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By René Lefebvre

Numerical simulations of the physicochemical processes related to acid rock drainage (ARD) in the Sugar Shack South rock pile of the Questa Mine were performed with the TOUGH AMD simulator. The objectives were to 1) identify the main processes responsible for observed present-day conditions, 2) provide an estimate of gas phase humidity transfer, and 3) give a preliminary indication of the potential impact of closure involving the installation of an alluvial soil cover. Modeling results indicated that the mine rock geometry (thin layers placed along steep mountain slopes) favors the onset of strong thermal air convection. Simulations also indicate that resloping the piles would not significantly reduce convection and oxidation. For simulation purposes, a potential cover with the permeability range of a local alluvium was investigated and found to be of questionable effectiveness since its permeability can exceed the value of 3x10-13 m2 required to prevent thermal air convection and reduce ARD.

Nov 1, 2002

By P. P. Andrieux

The recovery of the Zone G crown pillar, located between the bottom of the open pit and the top of the underground workings at the Raglan Katinniq Mine in Nunavik, started in the summer of 2008 and should be completed by the end of 2009. This article describes the rock mechanics-based approach implemented to design the recovery of this valuable block of ore. The stereophotography-based ShapeMetriX3D technique was first used to provide a comprehensive assessment of the various joint sets that comprised the pillar. Then, the statistical distributions obtained for the dip, dip direction, spacing and persistence of these sets were used in conjunction with the geometry of the large-scale faults present in the area to build and run a series of explicit rigid numerical models. Each of these models had a slightly different jointing geometry, randomly constructed from these statistical distributions. Incorporating in a properly formulated numerical model the variability of some of the input parameters has allowed the engineering team to assess in a rational and reliable manner the likelihood of success of the proposed mining method and sequence.

May 1, 2009

By Michel Rodrigue, Sylvain Duchesne, Louis Racine

"LocationThe Louvicourt mine is located 20 km east of Val d'Or in Abitibi, in the northwest part of the province of Quebec. The mine is located on Highway 117 connecting Val d'Or to Montreal and very close to the main railway networkHistoryFive successive exploration attempts by Aur Resources resulted in the discovery of the large Louvicourt orebody in June 1989. Construction of the surface and underground infrastructures commenced in the spring of 1991. Milling operations commenced in July 1994. The entire project cost CDN$290 million, almost CDN$20 million less than initially estimated. The concentrator infrastructure cost CDN$64 million.Louvicourt mine is owned in partnership by Novicourt Inc. (45%), Teck Corporation (25%), and Aur Resources Inc., the administrator (30%).Brief DescriptionLouvicourt mine is the largest producer of base metals (Cu and Zn) in Abitibi-Temiscamingue. Its average daily production is nearly 4300 t of ore, for an annual production of 200 000 t of copper concentrate (28% Cu) and 33 000 t of zinc concentrate (57% Zn). After only a few weeks of operation, it had attained its objectives for the most part, and operations continue to be improved."

Jan 1, 2000

By Jörg Fischer-Bühner

Conventional 22ct Au jewellery alloys are comparably soft in the as-cast and soft-annealed state and hardening by cold-working is the only way of giving strength to the jewellery. The paper first focuses on hardening of 22ct jewellery alloys by conventional means, i.e. solid solution hardening with base metals (aiming particularly at an increased as-cast hardness) as well as precipitation hardening by alloying with base metals beyond the solubility limits and subsequent age-hardening heat treatment. Co-additions of ~2% turned out to result in most pronounced solid solution hardening up to ~100 HV1 in an investment cast & quenched state. Subsequent heat treatments, consisting of solution annealing at 850°C for 1h followed by water quenching and ageing at 300°C ? 400°C for ~ 1h lead to pronounced age-hardening with a peak hardness of ~ 260 HV1. In contrast, 22ct Au alloyed with Ni, Fe or Sb display no age-hardening effect within the same range of heat treatment parameters. The 2nd part of the paper reports on some preliminary trials to enhance the hardening effect of the base metals by additions of suitable elements, which possess a strong tendency to phase formation with the added base metal during ageing treatments. It is shown, that the age-hardening behavior of 22ct and 990/995 Au alloyed with Co or Ni can be remarkably influenced by additions of Sb. A total of only 10wt%0 of CoSb or NiSb-additions lead to a peak hardness of ~ 150 HV1 for a 22ct Au and ~ 100-120 HV1 for 990 Au , which is obtained already after very short ageing times (20-40min) at 300-400°C after solution annealing at 700°C / 1h / water quenching. It is suggested that the age-hardening mechanism in these alloys consists in precipitation of intermetallic CoSb- and NiSb-phases.

Oct 1, 2003

By P. J. Mehrfert

"Recovery of mineralized coarse particles is notoriously low in conventional concentrators that treat copper porphyry ores. The application of coarse particle flotation techniques has the potential to achieve comparable metallurgical performance at significantly coarser primary grind sizings. ALS Metallurgy has been conducting both internal research and commercial test programs to investigate the potential of Eriez HydroFloatTM technology on copper sulphide ores. Test data indicates that significant improvements in the recovery of copper sulphide bearing particles between 200µm to 850µm can be achieved using Hydrofloat technology compared to conventional flotation techniques. This paper summarizes the results from a selection of test programs that includes recovery by size data from both conventional flotation and HydroFloatTM tests. An explanation of the apparatus and test procedure will be given. Mineralogical analyses of the test products and characteristics that limit metallurgical performance will be discussed.Description of Apparatus and Test ProtocolThe HydroFloatTM laboratory cell is a clear plastic column with an internal diameter of 14 cm. Water and air are introduced to the cell through a circular manifold located in the lower portion of the cell. The cell has a conical bottom which directs slurry to a pinch valve that controls the discharge of tailings. Feed solids are introduced to the upper portion of the cell in slurry form. The cell is operated in a manner such that the manifold water creates a teeter bed zone of suspended solids in the middle portion of the cell. Tailings exit the bottom of the cell at a high pulp density, and most of the introduced water overflows the top of the column and is collected in a launder. Particles with a hydrophobic surface may attach to air bubbles that percolate through the teeter bed, rendering them sufficiently buoyant to be transported to the overflow launder.Three significant features of this arrangement enhance the potential to recover coarse, low grade particles by flotation techniques. Firstly, the hindered settling conditions created by the rising column of water allow coarse particles to become buoyant once attached to a modest sized air bubble. Secondly, the flow conditions within the cell are relatively quiescent compared to a conventional flotation cell that utilizes an agitator. This allows particles that have limited hydrophobic portions of their surface, due to a low content of exposed sulphide mineral, to maintain a somewhat fragile attachment to air bubbles long enough for successful recovery to the overflow. Finally, the absence of a froth phase at the top of the cell allows particles attached to air bubbles to immediately exit the vessel, reducing the potential to drop back into the pulp phase as bubbles burst or coalesce."

Jan 1, 2017

By M. Maldonado, J. A. Finch

"A flotation bank consists of a serial arrangement of cells. How to optimally operate a bank remains a challenge. This article reviews three strategies for optimizing bank performance: air profiling, mass-pull (froth velocity) profiling and Peak Air Recovery (PAR) profiling. These are all ways of manipulating the recovery profile down a bank, which may be the property being exploited. Mathematical analysis has shown that a flat cell-by-cell recovery profile maximizes the separation of two floatable minerals for a given target bank recovery when the relative floatability is constant down the bank. Available bank survey data is analyzed in respect to recovery profiling. Possible variations on recovery profile to minimize entrainment are discussed.INTRODUCTION Flotation is used to separate valuable minerals from each other and from gangue. To reach a target metallurgical performance, usually assessed in terms of concentrate grade and recovery, feed is passed through stages such as roughing, cleaning and scavenging. All these stages comprise serial arrangements of flotation cells known as banks, lines or rows. Although a bank is the simplest interconnection of cells in a circuit, i.e. the tails of one cell is the feed to the next cell down the bank, how to operate each flotation cell in a way that the whole bank performance is optimized remains a challenge. Significant efforts have been made towards understanding the effect of operating variables on the flotation performance of an isolated cell (Lynch et al., 1981; Finch and Dobby, 1990; Gorain et al., 1998). However in the case of banks the variables that can be manipulated increase with the number of cells in the bank and the problem of how to manipulate them to achieve optimum performance is difficult even disregarding variation in ore characteristics (Lynch et al., 1981, p. 16). In general, the more manipulated variables available the better for optimization purposes, however without clear guidance how to effectively use them it becomes an “embarrassment of riches”."

Jan 1, 2012

By A. Esterhuizen, S. Essack, H. Joubert, N. Fowler

Tenova Pyromet has developed innovative technologies for copper smelting and electric slag cleaning furnaces. Based on client feedback and requirements, innovative designs have been developed to address key design areas and improve furnace reliability, operability and hygiene. These developments include the NovaLance™ lance system to prevent lance bending on top submerged lance furnaces, the SlagFlo™ slag tapping flow control device to better control bath levels and tapping rate for granulation, and an electrode seal for improved sealing directly onto the electrode casing to allow water-cooled electrode components to be located above the furnace roof. The potential application and benefits of these innovative designs are discussed. INTRODUCTION Tenova Pyromet has a long history in the engineering and supply of innovative electric furnace and related equipment for the base metals and platinum industries. Recently Tenova Pyromet has used its furnace equipment design experience to engineer innovative solutions for top submerged lance (TSL) furnaces, and potentially other furnace technologies. These equipment design solutions are developed to address specific operating challenges and operator requirements. Three of these innovative equipment developments are discussed in this paper. First the NovaLance™ lance technology to prevent lance bending during operation in TSL furnaces, such as used for primary copper smelting, is described. Lance bending has been identified as a significant problem for TSL furnace operators as it causes down time and affects furnace availability. The SlagFlo™ device to control the slag flow rate during tapping has been developed based on specific requirements in the mineral wool industry. The SlagFlo™ device can be used to control slag bath levels in primary smelting, converting and slag cleaning furnaces for base metals including copper. In addition, it can be remotely activated for the safe closing of slag tapholes located upstream from a water granulation system. Finally, Tenova Pyromet developed an electrode seal that seals directly onto an electrode surface. This is a special requirement related to base metals and platinum electric smelting and slag cleaning furnaces where furnace operators prefer to keep the water-cooled electrode equipment above the furnace roof. The seal can be used to seal directly onto the potentially hot and uneven surface of Söderberg, pre-baked and graphite electrodes.

Jan 1, 2019

By A. T. Robles, L. Buckingham

"When certain gold ores containing pyrite, graphite, humates and fumates or other organic compounds which are possibly adsorbed on clay minerals are treated with aqueous solution of alkali metal cyanide, the aurocyanide complex which forms is adsorbed by these ""pregrobbing"" species in the ore. Dissolution of gold proceeds until chemical equilibrium is attained between the cyanide complex adsorbed by the ore and in solution.Sodium lauryl sulfate (SLS) may be used to decrease the adsorptive activity of the prerobbing species in the ore. It has successfully improved recovery at Holt-McDermott Mine and is highly biodegradable.INTRODUCTION Precious metal-bearing ores containing preg-robbing species are poorly amenable to standard cyanidation techniques. The ""preg-robbing"" impurities with which they are associated tend to adsorb the gold cyanide complexes and carry them through the circuit to the tailings. Also, gold may be associated with these impurities in the ore and not be leached by the cyanide complexing agents used in conventional cyanidation techniques.Methods for dealing with the problem of preg-robbinq impurities in gold ores are:Carbon-in-Leach (CIL), in which granular activated carbon is added to compete with preg-robbing species for the gold cyanide complexes. This process can improve gold recovery in mildly preg-robbing ores especially when fine carbons with very high activities are used. However, with severely graphitic ore, the carbon associated with the rock may outperform the granular activated charcoal.Chemical Oxidation, in which the ore is subjected to preliminary chemical oxidation techniques to oxidize carbonaceous materials using such diverse reagents including ozone, sodium hypochlorite, calcium hypochlorite, chlorine gas, permanganates, perchlorates, chlorates and oxygen prior to subjecting the oxidized ore to standard cyanidation treatment to extract gold. This is generally a costly method and will not prove economical on a low-grade ore."

Jan 1, 1992

By C. Schuffeneger

"The design of SAG milling circuits for mining projects requires the incorporation of the energy consumption considerations and the evaluation between different flexibility-adding options to absorb the time-dependent variation in the ore lithology. In order to expand the focus of the engineering design, a higher level of deepness and quality in the baseline information must be achieved to elucidate all of the constraints on throughput, energy consumption and product quality generating a design optimization consistent with an integrated vision of the process. This paper presents a review of a collection of typical examples of the copper and gold mining project in the Chilean Andes, in which both process and energy efficiency criteria are considered when the focus is to deliver an integral solution that incorporate those areas in the design. The intensive use of energy in the SAG milling, the process continuity and the quality of the product are a function of the proper design and selection of grinding equipment and plant layout, aligned with the mining plan and associated with projected future expansions and production increases.INTRODUCTION Autogenous and Semiautogenous grinding technology, large diameter and short length mills, begins with the Handsel design. During the decade of 1930’s, Handsel-Hardinge studies led to cascade mill development. Nowadays, 80 years later, continuous improvements in design and technology have been conducted to a completely new generation of gearless SAG mills that have led to an increasing capacity at the concentrator plants. Considering the existing alternatives, SAG mills are the most implemented option for the grinding circuit today. This work presents a review of the SAG mill implementation parameters and circuit considerations and its correlations in the most recent projects in Chile with an ore treatment capacity above 50 ktpd since the decade of the 90’s up to now. From this period, the tendencies will be analyzed using project design data. Based on process design information, the recent SAG mill history in relevant projects related to the new generation of commercial SAG mills, technical associated considerations and performance will be discussed. Circuit selection based on energy utilization will be revised to bring up a more holistic perspective on the SAG mill circuit design concepts. As is now well known, the heart of every concentrator plant are the grinding mills. Higher demands on throughput, availability and power consumption optimizations require not only high performance electrical equipment but also a well selected grinding circuit. The energy efficiency issues associated to the circuits design will be reviewed."

Jan 1, 2012

By Brian Hart, Hong Zhong, Liuyin Xia, Kyle Douglas

"The application of hydroxamic acid as flotation collectors is fast becoming of significant interest for the selective flotation of oxide minerals along with upgrading oxidised based metal ores and minerals. In the hydroxamate molecule, both O and N atoms in the -CONHOH group are identified as coordination atoms in many complexes and their characteristic structure determines the strength of the chelation complex between the hydroxamate and metal ion. The chelating performance of hydroxamates with transition metals including Cu, Ni, Zn, Fe, Cr, Mn and Co, the alkaline-earth metals (Be, Ca) and heavy metal (Pb) has been studied. Cytec has developed and patented a range of alkyl hydroxamates as flotation collectors for oxidised base metal sulphides, metal oxide minerals and precious metals. This paper introduces two new structures of hydroxamate collectors (Cyclohexyl and 4-tert-butylbenzoyl hydroxamates) and evaluates their characteristics relative to alkyl and benzoyl hydroxamates. Laboratory small-scale flotation tests were conducted with ilmenite and wolframite. The use of 4-tert-butyl benzoyl hydroxamate resulted in a best flotation performance for ilmenite. A relatively low cyclohexyl hydroxamate dosage was required in the flotation of wolframite to obtain comparable results to the alkyl and benzoyl hydroxamates. It is also shown a significantly improved flotation performance with 4-tertbutyl benzoyl hydroxamate in the flotation of ilmenite plant ore in comparison to the oleic acid or fatty acid collectors typically used for ilmenite flotation.INTRODUCTIONHydroxamic acid has been reported as an effective collector in small-scale flotation tests for a wide variety of oxide minerals and ores including copper (Lee et al., 1998, Lee et al., 2009), iron (Quast, 2000), tin (Sreenivas and Padmanabhan, 2002; Wu and Zhu, 2006), tungsten (Marinakis and Kelsall, 1987; Xia et al.,2004), and rare earth metal minerals (Ren et al., 1997; Pradip and Fuerstenau, 1991; Assis et al., 1996; Pavez et al., 1996; Zheng et al., 1996; Chen et al.,2005).As part of our previous research project, a selected suite of hydroxamic acid collectors including fatty, aromatic and modified hydroxamates (naphthoyl, cyclohexyl, benzoyl, octyl, 4-tert-butyl benzoyl, salicylic hydroxamates) were tested in order to examine their potential for recovery and selectivity of rare earth minerals. In these tests it was shown that the flotation performance with the hydroxamate collectors was significantly better than the phosphoric acid collectors on no slimes removed samples (Brian, et al., 2014; Liuyin, et al., 2014 and unpublished internal technical reports). Furthermore the tests revealed that for most of the hydroxamate reagents tested, their dosage requirements to achieve recoveries at the same levels was less than that for the phosphoric acid collectors. Recovery of both La and Ce was significantly better for the salicylic hydroxamate and that Nb, Y and Zr recovery were favoured by the octyl and benzoyl hydroxamates (Brian, et al., 2014; Liuyin, et al., 2014). Comparison among the hydroxamate collectors showed that the flotation and recovery performance of cyclohexyl (CHH) and 4-tert-butyl benzoyl (TBH) was not as good as the other hydroxamates for rare earth recovery."

Jan 1, 2015

By Marc Legault

The Duparquet mining camp situated along the Quebec segment of the Porcupine-Destor Fault was the site of gold exploitation from 1933 to 1956 and 1988 to 1991. Numerous gold showings and deposits straddle the fault. An ongoing regional metallogenic study by the Quebec Geological Survey has identified five main types of gold mineralization, each showing a distinct style, alteration, control, metal content, and timing. In order to maximise the impact of this study, a 3D regional common-earth-model was constructed along a critical segment of the Porcupine-Destor Fault with the gOcad® technology. The realisation of this model required the maximum use of the public SIGEOM numerical database, as well as the recovery of significant private data from exploration company partners. The 3D model is also a powerful new dynamic exploration tool, which can be queried using geological criteria characteristic of the different gold deposit types. This 3D model can be modified and improved continuously by adding data from new drilling, mapping or geophysical surveys. The case of the Porcupine-Destor Fault illustrates the importance of 3D common-earth-modelling in delivering refined technological geological syntheses likely to attract significant investments from the mining exploration industry, especially for deep exploration programs within mature mining camps.

May 1, 2004

By Gary Anderson

??Privately Held Corporation ??Incorporated in Delaware, May of 2002 ??HQ in Malvern, PA (just outside Philly) ??Approx 40 employees ?9 Field Engineers ?MSHA Certified ?10 Development/NOC Engineers ?Site Survey/Site Design ?RF Engineers ??Standards Based ?IEEE 802.11 ??Commercial Off the Shelf (COTS) ?Gateworks, Ubiquity, Atheros, Linux Based ??Technology was developed and inspired by the lack of communications during the terrorist attacks of Sept. 11, 2001

May 1, 2009

By Gavin Ritson, Chris Ward

"The oil sands industry is still fairly young with the first viable oil sand operation having been started in Alberta in 1960. Since then numerous modifications and improvements have been tried and implemented. The current process makes use of high velocity pumping of oil sands slurry with hot water (hydrotransport) to achieve separation of bitumen from the sand.A number of the oil sands processes have been adapted from unit operations that are used in mineral processing, such as crushing, screening, flotation, cycloning and thickening. This paper outlines a typical oil sands process flowsheet and investigates the differences and similarities in technologies and costs to other mineral processing industries. It also considers the very large throughputs required, and presents some of the difficulties and challenges currently faced by the industry as a result of high demand for oil and environmental pressures.INTRODUCTIONOil sands (also known as tar sands) deposits are found throughout the world. The Athabasca Oil Sands deposit in Aberta is the largest of these. Oil sands consist of a mixture of crude bitumen (a semi-solid form of crude oil), silica sand, clay minerals, and water. The Athabasca, Peace River and Cold Lake deposits cover 141,000 square kilometers and contain about 1.7 trillion barrels (270×109 m3) of bitumen in-place, comparable in magnitude to the world's total proven reserves of conventional oil"

Jan 1, 2009

By J. Don Scott

Analytical predictions of the rate and magnitude of settlement of deposited oil sands tailings slurries generally overestimate how fast pore pressures will dissipate. Field deposits of nonsegregating tailings to mature fine tailings show continued high pore pressures near the surface which impede surface reclamation. In geotechnical analyses which predict the consolidation behavior of soft soils a finite strain theory is used. Effective stress-void ratio and void ratio-hydraulic conductivity relationships determined from laboratory large strain consolidation tests, are used in the finite strain predictions. This theory, however, cannot predict the full range of sedimentation, consolidation and pore pressure dissipation which occurs in large scale deposits of thixotropic tailings slurries. A new large strain consolidation model which assumes that the creep rate of the slurry exceeds the pore pressure dissipation rate is being investigated. This model is relevant for rapidly deposited, low permeability thixotropic slurries where the upwards drainage path increases by several meters a year, such as, in oil sand fine tailings ponds and nonsegregating tailings deposits. The model will be verified by analyzing the 10m high column of fine tailings at the University of Alberta which has been monitored for over 20 years and in which the excess pore pressures are still very high.

May 1, 2004

By Jose R. Hernandez-Aguilar

"This paper revisits data from previous studies (Hernandez-Aguilar, 2010, 2011) to better understand the link between metallurgical performance and pulp-zone bubble size (Db) in full-scale flotation systems. To obtain conclusive evidence exclusively related to the pulp (collection) zone, the experiments were designed in those studies to control both the bubble generation method and the influence of the froth zone on the overall metallurgical performance in industrial and pilot-scale flotation columns. The results showed that Db had a significantly larger effect on the recovery of coarse (> 75 µm) particles compared to the effect on fine (< 16 µm) particles. It was observed that, under certain practical conditions, the recovery of coarse particles was close to zero, but dramatically increased by reducing Db. The evidence revealed an inconsistency of the so-called “k–PSb” model: at constant froth recovery, increasing Sb (i.e., the rate of production of bubble surface area) did not always result in higher recovery, as the model predicts. Furthermore, the evidence showed that it was not the Sb but the bubble size that proved to be a more reliable link to metallurgical performance. Only in the presence of suboptimal-sized bubbles (Db > 2 mm) did the froth zone seem to play a role, possibly reflecting an effect of pulp-zone bubble size on froth stability. However, the role of the froth was negligible for Db < 1 mm.High-resolution mineralogical measurements performed on process samples revealed that, regardless of the degree of liberation, Db had a profound effect on the shape of the recovery-by-size curve, particularly the coarse particle size fraction. This observation is key as it implies that the loss in efficiency associated with floating the coarse particles was not the result of neither particle hydrophobicity nor particle detachment issues: even in the absence of mechanical agitation, liberated and highly hydrophobic coarse particles did not seem to attach to the bubbles in the first place, an inefficiency that was corrected by reducing bubble size. The data analysis suggests that poor attachment efficiency can practically affect both fine and coarse particles but via different mechanisms which are discussed here."

Jan 1, 2017

By Dong-kil Lee

Field tests have been conducted to investigate the characteristics of flow and physical chemistry of acid mine drainage(AMD) in the Hwangji-Yuchang settling pond in south Korea. pH and ferrous concentration of AMD flowed in the settling pond is 6.79 and 25.5 mg/l, respectively. As a results, we found that the ferrous oxidation reacted strongly around the inlet of the pond and the distributions of physicochemical properties is depended on flow characteristics and ferrous oxidation rate of AMD.

May 1, 2011

Cobalt mostly occurs as a minor, but valuable, constituent in most nickel and a few copper ores, however it is not generally found alone in commercially viable deposits. Its concentration and extraction are therefore intimately linked to the recovery of the primary metals and the major task for the metallurgist is to extract cobalt of commercial grade from a much larger mass of either nickel or copper and sometimes both. With a particular focus on Vale Inco?s operations, this paper provides a brief overview of the mineralogy of the main deposits being currently exploited that contain cobalt as a co or by-product. The concentration and then extraction to metal are reviewed and some advances released into the public domain are discussed.

May 1, 2009

By M. Abzalov

"Control of analytical data quality is usually referred to in the mining industry as Quality Assurance and Quality Control (QAQC), and involves the monitoring of sample quality and quantification of analytical accuracy and precision. QAQC procedures normally involve using sample duplicates and specially prepared standards whose grade is known. Numerous case studies indicate that reliable control of sample precision is achieved by using approximately 5% to 10% of field duplicates and 3% to 5% of pulp duplicates. These duplicate samples should be prepared and analyzed in the primary laboratory.Bias in the analytical results can be identified by inclusion of 3% to 5% of the standard in each sample batch. Several different standards are used, with values spanning the practical range of grades in the actual samples. A blank (a sample in which the concentration of metal of interest is below detection limit) should also be included. Standard samples alone cannot identify biases introduced during sample preparation, and therefore approximately 5% of the duplicate samples (coarse rejects and pulp) should be processed and assayed at another, external, reputable laboratory.This paper discusses techniques used for estimation of errors in precision and accuracy, and overviews diagnostic tools. It is shown that one of the most commonly used methods, the Thompson-Howarth technique, produces consistently lower results than other methods. These results reflect the nature of this method, which relies on the assumption of a normally distributed error, and thus produces biased results when errors have a skewed distribution. This study concurs with the suggestion of Stanley and Lawie (2007: Exploration and Mining Geology, v. 16, p. 265-274) to use the average coefficient of variation (CVAVR(%)) as the universal measure of relative precision error in mine geology applications: Le contrôle de la qualité des données analytiques est habituellement désigné sous l’appellation d’Assurance et Contrôle de la Qualité (ACQ), elle implique le suivi de la qualité des échan¬tillons et la quantification de la reproductibilité et la précision analytiques. Les procédures des pro¬grammes d’ACQ impliquent habituellement l’usage de duplicata et de standards analytiques dont la teneur est connue. Plusieurs études de cas indiquent qu’une bonne fiabilité du contrôle de la précision des échantillons est atteinte par l’usage de 5% à 10% de doublons sur le terrain et de 3% à 5% de doublons de pulpe. Ces duplicata devraient être préparés et analysés au laboratoire principal.Un biais des résultats analytiques peut être identifié par l’inclusion de 3% à 5% d’échantillons standard dans chaque envoi d’échantillons. Plusieurs standards sont utilisés, avec des valeurs couvrant l’étendue des teneurs habituellement rencontrées dans des échantillons réels. Un blanc (un échantillon dans lequel la concentration d’un métal donné est sous la limite de détection) devrait aussi être inclus. L’emploi exclusif d’échantillons standards ne permet pas l’identification de biais résultant de la préparation des échantillons, de telle sorte qu’environ 5% des duplicata (rejets grossiers et pulpes) devrait être traités a un autre laboratoire indépendant et fiable.Cet article passe en revue les techniques utilisées pour évaluer l’erreur liée à la précision et a la reproductibilité, et effectue aussi un survol de divers outils diagnostiques. Il ressort de cet examen qu’une des techniques les plus fréquemment utilisées, la méthode Thompson-Howarth, fournit des estimés systémati¬quement inférieurs à ceux provenant des autres méthodes. Ces résultats sont un reflet de la nature de cette méthode, laquelle assume une distribution normale de l’erreur, biaisant ainsi les résultats lorsque l’erreur présente une distribution asymétrique. La présente étude recommande de privilégier l’usage du coefficient moyen de variation (CVAVR(%)) en tant que mesure universelle de la précision relative de l’erreu"

Jan 1, 2008

By Weng Fu, James Vaughan, Stefan Lakemond

Uranium bearing copper sulphide flotation concentrates produced from iron oxide copper gold uranium (IOCG–U) ore contains radionuclides such as 238U, 230Th, 210Pb, 226Ra, 210Po, which have the potential to reduce their marketability, thus posing a challenge to the industry. Thus, a two–stage leach process has been proposed in this study. In first stage, a sulphuric acid leach process effectively dissolve most of the 238U and 230Th into solution, but other radionulclides (mainly 210Pb, 226Ra and 210Po) remain associated with copper sulphide minerals owing to their low solubilities in sulphuric acid solution. In the second leaching stage, the use of methanesulfonic acid (MSA, CH3SO3H) is investigated to selectively dissolve the 210Pb, 226Ra and 210Po from the residue of the first stage. The results indicate that 96% of 238U, 87% of 230Th, 90% of 210Pb, 86% of 226Ra and 17% of 210Po are dissolved using 3 mol/L MSA solution at 90°C for 3 hours, which represents a dramatic decrease in the radioactivity of the copper concentrate. INTRODUCTION Australia is host to one of the largest iron oxide copper–gold–uranium (IOCG–U) deposits in the world. Most of the value in these deposits is associated with copper. In mineral processing, the gangue minerals are separated from copper sulphide minerals that report to a copper flotation concentrate. However, due to the strong association of uranium with copper minerals and hematite, even clean copper concentrates can contain significant amounts of uranium (238U) and its radioactive decay elements, of which thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) are the long life radionuclides. These hazardous radionuclides negatively affect the marketability of the copper concentrates. Customer copper smelters in China, Japan and Europe may consider the radionuclides penalty elements or may not be able to process the feed. Therefore, there is a strong motivation to remove radionuclides from copper concentrates at the mine site before shipping to custom smelters in global market. Hydrometallurgical leaching has been widely employed to remove radionuclides from different kinds of minerals such as copper concentrates (Ragozzini & Sparrow, 1987), zircon concentrates (Aral, Sparrow, McDonald, & Norgate, 2007), and coal ash (Lei, Qi, Sun, Xu, & Wang, 2014). Leaching using sulphuric acid (H2SO4) solutions is the most widely used process for the extraction of uranium from uranium ores due to the relatively low cost and wide availability of the acid (Bhargava et al., 2015; Gilligan & Nikoloski, 2015). The leach process involves treating ground ore slurry with sulphuric acid at elevated temperatures (typically 60–90 °C) under oxidising conditions in order to convert the uranium in the minerals 2+ from the relatively insoluble tetravalent form (UO2) into water–soluble hexavalent state (UO2), which then complexes with SO42- and forms UO2(SO4)22- in solution. The uranium oxidation is generally carried out in the presence of ferric ion (Fe3+), regardless of the reagent and oxidant used. The most commonly used oxidants for uranium include sodium chlorate, pyrolusite and oxygen (Ring, 1980). These oxidants act indirectly by converting ferrous sulphate, formed by the oxidation reaction of UO2 in slurries, into ferric sulphate. The presence of Fe–containing gangue minerals such as hematite in the ore usually provides sufficient Fe required for the oxidation of UO2. After sulphuric acid leaching, the locked thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) elements are chemically liberated from hematite and uranium mineral grains (Ciobanu, Wade, Cook, Schmidt Mumm, & Giles, 2013). However, the extraction rate of radium (226Ra), lead (210Pb), and polonium (210Po) in sulphate solution is very low due to the limited solubilities of (Ra, Pb, Po)SO4 (Bagnall & Freeman, 1956; Liu & Papangelakis, 2006; Nikitin & Tolmachev, 1933).

Jan 1, 2019

By Michael B. Cortie

Mesoporous gold sponge has the unique property of being both metallic and highly resistant to oxidation. It has potential application in catalysis, in bio-sensors, in optical coatings, in analytical chemistry and, as we show here, as the basis for a new kind of ultra-capacitor. Due to the cost of gold, the most probable niche for a gold-based ultra-capacitor would be in the high-power/high-energy regime, a region where gold would compete with devices based on RuO2. A high internal resistance limits the power that can be usefully drawn from existing carbon-based ultra-capacitors, and that this problem can potentially be overcome by gold-based devices. A simple proof-of-concept ultra-capacitor based on mesoporous gold is described and its behaviour during charge and discharge cycles examined. In this work a step change in the input or output voltage of the device was used as the controlling parameter. There was also a residual faradaic current resulting from traces of undissolved aluminium left over from the AuAl2 precursor used to make the sponge, and some charge storage due to polarization of the solution. Deconvolution of these three effects was not entirely accomplished, but an ostensible capacitance of about 7 to 14 mF/g Au was demonstrated. Further improvement from these early results seems likely.

Oct 1, 2003