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By T. T. Campbell

Research conducted by the Bureau of Mines demonstrated the feasibility of preparing columbium and tantalum metals by the application of Kroll-process techniques. Yields in excess of 95 percent were obtained in a modified Kroll-process reduction apparatus constructed from nickel and Inconel.4 Operating conditions during reduction and distillation were determined. Optimum temperatures during sodium reductions ranged from 650° to 750° C and for magnesium from 700° to 800° C with retort pressures ranging from 3 to 7 psig. Undesirable vapor phase reactions occurred when temperatures exceeded 750° C during sodium reductions or 850° C with magnesium. Vacuum distillation at 850° C effectively removed volatile salts and excess reductant from the reduced metals. Calculations based on the results obtained in small scale tests indicate that reaction rates of up to 34 lb/hr could be obtained during columbium reductions and up to 60 lb/hr during tantalum reductions in production scale reac¬tors. The small, laboratory-scale techniques used in this study could be adapted to commercial practice. The reduced powder or sponge metals can be consolidated by conventional arc-melting techniques, and the arc-melted metals can be fabricated into ductile sheet at room temperature. Analyses of arc-melted buttons prepared from Kroll-process tantalum or columbium showed that tantalum of greater than 99.8-percent purity was obtained and that columbium purity exceeded 99.7 percent. A significant purification of the reduced metals occurred when they were consolidated by electron-beam melting, and the purity and ductility of electron-beam-melted Kroll-process tantalum and columbium compared favorably with the commercial metals. After electron-beam melting, the purity of the tantalum exceeded 99.95 percent, and columbium purity was approximately 99.9 percent.

Jan 1, 1962

Provide a coalbed methane data source for industry use in mine planning. Approach Coalbed methane data have keen collected and formatted into a computer implemented data base with software developed for storage, retrieval, and generating files of selected data in response to information requests and for statistical analysis of relationships among various coal parameters. How It Works Coalbed methane data is obtained by the Bureau's direct method test on exploration coal cores. The test involves sealing fresh coal cores in desorption canisters and periodically bleeding the gas into a water-filled, graduated cylinder to measure the volume of gas released. Coalbed methane data collected over the past 9 years have been entered into a computer-implemented data base for efficient retrieval and statistical analysis. Data base processing is accomplished with a commercially available storage, sorting, retrieval, and report writing software package (Datatrieve 11). Information requests from the coal industry are processed with the system, and the data in the desired output format am printed and forwarded to the requestor. Information such as coalbed name, location (state and county), depth of sample, gas content, and coal rank are available from the system. The data can be used for

Jan 1, 1982

By F. J. Smith, W. A. Gallagher, C. A. Herbert

"INTRODUCTION A fire started about 10 a.m., November 10, 1947, at the Kings mine, Princeton Mining Co., Princeton, Ind., about 1,800 feet inby the main shaft bottom on the main west haulage road at a point estimated to be 2 miles from the faces of the main west entries. No lives were lost, as 27 men escaped from the mine after a series of explosions, which necessitated sealing the mine on the surface. This information circular shows"" how adverse conditions might be overcome, when reopening a sealed mine, by expert planning and close cooperation on the part of various organizations. Conditions found in the mine after it was reopened were comparable to the worst that had been anticipated, yet the mine was recovered with comparatively little difficulty and a minimum of risk. The open workings in the mine covered a vast area, but most of the mine resumed production of coal after being sealed for only 37 days.The information contained herein also points to the desirability of adhering as closely as possible to a predetermined schedule of operations."

Feb 1, 1949

By Deborah A. Kramer

As part of the Nation's growing concern with the competitiveness of U.S. firms in the world economy, especially with respect to advanced materials, the Bureau of Mines assessed the actual and potential recovery and manufacturing capabilities for gallium and gallium arsenide (Gacis). GaAs has advanced from a laboratory curiosity to a material with important "high-tech applications within only the last few years, and although protected North American gallium supplies are currently considered adequate, consumption could grow to the point that this assessment would need reevaluation.

Jan 1, 1988

By Stephen D. Smith

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Also included are tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may he measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output." It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1989

By George J. Conroy

This Bureau of Mines publication describes several fault locators and methods, including time domain reflectometers, a frequency domain reflectometer, tone generators, an infrared method, the Murray loop method, and high-voltage "click" methods. The Bureau of Mines has been conducting research into these methods for several years, to improve mine safety and facilitate production through rapid, safe location of trailing-cable faults. The problems encountered in practical applications are discussed, and schematic diagrams of several instruments fabricated by the Bureau are presented. Since no present single method of locating trailing-cable faults is universally applicable, a kit composed of several of the more promising fault locators is advisable.

Jan 1, 1978

By Ronald D. Hill, Elmore C. Grim

The removal of overburden often exposes pyritic materials (iron disulfide). As shown in equations 1 and 2, the oxidation of this material results in the production of ferrous iron and sulfuric acid. The reaction then proceeds to form ferric hydroxide and more acid, as shown in equations 2 and 4. [ ] Consequently a low pH water is produced (pH 2-4.5). At these pH levels, the heavy metals such as iron, manganese, copper, and zinc are more soluble and enter into the solution to further pollute the water. Water of this type supports only limited water flora, such as acid-tolerant molds and algae; it will not support fish life, destroys and corrodes metal piers, culverts, barges, etc., increases the cost of water treatment for power plants and municipal water supplies, and leaves the water unacceptable for recreational uses. The amount, and rate of acid formation, and the quality of water discharged are a function of the amount and type of pyrite in the overburden and coal, time of exposure, characteristics of the overburden, and amount of available water(l). Crystalline forms of pyritic material are less subject to weathering and oxidation than amorphic forms. Since oxidation by oxygen is the primary reaction during early acid formation, the less time pyritic material is exposed to air, the less acid is formed. Thus, a positive preventative method is to cover pyritic materials as soon as possible with earth, which serves as an oxygen barrier. In terms of mining, this step is accomplished by current reclamation techniques and small open pits.

Jan 1, 1974

Table B-1. Summary of respirable coal mine dust samples collected under 30 CFR 90 by MSHA inspectors for underground occupations, 1988-92* [ ]

Jan 1, 1997

Research workers from the Bureau of Mines and industry met with other government and industry representatives at the Mont Chateau Lodge, Morgantown, W. Va., on May 30-31, 1973, to discuss the current status of methane control in eastern U.S. coal mines. The opening remarks, the eight technical presentations, and the discussions of the members of a government-industry panel are published here for the benefit of those concerned with the control of methane in coal mines. In addition, an introduction has been added to present the background of work in this field.

Jan 1, 1973

By N. A. C. Smith

During the past, six, years, the Bureau of Mines has made and. published several hundred analyses of typical crude oils and 'has developed a system of interpreting the analyses and of classifying crudes. This system is presented here with. It is apparently equate for classifying crude oils into four main groups and has also been found very convenient in studying the geological relationships between crude oils, and the probable refinery yields of valuable products from them. Crude petroleum is morn to be a very complex substance. An analytical statement of its properties must, therefore, consist of two distinct parts, - first, the report of the results of the determinations made by the analyst in the laboratory, - second, the proper arrangement, classification and interpretation of these results so that the analysis, as a mole, will indicate the meaning- and the relative- importance of the essential characteristics of the oil.

Jan 1, 1927

By Roy H. Grau

The National Institute for Occupational Safety and Health (NIOSH) has conducted research to improve the ventilation of large-opening mines whose entries are at least 93m2 (1,000 ft2). The ventilation of large-opening mines is unique compared to other types of mines because (1) it is challenging to keep airflow velocities high enough to effectively remove or dilute airborne contaminants because the entries are so large, (2) large air volumes can be moved through the mines with little static pressure drop, and (3) stoppings that are used to direct ventilation airflows are costly to construct and to maintain. The research results suggest that the ventilation of large-opening mines is improved significantly by incorporating ventilation planning into the mine planning process, using propeller fans to direct airflow, developing new stopping materials and construction methods, and using long pillars to eliminate crosscuts where possible.

Jan 1, 2009

By Walter E. Pittman

This Bureau of Mines study surveys the current state of technology and the various research efforts that have been undertaken to dewater the dilute phosphatic clays generated in the production of phosphate rock. The research described includes early dewatering experiments, fundamental studies of clays and of flocculation, and minor dewatering techniques such as freeze-thaw methods, the ANDCO process, moving screens, sand wick, crust development, and overburden pumping. Some methods that are currently being evaluated are described. They include the Estech sand-clay mix process using the Enviro-Clear thickener, sand-clay sandwiching, dredge mix, dredge process, and the sand-spray process. Developing technology for dewatering phosphatic clays also is described, including the Bureau of Mines rotary trommel method and the Gardinier process.

Jan 1, 1984

By John P. McDonnell

This U.S. Bureau of Mines report describes the results from an in-mine investigation of an alternative longwall gate road design. The coal mine operator modified the pillar layout (reversed the location of the big and small pillars) in a portion of a three-entry longwall gate road area. The modified pillar layout was an attempt to reduce stress and, subsequently, stress-related ground control problems (cutter roof and dynamic floor heave events) in the tailgate region during "second-panel" mining. The results from borehole pressure cells installed in the modified gate road area showed that the ground pressures in the panel edge and adjacent small pillar were significantly reduced during second-panel mining compared with ground pressures experienced in the typical pillar layout gate road areas. The reduced stress levels around the tailgate entry adjacent to the second panel, as compared with the tailgate stress levels with the typical pillar arrangement, contributed to improved tailgate ground conditions in the test pillar zone.

Jan 1, 2010

By G. E. McClelland

As part of its mission to assure an adequate domestic supply of metals essential to the Nation's welfare, the U.S. Department of the Interior, Bureau of Mines, investigated a particle agglomeration technique as a means for improving the flow of leaching solution through heaps of clayey or finely crushed, low-grade, gold-silver ores. Bench-and pilot-scale experiments showed that the percolation rate of cyanide leaching solution was markedly enhanced by mixing the ore with a portland cement binder, moistening the mixture, and mechanically agglomerating and aging the feed prior to heap building and leaching. The rate of gold and silver recovery markedly increased because of the increased, uniform percolation of leaching solution through the agglomerated feed. The use of concentrated cyanide solution instead of water during the agglomeration procedure decreased the leaching time required to obtain maximum recovery. Results of bench-and pilot-scale experiments are discussed.

Jan 1, 1981

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

9. Remote Sealing System Sensitivity 9. 1 Introduction In the previous sections a description of the overall system has been presented along with detailed descriptions of the equipment and techniques employed with the preliminary probing system, the seal em¬placement system and the seal checking system. In addition, the use of these subsystems in a specific mine application has been described in considerable detail. A broad range of parameters of interest was specified in the contract, as summarized in Section 1. 3. Most of these are a function of the general location; i. e. , the location of the mine, and the specific location; i. e. , the location of the boreholes. These parameters of interest include passage size, shape, depth, slope and water con¬ditions. The length, diameter and location of the boreholes within the mine passage and on the surface are critical parameters as well. A few additional parameters may affect one or more of the remote sealing subsystems. These include temperature, topography, rock and soil conditions, and underground water. While variation in these parameters will not render the system inoperative, consideration of them in the planning stages will simplify and expedite the field operation. In the following sections the effect of the various parameters on the remote sealing operation will be discussed. For clarity, the several tasks, borehole drilling and casing, preliminary probing, fly ash delivery, foam topping and seal checking, will each be considered separately.

Jan 1, 1973

By J. C. White

A research study was conducted to devise a method for producing phosphoric acid directly from unbeneficiated Florida phosphate matrix. This research was performed as part of the Bureau of Mines, U.S. Department of the Interior, goals of improving minerals and metals recovery from domestic resources and of minimizing the environmental impact associated with mineral recovery operations. This report describes research in which unbeneficiated, dry, south-central Florida phosphate matrix was digested with sulfuric acid in a continuous-circuit, five-tank reactor to yield phosphoric acid and gypsum residue. Feed capacity of the reactor was 100 pounds (45 kg) of dry matrix per 24-hour day. When digestion was carried out at 185° F (85° C), acid filtration rates of up to 420 pounds of P20S per square foot per day were attained. Combined iron and aluminum impurities in the product filter acid were about 60 percent greater than values reported in commercially produced acid derived from concentrate. phosphate recovery was 87 to 90 percent of the phosphate contained in the as-mined matrix.

Jan 1, 1978

By Carl E. Norman

An investigation of geologic structure on macroscopic, mesoscopic, and microscopic scales was conducted on near-surface igneous and metamorphic rocks in which the existing stress field was determined by in situ methods. A consistent NE-SW orientation of the maximum compressive stress in the horizontal plane at four of five test localities appears due to the intrusion of NW-trending diabase dikes. Structural features at the mesoscopic scale show no consistent directional relationship to determined stress directions. Petrofabric diagrams of open microfractures show preferred orientations, but these are not consistently related to the orientations of larger structural features, such as joints, foliation, or mineralized shear zones. However, at five of six test sites the preferred direction of microfractures occurs nearly perpendicular to the maximum principal stress directions; an anomalous parallel relationship exists at a test site in an intrusive rock body. The results suggest that the open microfracture subfabric may provide a means for gaining information on the directional properties of stress fields. Such information can be obtained from oriented cores taken from holes which exceed the approximate 100-foot depth to which other in situ methods are presently limited.

Jan 1, 1970

By L. Cheng

This Bureau of Mines report summarizes an investigation of the amount of respirable dust adhering to the surfaces of seven run-of-face broken bituminous coals. The number of respirable-size (0.9 to 10 micrometers) particles adhering to the run-of-face coal ranged from 1011 to 1012 particles per pound of coal and was approximately inversely proportional to the mean lump size of the coal sample, otherwise it did not vary significantly with the coal seam, mining method, or winning machine. Based on these results, about 16 lb of ordinary run-of-face broken coal would have enough respirable-size adhering dust to contaminate 1,000,000 ft3 of air up to the 2 mg/m3 level, if this adhering dust should become airborne. Although brief studies here suggest that a negligible amount of new respirable dust is formed due to fracture of the broken coal during dropping, dislodging of old adhering particles during secondary handling operations is a potentially dangerous source of airborne respirable dust.

Jan 1, 1973

By D. L. Boreck

Thick coal seams are common in the Western United States, Many seams are over 50 it thick (some are over 200 ft thick) and are too deep to extract using surface methods. Currently, such deposits are developed using standard "eastern" mining methods which only extract a few feet of total seam thickness, often rendering the remaining coal unminable with current technology. Novel methods that increase thick-seam recovery have been developed and are currently being used in Europe. These methods--high-face single-pass and multislice longwall, longwall caving, and hydraulic mining--have great potential for use in the United States. Successful use of these methods is an objective of the Bureau of Mines. Their use requires, among other things, a full evaluation of geologic features common to thick coals. The objective of this report is to present and summarize those features that will affect the introduction of the methods into thick-seam mines in the Western United States. The geologic elements delineated are three-dimensional configuration of the seam, cleat development, joints and fractures, roof and floor lithology, and faulting.

Jan 1, 1986

By O. C. Baptist

The gravitational pressure gradient (GPG) in porous sandstone containing free gas was determined to define the proper GPG to use when calculating the rate of downdip flow of oil in the Sub-Scalez No, 1 sand, Elk Hills field, Naval Petroleum Reserve 1. The GPG was determined at several gas saturations using long, artificially consolidated sandstone models that were mounted vertically in some tests and horizontally, with rotation, in others. Also determined by laboratory and field tests were relative permeabilities, capillary pressure relations; critical gas saturation, water sensitivity, and depletion drive performance. The critical gas saturation in the models having an absolute permeability of 1 to 2 darcys was about 2 percent of pore volume. The GPG with the critcal gas saturation was that due to the weight of the gas-saturated oil. The GPG in the upper part of the models was reduced as gas saturation increased to a value considerably larger than the critical. The exact gas saturation at which the GPG became less than that due to the weight of the oil could not be determined but was estimated to be of the order of 10 percent of pore volume. Tests indicate that the rate of oil production is not permanently reduced by exposure of the sand to fresh water but that the rate of injection of fresh water will be considerably less than that to brine, Methods for determining the factors mentioned above are discussed.

Jan 1, 1967