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By C. Pawlik, R. T. Jones

Cobalt occurs together with copper in the southern African copper belt, and a large portion of this cobalt ends up in copper smelting slags, mostly dissolved in oxide form. It is possible to achieve high recoveries of cobalt by reductive smelting of the copper slags, using some form of carbon as a reducing agent in an electric furnace. For example, a 40 MW DC arc furnace was operated at Chambishi Metals in Zambia from 2001 to 2008, and demonstrated cobalt recoveries of around 80% from slag to an iron-rich alloy containing copper and cobalt. The alloy was atomized prior to leaching. With the recent increase in demand for cobalt (and the resulting high metal prices), there has been increasing interest in this process route. There is also an alternative hydrometallurgical process for recovering the valuable metals from the slag. The choice between these process options requires a trade-off between capital and operating cost and environmental acceptability. This paper examines the potential for cobalt recovery from slags, and outlines various process options. INTRODUCTION Cobalt has had a number of important uses in society since antiquity, and its principal use has changed dramatically over time. Since at least 2250 BC, cobalt-based pigments (cobalt blue) have been widely used to colour manufactured goods such as glass and pottery. Later, cobalt became known for its magnetic and wear-resistant properties and high-strength alloys, and most of the cobalt produced was consumed in the production of cobalt-based superalloys. The greatest recent growth in cobalt demand is due to it being essential to the rechargeable lithium-ion batteries used in consumer electronic devices and increasingly to drive electric vehicles. Cobalt is usually produced as a by-product of copper or nickel. The copper belt in the Democratic Republic of the Congo (DRC) and Zambia supplies most of the world's cobalt production. In 2018, the DRC was expected to produce 90 000 tons of the world total of 140 000 tons of cobalt (Shedd, 2019). This paper focuses on the southern African copper industry, and specifically the cobalt that is able to be produced as a co-product from this. A BRIEF HISTORY OF SOUTHERN AFRICAN COPPER SMELTING Copper deposits in South Africa have been documented since at least 1685, when the Cape governor, Simon van der Stel, ‘discovered’ the 'Copper Mountain' at Springbok. South Africa's first public commercial mining company (imaginatively called the 'South African Mining Company') was established in Cape Town in 1846, to exploit the rich copper resources that were believed to exist in Namaqualand.

Jan 1, 2019

By C. Caners

One of the main uses of fossil fuels is in the transportation sector, leading to environmental consequences such as climate change. In order to move towards a more sustainable energy infrastructure, a transition must begin from fossil fuels to renewable fuels, derived from e.g. biomass. One means of facilitating this transition is to develop reforming technology that can extract hydrogen from a suitable fuel that is either fossil fuel or renewable in origin. The hydrogen would be feed to a 'fuel cell' engine that would power the car, truck or bus. One reforming technology that is attractive for automotive applications is autothermal reforming (ATR). Autothermal reforming is the combination of steam reforming and partial oxidation, whereby a portion of the fuel is combusted using a sub-stoichiometric amount of air, and the resulting thermal energy drives the more desirable steam reforming reaction. ATR is attractive for fast start-up, rapid load following and ease of control. ATR also has the benefit of smaller volume and fewer peripheral requirements as compared to other reforming technologies. Recently, a bench-scale gasoline autothermal reformer (ATR) was constructed and tested. This ATR employs a novel design, consisting of three concentric annuli in order to promote heat transfer from the partial oxidation reaction to the steam reforming reaction. Concurrently, a CFD based model (FLUENT) of the ATR that considers the geometric complexity of the reformer was validated. In spite of the use of simplified kinetics, the model predicted well the observed trends in temperature and overall performance. This paper will discuss the use of the model to improve the design of the ATR. The impact of various system parameters upon performance will be investigated along with alterations in the geometry of the ATR. The various tradeoffs in performance and system volume/size will be highlighted in the context of a fuel cell power system.

Jan 1, 2005

By Jacob Wood, Robert Matusewicz

The Outotec® Ausmelt Top Submerged Lance (TSL) Process has achieved widespread commercial acceptance over the past 40 years for the processing of copper, nickel, lead, tin, zinc and precious metal bearing feeds. The continual development and evolution of the technology during this period has resulted in a more intense smelting process with higher energy efficiency and lower operating costs. More recently, considerable effort has been invested in decarbonisation of the process through improvements such as increased oxygen usage, dry feed injection and use of low-carbon auxiliary fuels. This paper covers a number of these recent advances to the technology and highlights their impacts on energy consumption and CO2 emissions for a range of non-ferrous smelting flowsheets. INTRODUCTION Relentless demand for improvements in the profitability, safety and environmental performance of non-ferrous smelting plants has driven a continual development and evolution of processing technologies in this industry. In response to these demands, a number of bath smelting technologies have emerged over the past 40 years and have been implemented for the treatment of primary and secondary feedstocks. The Outotec® Ausmelt Top Submerged Lance (TSL) Process (henceforth Ausmelt Process) is one such bath smelting technology which has been widely adopted in a large number of greenfield projects and brownfield plant modernisations (Wood & Hughes, 2016). Emissions of CO2 from the production of non-ferrous metals represent approximately 4-5% of global totals (Rankin, 2012), comparable with the almost 10% attributed to iron and steel production. Despite significant improvements in the energy efficiency of modern smelting technologies (Coursol, Mackey, Kapusta & Cardona Valencia, 2015), primarily through increased oxygen usage, further innovation and development is still required to address their reliance on fossil fuels such as coke and coal. Transformation of the non-ferrous smelting industry to low-carbon technologies and process flowsheets is lagging behind the power and transport sectors, which have witnessed significant growth in clean/renewable energy technologies to reduce CO2 emissions and address the issue of anthropogenic climate change (IRENA, 2018; IEA, 2018).

Jan 1, 2019

By A. Poor Zaeif Doost

With columns being installed in rougher section at Miduk Copper Complex, the rougher feed mainly reports to rougher-scavenger cells. To evaluate the efficiency of regrinding circuit, we conducted flotation experiments on samples of the feed and the products of the regrinding circuit. The grade difference of these products at 85% recovery was considered as the efficiency index. Results show that, with weight recovery of the rougher-scavengers the efficiency of the circuit increases. Exclusion of the rougher-scavenger concentrate from the feed to the regrinding circuit, resulted in an increase in the efficiency index from 10.12 to 17.6%.

Jan 1, 2012

By S. Knapp

Inconel 600 pipes welded to Carbon-Steel are used in CANDU nuclear reactors. Fracture of these welded tubes would have important consequences in term of safety, and therefore their mechanical properties need to be better understood. In this study, the weld region was analyzed at various length-scales using optical microscopy, micro hardness testing, small and large scale tensile testing and digital image correlation (DIC). Large grains were observed in the weld region and smaller grains in the Inconel and carbon steel base metals. Micro-hardness profiles showed variations across the weld and through thickness and were justified in terms of residual stresses in the sample. Large tensile samples were extracted from the welded pipe and were used to identify the material in which fracture initiates. In addition, the local strains in each material were obtained using digital image correlation. Local stress-strain curves were built from the DIC data and compared to stress-strain curves obtained from miniature tensile samples extracted from the carbon steel, Inconel and weld regions. The results demonstrate the advantage of using DIC for extracting local material properties in dissimilar weld systems. Variations in the materials stress-strain curves thought thickness are also presented and emphasize the need for obtaining a complete map of the mechanical properties in the weld region for predictive models to be accurate. Preliminary fracture studies will also be presented.

Jan 1, 2011

By Jean A. Bastien

Cette présentation décrit les étapes de développement et l?exploitation souterraine au puits Penna chez Agnico-Eagle division Laronde. Les sujets suivants sont touchés : le fonçage du puits, le développement des niveaux, la méthode d?exploitation, la manutention de la roche brisée, le méthode de remblayage et la ventilation. En résumé : le fonçage du puits s?est fait sur 2,240 mètres de novembre 1995 à mars 2000. Le développement des niveaux a débuté en octobre 1998. Les opérations de minage ont débutés en août 99 dans le premier horizon situé au dessus du niveau 122. Les chantiers sont exploités par longs-trous d?environ 25 mètres de long avec un diamètre de 10 cm. Les accès à la zone minéralisée sont transverses. Le minerai est soutiré des chantiers et acheminé au passe-minerai a l?aide de chargeuses navettes. Par la suite, le minerai passe sur un marteau, est concassé et transporté sur un convoyeur, jusqu?au silo de 4,500 tonnes au-dessus de la station de chargement automatisée du niveau 152 d?ou les skips sont alimentés. Le remblai en pâte est envoyé de la surface par des trous ayant un revêtement d?acier. Le diamètre intérieur est de 15 cm. Le réseau de ventilation est principalement alimentée par des ventilateurs de surface (système aspirant et souflant) conçus pour acheminer sous-terre un maximum de 640 mètres cubes par minutes (1,350,000 pcm).

May 1, 2001

By M. McKim

"Due to the fact that there were no formal papers submitted for this session we can only print the discussions of the papers. a) Maqnetic Mill Liners : M. MckimE. MarcotteFalconbridge LimitedReplyIn looking at the slides on magnetic mill liners a question comes to mind, particularly in the case of a large diameter mill using large grinding media, concerning the potential hazzards which may exist from large chuncks of steel hanging in the mill. Would you comment.The magnetism was sufficiently strong from liner to liner to hold ........................ .(We are sorry but we could not transcribe the full reply to this question as no microphone was used by the speaker and i't was impossible for us to complete the rest).·"

Jan 1, 1984

By H. Dundar, C. Dzomeku

An extensive testwork was performed around the HPGR plant at GoldFields Ghana Limited Tarkwa Gold Mine. The HPGR was used to prepare the feed for heap leaching. The circuit was configured in such a way that the edge material from the HPGR discharge was recycled for further crushing while the product from the centre reported to the heap leach section. The set-up of the Polysius HPGR provided an opportunity to study the effect of different design and operating variables. This paper will discuss the results from the tests performed to assess the effect of rolls’ speed and applied pressure on the capacity and the grinding efficiency of the HPGR. Applying different pressure values appeared to have an influence on the amount of edge material recycled.

Jan 1, 2012

By H. Dundar

The first application of High Pressure Grinding Rolls was in 1985 at a cement plant, for the purpose of capacity improvement. Then various circuit configurations were derived to achieve a reduction in overall specific energy consumption, by transferring more of the grinding required to the HPGR. In most circuit configurations, the recycle of fines is required for effective breakage between the rollers. By increasing the fines amount in the feed material to a specific level within the recycling load, a uniform material bed is created and a higher pressure gradient along the roller width is obtained, resulting in compact flakes, including more fines. The fines recycle results in enhancement of the interparticle breakage. This paper will discuss the effect of the feed size distribution on HPGR performance.

Jan 1, 2012

By J. M. Toye

The Canadian nuclear fuel business relates primarily to supplying fuel for Candu reactors. The product development, manufacturing and marketing activities of our nuclear fuel industry will therefore be determined by the rate of growth of the Candu nuclear reactor business. The nature of this relationship between the Canadian nuclear fuel industry and the Canadian Heavy Water Reactor program will be considered, with particular reference to the factors influencing future economic growth.

Jan 1, 1969

By George Dogbe

Open pit optimization forms the basis of mine design, production planning and construction of mine facilities. The negative effects of this phase may include substantial reductions in ore recoveries, relocation of waste dumps and surface infrastructure, extraction of unwanted waste, with a cumulative effect on mine value reductions. As a result, this area has received significant research focus using linear and dynamic programming, heuristic, genetic and stimulation algorithms and the graph theory. These algorithms are derived from rigorous mathematical models, but they are built on the assumption that all the periodic production capacities are extracted at the time of analysis. This assumption weakens the models because mining occurs over significant time period. In order to develop a comprehensive model that accounts for the timing of material extraction, the current models, which are built on the economic block value (EBV) concept, must be modified to account for time. In this paper, the authors develop a model of the optimization problem using the 2-D Lerchs-Grossmann?s optimization algorithm. This model is used to investigate the effect of periodic discounting on the optimal pit layout design by designing an integrated pit optimiser (IPO) that incorporates ?production scheduling?. IPO uses the ensuing discounted economic block value (DEBV) as a basis for the pit optimisation process. The time-dependent model is compared with a time-independent model. The results show that discounting has no effect on the optimal pit contour although the reported pit value is overstated if the EBVs are used instead of the DEBV. The authors, however, believe that this conclusion may not be general and could have been influenced by the nature of ore body geometry and the proposed mining strategy.

May 1, 2004

By Shinji Shirakawa

The gold wire bonding technology is widely used for electrically connecting aluminum pads on IC devices to external terminal of semiconductor. In 1960?s, the tensile strength of gold bonding wire was about 100 MPa only. However, recently the wire with 300 MPa in strength has been developed. Since the gold bonding wire was started to use for IC package in early 1960?, the many types of gold bonding wire has been developing continuously in order to meet market?s needs, such as high density, small size and thin type of IC packages. Moreover, electronic equipments were used in automobile applications and also demanded good reliability under severe temperature environment. Thus Au-Pd alloy wire has been introduced instead of the wire with 4N(99.99wt%) purity gold to provide excellent reliability in Au-Al bond interface. The phenomena at Au-Al interface in the high temperature storage have been already explained by several studies as follows. There are five phases of inter metallic compound (IMC) between gold and aluminum. Just after bond gold ball on aluminum pad, Au5Al2 phase was formed and occupied almost all of IMC area. During high temperature storage test, Au5Al2 phase transformed to Au4Al phase, then this phase was corroded by Bromide (Br) ion that was isolated from molding resin. Thus the reliability between Au and Al degraded. In case of Au-Pd alloy wire, the concentrated palladium phase (Au-Pd-Al) was formed at the interface between Au alloy ball and Al pad. The Au-Pd-Al phase prevented from transforming between Au and Al, therefore Au5Al2 phase was hard to transform to Au4Al phase. Consequently the reliability at the interface between Au alloy ball and Al pad was less degradation. However, in recent study using several advanced analysis technique, Au4Al phase was found at the interface between Au alloy ball and Al pad same as the case of conventional gold wire (4N purity gold bonding wire). It was suggested that the formation of concentrated palladium phase (Au-Pd-Al) related the excellent reliability at ball bonding process.

Oct 1, 2003

By E. G. Joe

"The continuing increase in costs for power and fuel are affecting significantly the cost for milling of Canadian ores. In order to ascertain the scope and source of energy consumption in Canadian mills for further energy conservation opportunities, CANMET, in cooperation with the Canadian Mineral Processors carried out a detailed survey on the metallic mineral processing plants. Sixty-seven mills representing almost 300 million tons of annual capacity participated in the survey. The results indicated that in general, copper and iron ore mills, representing the bulk of the tonnage, consumed relatively low levels of energy per ton. Nickel-copper, zinc-copper and lead-zinc ore mills were moderate in energy consumption, while uranium and some copper-lead-zinc mills reported much higher energy consumptions due primarily to the increased heat requirements of the ore pulp. While the plant heating costs varied somewhat with the location in Canada, it was apparent that the lowest heating costs were achieved by those built with proper insulation and energy conservation design. If the cost per million British Thermal Units is taken as $2.00, the mill energy costs generally ranged from 40¢/ton up to $1.20/ton.IntroductionEnergy consumption in milling has always been of significant interest to Canadian mineral processors who traditionally calculate their milling costs down to pennies per ton. Even the measure of an ore's grindability is expressed empirically by Bond in kilowatts hours per ton milled. Some of the mills located in isolated areas were obliged to generate their own electrical energy from fossil or petroleum-based fuel at a cost substantially higher than that obtainable from captive or public hydro-electric installations. These mills practiced energy conservation long before the advent of O.P.E.C. energy cost inflation. One example of this was the use of electric boilers to produce process and heating steam during off-peak electrical load periods."

Jan 1, 1978

Overview of Presentation Why Enter Agreements with First Nations Making it Win-Win ?The Principles The Process Making the Process Work Resource Agmts Defined Resource Agreements are legally binding agreements between a resource company and the First Nation(s) whose Aboriginal or Treaty rights may be impacted by the activities of the proposed project

May 1, 2009

By A. S. Baillie

THE subject of taxes appears to engage our attention altogether too lightly. At least it would seem that, notwithstanding the increase in the cost of government, and its concomitant increased taxation, little constructive work is being done with a view to solving the problem of increased taxes. I believe that the inattention of the public generally to the subject of increased taxation is due largely to the fact that shareholders are not advised of the amount of taxes paid by industry. Were companies to advise their shareholders the amount of monies paid or payable out of each year's earnings for taxes in one form or another, and were such amounts compared with the amounts available for distribution to shareholders, the effect would be a general demand for more equitable taxation methods. While I am not unmindful of the burdens and inequities in taxation confronting industry generally, I believe that the mining industry in this Province does not fully appreciate the burden represented by the costs of taxation. My reason for this belief is based partly upon1the fact that no serious effort has so far been made to devise some means By which the mining industry in British Columbia might protect itself against the ever-increasing burden of taxation. In addition to this fact the widely diverse nature of mining in British Columbia makes the accumulation of comparable data a problem which, so far as I can ascertain, has never been attempted in a manner which would be authoritative. It should not be necessary to cite the effects of this burden upon any one mining company or upon any branch of the mining industry, such as coal mining, placer mining, base-metal mining, or the precious-metal mines. In my opinion, the operation of our mines by large corporations is conducive to the payment of taxes with much less protest than would be the case were the taxes being taken out of the earnings of just a few partners or a very few shareholders. We appear to be too unmindful of the taxes, paid by mining companies, of a kind that are not so prominently brought to our attention as are the taxes which are calculated upon the taxable income of the company at the end of its fiscal year. British Columbian mining companies pay many other taxes besides those which are calculated upon taxable income. Among these are school taxes, property taxes, gasoline taxes, mineral taxes, coal royalty, to say nothing of fuel-oil tax, sales tax, and excise taxes.

Jan 1, 1935

By A. Burduk

The traditional approach to managing information flow between a mine underground and overground, applied in copper mines of KGHM Polska Miedz S.A., is mostly based on exchanging spoken information using the mine telephone network and printed documentation. This way of information flow significantly influences effective use of time of a shift foreman employed at a mining division. In order to minimise multiplication of significant information generated as paper documentation, a concept of an IT system module to input basic data concerning operation of the mining division was developed. The idea is based on computer software that permits inputting data in the underground and their immediate sending to the overground. The above-mentioned solution will permit significant reduction of administrative work time that each foreman has to do on each shift. The time saved on filling forms and communication will permit the foreman and the other workers involved in information flow to spend more time for execution of their basic duties. In the case of the supervision employees working in the overground, the IT system will allow all the interested persons to be informed directly, with no necessity to transfer the information on the situation in the given mining division by turns from one to another. On the other hand, saving time on administrative works will permit the foreman employed in the underground executing more detailed inspection of workplaces in his subordinate mine division. Thus, availability of the foreman for the mining division operation will be improved. KEYWORDS

Aug 1, 2013

By W. L. Stuewe

For the purpose of this paper I shall, in order to limit myself, define the words 'Maintenance' and 'Equipment' as follows: Maintenance shall mean the 'care of or 'the sustaining of equipment in as nearly perfect condition as possible. Equipment shall mean any item of a mechanical nature entering into the production of coal; it will be seen that unless one limits the use of this word it could take in administration as well as operative equipment, and include metal mines, mills and smelters, and manufacturing plants. In any industry the first consideration is the proper operation of all units entering into the production of the article manufactured or produced. I wish to quote here what a man, well known internationally in financial circles, told his operators at the time a large expansion programme was under consideration. His exact words were: "I do not care how much it is going to cost. What I want to know is how much it is going to cost to operate and maintain. It is the continuous drain for repairs that costs us the most money." The truth of this statement has been proved time and again, and many companies have found the cost of maintenance to be the balance between profit and loss-so much so that, in two instances with which the writer is familiar, the mechanical equipment was practically replaced throughout. I bring this point out here to emphasize the value and necessity of keeping abreast of the times, and obtaining maximum efficiency with the minimum outlay. Time is indeed money where delays occur due to defective or poorly kept equipment, and it is absolutely necessary to prevent machinery from becoming defective or inefficient.

Jan 1, 1930

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

Resistance spot welding is the most common type of welding in the automotive industry. In RSW the size and shape of welding nugget is one of the most effective factors on mechanical properties, such as tensile shear strength and fatigue strength. so properly adjusting the variables of the welding is necessary .in this study the effect of different parameters of RSW including time, current, electrode force, geometry of electrode so diameter and angle of electrode tip in the shape and size of welding nugget evaluated. for experimental procedure, low carbon steel sheet st12 is used. the process is simulated with finite element method by using ANSYS software. for the formation of welding nugget a 2 dimensional symmetrical model electrical-thermalmechanical is used and for elevate the accuracy ,we determined the properties of material related to temperature. The results show that increasing the time and current of welding, the diameter of spot weld also increased and the role of current is more impressive. and also increasing the electrode force decrease the diameter of the nugget due to increasing the contact area and decreasing the resistance .increasing the diameter of electrode tip cause increasing contact area and decreasing the resistance and decreasing the diameter of the nugget. furthermore, changing tip angle and electrode diameter don't show sensible change in the geometry of the welding nugget. comparison between simulation and experimental result show a good adaption.

Oct 1, 2011

By A. Valenzuel

Arsenic is a common impurity in copper sulfide concentrates treated pyrometallurgically, which inevitably during the smelting-converting process reports in the final copper product affecting its properties, but also it is a very toxic occupational hazard. Arsenic recovery or disposal from concentrates or arsenic-containing copper smelter dusts have been practiced in the metallurgical industry for many years. It has been recovered principally as arsenic trioxide by roasting or leaching then precipitated. On the other hand, several hydrometallurgical processes have been developed and implemented in smelters to remove it from arsenicbearing dusts and stabilize it prior to disposal in the form of a solid compound, either as calcium arsenate, arsenic sulfide or ferric arsenate. This paper reviews the methods implemented for arsenic recovery worldwide and arsenic disposal in the metallurgical industry.

May 1, 2001