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By B. D. Nash

The Bureau of Mines continued its research into the recovery of fluorine by the phosphoric acid acidulation defluorination of phosphate rock concentrates. A small process development unit with a capacity of about 10 kilo-grams of charge per hour was operated, and concentrates from both Idaho and Florida were processed. Over 80 percent of the fluorine was evolved and recovered as a dilute fluosilicic acid solution. Phosphate extraction from the concentrates always exceeded 98 percent. The fluorine was converted to a synthetic fluorspar product (3CaFa?SiOa) suitable for use as a slag conditioner in electric furnace steelmaking operations.

Jan 1, 1977

By Aner W. Erickson

"Magnetite iron deposits on Tolstoi Mountain were examined as part of the investigations by the Bureau of Mines of iron and copper ores on Prince of Wales Island. The Tolstoi Mountain project was a part of a program for investigating mineral deposits in Alaska, under the general supervision of R. S. Sanford, acting branch chief.A preliminary examination was made by S. P. Holt, mining engineer of the Bureau of Mines, in company with John Reed, L. A. Warner, and W. S. Twenhofel of the Federal Geological Survey, on July 14, l943. Three samples were taken, rough estimates were made, and it was proposed that the area be mapped, topographically and geologically,. Dip-needle work was added to the program, and it was decided that, should results warrant, the deposits would be diamond-drilled.From March 26 to May 28, 1944, the deposits were examined thoroughly by Bureau of Mines personnel under the direction of the author. Thirty-two acres were mapped with contour intervals of 10 feet, grids were established covering the principal outcrops, over 1,500 dip-needle readings were secured, and the magnetite bodies were outlined. Additional information was gathered by trench inch and channel-sampling, 600 linear feet of trench being dug and 32 channel samples being cut. Finally, the mapped area was checked for nonoutcropping deposits by taking dip-needle readings at 10-foot intervals along the traverse lines, creeks, trails, and all outstanding topographical features. This re-connaissance work gave sufficient coverage of the 32 acres to eliminate the possibility of further magnetite bodies of any consequence remaining undiscovered.Acknowledgment is made to Nile Johannsen, assayer, Territorial Department of Mines, Ketchfkan, Alaska, for determination of samples.The deposits are on Prince of Wales Island in Southeastern Alaska near Tolstoi Pay, a deep-water indentation at the northwest and of Kasdan Peninsula. The physical features are shown on figures 1 and 2 and the location of the deposition figure 3. Old workings were found on the west side of Tolstoi Mountain; between elevations of 650 and 1,150 feet, at distances of 3/4 to 1-1/4 miles from the east shore of Tolstoi Bay.Access to the area is over a brushed foot trail built by the Bureau of Mines. Topography would permit construction of either surface or aerial tramways at moderate cost but would make road building expensive. Deep-water navigation, permitting inexpensive water transportation, is possible the year around.Kasaan Peninsula is an area of moderate relief, being considerably less rugged than the mainland to the east. Most of the mountains and ridges are less than 2,500 feet in height and show evidence of having been covered by the ice cap of the Pleistocene age. Rock exposures below elevations of 2,000 feet are limited, as extensive overburden 2 to 20 feet deep covers the greater part of the peninsula."

Dec 1, 1948

By R. B. Prater

The Bureau of Mines conducted research to separate the F from byproduct Zn concentrates obtained from fluorspar (CaF2) production, as part of the Bureau's effort to devise efficient, environmentally acceptable technology for recovering Zn from resources considered undesirable by Zn producers. Sulfuric acid (H2SO4) was found to be effective in F removal, while ammonium carbonate [(NH4)2C031 was not. The most important variables for reducing the necessary residence time were found to be temperature and agitation. Optimum leaching conditions were 75° C and 500 r/min for 2 h at 40 pct solids with 0.2 g acid per gram of concentrate, which resulted in a 98.3-pct F extraction. Zinc losses during F removal were in the range of 2 to 3.3 pct. Other elements such as Fe, Cd, Ca, and Cu were also partially dissolved. About 93 pct of the F was removed from the leach solution by neutralization and precipitation with calcium hydroxide [Ca(OH)2]. Additional treatment might be necessary to limit the buildup of soluble elements in the recycled leach solution.

Jan 1, 1985

By R. K. Koch

The normal spectral emissivities of liquid Ti, V, Zr, Mo, and Pt were determined at the fusion temperatures in an electron-beam furnace using a water-cooled copper hearth. The normal spectral emissivities were estimated above the melting points by using adjusted two-color temperatures as approximations of the true temperatures for substitution in Wien's equation. Simultaneous brightness temperatures were determined with a micro-optical pyrometer. The true temperature ranges covered were 1,668° to 1,885° C for Ti; 1,919° to 2,013° C for V; 1,855° to 2,367° C for Zr; 2,610° to 2,751° C for Mo, and 1,772° to 1,990° C for Pt. The spectral emissivities for titanium and zirconium decreased with increasing temperature. At an effective wavelength (?) of 658 mµ the emissivity of titanium ranged from 0.51 to 0.45 and zirconium, from 0.47 to 0.41. The emissivities of vanadium (? = 658 mµ) and molybdenum (? = 657 mµ) were constant at 0.41±0.02 and 0.33±0.01, respectively. The spectral emissivity of platinum (? = 658 mµ) was constant at 0.39±0.02 up to 1,900° C; above that temperature anomalous data were obtained. A mass spectrometric study indicated that platinum was reacting with back-streaming silicon vapors from the diffusion pump when the ambient pressure was greater than 2 X 10-5 torr.

Jan 1, 1973

By Mark R. Pettitt

After a long series of laboratory and in-mine tests, a cost- effective, mineworthy, reduced-noise auger miner cutting head was de signed, fabricated, and field-tested by Wyle Laboratories under contract to the Bureau of Mines. Compared with standard auger cutting heads, the new heads reduced noise by 10 dBA at the jacksetter's position and by 6 dBA at the operator's position. This report contains detailed fabrication instructions, including engineering drawings, that show how a standard auger cutting head can be modified to produce a reduced-noise auger.

Jan 1, 1984

By Bruce F. Grant

This report discusses research being done by the Petroleum and Natural Gas Branch und the Applied Physics Branch of the Bureau of Mines to deter-mine the most effective uses of explosives in shooting oil and gas wells, as measured in terms of rates of production from the wells. An experimental investigation of the effects of detonating explosives in shallow holes drilled in rocks, chosen to be similar to those forming oil and gas reservoirs, forms the basis of this study. Records obtained from strain gages placed in the rock around the experimental shots permit determination of the generation and propagation characteristics of the strain wave. Water-injection tests made on the test holes before and after shooting allow the increase in fluid conductivity resulting from the shot to be determined. By rotating these data to the physical properties of the rock, and by conducting shooting experiments over the range of rock types common to oil and gas reservoirs, it is expected that relationships between the fluid conductivity and the properties of the explosive and rock can be developed and used for designing efficient shots for oil and gas wells. Four series of experiment.al tests were completed during the summer of 1949 and are described herein. The results of these tests confirmed the feasibility of the experimental approach and permitted outlining the plans for future research discussed in this report. This report is presented to acquaint industry with this research program and the progress to date, so that the Bureau may have the benefit of suggestions from interested readers.

Jan 1, 1950

By J. G. Kirby

The number of petroleum refineries in the United States continued to decline during 1954, and according to the Bureau of Mines annual survey there were 326 refineries with a total daily throughput capacity of 8,420,630 barrels, as of January 1, 1955. The increase in capacity for the year was 413,733 barrels daily, while the number of refineries declined 11. The capacity of the average refinery to process crude oil increased during 1954 from 23,759 barrels daily to 25,830. Breaking down the crude-oil capacity increase, by refining districts; 32 percent was installed at refin¬eries located in the Texas Gulf Coast district, 25 percent in the East Coast district, and 13 percent in both the Louisiana Gulf Coast and the California districts. The Appalachian No. 1, Texas Inland, and New Mexico refining districts reported declines in capacity during the year. Additional crude-oil capacity under construction, January 1, 1955, totaled 146,800 barrels daily. Included in this total are 4 new refineries, 1 each in California, Minnesota, New Mexico, and Washington. In addition to the' new facilities, equipment producing 1.49,550 barrels daily is being replaced.

Jan 1, 1955

By John C. Machisak

THE INJURY data and experience at quarries and related plants of the United States are presented in this publication under the following general sections (A) General injury experience: Tables 1-3: Current data on number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment data. (B) Injury experience at different kinds of quarries: Tables 4-5: Current data on number of injuries, injury-frequency rates, location, accident agency, degree of injury, and related employment, data. (C) Injury experience by States: Tables 6-20: Current data on the number of injuries, injury-frequency rates, accident agency, degree of injury, and related employment data. (D) Selected injury data: Tables 21-30: Current data on various selected factors of operating conditions at different kinds of quarries, including employment size-groups, length of shifts, comparative severity of injuries, and injury data and related employment experience at dimension-stone and nondimension-stone quarries and at underground quarries. (E) Historical injury experience: Table 31: Injury and employment data on the quarrying industry for 1911 through 1957. Statistical data on injuries and related employment in the quarrying industries have been collected annually from the operating companies since 1911. Reporting to the Bureau of Mines is voluntary; there is no Federal law compelling operators of quarries and related plants to supply such data. Data presented herein may not be complete for the entire industry. They are however, believed to be representative of the hazards common to all quarry and related workers. Moreover, the figures are comparable as between States-a significant fact in view of the lack of uniformity among the States with regard to the classes of injuries covered by State reports and other factors that tend to make it impracticable or impossible when using State records to

Jan 1, 1960

By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By J. W. Sterner

The Bureau of Mines conducted studies on four makes of Japanese automobiles, three 1981 and one 1982 model years, received from three manufacturers to determine if their materials composition would present problems to the current technology used to process junk automobiles for metal recovery. One of each make of automobile was hand-dismantled to determine the materials composition. In addition, two nearly identical automobiles of each make were shredded at a commercial operation where all metal products and rejects were collected for analysis to determine metal and nonmetal distribution. The average weight of the four automobiles to be dismantled, less batteries, tools, and fluids, was 1,938.3 lb. The weight was distributed as 1,472.9 lb. ferrous and 115.6 lb nonferrous metals, 275.2 lb combustibles, 72.3 lb noncombustibles, and 2.3 lb electrical components. The dismantled automobiles, less gas tanks, fluids, tools, wheels, tires, and batteries, which were all removed from the automobiles that were shredded, contained an average of 1,389.1 lb ferrous and 101.6 lb nonferrous metals, 305.7 lb nonmetals, and 2.3 lb electrical components. In comparison, materials collected from the shredded automobiles averaged 1,304 lb ferrous metals, 80 lb nonferrous metals, and 341 lb landfill materials. There were no materials used in the manufacture of the late model Japanese automobiles that should present handling or processing problems to the steelmaking or secondary metal recyclers.

Jan 1, 1984

By G. E. McElroy

"The development of certain mines in the East Tintic mining district, Utah, has been hindered considerably by the presence in the rock strata of heavy irrespirable gases which at times flood the lowest working places, as well as by abnormally high rock temperatures in the lower horizons. A study of these features was completed in the spring of this year, and the information obtained is summarized here.Heavy gases.Only four mines have been affected to date by the presence of heavy gas, and only one of these is producing lead-silver ores in quantity. These four embrace a territory extending about three miles north and south and about two miles east and west, while both within and fringing on this territory are a number of prospects which have not been affected.Thus far no fatalities have resulted from gas inflows, but a number of men have been temporarily overcome, and a few have had narrow escapes from death by suffocation. That the record is not more serious is mainly due to the fact that the gas inflow, as a rule, is relatively slow, mining operations have been quite carefully conducted, and the presence and extent of a gas inflow can be easily determined by its extinguishing action on the flame of miners' lights.When first encountered, about 1910, gas inflows occasioned much lost time. In some months the lost time averaged as much as ten days, while one mine cites for a certain month a maximum of 26 days lost out of a possible 28 working days. With improvements in mechanical ventilation and the passing of time, interference with work from the presence of gas has gradually lessened. During the last few winters, the main trouble has been with the mines being flooded with gas overnight when fans were not operated, although men have been driven out of the lowest development openings several times each winter with fans operating. At present, the main danger is in the lowest development openings having only one exit, wherein men might be trapped and possibly suffocated during an unusual and extremely rapid inflow of gas, or during an ordinary inflow, should the one source of power for the fan be disabled."

Aug 1, 1921

By D. W. Dareing

Multiple branch wellbores and horizontal holes, when applied to deep lying ore bodies, have the potential of significantly reducing well costs by reducing total footage drilled per acre of well pattern. In addition, horizontal holes may increase sweep efficiency. Well completion is a major problem. They must be cased to contain leaching solutions within the underground portion of the production loop. Several drilling and completion concepts are given and evaluated in the report. Our evaluation shows that there is economic incentive to further develop these concepts for field application to ore bodies 1,500 feet. Multiple branch concepts are the most attractive. They can reduce well costs by as much as 30° when applied to 2,000 feet ore body depths (44%, at 5,000 feet) and can accommodate a lamer pump than conventional vertical wells. We recommend this concept be developed further to accommodate either dual or triple branches.

Jan 1, 1980

By Patricia J. Leonard - Mayer

A Bureau of Mines surface resistivity method has been used to determine the joint strike and coefficient of anisotropy of jointed , nearsurface formations at five study areas . The field studies demonstrate the use of rotated , or azimuthal , Wenner-Lee arrays for determining the strike of predominant joint sets . The results of the field studies include the following : in a formation having a predominant , vertical joint set , the maximum value of the apparent resistivity ( pa ) occurs in the same direction ( azimuth ) as the joint strike ; the polar coordinate graph of pa for such a formation is approximately elliptical ; the coefficient of anisotropy ( ^ ) can be calculated from the field data , and values of λ for jointed formations are in the same range of values reported for layered formations ; values of λ are higher at mined sites than at unmined sites . The azimuthal resistivity method and horizontal profiling were used at a site in Pennsylvania to delineate a zone of intensely jointed and fractured bedrock that provided a flow path from a surface stream to a mine . Analysis of the data has been based on a simple model of a jointed formation having a single joint set ; the success achieved to date indicates the need for a more complex model and additional field data .

Jan 1, 1983

"Qatar, crude petroleum, production, annualdata MY 1949-51Quality mine, Ark., coal, carbonizing properties TP 667washabilty study RI 496N. Dak., lignite, grindabilty as function ofmoisture, tests, results RI 5167"

Jan 1, 1960

By W. T. Millar

Field reconnaissance and laboratory tests on clay from South Windsor, Hartford County, Conn., indicate that the clay is suitable for lightweight aggregate raw material. Exploration of the deposit supports the conclusion that the reserves of clay are sufficient for economical mining operations to produce lightweight aggregate. Preliminary tests indicated that the clay has a short bloating range. Initial expansion occurred at 2,000° F, and at 2,100° F the clay was slightly overfired and sticky. Rotary kiln tests verified the preliminary data, and these tests showed that the clay would make a good lightweight aggregate if the processing temperature and the kiln feed sizes were closely controlled. Lightweight concrete made from the processed aggregate had properties comparable to those of concrete made from a commercial clay aggregate.

Jan 1, 1964

By E. C. Perkins

This report describes a ferric chloride trap, based on formation of a low-melting sodium chloride-ferric chloride mixture of near-eutectic composition, and its use in chlorination of impure titaniferous materials. The trap is placed in the hot gas stream between the chlorination reactor and the condenser. Virtually all of the iron is removed by the trap. The condensed titanium tetrachloride is free of suspended solids and contains only a trace of iron. Four examples are given of the use of the ferric chloride trap in chlorination of impure titaniferous materials. INTRODUCTION In the Kroll process, ductile titanium metal is produced by reducing titanium tetrachloride with magnesium metal.4/ In commercial practice, titanium tetrachloride is produced by chlorinating titaniferous materials in the presence of carbon.2/ In 1957 most producers were using rutile, and virtually all plants were designed for its use. About four-fifths of the domestic consumption of rutile was imported from Australia. The Bureau of Mines, under provisions of contract DMP-116 with the General Services Administration, studied electrosmelting of domestic ilmenites and titaniferous magnetites to produce high-titanium slags with pig iron as a byproduct. Under the same contract, chlorination studies also were being made of these slags. Smelting was done at the Northwest Electrodevelopment Experiment Station, Albany, Oreg., and chlorination at the Electrometallurgical Experiment Station, Boulder City, Nev.

Jan 1, 1958

By J. H. Wiggins

In 1919 the United States was threatened with a shortage of gaso- line. In spite of this well-known fact, a detailed field investigation has shown that in one stage only of handling crude oil the volume of gasoline that evaporates is equal to one-thirtieth of the country's yearly gasoline production. This loss occurs during the few days that the oil is stored on the leases before being taken by the pipe line, and in 1919, in the Mid-Continent field alone, it amounted to 122,100,000 gallons. Large as it is, it is only a part of the loss on the lease. Investigation has further shown that the gasoline in crude oil evaporates from one-half to six-tenths as rapidly as the same gaso- line after being distilled and stored, all evaporative conditions being the same. Many wastes in the oil fields are called "necessary." By this is meant that the cost of preventing the waste is greater than the gain through saving. Evaporation losses have fallen heretofore in this category, but now they must be considered unnecessary. In other words, it is no longer economical for any handler of crude oil to permit losses through evaporation. In accordance with its purpose of seeking to conserve mineral resources, the Bureau of Mines investigated the loss of gasoline by evaporation in the storage and handling of petroleum. Inasmuch as most producers had not decided that their losses justified cor- rective measures and no evidence was available on the comparative losses in various stages of handling the oil, the investigation was limited to determining by experiment and observation the nature and magnitude of evaporation losses, where the greatest losses are, and the factor controlling evaporation.

Jan 1, 1922

By C. J. Wilhelm, John M. Devine

"Hydrogen aulphide associated with natural as was noted as early as at Point Albino, Canada. 4 The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence ma by no means common. However, in recent years, with the development of the producing zones of west Texas and the Texas Panhandle the production of ""sour"" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor-frequently a major problem—in the drilling and operation of any wells in those areas.The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen sulphide. From the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. 5 Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.6"

Sep 1, 1931

By D. P. Lindroth

The Bureau of Mines is engaged in research on ground probing radars for detection of geologic hazards in advance of mining. Penetration distances and interpretation models depend on the dielectric properties and wave propagation characteristics for coal measure stratified media. Relative dielectric constants and dissipation factors were measured under ambient conditions for Pittsburgh Seam coal measure rock over the frequency range of 20 to 100 MHz by the susceptance-variation method. The rock types measured were representative sedimentary rock located above the Pittsburgh Coal Seam. Extreme values for the computed attenu-ation distance ranged from 1.7 m at 100 MHz for siltstone to 230 m at 20 MHz for a particular limestone.

Jan 1, 1984

By V. F. Parry

The major industrial uses of char or semicoke produced by low-temperature carbonization of coal4/ are as fuel for generating electric power, for blending with metallurgical coking coal as a substitute for low-volatile coals, and for gasification to produce synthesis gas for chemical purposes. This paper discusses various methods for carbonizing coal, emphasizing processing of the noncoking coals to produce char for thermal power-plant fuel and for blending with metallurgical coking coals and tar for chemical use. Low-temperature carbonization is a relatively simple processing step involving heating coal to about 900° to 1,200° F. to decompose the coal into 4 main products: (1) Semicoke or char; (2) complex, partly oxygenated liquid hydrocarbons or tar; (3) fixed gases; and (4) water. If the coal is heated rapidly under conditions that prevent decomposition of the primary products, 68 to 87 percent of the net heat in the raw coal is left in the char and 10 to 23 percent of the potential heat appears in the primary tar. Fixed gases represent approximately 7 percent of the heat and approximately 2 percent is lost or dissipated in the reactions of decomposition. Considering the different ranks of coal in the United States, the yield of tar will vary from about 9 to 44 gallons per ton, therefore it is important that each coal be carefully considered if it is to be carbonized for industrial use.

Jan 1, 1955