Search Documents

By T. Johnson, D. Kelley, J. Graham

"Hydrometallurgical processes can be exceptionally corrosive. Conditions associated with metal extraction and refining require materials of construction that can withstand process acids and acid chlorides at temperatures up to 90°C (194°F). Process vessels, piping, scrubbers and ducting can be rapidly compromised in these aggressive environments if not designed with care. Design engineers are challenged to find materials that can stand up to hydrometallurgical processes especially for copper, zinc, nickel, cobalt and uranium. This paper will evaluate material solutions to determine which provides attractive economics for initial procurement as well as high durability for reasonable life cycle costs.INTRODUCTIONMining activity in a number of metal ores has been running quite high over the last few years. In particular, those metals that employ acid functional extraction processes such as copper, nickel cobalt and uranium have been particularly active.The world’s largest nickel mine – the massive $4.76 billion Ambatovy nickel mine on the African island nation of Madagascar is nearing completion. When it reaches its full production capacity in 2013, the mine will produce 60,000 MT/yr of nickel and 5600 MT/yr of cobalt. Coming on the heels of the Ambatovy project is the Long Harbour Processing Plant in Newfoundland, Canada which will process the ore from Vale’s Voisey Bay mine in Labrador. Voisey’s Bay is expected to generate more than 50,000 MT/yr of nickel ore when it starts up in 2013. Next up will be the Boleo project in Mexico on the Baja peninsula. When commissioned in 2013, the $858 Million Boleo project is expected to produce 60,000 MT/yr copper, 3100 MT/yr cobalt, 36,000 MT/yr zinc and 100,000 – 250,000 MT/yr manganese carbonate.High nickel alloys and rubber lined steel have been used for decades to design corrosion resistant equipment for mineral processing environments. These materials demonstrate reasonable resistance to corrosion for most environments. Unfortunately, higher nickel alloys are quite expensive. Rubber lined steel is a bit more affordable but requires continuing service over time which ultimately drives up its cost as well. FRP (Fiberglass Reinforced Plastic) has also been used extensively in mineral processing for tanks, piping and ducting employed in aggressive environments. Today, more and more design engineers and material specifiers are calling for FRP composites for both new and replacement equipment used in the refining and processing of a variety of metal ores."

Jan 1, 2012

"Introduction The first documentary record of coal nurung on Vancouver Island was that of the Hudson Bay Company operations in the Suquash area in 1836. Between 1836 and 1862, the Hudson Bay Company mined some 65,000 tonnes from this Suquash field and the Nanaimo coal fields discovered in 1851. However, systematic mining of coal did not take place until the Hudson Bay Company holdings were sold to the Vancouver Coal Company in 1861, and a rival company under Robert Dunsmuir was established in 1869. These two interests under various organizational names and jointly as the Canadian Collieries (D) Ltd. (1928) developed and exploited the coal seams of the Nanaimo and Comox Basins from 1852 to 1966. Because of the proximity of the coal outcrops to tidewater, the coal was readily marketed to ocean-going and coastal ships for fuel. However, during the turn of the century the main market was to meet the demand of the developing cities along the west coast of Canada and the United States for residential and commercial heating. Island-based copper smelters and brick factories, and the coming of the railroads motivated by steam engines increased the demand. This economic success of the industry continued until 1922 when a peak production of over 1,750,000 tonnes was reached. Following 1922 labour unrest in the industry, which affected the certainty of supply, and the availability of alternatives in the form of California petroleum and mainland coal combined to cause a rapid and steady decline in the demand for Island coal. In spite of post-and pre-wartime prosperities the trend could not be reversed. Serious coal mining phased out in the Nanaimo area in 1939 and in the Comox area in 1967. puring the 114 years in which the industry flourished over 75 million tonnes of coal were mined from more than 30 mines and a minimum of ten new mining communities were established on Vancouver Island."

Jan 1, 1985

By J. R. Kish, J. Dabrowski

"The susceptibility to intergranular corrosion modes is a major technical issue preventing widespread utilization of higher strength welded AA7xxx extruded beam profiles, in the peak-aged T6 condition, in automotive bumper assemblies. A study was undertaken to evaluate the relative exfoliation corrosion resistance (ASTM G85-A2) as a function of joint design parameters, namely the base alloy composition, heat-treated condition and beam orientation after exposure to a cyclic acidified salt spray test. This paper documents the major findings extracted from this study.INTRODUCTIONBumper systems play a predominant role in the passive safety of an automobile, since they are one of the main structures for absorbing the collision energy in the event of an automobile crash. Heattreatable AA6xxx-series (Al-Mg-Si) and AA7xxx-series (Al-Zn-Mg) Al alloys, with relatively high strength, toughness, energy absorption, weldability and formability, make it possible to design costcompetitive bumper systems to crush in a controlled fashion. In this context, Cu-lean AA7xxx extrusions, such as AA7003 and AA7108, which exhibit higher strength than AA6xxx extrusion, such as AA6082, represent an attractive light weight material from which to fabricate bumper assemblies (Clausen et al., 2000; Pedersen et al., 2008; Chen et al., 2009).Arc welding is a key joining process for AA7xxx alloys within the transportation industry. A major technological issue preventing widespread utilization of arc-welded AA7xxx joints is the susceptibility to severe localized corrosion (Kent, 1970, Reboul et al., 1985; Holroyd et al., 1987). It generally occurs as exfoliation corrosion within a heat affected zone (HAZ) a few millimeters from the weld bead, or a type of stress corrosion cracking (weld-toe cracking), which initiates at the weld toe and propagates into the interfacial region between the weld bead and the HAZ (so called “white zone”). In addition to the micro-galvanic cell activity induced by the intermetallic compound constituent and strengthening particles present, there is strong evidence that macro-galvanic cell activity between the weld bead and base AA7xxx alloy may be playing a controlling role. Electrochemical profiles taken across fusion welded joints, in cross-section, during exposure to saline solutions suggest that a significant potential difference exists across the AA7xxx arc-welded joint (Shumaker et al., 1967; Grauer and Wiedmer, 1980; Tuck, 1985, Onoro and Ranninger, 1993). These studies consistently show that the HAZ and base alloy are more electronegative with respect to the weld bead (arc-welded with AA5xxx filler wire). Despite this initial important work, the majority of the recent corrosion research effort on welded AA7xxx alloys has focused on the performance of friction stir welds (Lumsden et al., 1999; Wadeson et al., 2006; Hatamleh et al., 2009)."

Jan 1, 2012

By B. A. Monkman

"IntroductionONE OF :THE most effective methods by which the construction industry is combatting mounting building costs is by making increased use of lightweight materials, thus reducing the dead load to be carried •by structures. This applies to non-metallic materials as well as to metallic ones, and particular attention has been given to developing lightweight aggregates for use in concrete.The use of lightweight aggregates is not new and, in fact, dates back to the Roman Empire, when pumice was used in the walls and domes of the Roman buildings. More recently, and up to a decade or so ago, the demand for these aggregates was met from deposits of volcanic cinders, pumice, scoria, etc., and from the by-products of blast furnaces and coal burning boilers. However, these sources of supply are no longer sufficient to meet the demand, for transportation costs pretty well restrict the use of the natural lightweight aggregates to the western cordillera regions where the deposits of these materials occur, and the use of expanded slag aggregates to the areas neighbouring the plants where slags are produced. As for cinders, the supply has been greatly reduced by the conversion of industry to fuel oil, natural gas, and powdered coal, and the large stockpiles which existed previously have been pretty well exhausted.Industry's approach to the problem of a decreasing supply, in the face of an increasing demand, has been characteristically direct. The solution has been to construct plants whose sole .purpose is to produce economically an acceptable light-weight aggregate from materials close at hand."

Jan 1, 1955

By A. J. Pearce

MOST mines have a model of some kind to illustrate either geological structure, mining operation, or some special condition or feature of the property. The type used depends on the particular feature or use for which it is intended. At Dome Mines we have developed an interesting and practical application of the horizontal-type model. This model shows the workings of each level horizon plotted on glass. These glass panes are set in frames which, in turn, rest on drawers equipped with rollers which can be pulled out as desired into a light chamber. The features of this model are its rigid steel construction and that any desired number of level plans can be pulled out, eliminating any other interference from other levels. Figures 1 and 2 are photographs of the model cabinet and show its construction and general features. The cabinet is of steel construction with the following overall dimensions: width, 6 ft. 5 in.; depth, 6 ft. 7 in.; height, 5 ft. 2 in. When not in use it can be completely closed-in, making the cabinet practically dustproof. There are 30 drawers, one for each of the 29 levels and one for the surface. The glass in each drawer is divided into two panes, 36 in. by 36 in., of flatdrawn double-diamond 'lustraglass' with about l/32 in. between adjacent edges. The panes are held rigidly in the frames, which are lined with felt strips, and may be adjusted by set screws, four of which on each drawer are shown in Figures 1 and 2. The level workings, on a scale of 1 inch equals 100 feet, are traced in ivory black Windsor & Newtons artist oil paint. Co-ordinate lines are shown in crimson lake, and main geological contacts are shown in their respective colours. Figure 3 is a photograph looking down on one of the levels. The lighting consists of 14 30-watt fluorescent bulbs, with reflectors, under frosted glass. These lamps are much more satisfactory when operated by 60-cycle rather than 25-cycle and, as we had available nearby a source of direct current, this was used. The electrical unit consists of a rotary converter from d.c. to 60-cycle. This arrangement gives perfect lighting, allowing most colours to be easily distinguished. Figure 1 was photographed using this source of light, Figure 2 using an outside floodlight.

Jan 1, 1945

By R R. Wainwright

Friction-type hoists have been in operation at Geco Mines Limited since Septtember, 1957. At the end of the year 1963, the skip hoist had handled nearly ~ million tons of ore and waste. In March, 1962, with the deepening of the shaft, the hoisting de11th was increased from 1,450 to 2,450 feet. Operating experience with the hoists, hoist and balance ropes, rope treads and other related equipment is presented. The paper is intended to supplement an earlier one -"Heavy-Duty Friction Hoisting at Geco Mines," by W. M. Harvey (C.I.M. Transactions, Volume LXIII, 1960, pp. 193 -197). General G ECO Mine Limited is located at Manitouwadge, Ontario, approximately 160 miles east of Port Arthur and 190 mile northwest of Sault Ste. Marie. The Company was formed to exploit a copper-zinc-silver orebody, with current ore reserve (1963) of approximately 21 million tons. The production plant was designed to mine and treat 1.25 million tons per annum. The production and service hoists are mounted at-the top of a reinforced concrete tower above the shaft.

Jan 1, 1965

By Doug Ashbury

Diamond Miners? Challenges ? Remote ? 300 kilometres from Yellowknife ? Sub-Arctic conditions ? permafrost, climate ? No power ? No all-weather roads ? Ore bodies difficult to find ? Caribou, fish of special concern ? Communities with low education, little experience, but high expectations ? Major investment required ? Diavik C$1.3 billion

Apr 1, 2005

By H. A. Oaks

FROM 1921 to 1939, the aeroplane played an increasingly important role in Canadian prospecting and mine development. This service has been interrupted by the war, but undoubtedly it will be accelerated in the postwar years, if suitable aircraft are available. The purpose of this paper will be to review the uses to which the aeroplane has been put in prospecting and development in the past, and its future possibilities as an aid in prospecting. If by review, and deduction, we get a clear picture of what we expect the prospecting plane to do, we may be able to arrive at a very close approximation of its required characteristics and, from this, an idea of costs. 'Function' is defined as the mode of action by which it (the aeroplane) fulfills its purpose. We will endeavour, therefore, first to find what this purpose is, or should be, so that our expectations will not be too limited nor too great-and then find, by analysis, what performance we require in an aeroplane to meet our reasonable expectations at an economic price.

Jan 1, 1945

By Zhang Junzhi

This paper relates cross-border mergers and acquisitions (M&A) risk management theory to actual coal enterprises in China. The 3 phases of M&A are preparation, implementation and integration. By using the Analytic Hierarchy Process and fuzzy evaluation methods, we will try to establish a model to assess risks of the cross-border M&A of China?s coal enterprises. We then apply this model to the case of Yankuang Group acquisition of the Felix Company and receive the assessment results. There are significant reasons for quantitative research on risks of cross-border M&A of China?s coal enterprises, such as effective prevention and risk-aversion, and facilitation of cross-border M&As.

Aug 1, 2013

By Matthew R. Ward

This paper aims to describe the reasons and methods to extend enterprise networks into underground mines. Currently mines use a number of communication networks for telephones, PLCs, two-way VHF radio and computer networking. Each system can have different wiring, protocols, converters and interfaces all which require expansion and maintenance. The convergence of voice, video and data using Ethernet and TCP/IP has the very real benefit of one ?wire? for underground networks. Now that the majority of underground equipment can communicate using TCP/IP, network convergence can offer reduced network expansion and maintenance costs. Cost savings are good, but the truly exciting aspect of network convergence using Ethernet is the low-cost, high speed wireless networking now available . These wireless networks offer an opportunity to facilitate mining automation even on a small budget. How would mine operators change they way they operate if they could gather vehicle location and data in real time? What about controlling equipment remotely? The list of applications is long and includes traffic control, dispatching, real-time ore blending, tele-operation, automated production reporting, vehicle health monitoring, elimination of paper forms and immediate network access for surveyors and geologists. An ideal converged network for underground mining would be robust, inexpensive, easy to expand, enable fast and secure connections while keeping voice communication performance equivalent or better than what is now provided by VHF radio

Apr 1, 2005

By T. W. Wong, M. A. Whitney, A. Hadadzadeh

Uniaxial compression tests were performed on cylindrical specimens, 10mm in diameter and 15mm in height, machined from an extruded AZ31B magnesium billet. The tests were conducted under isothermal conditions to a true strain of 0.5. The study compares macroscopic flow anisotropy between the extruded (ED) and transverse (TD) directions in the temperature range of 300°C to 500°C, and strain rate range of 0.001s-1 to 1s-1. Compression of ED specimens at low strain rate (0.001s-1) exhibited axisymmetric flow, and no significant differences were observed between geometries of specimens deformed above 350°C under the same strain rate. Deformation of TD specimens at low temperature and/or low strain rate resulted in elliptical cross-sections, with the anisotropy of flow being less significant at higher temperatures. Other studies performed using rolled plates have proposed that pyramidal slip and cross-slip at higher temperature eliminate the effects of initial texture, while the dominance of prismatic slip at lower temperatures will result in anisotropic flow. It is believed that the initial fiber texture common among extruded HCP-structured materials plays a role in the anisotropic deformation behaviour observed in the extruded specimens

Jan 1, 2015

By Marsh A. Cooper

THE THEME of my remarks provides a great deal of latitude. I shall therefore take advantage of the scope it offers to look at our industry across a broad spectrum. My observations reflect a Canadian mining man's varied career as a geologist, mine operator, geological consult ant and company executive in Canada and overseas ... under differing cultures, business environments and political jurisdictions. I was fortunate to come into this industry in the mid-1930's when it was characterized by great enthusiasm, drive and resourcefulness. It was the beginning of a burgeoning era of some 30 years' duration in which the individualist, the entrepreneur and the builder found ample room for expression. As I contemplate the environment in which we now have to operate and try to perceive what lies ahead, I find myself deeply disturbed. Something serious has happened to this industry along the way. It appears that our very success has been the source of our undoing. I believe it is useful to summarize our industry's basic strength at home as a take-off point f or assessing its position in world terms. I hope that I can focus on some of the things that, in my view, must be done for this industry and by this industry to restore Canada's historic role in the world mining community. The Canadian mineral industry provides 140,000 jobs. It pays the second -highest average weekly wages and salaries among the country's major industries. The output per employee in the mining industry is estimated at about three times that for the economy as a whole.

Jan 1, 1977

By James McMahon

Although doubt has been expressed many times as to who first brought self-contained breathing apparatus to this side of the Atlantic, there is none whatever that the first organized station was established at Glace Bay, N .S., by the Dominion Coal Company, in 1907. This station was started with 20 sets of 1907 "Draeger" apparatus and all necessary station equipment and supplies. After the fire at No. 1 pit, Sydney Mines, in 1908, the Nova Scotia Steel Company installed 15 sets of "Draeger" and sup-plies, which were housed in a rescue car (a converted pull-man.) In 1909 or '10 a fire occurred at the Back Pit, Stellarton, where the apparatus from Glace Bay was used, and subsequently the Acadia Company erected a station and in-stalled 10 sets of "Securitas" apparatus. In 1912 the station at New Waterford was opened and equipped with "Draeger," and the same year the station at Springhill was built and equipped with the same type. Sometime during past years the Nova Scotia Steel Company acquired a couple of "Proto" machines, and after the explosion at the Allan shaft in 1918 the Acadia Coal Company added some "Gibbs" to their station. From this it will be seen that when the coal-fields were organized under the British Empire Steel Corporation the equipment was rather mixed, therefore steps were taken by the executive to stanardize the whole of the rescue and recovery work.

Jan 1, 1924

By G. Reuben Yourt

THIS paper is chiefly a description of the improvements in dust control chat have been brought about in the assay office grinding room at Wright-Hargreaves. The fume exhaust systems are briefly included because they also are important to the health of the employees. There are three chief factors which determine the efficiency of a dust control system: First, the amount of time and thought spent in designing it. Second, how close! y it is kept up to date with the growth of the plant-a system that is adequate for the number of machines operating when it is installed may fall short of fulfilling its purpose as the plant expands. Third, unless someone is held directly responsible, a system is likely to get out of repair and gradually lose its efficiency-this can easily be detected by regular dust surveys. In designing the present system at Wright-Hargreaves, the object kept in mind was to reduce the dust concentration of all operations to a safe limit, chat is, well under 300 particles per cubic centimecer of air. By doing this, a condition would be attained chat would make it possible to discontinue the use of respirators, which at best are not very comfortable and do not remove all of the hazardous fine-dust particles.

Jan 1, 1941

By L. Li

Iron removal is a common procedure in hydrometallurgy of non-ferrous metallic ores. Chemical precipitation and solvent extraction are currently the main methods employed for separation of iron from copper leach solution. However, chemical precipitation methods have the problem of producing large amounts of iron precipitates, and/or requiring high temperature and high pressure conditions for precipitation. The precipitates are difficult to separate from the solution. Emulsification is a general problem for solvent extraction, which causes loss of extractants and contamination of the electrolyte. A common problem for solvent extraction and chelating ion exchange processes is the difficult iron stripping process. Therefore, finding an efficient and environmentally friendly method for iron removal is of great significance. In this paper, new processes of using ion exchange resins to remove iron from copper leach solution have been investigated. Salicylic acid, amino carboxylic acid, amino phosphonic acid and hydroxy-oxime resins were employed to adsorb iron from a simulated copper leach solution containing 40 g/L of Cu2+ and 36 g/L of Fe3+. It was found that a hydroxy-oxime resin, named Z-Fe, has excellent adsorption selectivity on Fe3+. Desorption behavior of the resin was studied by two step elution using dilute H2SO4 and oxalic acid solution, respectively. After optimizing the adsorption-elution processes, the extent of removal of iron from the simulated copper leach solution using resin Z-Fe was 90%, while copper recovery could reach 100% in closed circuit processing.

Jan 1, 2016

By Oliver Hall

WITH the friendly consent both of the Institution of Mining and Metallurgy, for whom this paper was written, and of the author, we had the pleasure of publishing Mr. Oliver Hall's paper on Mining at Noranda in our issue of last March and of having Mr. Hall present it at the Montreal Meeting. In the following pages we now report the discussion elicited by the paper at a meeting of the Institution in London on March 18th. The report is taken from the April, 1937, issue of the Bulletin of the Institution, to whom we again tender our thanks. THE PRESIDENT (MR. ROBERT ANNAN) said that this paper was, by arrangement with the Institution and the author, also being published by the Canadian Institute of Mining and Metallurgy for approximately simultaneous discussion. He was sorry that Mr. Oliver Hall could not be present to introduce it in person, for he was sure that the author would have had many more details to give about this most interesting mine. The paper contained a very useful account of mining operations, and personally he had been pleased to see the tri-dimensional projections of the orebody in Figs. 3 and S. It was a good illustration o the value of that method in presenting the form of an orebody such as this. While he had no desire to go into technical details, he wished to call attention to a remark in Mr. Hall's introduction, in dealing with the history of the mine and the principles on which it was run. The author had given an account of the early difficulties in solving geological problems, and later of the economic difficulties of seeing this mine through a period of intense depression in metal prices. He stated that it was clear that, to maintain income, tonnage must be increased, and, to maintain profits, costs must be decreased. It would be observed that there was no question of increasing the grade of ore. Then the author went on to say: 'Having set the house in order in the years of adversity, the higher price for gold is being used to mine to still lower limits and lengthen the life of the enterprise and the welfare of those dependent on it'.

Jan 1, 1937

By J. Donnelly, A. V. Deev

Substitution of coal and coke by renewable carbon (charcoal) is a low-risk and low-capital path to 50% or more reduction in net CO2 emissions by the steel industry. However, the high cost of charcoal and its low availability in most countries are barriers for the implementation of this approach. Development of an efficient wood carbonisation technology (slow pyrolysis) capable of producing large-volumes of charcoal from low-cost wood feed (e.g. wood wastes or forest residues) is an essential step towards the use of renewable carbon by the iron and steel industry. This paper provides a summary of the progress made over several years of R&D covering: (1) development and piloting of a new energy efficient slow pyrolysis process for production of charcoal from woody biomass at a competitive cost to the PCI coal, (2) techno-economic evaluation of the process. The main feature of the process is that the material undergoing pyrolysis is heated spontaneously without the supply of heat or air to the reactor. This makes it possible to carbonize large volumes of small-sized wood (e.g. wastes and residues) in a single reactor unit and capture high calorific value pyrolysis by-products

Jan 1, 2015

By R. A. Lunceford, K. C. Shaver

Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km Acquired by Teck Corporation in 1990, the White Earth project, located in southwestern Colorado is the largest titanium resource in the U.S. Teck Corporation has conducted geologic, reserve, mineral processing, pre-marketing, and environmental baseline studies directed toward the economic feasibility of producing titanium pigment. The White Earth project is situated in a 31 km2 alkalic-carbonatite complex intruded into Precambrian granite and metamorphic rocks about 570 million years ago. Perovskite occurs in a 8 km by 1.2 km

Jan 1, 1998

By Xu Feng, Han Shufeng, Zhu Bin, Wang Mingming

Due to urban subway tunnels mostly built in the cities with highly density buildings, the geological and construction conditions is complex, especially certain sections of the subway tunnel will pass through from the foundation of the overpass, therefore the stability and surface deformation control of that section’s tunnel excavation is particularly important. Taking Xi'an Metro Line Three interval tunnel as a research object, we have used FLAC3D simulation to analyze the tunnel’s surrounding soil deformation and tunnel lining stress distribution under bridge foundation with shallow buried covered excavation method. Analysis results show: (1) After the excavation of the tunnel right line, due to the bias of the upper bridge foundation the right of the tunnel showed relatively large deformation. In order to ensure the construction safety, we recommended using the grouting anchor reinforcement on the right side wall to further control the deformation zone. (2) The maximum vertical displacement of the ground occurred in the right wall of the tunnel portion which was due to the intensity of soil outside the grouting range of the arch is low, as a result the deformation is larger; this position requires special attention, strengthening the monitoring measurements of this part is necessary to avoid the large deformation and other adverse effects of the upper portion of bridge foundation. (3) The maximum vertical force area of the initial lining of the tunnel is in the middle of the side wall, while the second lining in this part of forces is smaller, thus at the beginning of the construction of the liner, attention should be paid to this area. On-site grouting or steel bracing reinforce support may be used if necessary.

Jan 1, 2015

By Minghao Hu, Hongbo Zhao, Jun Wang, Wenqing Qin, Rui Liao, Central South University

"In the present work, X-ray diffraction (XRD) analysis, X-ray photoelectron spectroscopy (XPS) analysis and electrochemical analysis were carried out to investigate the intermediate species and electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms. For bioleaching of chalcopyrite by the sulfur oxidizing microorganism Acidithiobacillus caldus, the redox potential was always lower than the appropriate value and chalcopyrite was mainly directly oxidized to polysulfide (Sn 2-), thus resulting in low copper extraction. As for bioleaching of chalcopyrite by the iron oxidizing microorganism Leptospirillum ferriphilum, chalcopyrite was mainly directly oxidized to polysulfide at the initial stage where redox potential was lower than the appropriate value and resulted in low dissolution rate. At the middle stage where redox potential was appropriate (about 350–480 mV vs. Ag/AgCl), chalcopyrite was mainly transformed to intermediate species of Cu2S rather than polysulfide, thus resulting in high dissolution rate. At the later stage where redox potential was higher than the appropriate value, chalcopyrite was mainly directly oxidized to polysulfide which caused the later passivation of chalcopyrite. Finally, a model of electrochemical dissolution process of chalcopyrite in the presence of sulfur and iron oxidizing microorganisms was provided.INTRODUCTIONBiohydrometallurgy is considered as one promising mineral processing technique in processing low grade ores due to the advantages of simplicity, low cost and eco-friendly. Chalcopyrite (CuFeS2) is the most abundant copper-bearing resource, accounting for appropriately 70% of the known reserves in the world, while is recalcitrant to bio-hydrometallurgy mainly due to the coated passivation layer (Klauber, 2008; Li, Kawashima, Li, Chandra, & Gerson, 2013). However, the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching are still uncertain. The microorganisms assisting chalcopyrite dissolution can be mainly classified into three types, including mesophilic microorganisms (e.g., Acidithiobacillus ferrooxidans, Acidithiobacillus thiooxidans and Leptospirillum ferrooxidans), moderately thermophilic microorganisms (e.g., Acidithiobacillus caldus, Sulfobacillus thermosulfidooxidans and Leptospirillum ferriphilum), and extremely thermophilic microorganisms (e.g., Metallosphaera sedula, Sulfolobus sp., Acidianus sp., and Sulfurcoccus mirabilis). Moderately thermophilic microorganisms have a better prospect in the future industrial application of chalcopyrite bio-hydrometallurgy (Olson, Brierley, & Brierley, 2003; Rohwerder, Gehrke, Kinzler, & Sand, 2003). Hence, investigating the detailed dissolution and passivation mechanisms of chalcopyrite bioleaching by moderately thermophilic microorganisms is of important significance, which will provide essential information for promoting chalcopyrite bioleaching by moderately thermophilic microorganisms in laboratory or industrial plant."

Jan 1, 2016