducted by DuBois et al.[2] using the forced OscillatiOn technique. This technique, however, was limited to frequencies below 30 Hz. Further studies by Van Den Berg [6] revealed thatthe lung reflected higher frequency sounds (100-10,000 Hz), instead Of behaving as an anechoic termination. This discovery has lead to several studies of the acoustical properties of both human and animal lungs at high frequencies [3,4,5]."

Jan 1, 1988

By W. P. Stroud

In this U.S. Bureau of Mines report, the conditions required for the direct reconstruction of a tomogram from observed line integrals are examined. Because of the limited access to the working faces in coal mines, the special case of access to only two opposite faces is emphasized. Classical matrix methods were used for small dimensional (2 by 2, 3 by 3, and 4 by 4) applications to determine the limitations and the requirements for a solution. The results for large (n by n) grids were then inferred and generalized from those of the smaller grids and matrices. Limited access tomography is found to be appropriate for in-seam hazard detection from seismic and microwave data, but it is shown that additional data must be added to obtain a direct solution.

Jan 1, 2010

To provide a means for rapidly evaluating proposed mine layouts in order to avoid potential hazards while minimizing loss of coal. The Approach: Development of a computer program that will compute many possible mine layouts by changing the mine plan until the arrangement giving minimal hazards with optimum extraction is found. How It Works: The Hazard Evasion Program for Mine Planning, developed by the Bureau's Denver (Colo.) Mining Research Center, tests hundreds of possible solutions to a mining layout, and by sorting out the 10 best (based on the criteria of maximum safety for workers with minimum abandoned coal), limits the number of choices that need to be considered and appraised for applicability to a given mine scheme. The program is applicable for room and pillar or longwall mining, for oil and gas well hazards, and for other hazards that can be described mathematically such as channel sands, potential bad roof areas, faulting, voids, or water pockets.

Jan 1, 1974

By T. N. McVay

The Bureau of Mines has developed a field test for detecting the presence of columbium in a variety of minerals containing the clement. The test consists of fusing the mineral or rock powder with potassium pyrosulfate in a porcelain crucible, digesting the melt with hot dilute hydrochloric acid to release the columbium oxide (Cb205), and subsequently reducing the columbium oxide to a lower oxide by adding tin, which gives a blue color to the contents of the crucible. The method will detect 1 percent of contained columbium oxide (Cb205) in a mineral sample provided no tungsten is present. If a mineral containing appreciable titanium is test,-!d in the same manner, the solution in the crucible becomes violet. In the presence of columbium, titanium at first causes a violet coloration of the solution, which after a few minutes is masked by the stronger blue of the reduced columbium oxide. Although tantalum oxide (Ta205) does not interfere with the columbium test, tungsten gives a blue color that is indistinguishable from the color obtained with columbium. A simple method is available to detect the presence of columbium in the absence of tungsten, but when the presence of tungsten is suspected, the sample must be subjected to somewhat more elaborate chemical tests to determine the presence or absence of columbium. Although these latter tests can be made in the field, several steps are involved that arc best performed in the laboratory with simple equipment.

Jan 1, 1962

Minimize the risk of conveyor belt fires in underground coal mines by improving the accuracy of and means by which flammability data are acquired. Approach Develop a large, laboratory-scale flammability test for mine conveyor belting that realistically assesses its fire resistance. Background A conveyor belt fire in an underground coal mine is a serious threat to life and property. To minimize the risk of belt fires, the U.S. Code of Federal Regulations (CFR) for underground coal mines requires approved fire-resistant belting. Despite this precaution, about 25% of the reportable underground coal mine fires from 1983 through 1988 involved conveyor belting. In several instances, hundreds of feet of belting were destroyed. The current flammability test for fire-resistant belting is specified in 30 CFR, Part 18.65 and is conducted by (be Mine Safety and Health Administration (MSHA). The small-scale test is performed in a 21-in-cubical chamber with 6-in-long by 1/2-in-wide belt samples. To evaluate the flammability of conveyor belting under more realistic conditions, the U.S. Bureau of Mines conducted large-scale fire tests of belting. The large-scale data were then utilized in the development of an improved laboratory-scale flame test for fire-resistant belting.

Jan 1, 1991

By Carlton E. Brown

In 1935 , Brown and Yant / described a microprojector ( microscopic arrangement for projecting images on a screen ) for use in counting and measuring the size of dust particles in Owens - jet dust - counter and simila dry samples of dust collected from the air . In 1938 Brown and others , described a modification of this microprojector that could be used also in counting dust in impinger samples . Microprojectors of this second type have been set up by many mining companies and others and have been made commercially available . Hamly and Pullen5/ described a modification of this microprojector for use in making rapid comparative estimates on konimeter samples and other determinations . This report contains information on still another modification named the "midget microprojector " because of its small size .

Sep 1, 1944