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By M. H. Allan

SASKATCHEWAN POWER CORPORATION is a Provincial Crown Corporation responsible for the production transmission and distribution of electric power and natural gas in the Province of Saskatchewan. Through the electric power responsibility, we became interested in the coal reserves in Saskatchewan, which, although still somewhat of an "orphan fuel" in the early and mid 1950's, gave the promise of providing a low-cost source of energy for electric generation. Coal in Saskatchewan, a lignite with an "as-received" heating value of from 5000 to 6500 Btu's per lb and up to 40% moisture, was first recorded in 1853 . By the end of the 19th century, many small mines were in operation in the Estevan, Coronach and Shaunavon areas supplying local inhabitants with a cheap source of heat. These small mines, some of them prosperous, some of them not, continued operation right up to the late 1940's, when oil replaced coal in the market place. The year 1930, however, saw the introduction of the new technique of strip mining in the Estevan area. This technique revolutionized coal mining. It was now possible to use large machinery to uncover the coal and cast the overburden to one side instead of burrowing through thin seams of coal varying from 2 to 10 feet thick. The overburden cast aside by these large mechanical shovels, or later draglines, created heaps of spoil which at that time, during the depression, were a sure sign of prosperity and the welcome news that people had jobs. By the late 1940's, coal production had dropped off, but the spoil piles remained and were now labelled by some as "scars on the landscape", even though there had been some natural succession of grasses. In addition, some people had planted trees in experimental plots and even some aerial seeding had been done.

Jan 1, 1978

By G. F. Miller

ONLY IN THE Province of Saskatchewan is natural sodium sulphate found in Canada in amounts large enough to make recovery economically sound. Geologists have estimated that the numerous deposits within the Province contain upwards of 200 million tons of Glauber's salt. There are twenty-one deposits in the Province which contain 500,-000 or more tons and about two dozen with lesser amounts. The first recorded production of sodium sulphate in Saskatchewan was in 1918. The company concerned, and others that attempted to develop the industry in its early stages, were unsuccessful. Their failures were caused by two main factors -lack of knowledge of efficient operating methods and the unstable market situation for the finished product. Today, the situation is changed in both respects and the product, commonly referred to as 'saltcake", is a very important chemical requirement of many industries throughout the world. Before proceeding with remarks on manufacturing methods it should be stated that, although this is a general paper on the manufacturing methods and end uses of the saltcake produced in the Province, the writer is, of course, more familiar with the plants operated by Saskatchewan Minerals than with other operations and perhaps may be excused for dealing more particularly with the plants of that Compa11y.

Jan 1, 1958

By D. Harris, G. Ye, G. Oprea, J. Rigby, T. Troczynski

Sintering and ceramic bonding in refractory castables take place mainly in the binding system during the first heat-up and in service. Consequently the strength and the corrosion resistance of the hot face layer depend on the sintering ability of the complex mix of ceramic powders constituting the binding system. As a result, the use of nano- sized reactive powders in the binding system mixes would activate the sintering and enhance the ceramic matrix formation at temperatures below 1300°C. Our work presents the experimental data on sintering behavior of binding systems containing magnesium aluminate and alumina nano-powders in the temperature range of 800-1450°C. The results indicated that a ceramic matrix, similar to high temperature fired bricks, could be generated after firing at the relatively low temperatures available in the non-ferrous smelting furnaces.

Jan 1, 2004

By Y. Hanada

Electrorefining at higher current density is desirable due to the increase in productivity attained without expanding the plant size. However, increasing the current density in common commercial practice causes problems such as anode passivation, dendritic deposition, cathode impurities and energy consumption. In general, agitation of the electrolyte is effective in suppressing these problems. To apply the agitation to commercial practice effectively, the method of agitation is important. One possible method is agitation by gas injection. In this study, fluid motion characteristics with gas injection between electrodes were investigated using a water model. Flow patterns were observed and fluid velocity was measured using a particle tracking method. It was found that the time-averaged velocity near the electrode walls was of the order of 0.1 m/s in the conditions. The flow was highly turbulent. The turbulent component of velocity was the same order as the time-averaged velocity. The mass transfer coefficient between the wall and fluid doubled when the effect of turbulent intensity was taken into account. The effects of gas injection on the electrolysis behaviour at high current density were discussed in terms of the mass transfer. It is suggested that gas injection could suppress the problems at high current density.

Jan 1, 2007

By T Salman

The construction and use of the B.E.T. (gas adsorption) apparatus is described. Examples are given for the determination of large and small surface areas using nitrogen and krypton. Introduction A NY study of the milling of ores from crushing to grinding, classification, and concentration and finally dewatering of the products involves solid particles which are either in contact with a gas or a liquid phase. The surface area of the solid and its characteristics constitute important parameters in all mineral dressing operations. The success of any particular operation is dependent on the interaction of the surface of the solid particles with the gas or the liquid phase. Particle size and specific surface (surface area per unit weight) continue to be important parameters in the flotation research associated with the adsorption of collector molecules or ions on mineral particles, as in the early years of mineral dressing research (1). In order to understand the mechanism of the flotation process, it is essential that the surface properties of the adsorbent be known.

Jan 1, 1965

By Michael S. Moats, Alex Luyima, Tomas Oliveira

Some commercial copper electrowinning facilities use Cyquest N-900 (a polyacrylamide) or HydroStar (a modified polysaccharide) to improve the density and smoothness of copper electrodeposits. However, the effects of these additives have not been studied extensively in the open literature. Thus, the electrodeposition of copper at 40 oC from a non-stirred synthetic electrowinning electrolyte (40 g/L Cu2+, 160 g/L H2SO4, and 20 mg/L Cl-) in the presence of various concentrations of either additive was evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). CV results show that neither additive has much effect on the nucleation overpotential of copper electrodeposition on stainless steel. However, Cyquest N-900 polarized the copper deposition reaction upon the return sweep. The EIS data indicates that Cyquest N-900 increases the reaction’s charge transfer resistance and creates a second low frequency loop. HydroStar had minimal effect on the electrochemical data generated by CV or EIS. Thus, the mechanism by which HydroStar affects the copper deposition reaction still needs to be determined.

Jan 1, 2014

By B. Krysa, A. Mitsui, T. L. Koehler

The presence of arsenic, even at trace levels, in copper processing leads to the risk of arsine gas where reducing conditions exist that can reduce any soluble arsenic present to its minus 3 valance state and generate hydrogen gas from the solutions. This risk is understood to be significant within the industry, particularly in the case of liberator cells where copper concentrations in solution are drawn down to remove the copper and impurities from the bleed stream. However, there are numerous other potential areas where the arsine gas risk exists including contact between active metal such as iron, zinc or aluminum and arsenic bearing solutions in pyrometallurgical dust treatment, refining and acid plant operations. In turn this breaks down to different mitigating strategies dependent on the risk scenarios considered; for example, how this risk interacts with Change Management, Confined Space Entry or Contractor Training. The ISO 45001 is an emerging standard meant to improve employee safety, reduce workplace risks and create safer working conditions all over the world. The paper shows a case study of how a framework consistent with the tenets of ISO 45001 has been used to provide a consistent assessment of this risk for a wide variety of copper operations and the expectations of how this may be used to effectively improve the effectiveness of barriers against future incidents. INTRODUCTION Arsine gas (AsH3), first identified in 1775, is a highly poisonous, colorless, non-irritating gas with a mild garlic odor that is heavier than air. Arsine gas is generated when reducing conditions are generated in the presence of hydrogen ions and arsenic compounds. Present permissible occupational exposure limit as defined by Occupational Safety and Health Administration (OSHA) as an 8-hour time-weighted average is ppm (0.2 mg/m3). Further increasing the risk, conventional respiratory protection utilizing half or full masks with gas filtering cartridges provide minimal protection against arsine. In copper processing plants, the risk of arsine generation is well understood in liberator cells, which are part of the electrolysis process. In this process, solutions containing copper are reduced in copper concentration removing not only the copper, but also arsenic, antimony and bismuth. The residual solution can be bled to control impurity build-up in the refinery. In this process, if the copper concentration is reduced to the point where As3- can form, arsine gas is generated via reaction with hydrogen ions generated during the plating process. The copper concentration at which arsine gas is generated depends on copper concentration at the cathode surface, the temperature and the acidity. As a result, there is always a risk of arsine gas generation in the liberator cell. Process measures to minimize or mitigate arsine evolution are tight control on final copper concentration, warm temperatures, fresh feed distribution and internal acid recirculation rates. Operator exposure protection measures are hooding, ventilation, arsine detection systems, restricted personnel access, automated shutdown controls and pre-defined evacuation plans.

Jan 1, 2019

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By D. E. Gill, A. Piche, S. Dufresne

"SOMMAIREUne méthodologie de prévision des coûuts de forage en galeries est proposée. Cette méthodologie a été élaborée pour les perforatrices pneumatiques manuelles. Elle est composée de quatre modèles: (1) un modèle de pénétration conduisant à la prévision du temps de forage; (2) un modèle d'estimation de la durée de vie des fournitures; (3) un modèle d'estimation de fa quantité d'énergie consommée; et (4) un modèle de calcul de couts. Elle fait intervenir la résistance en compression uniaxiale de la roche du massif foré, le diamètre des trous, Ie type de perforatrice utilise, fa pression d'air d'opération, la longueur des fleurets, les temps morts associes au forage ainsi que le rendement des compresseurs, des perforatrices et du réseau de distribution de l’air comprime. L 'application de la méthodologie est illustrée à l’'aide d'un exemple, suivi d'une courte analyse de sensibilité et d'une brève discussion. ABSTRACTA drilling cost estimation methodology for underground headings is described. This methodology has been developed for percussive hand-held drills. It comprises four models: (1) a drillability model used for the prediction of the drilling period; (2) a model for the prediction of bit and rod lives; (3) an energy model; and (4) a cost model. It makes use of the uniaxial compressive strength ofthe rock drilled, hole diameter, drill type used, operating air pressure, drilling rod length, dead times that may occur during the drilling operation as well as compressor, air distribution network and drilling machine efficiencies. The application of the methodology is illustrated with an example, followed by a short sensitivity analysis and brief discussion."

Jan 1, 1994

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By M. B. McClenaghan

"The Ontario Geological Survey completed a regional till sampling project between 1984 and 1988 in the Black River Matheson (BRiM) area of northeastern Ontario. The project was designed to aid mineral exploration in the area by documenting the Quaternary stratigraphy and by providing a database of till geochemistry. This paper summarizes the results from the sonic overburden drilling component of the BRiM project carried out in areas of thick drift (> 5 m). Results from till sampling in areas of thinner drift (<5 m) have been presented in a separate paper. Approximately 1100 till samples were collected from 225 sonic drill holes. For each sample, the non-magnetic heavy mineral (>3.3 S.G.) and fine (-250 mesh) till fractions were analyzed geochemically and visible gold grains were recovered by panning.Gold and other multielement geochemical data were plotted using proportional symbols to highlight anomalous areas and to demonstrate how to evaluate and interpret a very large geochemical dataset. Thresholds for identifying anomalous concentrations of Au in till samples, defined using the 95th percentile, are 1500 ppb and 12 ppb for the heavy mineral and fine fractions, respectively. The heavy mineral fraction of older ti1ls and to a lesser extent, Matheson Till, display a number of significant gold anomalies in the study area, which in a few cases, are associated with base metal anomalies. The vertical position of gold anomalies in Matheson and older ti1ls varies from directly on bedrock to several meters above the bedrock surface and can provide information of relative ice transport distances."

Jan 1, 1994

By V. A. Leão, M. L. M. Rodrigues, L. C. Sicupira, I. C. B. Rodrigues, T. C. Veloso

Brazilian sulphide ores can contain a significant content of chloride and fluoride, which are harmful to bacteria and thus bioleaching. This work summarizes a four-year research investigation on the effect of fluoride on both bacterial growth and sulphide bioleaching, supported by studies carried out with secondary copper ores. Firstly, the influence of fluoride on the kinetics of ferrous iron bio-oxidation with Sulfobacillus thermosulfidooxidans was addressed. Values as low as 10.0 mg/L F- fully inhibited bacterial growth, although fluoride toxicity could be overcome by the presence of aluminium, which reduced the concentration of hydrofluoric acid through the formation of aluminium-fluoride complexes. This required at least a 2:1 aluminium/fluoride molar ratio, which ensured bacterial growth rate values similar to that observed in the absence of fluoride ions. Subsequently, both batch and column bioleaching with mesofiles (30 ºC), moderate thermofile (50 ºC) or hyperthermophiles (67.5 ºC) of two secondary copper ore samples were analyzed with focus on the relevant effects of fluoride-containing minerals on the bioleaching of such sulphide ores.

Jan 1, 2014

By Julian V. Simela

Conventional methods of underground surveying use theodolites/total stations and 3D laser scanners to obtain information about the underground environment. Current methods of geo-referencing these instruments to a mine reference system include triangulation, trilateration and resection. However, despite technological advancements, surveying procedures have remained slow, laborious and relatively unchanged during the last half-century. Recent innovations in the robotics community have shown that automated mapping of underground mining tunnels can be undertaken using 2D/3D laser scanners. These techniques have the potential to, in turn, improve upon current underground surveying and mapping methods. Automating surveying and mapping using current surveying tools without changing the setting up procedures or removing current constraints, or even changing the type of equipment used, does not change the status quo. The problem of moving from a static, tripod based surveying and mapping system to an unconstrained mobile surveying and mapping system is the subject of this paper. A current challenge for automated mapping is the ability to automatically geo-reference a mobile mapping system to a mine reference system. For a mobile mapping system that uses a horizontally mounted 2D laser scanner to gather data of the underground environment, the challenge of determining its position and orientation within the mine environment is magnified even more. This paper introduces Mobile Automated Scanner Triangulateration (MAST), a technique under development at Queen?s that is designed to geo-reference a mobile mapping system to a mine reference system for the purposes of underground mine surveying. MAST quickly and automatically determines scanner 2D position and orientation (azimuth) in a mine reference frame by using minimal human input.

Aug 1, 2013

By J. J. Benitez

MIBC (methyl-isobuthyl carbinol) was previously shown to enhance significantly sylvite flotation when used at the stage of preparation of amine dispersions. In this paper Atomic Force Microscopy (AFM) is used to study the effect of MIBC on deposition of octadecylamine (ODA) on the surface of mica. The AFM images indicate that amino terminated, and therefore hydrophilic, deposits of ODA are observed on the mica surface in the ODA dispersions free of MIBC. In the presence of MIBC a methyl terminated (hydrophobic) monolayer is obtained on the mica surface. The transition between the monolayer and bilayer phases is due to the presence of MIBC. Experiments carried out in distilled water reproduced the results obtained from the brine. Working in pure water instead of brine simplifies the preparation conditions and the analysis by AFM.

Jan 1, 2006

By Y. X. Li, L. R. Xiao, S. Gong, S. S. He

Porous copper and porous copper based alloys with controllable pore structure have been manufactured successfully by sintering evaporation process. This process consisted of mixing copper or copper based alloys with NaCl powders, hot pressing and final high-temperature sintering to evaporate the filler material of NaCl powders. NaCl was eliminated completely during vacuum sintering, and strong metallurgical bonding in the walls was achieved. The pores’ structural parameter (pore size, shape, and direction) and porosity can be controlled effectively. These porous copper and porous copper based alloys with controllable pore structure have great potential in many fields. Including heat dissipating materials, heat absorbing materials, chemical catalyst carriers, electromagnetic shielding materials, filtering materials, damping materials, silencing materials, battery electrode materials. INTRODUCTION The development of porous materials began in the 1960s. The research of activated carbon with high specific surface area made porous materials enter the stage of material research (Belyakov et al., 2008; Ferey et al., 2008). With the rapid development of science and technology, porous materials play an important role in material research, and gradually become an indispensable part of the material research field (Wu et al., 2012). The research of porous materials has gradually extended to metal, ceramics, plastics and glass and other fields. It has been successfully applied in many fields, such as functional materials, industrial production, aviation, medical materials, biochemistry and electronics, which fully shows that porous materials have considerable development prospects. Porous silicon, plastic porous materials and glass porous materials are the most widely used in the field of non-metallic porous materials (Capelle et al., 2012). Compared with non-metallic porous materials, metal porous materials have developed rapidly in the late 1980s and become new materials with good mechanical properties and excellent physical properties. Porous metal materials have many advantages, such as large specific surface, small specific gravity, good silencing effect, high stiffness, high electromagnetic shielding performance, good shock absorption performance, etc (Li et al., 1999; Ferey et al., 2008). Among its many applications, metal porous materials can be used as both functional materials and structural materials. In some cases, metal porous materials have dual functions and structures. It is a multi-purpose engineering material with excellent performance. At present, porous copper, porous aluminium and porous nickel are the most concerned materials (Chen et al., 2002; Yang et al., 2017; Liu et al., 2018). The preparation methods of porous copper and copper-based alloys mainly include self-propagating high temperature synthesis (SHS), capsule-free hot isostatic pressing (CF-HIP), spark plasma sintering (SPS) (Kvanin et al., 2008; Takahashi et al., 2008; Zhang et al., 2014). However, these methods can not accurately control pore structure parameters (including pore size, shape, orientation, distribution, etc.). In porous materials, pore structure plays an important role in the overall performance of materials. In order to control pore structure parameters accurately and optimize material performance, it is necessary to explore and develop new preparation technology. In this paper, the sintering evaporation process (SEP) was introduced for the preparation of porous copper and copper-based alloys. The core process of the preparation method is hot pressing and evaporative desalination. Hot pressing can make the pore orientation consistent. Evaporative desalination can ensure the complete removal of NaCl in the form of vapor in a short time, thus eliminating the corrosion of residual NaCl on the matrix metal (Gong et al., 2011).

Jan 1, 2019

By H. H. Claudet

PROBABLY the first flotation mill for treating molybdenite ores was put into operation .in Norway during 1913, when the writer was employed to introduce and apply the Elmore vacuum flotation process at a mine in southern Norway. These operations proved successful and led to other similar installations in that country. It remained, however, for Norwegian engineers themselves to iron out their difficulties and establish the molybdenum industry on a basis which ultimately attained world importance. Just as today, an urgent demand for molybdenum arose during the world war of 1914-18. By 1916, many molybdenite properties were in operation in Canada and several small concentrating mills were under construction. At one of these, in the Ottawa Valley district, the opportunity came for applying the Elmore vacuum flotation process, using a flow-sheet similar to that adopted in Norway. Later, as one of the staff of the General Engineering Company, who had already developed a highly efficient flowsheet for treating molybdenite ores, using the Callow pneumatic flotation process, the writer devoted considerable time to research work and investigations on a number of molybdenite projects and deposits in eastern Canada. The bulk of Canada&apos;s production of molybdenite was coming at that time from the Moss mine at Quyon, Que., where concentration of the ore was effected by water-film flotation. It is of interest to note that this process, based on the principle of surface tension, had been developed and introduced by the late Henry E. Wood, of Denver, Colorado- one of the original owners of the Moss mine-at the time he was investigating the Elmore vacuum process in his Denver plant. The process, with certain modifications, was used at several other properties in eastern Canada, and notably in the ore dressing laboratories of the Department of Mines at Ottawa and in a plant at Renfrew, Ont., in both of which ore from deposits in various parts of Canada was treated, with recovery of very appreciable amounts o much needed molybdenite. During the summer of 1917, the water-film flotation mill at the Moss mine was dismantled and the plant was re-modelled by the General Engineering Company to include the Callow system. This installation, using improved flotation methods, was highly successful both as to recovery and grade of concentrate, and proved a decided advance in molybdenite concentration, a recovery of upwards of 90 per cent being obtained, with a concentrate grading over 90 percent MoS2.

Jan 1, 1944

By O. Lashkari

Swirled Enthalpy Equilibration Device (SEED) is a new patented Slurry-on-Demand, SoD, processing route. The semi-solid slug preparation is carried out by off-center swirling of aluminum melt in a metallic mould. As part of the current research program on the semi¬solid processing of aluminum alloys, the morphological evolution of 356 aluminum foundry alloy microstructure is reported here. Semi-solid slugs were prepared using two different pouring temperatures of 645°C and 695°C respectively. Morphological evolution of the semi-solid microstructure was characterized using image analysis through measuring of primary a-Al particle size, number density, aspect ratio and sphericity. The possible relationships between microstructural features and process parameters were also investigated. The current report covers the effect of pouring temperature on the morphology of primary a-Al dendrites and attempts are made to explain the differences between the predicted percentage primary a-Al phase and those of the actual values in the as-cast slugs.

Jan 1, 2004

By C. -S. Xie, J. -H. Kong

The microstructure and mechanical properties of X80 hot-rolled thick steel strips with a thickness of 17.5mm produced in Wuhan Iron & Steel Company (WISCO) are introduced in the paper. The steel strips as fabricated through proper thermomechanical processing (TMP)/ on-line accelerated cooling (OLAC) processing have shown high strength and toughness, low brittle transition temperature, good weldability, and high Shear Area (SA) percentage in Drop Weight Tear Test (DWTT). The microstructure of the steel strips is characterized with mainly acicular ferrite, and fine dispersed Martensitc-Austenite (M-A) phases. It is determined that the mechanical properties are improved due to the presence of the fine M-A phases and precipitates, which could be formed by reducing the finish rolling and coiling temperatures.

Jan 1, 2005

By C. Caballero, M. Rosales, C. León, A. Valencia, R. Fuentes, A. Moyano

Slopping is the formation of waves in the converter due to the gas injection by tuyeres. Those waves produce a premature wearing of the refractory lining of the reactor due to its great amplitude. The affected zones are the tuyere line (outlet gas from tuyeres) and the front of this line. In the present work, a theoretical and experimental study is made to develop a theory that determines the variables involved in slopping, characterizing the more important parameters of operation in the phenomenon of slopping. In addition, this theory will allow for determination of new technological alternatives of the blast injection permitting to depress the slopping phenomenon.

Jan 1, 2007

By K. Poorhaydari, B. M. Patchett, D. G. Ivey

In this paper, some applications of carbon extraction replicas, as samples for transmission electron microscopy (TEM), are discussed. Modern high strength microalloyed (HSMA) steels, used as structural or pipeline materials, have very small grains with substructures. Replicas used in TEM can resolve the grain boundaries and can be used for grain size measurements in cases where the small size of the grains pushes the resolution of conventional optical microscopes. The grain size variations obtained from replicas correlated very well with mechanical property variations, indicated by hardness, in the fine-grained heat-affected zone and base metal of some welded HSMA steels. Replicas are also very suitable samples for precipitate examination with analytical TEM. Advantages and limitations of the application of replicas, as well as some corrections for the estimation of the volume fraction of fine precipitates, are discussed.

Jan 1, 2005