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By M. N. Pons, E. Benizri, B. Laubie, A. Bani, Université de Lorraine LRGP, P. Kidd, A. J. M. Baker

"Serpentine (i.e. ultramafic) outcrops in Europe cover more than 10,000 km2 and have a low-fertility and low-productivity, making them unattractive for traditional agriculture. In general, these areas are slowly abandoned by local farmers, affected by strong rural exodus and landscapes undergo a process of closure. However, ultramafic landscapes have the potential to provide multiple ecosystem services that can contribute to Europe’s goals towards insuring food security, production of renewable raw materials and renewable energy. Phytomining (agromining) aims at cultivating metal hyperaccumulator plants that are able to accumulate Ni and other strategic elements from metal-rich soils and transport them to the shoots (>1%), which can then be harvested as a bio-ore. Such metal-rich biomass can be used to recover highly valuable metals, e.g. nickel (Ni) and also to produce energy (heat, electricity). Nickel agromining can thus offer an eco-efficient alternative to classical pyro- or hydrometallurgical processes without disturbing the soil cover and the geology from soils and rocks that would be considered as low grade ores or sterile material for conventional mining methods.Phytomining agroecosystems can lead to better soil resource efficiency and can offer a fully integrated, new agromining agriculture that could cover thousands of km2 in Europe, benefit local communities with a sustainable rural development and provide a wide array of ecosystem services which will need to be optimised under a life cycle assessment methodology:1. Production of bio-sourced metal products2. Production of energy biomass3. Restoration of soil fertility for conventional agriculture (Ni stress)4. Limiting Ni intake by local populations and farmers5. Use and conservation of local biodiversity (plant and soil fauna and microflora) as cultivated ecosystems6. Store carbon in cultivated soils7. Enhance pollination activity at landscape level.Nickel agromining could therefore change the economical balance in historically-disadvantaged ultramaficregions of Europe"

Jan 1, 2016

By R. D. H. Wigmore

"The title of this paper probably sounds quite simple and self-explanatory. The problem, however, was not a simple one, and proved somewhat baffling and expensive over a period of years. After outlining the problem, and the methods which were used to overcome it, we will present our solution, or perhaps it would be more accurate to say the partial solution which we reached.We have in the cyanide circuit at Upper Canada two Dorr Single Tray Thickeners with 30 ft. diameter wood stave tanks 12 ft 4 1/ 2 in. deep. In the years prior to 1948, when the tonnage was 250 to 280 tons per day, two stage thickening was practised. As the tonnage was increased to 450, 500, and finally 560-600 the thickeners were used in parallel.Some settling problems were encountered, and in those days the means to combat these problems were very few. The only remedy was to dump in pounds and pounds of lime. Then along came a few reagents, and the writer remembers one in particular, - 11 Carboxel11 (carboxymethlycellulose). When water or solution was added to this reagent, the result was a gooey mass somewhat resembling tapioca. One drawback was that it stayed in this state, and didn't go anywhere. A method was finally developed of containing the mass (or mess) on a fine screen, and dissolving some of it was a fine spray of solution. The only thing the writer recalls was that it was not a very effective settling agent.Shortly after this time, along came the new flocculents, first a few, and then many, and our settling problems were over.But when the settling problem was solved at Upper Canada, some other problems were creeping up on us."

Jan 1, 1965

By A. F. Beck

Abstract Canada has opened up a geological province in ?Western Canada which offers a new .stimulus to oil exploration geophysics. The problems of instrumental technique, interpretation, and logistics involved in the exploration of this new territory are presented in this paper and some of the efforts being undertaken to overcome them are discussed. The scope of this programme, its possible trend and extent, especially when viewed .against the background of the exploration effort in the United States, is touched upon. Introduction The science of earth physics was first applied to the search for oil on this continent some twenty-five years ago when torsion balance and refraction seismic methods were initiated in the Gulf Coast area of the United States. Since that time advances in the various branches of the science have been sporadic as new fields for their use opened up in the search for deep salt domes as well as less well-defined geological structures; in the application to well logging as part of the exploitation of petroleum; and in underwater surveys, aerial surveys, etc. In the present paper, attention has been concentrated only on the Western Canada plains area because of the recent remarkable growth of geophysics as an oil finding technique in this region. The other prospective oil areas of the West Coast and the Eastern Provinces of Canada are at present of minor importance, although they will undoubtedly receive increasing consideration in the future as accessibility to markets becomes a major factor and more improved geophysical and geological techniques are developed. A vast province in Canada, covering some 655,000 square miles of prospective oil territory (approximately one-half of the prospective oil area in the United States), has provided the new sphere of activity for geophysics (see Figures 1 and 2). Included in this area are immense inaccessible, uninhabited frozen regions which pose a new problem in logistics and operational techniques.

Jan 1, 1950

By C. S. Touchard, F. Bourgeois, L. Cassayre, Julcour-Lebigue C.

Developing a hydrometallurgical process that can overcome the refractory nature of chalcopyrite (CuFeS2) to leaching still eludes the minerals industry, despite major research efforts spanning decades. The several leaching experiments of this ore in sulfuric acid tend toward the same conclusion that the precipitation of elemental sulfur or iron containing species are the main dissolution inhibitors. Describing both the electrolyte composition and the various solid phases in equilibrium for the Fe-H2SO4-H2O system is essential to overcome this issue and to find an operating window. According to the thermodynamic models and to the thermodynamic data, we demonstrate, in this study, the need to use the Specific ion Interactive Theory (SIT) model to describe complex electrolytic systems through a limited number of parameters. Hence, the binary interactions for our case study have to be defined and estimated. This work develops a methodology to determine these parameters of the SIT model up to 90°C and an acid concentration of 1 mol/kg from published data for H2SO4-H2O and Fe(II)-H2SO4-H2O sub-systems or from new experimental data for the Fe(III)-H2SO4-H2O one. This method will eventually be applied to copper systems to lead to a thermodynamic description of the complete CuFeS2-H2SO4-H2O system. INTRODUCTION A leaching process consists in the dissolution of a solid phase into an aqueous medium in order to extract compounds of interest. It is a key step in the hydrometallurgical processes used in the primary production and recycling of metal components. One of the main leaching issues is the formation of passivating layers on the surface of solid particles, whose consequence is a partial or total hindrance of the dissolution. The leaching of chalcopyrite (CuFeS2) in sulfuric acid is a prime example. No industrial solution for the atmospheric pressure leaching of this ore has been developed to date because of passivation phenomena caused by the formation of elemental sulfur or iron-containing precipitates on the surface of the particles (Li, Kawashima, Li, Chandra, & Gerson, 2013). In the 1970s, the Pourbaix diagrams established for the Cu-Fe-S-H2O system at 25°C for low concentrated solutions (Garrels & Christ, 1965; Peters, 1976) agreed that copper and iron are fully dissolved at high potential and in acidic medium (pH < 4). However, they neglected the many stable solid phases that can form in these conditions. In addition, the Pourbaix diagrams of chalcopyrite in water, calculated with two recent databases (FactPS and Thermoddem 2017) associated to FactSage and PhreeqC softwares respectively, show large discrepancies at 75°C (Figure 1). Indeed, at high potential, FactSage predicts the formation of goethite FeOOH at a pH value of 1, while PhreeqC predicts the formation of jarosite (H3O)[Fe3(SO4)2(OH)6] for pH greater than 2.5.

Jan 1, 2019

By Robert B. Parsons

"It is quite likely that more than a handful of junior exploration companies will receive some startling news from their accountants this spring when 1989s tax returns are being prepared. These companies could find that, for the first time ever, they will have to write a cheque to the federal government on account of a new federal capital tax which became effective July I, 1989IntroductionMany mining companies which have never had to pay a federal income tax are finding that they indeed have a tax liability for 1989. Non-producing companies, such as junior exploration companies, almost automatically assume that they don&apos;t have to pay any income tax. But, a new tax imposed under the Income Tax Act catches especially the company that has no income.Effective July 1, 1989, a federal capital tax (some call it a corporation minimum tax) is payable by any corporate carrying on business in Canada where the corporation has ""taxable capital"" exceeding $10 million. As a result of the popular use of flow-through shares in recent years, many junior exploration companies are finding that their balance sheets show capital stock over $10 million, and that they are consequently caught by the new tax. Further, some of these companies are finding, to their chagrin, that the tax for 1989 was due on February 28, 1990, and that non-deductible interest is ticking away on unpaid taxes."

Jan 1, 1990

By Y. Tanaka, M. Maeda, S. Suzuki, C. Tokoro, T. Kato, K. Muto

Boron (B) co-precipitation was investigated with ettringite to establish a cost efficient method of removing B from acid mine drainage. For 25 mg/L of B solution, most appropriate pH for B removal was pH 11.5. The most appropriate amount of reagent for B removal within Japanese effluent standard (10 mg/L) was B:Al:Ca:SO4 = 1:3:9:4.5, which corresponds to the composition of Ettringite (Al:Ca:SO4 = 2:6:3). The effect of silicate, carbonate and temperature on efficiency of B removal is important as groundwater and hot spring water are often contaminated. When silicate and carbonate are present, more Al and Ca salts are needed for B removal since some aluminum and calcium precipitate with silicate and carbonate as kaolinite and calcium carbonate. These precipitates do not contribute much to B removal. As the temperature raised, the most appropriate pH for B removal decreased. B removal became less efficient as monosulfate precipitated more rapidly as ettringite.

Jan 1, 2015

By Q. J. Xu

In blasting sensitive areas, the use of traditional blasting for rock fracture is restricted. Soundless cracking technology has been presented to achieve rock fracture instead of blasting. However, when the diameter of a borehole is larger than 50 mm, it is very dangerous that the soundless cracking agent (SCA) will have a tendency to gush from the borehole, which also leads to cracking failure. In this paper, a new large scale borehole soundless cracking technology is presented, using a new enlarged drill bit and mechanical plugging, which could solve the hole gush problem. Experiments were made to measure the expansive pressure of the SCA working in boreholes of F40 mm and F100 mm. The difference between two sizes of cracking phenomenon was compared and analyzed to show that large scale borehole soundless cracking has larger expansion pressure and faster reaction speed than traditional soundless cracking. Based on the experimental data, finite element analysis was utilized to study the stress concentration and stress distribution between two neighboring large boreholes in several media during the cracking process. Using the data from experiments with finite element numerical simulation, the brittle material fracture condition was analyzed to design the parameters of the borehole mesh. With the theoretical analysis, the technological process and reference parameters of large scale borehole soundless cracking were proposed, including the borehole spacing, burden distance, depth of the borehole and so on. Then a single rock was cracked with the new enlarged drill bit and new plugging, and the results proved the feasibility of the new large scale borehole soundless cracking technology, which achieved the expected goal of improving the cracking ability and reducing the cracking time. This paper presents a new efficient rock cracking method for blasting sensitive areas, and which could apply to mining engineering, demolition engineering, excavation engineering and other engineering applications where there is a demand soundless and non-vibration fracturing of rock.

Aug 1, 2013

By W. G. McBride

THE present demand for men with engineering training exceeds anything in the history of the profession. Recent estimates indicate that mechanization of war has reached such a stage that at least twelve horsepower is required now for every one horsepower needed to run the machines of the first Great War. The scale of operations exceeds anything in the past, while more territory and people are involved than ever before. Many of our allies have inadequate or no facilities for producing the thousand and one articles absolutely necessary to the conduct of modern warfare. Lack of preparedness has made it necessary to produce at an unparalleled rate to gain parity with the enemy, while our losses have been so heavy that replacement, in itself, presents a task which might well stagger less courageous peoples. This means that not only is there an unprecedented demand for engineers to produce the machines, munitions, and supplies of war, but there is a correspondingly large need for men with engineering skill in the uniformed forces to operate and maintain the vast numbers of ships, &apos;planes, tanks, trucks, radios, and a myriad of other devices to carry on the varied activities of war. This abnormal demand came upon us after almost ten years of stagnation in the engineering industries. During this time many trained engineers drifted into other callings, while the lack of jobs for graduates caused a falling off in the number of men training for this profession. Consequently, the supply of well trained engineers was below normal when the madman of Germany precipitated us into the present turmoil. Added to all this, we in Canada are still suffering from governmental inefficiency in the utilization of the available supply of engineers. In the armed forces, engineers have been assigned to office and other work where their engineering training is not only wasted but for which men with more suitable training could be found. Mining engineers are debarred from service as aeronautical engineers, and students in mining engineering are denied the bursaries provided for aiding students in engineering. Mining and metallurgical engineers are both barred from the Ordnance department of the army. This arises from a misunderstanding in relation to engineering training. In Canadian engineering schools, all engineers are given a sound training in the branches of human knowledge which are fundamental to engineering: mathematics, physics, and chemistry. The basic difference between the several categories of engineers lies in the fact that training in the application of this fundamental knowledge to the solution of engineering problems is given in different subjects.

Jan 1, 1942

By E. P. Cadwell

"Throughout the years Cyanamid has been a supplier of cyanide and a supplier of information to the mining industry. In general, the knowledge of mineralogy is greatly overlooked. Mineral deposits in the Western hemisphere have been exceedingly rich in the past but now they are becoming poorer. In other words, we will have to use our talents to the utmost to extract the precious metals and base metals from these ores. Modifications of some of the mineralogical equipment displayed here belong in the mill.Cyanidation of copper has been one of the main projects in our labs in recent years. De-rimming or de-filming of copper in order to upgrade copper concentrate was the main aspect investigated. A study was made as to how wide spread was the filming of secondary copper on pyrite, and to what extent it affected the copper industry. It was very wide.Often there is no conception as to what the minerals are. One open pit copper producer with a chalcopyrite ore was producing a copper concentrate with a 5% copper value whereas chalcopyrite contains 35% copper. They used primary and secondary grinding and a regrinding section. The ore contained about 8 parts chalcopyrite to one part of other copper minerals. In tests, a 3 1/ 2% copper rougher concentrate, cleaned without regrinding but conditioned with cyanide for a low contact time of 30 seconds produced a 30% copper concentrate with 90% recovery by removal of the film. It was of utmost importance that some quantitative mineralogical analysis be made before flow sheet changes were made. Every man should be trained to do his own microscopic examination in order to get quick answers. The fundamental thing in all mineral dressing is to first of all know the minerals and the mineral associations."

Jan 1, 1964

By K. Ogawa, T. Yokoyama

Hydraulic fracturing technique, an applied technique to cause tensile fractures to rock by injecting water pressure to a certain closed section of the borehole, is a measurement method of in-situ rock stress. This technique has the highest track record for techniques used in sub 1000 meter. A feature of this technique is comparatively simple and easy for in-situ stress measurement, because the measurement is applicable when a drilled borehole is available. The predominant advantage of this method is that elastic constants such as Young’s modulus and Poisson’s ratio are not required for determining the value and direction of initial stress. The factors to determine the stress state are the water pressures of re-opening and shut-in of fractures around the borehole wall and its directions. With conventional methods, however, the accuracy of the derived stress states from the observation equations was often adversely affected by the lack of consideration of the remaining water pressure in fractures and insufficient stiffness of the pressurization system. We have developed a new hydraulic fracturing system based on a new test method concept overcoming these defects, and applied to a 300 meter deep borehole in granite. The most important improvement of the new system is an employment of a syringe pump which enables an accurate flow control of fluid with less than 1ml/min in the pressure of 30MPa. Therefore the new test system has a quick response for pressurising in the interval zone, and the measured data was confirmed extremely accurate.

Jan 1, 2015

By Bonnie Cooper

3D printing by fused deposition can be used on lunar soil. The soil can be precisely size-separated to make the 3D printing process work efficiently. Using a MASER instead of a LASER would allow us to use the finest fraction of lunar soil, AS-IS, to manufacture things on the Moon.

May 1, 2013

By Fred E. Gray

The mill of Bralorne Mines, Limited, is located on the government highway in the Bridge River mining district of British Columbia, approximately fifty miles northeast of Shalalth, the shipping point on the P.G.E. railway. Prior to 1931, the property now owned by Bralorne Mines, Limited, was operated by Lorne Gold Mines, Limited. During the early operation of the mine, the ore had been treated at various times in one of three small amalgamation mills on the property. With the succession to ownership by the Bralorne Mines, Limited, work was started on construction of a new mill of approximately 100 tons capacity per day. The new mill was put into operation in the month of February, 1932, and since that date has been in continuous operation, milling an average of slightly over 3,000 tons of ore a month. The ore treated in the Bralorne mill is a gold-bearing quartz containing a very small amount of silver. About 75 to 80 per cent of the gold is in the form of free gold, the principal remaining portion being intimately associated with pyrite and arsenopyrite. The gangue rock is quartz, together with varying but relatively small amounts of altered diorite or albitite. In some of the ore, usually the higher grade portions, there is also considerable talc, which forms much slime in grinding. The mill is situated near the portal of the main haulage tunnel and the ore is received directly from the mine ore-trains, which dump on to the grizzly over the coarse-ore bin of the crushing plant. Figure 1 shows the flow-sheet of the mill as it is now being operated. Various changes have been made in the flow-sheet and in the reagents since the commencement of operations, and doubtless minor changes will continue to be made in order to increase the efficiency of the mill. Among the more important changes were those from two-stage to single-stage grinding, and from amalgamation plates to blankets. The change in the crushing was made because too much crushing was done when both primary and secondary mills were employed.

Jan 1, 1933

By A. A. Rogozhin, E. G. Likhnikevich, S. I. Anufrieva, A. V. Kurkov

The Beloziminskoe deposit in Siberia is a large, potentially productive deposit of rare metals contained in ochreous apatite pyrochlore ores formed by weathering of a carbonatite. The ores are composed of pyrochlore, columbitized pyrochlore, monazite, apatite, magnetite, ferric and manganese hydroxide, titanic iron ore, zircon, hydromica, quartz, feldspar, and carbonates. A gravity-flotation enrichment flowsheet with application of cationic and anionic collectors has been developed. This flowsheet allows for obtaining a pyrochlore concentrate containing 44.3% Nb2O5 and 1.89% P2O5 with recovery of 55.83% Nb2O5 as well as an apatite concentrate containing 39.2% P2O5 and 1.05% TR2O3 with recovery of 62% P2O5 and 43.23% TR2O3 from ores containing 0.92% Nb2O5, 16.9% P2O5 and 0.6% TR2O3. Rare-earth concentrate containing 40% TR2O3 with recovery of approximately 10% TR2O3 was obtained at the same time. Major losses of valuable elements are related to slimes, which make up more than 50% of the ground ore. The niobium concentrate does not meet the phosphorus and radionuclide concentrations needed for the production of ferro-niobium. Acid leaching and sulfatization provided a high level of phosphorous and radionuclide removal. Conditions include hydrochloric acid pre-leaching at 75- 80°C with an 18% HCl solution for four hours and low-temperature sulfatization of acid-leached concentrate at 160-180°C for one hour followed by water leaching of the residue. The apatite concentrate could potentially be processed using nitric acid leaching. This technology is based on decomposition of apatite concentrate with 55-57% strength nitric acid with transfer of rare-earth metals into solution in the form of ammonium phosphate. This technology recovers a rare-earth concentrate containing 95% TR2O3 with extraction of 86%, and highly concentrated polynutrient fertilizer (ammophos) with phosphorus extraction of 95%. The completed research shows how complex multicomponent ores of residual soil may be processed for the extraction of niobium, phosphorus, and rare-earth products.

Jan 1, 2016

By R. F. Errington

"Radioactive minerals are found together with the more familiar ore minerals in veins, gossans, and pegmatites, Since they have a peculiar property, that of giving off penetrating radiation, the simplest means of field detection is by the use of some radiation detector.The two principal radioactive elements one may encounter are uranium and thorium. These may occur separately or together. At present there is very little demand for thorium and hence radioactive occurrences should be examined with some care to determine which element is present. To do this it may be necessary to have a chemical analysis made of samples from the occurrence. Uranium minerals that do not carry appreciable thorium have a conventional occurrence in quartz or carbonate veins. They are distinctive in appearance. Pitchblende, the principal ore, is hard, black, and very heavy. It weathers readily to soft, powdery minerals •brilliantly coloured orange, yellow, and sometimes green. It may be associated with familiar minerals such _as native silver, nickel-cobalt sulphides and arsenides, chalcopyrite, and hematite.It is the purpose of this paper to review very briefly the types of radiation detectors available .and to draw some general conclusions as to the types most suitable for particular applications.The highly penetrating gamma radiation is the most useful for detection of radioactive mineralization. The alpha rays have little or no penetration, and beta rays are stopped by thicknesses of a millimeter or so of material. We shall confine our remarks principally to those instruments intended to detect gamma radiation. These are of three types."

Jan 1, 1950

By Andreea Catalina Gluhoi

Oxidation and reduction reactions of N-containing molecules have been studied over different types of gold-based catalysts, Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 (M, MI, MII=Li, Rb, Mg, Ce, Zr, Mn, Cu) prepared by deposition precipitation with urea. In general, all the catalysts were already active at low temperatures. NH3 oxidation was effectively catalyzed by Au/CuO/Al2O3, a catalyst which also gives the highest yield in N2. NO reduction by H2 performed over gold-based catalysts produced N2O, N2 and NH3 and N2O reduction resulted in the formation of dinitrogen. For all the reactions, large synergistic effects have been obtained by addition of different kind of additives.

Oct 1, 2003

By Laura Kelsey

Contaminant Robust In Situ Water Extractor CRIWE Nafion-based water clean-up Extract purified water from natural extraterrestrial sources In situ water processing for downstream electrolysis Chemically resistant to process contaminants such as acid

May 1, 2013

By Kai Bartram

The successful application of color sorting machines has established sensor-based sorting in the mineral industry in recent years and is considered today as a significant innovation in processing technology. However, we are only at the beginning of (market) introduction. New sensor systems have been developed, which exploit material properties such as electrical conductivity, magnetization, molecular structure, thermal conductivity etc. This opens up new exciting preconcentration and upgrading possibilities for many applications such as nickel, gold, copper and other ores as well as for industrial minerals, diamonds and other gem stones.

May 1, 2009

By B. Jakovljevic, M. D. Soderstrom, T. McCallum, A. J. Quilodrán

Cytec has developed a new organophosphorus based solvent extraction (SX) reagent for rare earth separations. The new product, CYANEX® 572, has been formulated to allow efficient extraction while minimizing the strip acid requirements. The optimization of formulation strength is expected to significantly reduce the operating costs of these circuits. Modeling capabilities for CYANEX® 572 (similar to those used successfully in Cu and Co/Ni SX) have also been developed to aid in the design and optimization of the SX circuits. Simulations will be shown comparing CYANEX® 572 to a traditional rare earth extractant.

Jan 1, 2014

By Iain Sommerville, Hugh Mountford, Dawid D. Smith, Claude Dube, Brett Hixson

JW Aluminum use lean and Six Sigma techniques to continuously improve their target of reliable, repeatable and reproducible (3R) manufacturing. Six Sigma’s second stage gate, known as "Measure" involves identification and qualifying appropriate measuring systems. Metal quality (inclusions) are known in the industry to be an important element in 3R casting. The measurement of inclusions at JW Aluminum historically depended on outside vendors. In order to establish real time inclusion measurement ability within JW Aluminum, inclusion measurement systems in the marketplace were investigated. The qualification of a MetalVision MV20/20 ultrasonic inclusion analyzer are discussed as well as the subsequent application of the system in melting and casting improvement projects.

Jan 1, 2015

By E. W. Garner

THE greatest problem confronting business managers in modern times is not production, but distribution. It would be easy to expand productive output, but it is difficult to find markets for all that is produced. The fundamental source of economic difficulty, in the view of many observers, is a lack of proper balance between productive capacity and consumptive capacity. The studies conducted by the Brookings Institution on the general subject, "The Distribution of Income in Relation to Economic Progress", have led to conclusions of far-reaching significance, which may be summarized briefly as follows: (1) We have never lived beyond our economic means or capacity. (2) We have not been suffering from general overproduction. (3) We have not as yet reached a stage in our economic evolution at which it is possible to provide adequate standards of living for everybody. ( 4) It would require less than a 25 per cent increase in purchasing power among the masses to absorb our full productive capacity. (5) Production-curtailment programmes-whatever their merit in meeting temporary maladjustments-can only lead to national impoverishment. (6) Our inability to find markets adequate to absorb the full output of our productive establishments is explained by the unequal distribution of income and consequent restricted flow of purchasing power through consumptive channels. (7) The slow rate of growth of consumptive demand serves to retard the rate at which new capital is constructed, and hence the rate of economic progress. (8) The primary need is a rapidly expanding total income, and a broader diffusion of this income among the masses of the people. (9) A broader diffusion of income can best be achieved by reducing prices as rapidly as increasing efficiency will permit. That is to say, the benefits of technological progress, mass production, and low unit costs must be promptly passed on to consumers in the form of lower prices-giving more for each dollar.

Jan 1, 1936