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By Madaah Hosseini H. R., P. Abachi, S. Miraghaei

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si. The values of coercive force decreased after annealing but it seams that the residual strain developed during milling is not the major contributing factor to the higher values of coercive force in the mechanically alloyed powders and nanocrystals behave as single-domain particles without exchange interaction between them.

Jan 1, 2006

By J. P. Harrison, R. Roostaei

"In this paper we investigate the consequences of using conventional triaxial peak strength criteria in the polyaxial stress conditions that occur around the end of a long circular underground opening. A series of 3d boundary element analyses were performed using Examine3D to determine the stresses induced around the tunnel in different in-situ stress conditions. To discuss the applicability of a triaxial strength criterion in failure prediction, strength factors were computed for both the Ottosen polyaxial strength criterion and the triaxial Hoek-Brown criterion. Assuming that the Ottosen criterion is an accurate indicator of strength factor, the discrepancy from this value due to the Hoek-Brown criterion is the error in prediction.In order to simultaneously show the error in prediction and actual strength factor, a quantitative bivariate colour scheme is used to visualize the results. This allows rapid identification of regions with large error, and where either unsafe or overly conservative conditions occur. We show how the inappropriate use of triaxial criteria rather than polyaxial criteria leads to an under- or over-estimation of strength factor, and can result in uneconomic or unsafe design. Extending the analysis to different in situ stress regimes shows how the in situ stress conditions affect the assessment."

Jan 1, 2015

By Thomas G. Madgwick

Introduction Development of oil and gas is still centred in the Province of Alberta, much as it was when C. C. Ross read a paper on this subject three years ago at the Annual General Meeting in Montreal; but so far as gas is concerned, its early production in Saskatchewan seems now assured. The three years that have elapsed since Mr. Ross' paper have witnessed a growth in the world's production of oil that has created a potential supply out of all proportion to the demand for petroleum products, and one that has resisted the most energetic efforts of the industry entirely to control. The natural result has been very much to retard the active prospecting of new structures in the Prairie Provinces with any immediate view to oil production, although the same factor has not hindered the search for gas to the same extent. One consequence has been to divert the attention of organized oil operators from wildcat drilling to more detailed geological investigation than had hitherto been customary, sometimes accompanied by test drilling with a view to the elucidation of geological structure rather than to the immediate development of production which at the present is not needed. Nevertheless, in spite of the growth of this phase of oil prospecting - which the writer would be the last not to welcome as a very real blessing and of far greater value than indiscriminate wildcat drilling in either the complex structures of the foothills or the simpler but largely concealed formations of the plains- it is most satisfactory to have to record that in these three years the growth of production both of naphtha and the heavier crude-oil has kept pace with the by no means inconsiderable growth in the production and utilization of natural gas.

Jan 1, 1929

By J. Lu, D. G. Ivey, H. Henein

Microalloyed steels are widely used in the oil and gas industry. They are a class of high strength, low carbon steels containing small additions of niobium (Nb), titanium (Ti), molybdenum (Mo) and/or vanadium (V). These steels have good strength, toughness and excellent weldability, which are attributed in part to the presence of nano-sized carbides, nitrides and carbonitrides. In the pursuit of developing higher strength microalloyed steels, it is of great interest to quantify the size, distribution, volume fraction and chemical speciation of these precipitates. However, characterization techniques suitable for quantifying fine precipitates are limited. Possible characterization techniques include SEM, TEM and matrix dissolution. A comparison is presented of the various techniques.

Jan 1, 2005

By R. V. Kumar, C. Schwandt, S. Subramanian, S. Sampath, S. Vimalnath

Waste waters and industrial effluents containing toxic heavy metals such as Pb, Hg, As and Cr, beyond permissible limits (0.1 ppm, 0.01 ppm, 0.02 ppm and 0.05 ppm, respectively) (WHO, 2011), pose serious threats to the ecosystem, when discharged into the environment. It thus becomes imperative to monitor the concentration of the toxic heavy metals and treat them before discharging. In this study with the above objective in mind, a microbial sensor has been developed using P. aeruginosa cells drop coated onto a carbon paste electrode (CPE) for the detection of Pb(II) ions in aqueous solutions. Detailed biosorption experiments confirmed that complete bioremoval of lead could be achieved using P. aeruginosa cells under optimum conditions of pH and biomass loading. For the electro-analytical determination, the Pb(II) ions were initially preconcentrated on the P. aeruginosa modified CPE, reduced and then anodically detected with oxidation of Pb0 using differential pulse anodic stripping voltammetry (DPASV) technique. All the experiments were carried out in the presence of 0.1 M sodium acetate buffer and KNO3 as background electrolyte. The parameters namely pH, scan rate, biomass loading, deposition potential, deposition time and concentration of Pb(II) ions were optimized for the biomass modified CPE, to obtain maximum voltammetric response. Under the optimized conditions of pH 5.6, scan rate of 0.008 V/s, biomass content of 1.7–1.8×109 cells/mL, deposition potential of –1.2 V, and deposition time of 500 s, the developed microbial sensor showed a linear response for the peak current between 0.5×10-5 M and 1×10-8 M of Pb(II) ions with the R2 value of 0.9979. The lowest limit of detection (LLOD) was determined as 2.4×10-7M of Pb(II) ions (0.05 ppm). The redox mechanisms of Pb(II) ions on the P. aeruginosa modified CPE surface are discussed.

Jan 1, 2016

By J. Jin, J. D. Miller

"Bubble attachment at hydrophobic surfaces is of critical importance in the flotation recovery of mineral resources and fundamental experimental results have been reported in the literature describing the details of film thinning, rupture, and displacement. Now, for the first time, bubble attachment phenomena are examined using Molecular Dynamics Simulations (MDS). The simulation involves a nitrogen bubble containing 906 nitrogen molecules in a water phase with 74,000 water molecules at the hydrophobic molybdenite (001) surface. During the simulation period of 1 ns, film rupture occurs and the nitrogen bubble attaches to the molybdenite (001) surface, resulting in a contact angle of about 90o. In contrast, the film is stable at the hydrophilic quartz (001) surface and the bubble does not attach. Contact angles, determined from MD simulation after stabilization of the three phase line of contact, are reported and these results agree well with experimental and MDS sessile drop results. In this way, film stability and bubble attachment are described with respect to interfacial water structure for surfaces of different polarity. For example, the interfacial water molecules for the hydrophobic molybdenite (001) surface have relatively weak interactions with the surface when compared to the hydrophilic quartz (001) surface, as revealed bythe presence of a 3 A water exclusion zone at the molybdenite/water interface. INTRODUCTIONAttachment of air bubbles to mineral particles is of fundamental importance in understanding flotation separation phenomena. It is well known that attachment of an air bubble at a hydrophobic surface includes film thinning, film rupture, and film displacement (Somasundaran, 2006; Wilson, Adlard, Cooke, & Poole, 2000). Experimental techniques, such as high speed video, can catch the process of bubble attachment at a mineral surface (Drelich & Miller, 2012; Niecikowska, Krasowska, Ralston, & Malysa, 2012). However, molecular scale information to examine the phenomena has not yet been reported."

Jan 1, 2016

By R. Tremblay, M. Burrows

"In the summer of 1990, pilot scale testing of a Jameson cell was carried out at Falcon bridge Limited, Kidd Creek Division. The Jameson cell is self aspirating and has fewer mechanical parts, thus it has a lower operating cost compared to conventional cells. This lower operating cost combined with positive pilot scale results, justified the evaluation of two full scale cells in the plant. The plant test had two mandates:1. Gain a thorough understanding of the cells operation and design constraints.2. Develop a flow sheet to replace three divisions of copper cleaner flotation.This paper provides an overview on the installation, commissioning and evaluation of the two Jameson cells acquired. The current status of the test program is also discussed.IntroductionThe Falcon bridge Limited-Kidd Creek Division concentrator is located in Timmins, Ontario. The concentrator, commissioned in 1966 and expanded in 1978, consists of four parallel grinding and flotation divisions utilising small cell (60 ft3) technology. With increasing pressure to maintain low operating unit costs a series of studies were undertaken to assess the impact of new technologies in the flotation circuits. The goals of the project were to improve productivity through increased metallurgical performance and/or reduced operating costs.One of the technologies investigated was the Jameson cell designed by Dr. Graeme Jameson of the University of Newcastle and marketed by MIM Holdings Limited, Australia. This style of column technology was chosen based on its potential for reduced capital and operating cost versus large conventional cells.The success of pilot testwork in 1990 led to the installation of two production sized Jameson cells beginning in October 1991. The units were to be used to confirm pilot results and determine equipment requirements for flotation modernisation. This paper will discuss the results and experiences Kidd Creek has had with the Jameson cell from pilot scale through installation and commissioning of the plant units."

Jan 1, 1993

By E. Brouillette

Difficult operating and mining conditions such as low visibility, difficult roadbeds, fast cycling, small openings, and sharp corners create high demand for LHD manoeuvrability and operator dexterity. Operator experience and patience is especially solicited to fill the bucket rapidly and efficiently and performance can be particularly affected by the skill level of individual operators. Teleoperation and automated loading are viewed as options to improve overall equipment and operation performance in certain mining conditions. Comparative statistical measurements of autoloading performance in different production environments at Noranda demonstrate an increase in bucket filling efficiency and a reduction in filling variance, allowing LHD operation to be more consistent and within manufacturer specifications. Consequential cost savings and productivity increases are demonstrated to be transferable to other mining situations.

May 1, 2003

By B. R. Rakishev

When transferring from the railway transport to the combined automobile-conveyor transport by stripping works at coal mines, it was proposed to form at the working zone a concentration horizon for reloading part of the stripping volumes at the railway transport. The procedure is adduced for substantiating parameters of bloc-panels, depending on the step of transferring of reloading points in interrelation with the intensity of the working zone?s development with observing the balanced movement of parts of the stripping zone relative to the temporary concentration level.

Aug 1, 2013

By V. W. Shtenko, B. J. Ennis, P. H. Bridge

"The northeastern region of British Columbia contains large quantities of high-quality metallurgical coal. To market the coal, it was necessary to provide the required infrastructure which included rail access. This paper presents the role of the British Columbia Railway in the northeast coal development.In 1976, B.C. Railway undertook to study two main routes, one originating at Chetwynd and the other at Anzac, both located on the main line, north of Prince George. The routes studied are briefly described, detailing the methodology and engineering analysis carried out to permit the selection of a single route that would be the most cost effective, taking into consideration the construction, maintenance and operating costs. The operating parameters, track and grade standards, anticipated tonnage, construction costs and the final route selected are also presented.Pre-engineering analysis and studies of the route selected originating at Anzac, known as Tumbler Ridge Branch Line, and which commenced in 1977, were concluded in 1978. New mapping was developed to a scale of 1:2000 with good vertical and horizontal control. Based on the mapping data, terrain analysis, and designs developed, an estimate of construction costs and schedule of work was developed.Authority to proceed with the final design and construction was provided in December 1980, with the first shipment scheduled for December I, 1983. Final designs of all structures are discussed, including schedules, cost to completion, and control systems utilized. The decision to electrify the Tumbler Ridge Branch Line and related topics are discussed, with a brief description of train operations. The present status of the project is also presented."

Jan 1, 1983

By H. Fuchs, W. Hilger, E. Prosser

"The Lone Gull discovery of Urangesellschaft Canada Limited was made in 1974 as a result of extensive exploration activities for unconformity related uranium deposits in the Baker Lake area of the Northwest Territories. The structurally controlled mineralization is hosted in Aphebian metasediments and intrusive granitic stocks located approximately 2 km south of the unconformity between the Lower Proterozoic Aphebian and the Middle Proterozoic The/on Formation.The original discovery was made with a helicopter mounted radiometric system during systematic prospection over the unconformity. Diamond drilling was first carried out in 1977 and continued, with an interruption in 1981, to the present. A total of 25,500 metres and 199 holes have been drilled and outlined three ore zones. Preliminary geological reserves are estimated at some 16 million kgs. U30 8 at an average grade of approximately 0.4%.IntroductionUrangesellschaft initially entered exploration in Canada as a participant in joint ventures in 1968, and was incorporated in Canada in 1974 as Urangesellschaft Canada Limited. Subsequently, UG was among the first companies to apply exploration criteria developed from the Athabasca Basin, namely the Middle Proterozoic unconformity over Archean/ Aphebian basement, for selection of exploration targets in the geologically similar Thelon Basin.The Baker Lake area in the Keewatin District of the Northwest Territories was selected from the extensive Thelon Basin because it had the best accessibility (Fig. 1). The hamlet of Baker Lake located close to the geographical centre of Canada, is largely an Inuit settlement with a population of approximately 1,100 inhabitants. The distance from Baker Lake to the Lone Gull property is about 80 km. Baker Lake is connected to the tidewater of Hudson's Bay via Chesterfield inlet and is serviced by scheduled domestic flights several times weekly from Churchill, Manitoba, about 650 km to the south."

Jan 1, 1986

By Ki-Bok Min, Seokwon Jeon, Seung-Beum Choi, Taehyun Kim

"In order to investigate anisotropic characteristics of Boryeong shale in Korea, which clearly shows transverse isotropy, a series of experimental tests were carried out. Using Brazilian test, five elastic constants and tensile strength of the shale were evaluated. Elastic constants were determined by iterative procedure and in order to perform this procedure, constitutive model was modified to fit the experimental condition. The anisotropic ratios of elastic constants were evaluated and the applicability of the methodology was assessed. Apparent Brazilian tensile strength profile was investigated and the ratio of the maximum to minimum tensile strength was estimated. Results showed that the tested rock type had low to moderate anisotropic characteristics.INTRODUCTIONMechanical, thermal and hydraulic characteristics of many rocks vary according to direction, which is known as inherent anisotropy, and it is originated from stratified and/or foliated structure of intact rock and discontinuity of rock mass. Anisotropy is one of the long standing issues of rock mechanics field and it has to be taken into account in several engineering fields such as civil, mining and petroleum engineering. An anisotropic medium has 21 independent elastic constants without any assumption of symmetry. If a material has any symmetry, the number of elastic constants required to define its behavior reduces and eventually two constants are necessary if it has complete symmetry, which is known as isotropy. An anisotropic medium that has remarkable planar structure due to its stratification and foliation such as bedding is often called as a transversely isotropic medium. Transversely isotropic model is frequently adopted in many applications especially for sedimentary rock formation and five elastic constants are required to establish the constitutive model."

Jan 1, 2015

By B. Chareyre, H. Pourpak, L. Scholtès, E. Papachristos

"Numerical methods used to study hydraulic fracturing in low permeability rock masses need to take into account the interaction between the progressive failure mechanism of the intact rock matrix and the pre-existing natural fractures. A fully coupled hydro-mechanical 3D discrete elements model dealing with such interaction is presented here. The ultimate objective is to grasp the role of the rock-matrix failure on the propagation of the main fluid driven fracture under different stress fields and pre-existing fracture orientations. The proposed method provides the spatiotemporal distribution of the induced crack events which can be tracked during the simulations, making possible the identification of the local mechanisms leading to macro-failure in the rock matrix or reactivation of the discontinuity planes. Fluid flow inside a fracture, pressurized crack and hydro-fracking experimental tests were simulated as part of the validation process of the model and, are presented in this paper.INTRODUCTIONWith the expansion of shale gas and geothermal reservoirs exploitation, the technique of Hydraulic Fracturing (HF) has been widely used over the past years (McClure, 2012; Britt, 2012). Despite recent advances in micro-seismicity analysis or numerical modeling (Nagel et al., 2013), the way progressive failure of rocks affects the fluid flow depending on the in situ stress conditions or the rock heterogeneities is not fully controlled yet (Zoback, 2010).In this work we focused on setting up a three-dimensional discrete elements model to study fluid driven fractures propagation. The intact rock is modeled by a discrete element method (DEM) able to reproduce fracture initiation and propagation (Scholtès and Donzé, 2013, Garcia et al., 2013). The pre-existing fractures are explicitly modeled and can be individually defined or be part of a discrete fracture network (DFN) (Harthong et al., 2012). Their mechanical response is fully coupled with the fluid within a HM-DEM framework. The fluid flow and it’s interaction with the intact matrix and the pre-existing discontinuities is modeled through a Pore-scale Finite Volume (PFV) scheme specially enhanced for fractured rock modeling (Chareyre et al., 2012, Catalano et al., 2014) ."

Jan 1, 2015

By Y. W. Pan, Y. R. Liu

The disturbed natural rock mass tends to equilibrium state accompanying with non-equilibrium evolution process which has significant influence on the long-term stability of engineering structure. The deformation development in the non-equilibrium evolution is determined by two intrinsic processes, trend to equilibrium and damage development, which can be illustrated by evolution of excavated tunnel. Thus the creep and damage must be taken into account in study of non-equilibrium evolution process. Within Rice’s irreversible thermodynamics with internal state variable (ISV), the conjugate force function which equals to zero is a convex surface which divide the stress space into two parts, called equilibrium and nonequilibrium stress space respectively. The concept of effective stress of non-equilibrium has been proposed, in which the stress difference (d - d ) are the effective driving forces of non-equilibrium evolution process with hardening and damage effective. The formulations of inelastic strain rate and energy dissipation rate have been recast in the form of effective stresses. The inelastic complementary energy (ICE) is proposed to measure intensity of non-equilibrium evolution of material system. The specific equations of conjugated forces and kinetic equations of internal state variables are presented. The ICE and rate of energy dissipation are all calculated to be used to evaluate long-term stability of geo-engineering. The results show that rate of energy dissipation may be more convenience and flexible than ICE for internal state variable constitutive equation of rock mass.

Jan 1, 2015

By J. Q. Chen

The elastic-plastic behavior and the fracture mechanisms of two 2198 Al-Cu-Li thin sheets are investigated. The first material (2 mm thick) is in a recrystallized state after cold rolling. The second material (6 mm thick) is hot rolled and has a fibrous grain structure. The two materials are studied in both T351 and T851 conditions. Tensile tests are carried out along different sheet directions using flat and notched specimens. Fracture resistance was characterized using Kahn tear specimens and M(T) panels. Macroscopic fracture surface of smooth tensile specimens depends not only on testing material but also on the loading direction. For Kahn tear specimens, fracture is initiated in a small flat triangle whereas slant fracture is observed during crack propagation. Fracture mechanisms were investigated using scanning electron microscopy (SEM) and X-ray 3D tomography.

Jan 1, 2011

By S. Feinstein, I. Reznik, Y. H. Hatzor, O. Shitrit, Y. O. Rosenberg, H. J. Vinegar, S. Nguyen

"We report the effects of porosity and total organic carbon (TOC) content on the mechanical behavior of organic-rich chalks, based on laboratory measurements. The organic-rich chalks are from the Senonian Ghareb and Mishash formations. This deposit is an immature oil-prone source rock, about 300 meters thick, situated at shallow depths (several hundreds of meters) in the Shefela basin in central Israel. The study is based on core data collected from the Zoharim borehole.Three main phases comprise the bulk volume of this rock: 1) carbonate mineralogical phase (predominantly calcite); 2) pores (mostly saturated with brine); and 3) solid organic phase (type IIS kerogen). The mechanical effects of porosity (23-45%) and TOC (4-19%) are evaluated based on bulk incompressibilities vs. volumetric fractions analysis. Volumetric fractions of mineralogical and organic phases were obtained by porosity, density and TOC measurements. Saturated rock bulk moduli were measured through ultrasonic velocity measurements. Saturated rock bulk moduli correlate best with the sum of kerogen and pore volume fractions, rather than each of them separately. The volumetric fractions were also used to define the range of bulk modulus of the organic-rich chalk, using the Hashin-Shtrikman upper and lower bounds. Based on Marion's Bounding Average Method (BAM), the normalized stiffness factor of the chalk averaged at w=0.197, indicating a soft pore geometry. Using the average normalized stiffness factor, the BAM predictions showed excellent match with the saturated rock bulk modulus and the sum of kerogen and pore volume fractions. Based on our findings, it is inferred that kerogen grains do not support the solid skeleton but are distributed between the minerals grains. We also propose here a straightforward approach for calculating the Hashin-Shtrikman bounds, based on TOC and porosity measurements. The mechanical effects of porosity and TOC indicated here are very important for the understanding of the influence of immature kerogen presence in highly porous chalks, as the Ghareb and Mishash formations."

Jan 1, 2015

By Y. Wang

In this study, homogeneous (unseeded) precipitation of nesquehonite (MgCO3.3H20) by the reaction of MgC12 with (NH4)2CO3 in supersaturated solutions at 30 °C was investigated. Factors which influence the precipitation of MgCO3.3H20, such as initial concentration, temperature, stirring speed, titration speed, equilibration time, have been studied. SEM images show that the initial concentration and titration speed have significant effect on nesquehonite's crystal morphology and particle size. In addition, stirring speed and equilibration time also have some influence on its properties. With the optimization of operating conditions, the crystals can grow up to a length of about 40µm and a width of 5µm, indicating good filtration properties. High purity nesquehonite obtained in this study was calcined to produce highly pure MgO at 800 °C as shown by XRD results. The novel process may be used to separate Mg and Li from high Mg/Li ratio brines in Qinghai, China.

Jan 1, 2007

By Jeffrey D. Oke

While significant progress in underground construction engineering has occurred in the past few decades, a number of fundamental deficiencies persist regarding the recognition, prediction, and mitigation of underground construction hazards associated with complex geological conditions in rock and soil works, such as tunnelling. Many of these shortcomings could be addressed by improving geomechanical models which, in turn, would provide more realistic frameworks for determining input parameters for design analysis. This would improve predictions of construction efficiency for tunnelling and the formulation of more accurate modelling techniques (2D, 3D and 4D) required to optimize the design of engineered rock structures. This research focuses primarily on the issues related to forepole temporary tunnel support within weak rock masses. This research attempts to determine how best to numerically model forepole support. The behaviour and mechanics of forepole support has not been quantified and/or optimized. As well, there is a lack of in-situ and/or laboratory forepole and weak rockmass interaction parameters available. In terms of numerical modelling, there is a lack of understanding of the use of proper interaction parameters associated with the forepole and the rockmass. The parametric study that has been conducted by the authors demonstrates the influence of each of the forepole-rockmass interaction parameters and their sensitivity. Introduction

Jun 1, 2012

By C. Peña, C. A. Zaror, M. Bustamante, M. Vega

The goal of this paper is to present the carbon footprint of Chilean cathodic copper, as a function of the electricity generation mix, ore grade, and process efficiency. Ore grades and acid leach-solvent extraction-electrowinning (LX-SX-EW) yields in the range 0.5-1.0% and 60-80%, respectively, were considered here. Additionally, electricity supply from two Chilean suppliers, SING (1.0 ton CO2/MWh) and SIC (0.4 ton CO2/MWh) was assessed. Simulation results show that oxide plants located in northern Chile, served by the SING network, feature carbon footprint within 4.3 - 11.4 MWh I ton cathodic copper, as compared with 3.5 - 9.3 MWh I ton copper in plants served by SIC. The footprint was found to increase as ore wade and process yields decrease.

Jan 1, 2011

M INE production requires the coordination of the talents of men and the use of equipment. Mine operators maintain a continual surveillance of equipment, looking for improvements and modifications that will benefit them. Few give similar attention to the advances made in the education of mining engineers since they themselves graduated. That is not surprising. Education lacks the advertising budget available to manufacturers. A modification to improve a mechanical contrivance is advertised, and an advertiser's press releases get attention by publishers. The whole program for mining engineering education could be revolutionized and no one, except a few professors, would know about it. The Canadian Institute of Mining and Metallurgy's newly established General Commit-tee on Education can improve that situation. Nine groups of engineers in Canadian universities are trying to give undergraduates an education that will make them useful to the mineral industry as mining engineers. The tabulation offered here (Table I) is an analysis of the distribution of the undergraduate-teacher contact time.

Jan 1, 1963