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Synthetic dawsonite [NaAl(OH)2C03] has been prepared with crystallinity similar to that of dawsonite found in oil shale deposits of the Piceance Creek area of Colorado. Optimum experimental conditions were as follows: Na/Al atomic ratio, 43; temperature, 175° to 200° C; pCO2, 15 psig; and reaction time 5 hr. Chemical and spectrographic analysis revealed that the synthetic dawsonite was of high purity and Has essentially stoichwmetric. Similarity of the synthetic to natural dawsonite, demonstrated by X-ray diffraction, infrared spectrophotometry, and electron microscopy, suggests its suitability as a standard.

Jan 1, 1972

By M. J. Ackerman, C. R. Waine, W. M. Merritts, L. P. Mokwa

Tests were conducted in the Pocahontas No. 4 coalbed in southern West Virginia to determine if successful degasification techniques, developed during an earlier study in the Pittsburgh coalbed, would be effective in removing methane from those usually more gaseous coals. Specially designed long-hole drilling equipment and Bureau of Mines continuous recording devices were used to measure the quantity and methane content of the ventilating air during the investigation. Infusions were made with water at normal waterline pressures ranging from 200 to 220 psi or at pump pressures ranging from 400 to 650 psi. Results of the tests showed that methane emissions from free-flow bleeder holes were as much as 131 cfm. Infusions of some of the holes increased the methane emission from other holes and from the exposed coal surfaces near the working areas as much as 1,540 cfm. The methane content in the main return-air currents after infusion was reduced more than 86 percent of the amount recorded before tests were made.

Jan 1, 1963

By Jerry L. Huiatt

An accurate and reproducible procedure was developed using the gas-liquid chromatograph to quantitatively measure oleic acid on flotation products and in flotation water phases. The method comprised extraction of the oleic acid from the mineral surfaces with alcoholic NaOH, esterification of the extracted oleate, and chromatography of the methyl ester with an internal standard. Quantitative analysis of oleic acid on flotation products from test tube and bench-scale flotation tests with pure minerals and with natural ores proved the applicability of the method on a variety of minerals. The accountability of oleic acid added was 100 percent, ±5 percent.

Jan 1, 1968

By Stephen Utter

This report summarizes the procedure and results of an investigation to determine the stresses in the rock around an underground opening in the Climax molybdenum mine, Climax, Colo. This study is part of an overall investigation conducted by the Bureau of Mines to determine the stresses induced by block-caving mining. The purpose of this study is to obtain estimates of the magnitudes and directions of the principal stresses, the location of the maximum stress concentrations, and the effect of topography on the stresses.

Jan 1, 1962

By F. M. Goodwin, John Campbell, G. W. Jones

"INTRODUCTION In previous reports 5 results were given of a manhole investigation carried out over a period from June 1929 to July 193C in cooperation with the Edison Electric Illuminating Co. of Boston. Mass., and during 1931 in cooperation with the Edison Electric Illuminating Co. of Boston and the Boston Consolidated Gas Co., to determine the general hazards of combustible gases and vapors in manholes and other underground openings owned by the Edison Electric Illuminating Co. and to develop methods of eliminating these hazards. These investigations have demonstrated that the detection, control, and elimination of combustible hazards in manholes can best be obtained by a close cooperation of the interested parties through a systematic and continuous inspection of manholes, under proper supervision.The investigation carried out during 1932 has been along lines similar to those conducted during 1929, 1930, and 1931 test crew consisting of two men, one an employee of the Consolidated Gas Co. and the other an employee of the Edison Electric Illuminating Co., was continuously employed during the year in the testing of gases in manholes served by the Edison system. The test crew was under the direct supervision of John Campbell, superintendent of the special service department of the Edison Electric Illuminating Co., and F. M. Goodwin, vice president of the Consolidated Gas Co.As in the previous investigations, all tests were numbered. The test-data sheets, on which the information regarding the tests was recorded, were prepared in triplicate, ono copy going to the Edison Co., one to the gas company, and the third to the Bureau of Mines at Pittsburgh, Pa. These test-data sheets were then filed (1) according to the town, (2) the street location, and (3) the manhole number; in this way a complete record of each manhole tested was immediately available. A typical test-data sheet was given in the 1931 report. These data sheets were found to entirely satisfactory and no changes were made during the 1932 investigation. The procedure of sampling manhole atmospheres, shipment of the samples to Pittsburgh, and method of analysis has been the same as that described in the 1931 report and need not be repeated here. Likewise, there has been no change in the method of calculation of explosibility of the samples analyzed or the use of charcoal filter tests given in appendix A."

Jun 1, 1933

By P. W. Jeran, C. D. Sullivan, C. M. McCulloch

A series of geological surveys were completed in six coal mines in connection with a Bureau of Mines research program on methane control. The aim of these surveys was twofold: First, to study the overall geology of the coalbed, and second to use the resulting data to evaluate the influence of the geological characteristics of the coalbed on safe and efficient coal extraction. This report explains the advantages of geologic maps and fence diagrams in coal mining, and how the knowledge gained from such geologic investigations of mines can help control many underground problems.

Jan 1, 1975

By N. A. C. Smith

One of the most important considerations in any manufacturing industry is the production of stable material, that is, material which will not change in quality before it reaches the consumer. The manufacturer of gasoline, the refiner of crude petroleum, is handicapped in this respect by the varying nature of his raw material, but as far as it is commercially practicable, he has endeavored to improve his product, and in most cases he has been eminently successful. It sometimes happens, however, that a gasoline that is apparently normal when first made, will In time deposit small quantities of a gummy substance. The present Investigation was undertaken in the hope that it would throw some light on these gums and indicate how their formation might be prevented.

Jan 1, 1922

By J. H. Heginbotham

As part of the total metallurgical system to recover metals from secondary resources, the Bureau of Mines conducted froth flotation research, using cationic reagents to recover glass from urban refuse. Batch flotation tests showed that high-quality cullet can be obtained from glass-rich aggregates derived from municipal incinerator residues and unburned refuse. This was confirmed by pilot plant operations treating 350 pounds of flotation feed per hour. Aggregates containing 85 to 90 percent glass were wet-ground to minus 20 mesh, deslimed in two stages, and fed to flotation cells. The glass was selectively floated using an amine collector, usually in an amount under 0.2 pound per ton of solids in the feed. The glass concentrates from the rougher cells were cleaned by refloating two or three times. Over 90 percent of the glass in the deslimed feed was recovered in the cleaned concentrates.

Jan 1, 1978

By Arnold M. Lansche

Domestic Production.-Domestic production of white arsenic, AS,03, was derived entirely as a byproduct of smelting arsenic-containing copper ores by The Anaconda Company at Anaconda, Mont., and American Smelting and Refining Company at Tacoma, Wash. The Anaconda Company discontinued production of white arsenic in 1965. Arsenic metal was not produced. Consumption and Uses.-Most of the white arsenic produced in 1965 was consumed in manufacturing lead and calcium arsenate insecticides.

Jan 1, 1966

By John Millhiser, Stephen J. Kravits

The U.S. Bureau of Mines preproduction Wireless Survey System (WSS) and its performance during an in-mine test are discussed in this report. The WSS was developed to reduce downhole surveying time in order to increase the efficiency of drilling long horizontal methane drainage boreholes in coal. Borehole survey data are electromagnetically transmitted from the WSS7s downhole guidance probe, via the drill rod, to the uph'ole subsystem in less than 1 min per survey transmission, regardless of borehole depth. The WSS7s in-mine test consisted of providing borehole survey data during the directional drilling of a 2,538-ft horizontal methane drainage borehole in the Pittsburgh Coalbed. By considering available drilling time, which does not include hydraulic drill downtime and the time spent traveling portal to portal, 24 shifts were needed to complete the borehole. Of the available drilling time during the tcst, 50 pct of the time was spent drilling and 50 pct surveying and maintaining the WSS to keep it operational. Previous Bureau experience indicates drilling efficiency was increased 108 pct because of the WSS, in comparison with using a commercially available wire-run directional survey instrument at 10-ft intervals.

Jan 1, 1990

By R. H. Thompson

Six different types of blasting caps, mainly of the type used in coal mines, were evaluated to determine both their 1lF and DC characteristics. Two of the caps were of foreign manufacture. All the American made caps had "no-fire" (0.1% firing probability with 95% confidence, as determined by the Bruceton test) levels above 0.04 watts. One of the caps of foreign manufacture had a "no-fire" level of 0.023 watts. A worst case analysis of blasting cap pick up of RF power in coal mines was performed and safe distance curves were generated.

Jan 8, 1973

Hang ventilating air curtains so that they can be installed, moved, opened and closed more easily than curtains that are spadded or nailed in place. Approach Low-leakage plastic curtains fitted with grommets along the top were threaded onto a steel cable which is suspended from roof bolt plates. The system was tested in two mines. How It Works The curtains are threaded onto a steel cable which is suspended from roof bolt plates by S-shaped hooks. See Figure 1. The outby end of the cable is reeled off a hand operated winch; the inby end of the cable is anchored to a roof bolt plate by means of a cable grip and an S-shaped hook. To install the curtains the following procedure is used. First, the winch is located at least 5 feet outby the last open cross-cut. The base of the winch can be secured to the mine roof with short roof bolts, only about a foot long.

Jan 1, 1978

By W. E. Wallace, P. Bolsaltis, M. J. Keane, B. L. Rauaboni

Thermal treatment of respirable size silica dust samples results in marked changes in their hemolytic activity. These changes can be correlated with changes in the characteristics of the particle surface as measured by infrared spectra, zeta potentials, and specific surface area. Silica samples from various sources (Min-U-Sil, fumed silica, and a NIOSH standard sample) were heated or calcined at temperatures ranging from 100-1095C. The hemolytic activity of the crystalline materials decreased after thermal treatment. The behavior of the fumed material was found to be more complex. Material of very large surface area (small particle size) exhibits an initial increase in hemolytic activity upon calcination. This result confirms other experimental observations pointing to a particle size of maximum toxicity. Tre changes in hemolytic activity can be related to infrared spectra and zeta potentials of the materials. The absorption band in the 3200-4000 cm-1 frequency region of the fumed material disappears upon heat treatment while a sharp, characteristic band at 3750 cm-1 increases in intensity. Zeta potential measurements conducted in the pH range of 2.0-10.5 exhibit a unique change in zeta potential v.s. pH profile with heat treatment. These findings indicate that the removal of active surface silanol groups by calcination results in reduced cytotoxicity, as measured by a hemolysis test.

Jan 1, 1988

By M. L. Odenbaugh

The viscosity reduction effect of varied concentrations of leonardite (a naturally oxidized form of lignite) and leonardite-caustic on the rheological properties of a standard bentonite drilling fluid was studied and evaluated. The minimum plastic viscosity was found to occur at application rates of 4 lb of leonardite and 1.33 lb of caustic per barrel of drilling fluid. Leonardite-caustic treatment was not beneficial in treatment of salt-contaminated drilling fluids. Although filter loss rate was reduced; both yield values and gel strength were increased. Compared with other viscosity control agents) including quebracho) ligno-sulfonate) humic acids extracted from leonardite) as well as other reaction products of lignite) leonardite is less effective at low application rates but is an effective treating agent at rates of 2 Ib/bbl or more. Considering the comparable merits of the substance tested) the major factor in determining which agent to use should be based on cost consideration.

Jan 1, 1967

By Joseph E. Matta

The Bureau of Mines conducted tests using a tracer-gas technique to measure the effectiveness of the jet fan, which is often employed in mines to ventilate dead headings. Results of these tests show that jet fans can (1) ventilate dead headings beyond the maximum penetration distance indicated by smoke-tube detection of air movement, and (2) redistribute available fresh air through larger working areas. However, if the fresh air base is insufficient, the fan will merely recirculate the contaminated air and disperse it over a larger volume.

Jan 1, 1978

By David C. McHuron

The U. S. Bureau of Mines in their continuing research into sealants, selected MBAssociates to design, build, and test equipment and evaluate sealant as to its effectiveness is shale degradation. There were 20,050 sq.ft. of coal mine roof sprayed with a mine sealant and as a result, it has been estimated that the sealant coated roof has from 50% to 95% less roof falls than that roof which was not coated with sealant.

Jan 1, 1980

By William L. Rice

Geochemical humus sampling techniques were used by the Bureau of Mines in investigating a potential large, low-grade gold deposit in the Orogrande district, Idaho. Conifer needle humus samples were processed by ashing and fire assay-atomic absorption analysis. An area bearing anomalous concentra¬tions of gold and silver was outlined by the geochemical method.

Jan 1, 1970

By Webster S. Anderson

Two series of tests were run with planer model 'BB": one at the Arickaree mine of the San Francisco Chemical Co., Rich County, Utah, and one at the Roslyn No. 9 mine of the Northern Pacific Railway Co., Roslyn, Wash. The tests at the Arickaree mine were started on June 25, 1958, and continued until September 30, 1958. Prior to these tests, an electrically activated remote-control system was installed, and other modifications were made on the planer. The tests showed that the planer in general and the remote-control system worked very well; however, the various cutting tools used would not consistently penetrate and cut the phosphate rock. This indicated that the cutterhead design had to be changed before the planer would operate efficiently in phosphate beds similar to the "A" bed in the Arickaree mine.

Jan 1, 1962

By F. W. Cox

Exhaust emissions were measured from 25 aircraft turbine engines using Jet A fuel. Analytical apparatus, procedures, and results are described. Carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, and aldehydes were measured at engine operating modes representing power levels used in airline operation. Carbon monoxide, hydrocarbon, and aldehyde emissions were highest at idle and lowest at takeoff; oxides of nitrogen were lowest at idle and highest at takeoff. Of the total oxides of nitrogen emitted, nitrogen dioxide constituted from 10 to 100 pct, depending on the exhaust gas temperature. Engines retrofitted with smoke-reducing burner cans produced less carbon monoxide, hydrocarbon, and aldehyde emissions, and slightly more oxides of nitrogen then engines with standard burner cans.

Jan 1, 1972

By Robert C. Ellman

The Bureau of Mines studied lignite pulverization in a laboratory ring-roller mill. Both moisture content and the source of lignite were found to be important factors in pulverizer operation. Reduction of moisture content increased capacity and reduced power consumption, but predrying is more effective than in-the-mill drying in improving pulverizer operation. A combination predrier-crusher system produced significant improvements but other efforts to improve in-the-mill drying in the test mill were unsuccessful. Pulverization of frozen lignite was found to seriously reduce pulverizer capacity and increase power requirements.

Jan 1, 1972