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By van der Meer. F. P.

High Pressure Grinding Roll (?HPGR?) technology is applied in a broadening range of minerals processing applications for relatively wet or moist materials. HPGR grinding of dry material or involving drying and air classification is more common, for example in cement manufacturing. A number of minerals processing plants are also operating with dry material, either due to process reasons, such as considerations of preceding or subsequent process stages, or as dictated by local conditions of arid areas and scarcity of water. The present world-wide expectation of decreasing availability of water supply urges us to look for alternatives that minimize water consumption. Recently established and envisaged future HPGR applications with dry ores have indicated that the technology of dry crushing and classification as practiced in cement and limestone grinding can be applied in minerals processing. Moreover, dry technology could very well be applied for generating a final fine product at sizes near or below 100 microns, as may be required for beneficiation by, for instance, flotation, magnetic separation or tank leaching. Dry HPGR grinding requires special attention in maintaining suitable process economics, when considering power input in grinding, drying and classification. In some cases, HPGR capacity and roll surface wear life may be negatively affected by a lack of moisture in the feed. This publication summarizes some of the features of, and experiences in dry HPGR applications. This includes design aspects of the classification system and discussion of the wear protection of the roll surfaces. The paper also includes examples of operational experiences of dry practices in minerals processing and cement plants.

Jan 1, 2012

By T. Krumins, F. C. Ruff, M. Eichhorn, L. Zunti

Hatch Ltd. has recently completed a project to increase refractory gold ore processing capacity at Newmont Mining Corporation’s Twin Creeks facility. The objective of the project was to increase throughput by approximately 10% by adding a third autoclave feed pump to each of the two autoclave circuits. To minimize project capital cost, autoclave feed pumps from Newmont’s decommissioned Lone Tree facility were evaluated and found to be suitable for this new service. The existing pressure oxidation circuit was reviewed in a debottlenecking study to determine other upgrades required to facilitate the increased throughput. Interruption to operations was minimized with a detailed construction plan, supplemented with detailed 3D layout model sequencing studies. The focus of this paper is project development, multi-discipline design considerations, and implementation results.

Jan 1, 2014

By A. A. Iranzadeh

The performance of a tunnel boring machine (TBM) depends on the efficiency of the cutters, which can be influenced by geological conditions and rock mass properties. In this study, a three-dimensional numerical model, based on a discrete element method, was used to evaluate the effects of joint orientation and its spacing on the fragmentation process by a TBM cutter. Several models were constructed to study the effects of variable orientation; these models incorporated different spacing, variable spacing, different orientations on the fragmentation process, and different sections of the block model. Three parameters, consisting of induced tensile stress, induced shear stress and maximum displacement, were calculated. The stress in each section that forms chips was considered as critical stress; critical joint spacing and orientation in each section were determined. Results show that the critical orientation was in the range of 45 to 60º, where there was a possibility to achieve the maximum penetration rate. The critical joint spacing was 200 mm and, by increasing joint spacing, the value of critical stress decreased significantly. Furthermore, joint orientation could influence more than joint spacing in the rock cutting process.

Jan 1, 2009

By R. A. Crouse

The Tanco pegmatite at Bernie Lake, in the Lac du Bonnet mining district of southeastern Manitoba, is a unique deposit of Li, Rb, Cs and Ta, with substantial reserves of Be and several industrial minerals. This paper summarizes the present state of understanding the regional geology, structural setting, zoning, mineralogy and geochemistry of the pegmatite, and the mining and ore-processing methods used in its exploitation.

Jan 1, 1979

By J. S. Stewart

THE Mackenzie River Valley proper extends from Great Slave lake to the Arctic ocean (see map, Figure 1). From Fort Providence, near Great Slave lake, to Aklavik, near the Arctic coast, the distance by river is 1,000 miles. This will give some idea of the extent of the region. Throughout the length of the river valley, the Precambrian complex rocks are overlain by unaltered sedimentary rocks several thousand feet in thickness. These sediments are dominantly marine and Palaeozoic in age. In places, the Palaeozoic strata are overlain unconformable by Cretaceous an Tertiary sediments. The strata have been folded and, in general, the inclination of the beds to the horizontal is comparatively gentle. Here, then, we have the essentials for potential oil fields covering an area over 1,000 miles in length. This is probably the largest comparatively unexplored potential petroleum region in North America, and surface evidences of oil in the form of seepages occur in several places. Many of these seeps were known to the early explorers, and the first Geological Survey report on the Mackenzie River region, containing the results of field work carried out by R. G. McConnell in 1887-88, noted the petroliferous character of the Devonian strata and the indications of petroleum(l). This region is, however, handicapped by distance from markets and sources of supply of materials; by lack of modern transport facilities; by short season for river transport, and mountainous country separating the valley from the Pacific seaboard; and by the long winter season with weather that makes outdoor work difficult. These factors have tended to discourage the enthusiasm of would-be promoters, and so development in this region has been slow In 1920, a test well drilled about fifty miles northwest of Fort Norman discovered oil in commercial quantity, and three additional wells proved a small area to be productive.

Jan 1, 1944

By John B. Phillips

The mine is entered by a central vertical shaft, strongly timbered, and containing two compartments-one for the passenger cage, the other for the large skips bringing the ore to the surface. A man-way, for emergencies, is also provided, parallel to the shaft. The cage is a single-deck steel box, carrying about thirty persons; by means of arrangements above and below, it can also hoist and lower materials needed in the workings. Levels are run at intervals of 100 feet. In special cases, where the ore conditions warrant, sub-levels are operated, such as those at 1,113 feet and 1,123 feet (Fig. 7), which are connected by winzes with the 11 th level. One of these was pushed for 40 feet, and then abandoned because it was unprofitable to take up ore of the grade encountered. The ore between levels is removed by stoping. The drifts follow the course of the veins as much as possible, with numerous cross-cuts. Winzes, raises, connections, etc., are blasted out where needed. The main drifts are at least 8 ft. high by about 9 ft. wide. All former narrow drifts had to be widened some time ago, by ruling of the Ontario Department of Mines, to lessen the danger of accidents with cars in the small passages. Accurate plans of the under-ground workings are kept in the office, and extensive surveying is always being done underground to keep the maps up to date, measure the cubical contents of stopes, and so forth. Timber is extensively used in the construction of supports and chutes, and in the sinking of the shaft. Steel and concrete are too ex pensive to compete with timber, which 1s abundant in such sections as have escaped forest tires.

Jan 1, 1926

By W C. Shakespeare

The Ontario Committee on Taxation is making a comprehensive study of taxation in the Province of Ontario, and in this connection has received representations concerning mining taxation from a number of interested parties. Some of the more important recommendations on mining taxation are reviewed in this article. Introduction FOLLOWING the appointment of the Federal Royal Commission on Taxation, the Ontario Government, effective in November, 1962, appointed the Ontario Committee on Taxation to review taxes and revenues available to the Province of Ontario and its local governments, to co-operate with the Royal Commission on Taxation and with any other bodies of enquiry appointed by other provincial governments, and to make such recommendations as it sees fit to the Prime Minister of Ontario and the Executive Council. The members of the Committee are: MR. L. J. SMITH, F.C.A., Toronto, (Chairman) MR. ERIC HARDY, Toronto DR. R. CRAIG MCIVOR, F.R.S.C., Hamilton MR. CARL A. POLLOCK, Kitchener MR. R. BREDIN STAPELLS, Q.C., and Toronto. Like its Federal counterpart, the Royal Commission on Taxation, the Ontario Committee has held public hearings, has received written

Jan 1, 1965

By G. J. Biefer

"Fatigue and corrosion fatigue measurements were carried out on five commercially available metals -four steels and an aluminum alloy -which are used as structural materials in mine shaft conveyances. In the corrosion fatigue measurements, drain waters collected in the shafts of three different Canadian mines were used as corrodents. The mine waters had been selected on the basis of their relatively large differences in acidity and/ or composition.It was found that the corrosion fatigue strengths of the four steels were similar, despite their differences in tensile properties, and that the type of water used in the tests had little effect on the results. Mild steel showed the highest and most consistent values of the damage ratio (ratio between the corrosion fatigue and the plain fatigue strengths at 107 cycles). The corrosion fatigue behaviour of the aluminum alloy (ASTM Type 6061-T6) was found to differ markedly in the three mine waters. A high damage ratio (i.e., superior performance) was shown in a mine water in which the corrosion attack was uniform; much lower damage ratios were shown in waters which produced localized corrosion attack. Corrosion rates were too low to be deter-mined conveniently by conventional weight-loss methods, but calculations from polarization curves provided a rapid demonstration that corrosion rates were distinctly lower in the mine water which produced high damage ratios."

Jan 1, 1967

By M. Abumiya, N. Onodera

"The synthesis of large scorodite particles in non-ferrous metallurgical industries usually requires a high-cost operation involving heating and high-pressure autoclaving. To overcome these obstacles, an atmospheric-pressure process for scorodite synthesis (DMSP®) was developed, in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. This process gives scorodite of good crystallinity with particle sizes as large as 15-20 µm. The solutions used for scorodite synthesis in the DMSP® are prepared from various residues containing arsenic from non-ferrous smelters. The solutions may be contaminated with Cu, Sb, and Bi, for example, and therefore the effects of such impurities on the formation of crystalline scorodite need to be investigated. In this study, the effects of Cu, Sb, and Bi contaminants on the formation behaviors of scorodite particles in the DMSP® were investigated systematically.INTRODUCTIONThe synthesis of crystalline scorodite (FeAsO4·2H2O) is a suitable method for arsenic (As) stabilization and storage of As-containing by-products such as flue gas dusts in non-ferrous smelters. It is expected that the formation of large, highly-crystalline scorodite particles would be an ideal method for avoiding the release of arsenic to the environment. Generally, autoclave methods under pressurized oxidation conditions at temperatures above 100°C have been used for the formation of arsenic minerals such as scorodite. However, the autoclave method requires sealed vessels that are resistant to high pressure, heat and acids. This process is also unfavorable on account of the high construction expenses, and high running costs as a result of vapor heat loss. Processes for synthesizing scorodite under atmospheric conditions at temperatures below 100°C which do not need an autoclave have therefore been extensively investigated (Demopoulos, Droppert, & VanWeert, 1994; Demopoulos, 1996; Demopoulos, Lagno, Wang, & Singhania, 2003; Droppert, Demopoulos, & Harris, 1996; Filippou & Demopoulos, 1997).Recently, Fujita et al. (Fujita, Taguchi, Abumiya, Matsumoto, Shibata, & Nakamura, 2008a, 2008b, 2009; Fujita, Taguchi, Kubo, Shibata, & Nakamura, 2009; Fujita, Taguchi, Shibata, & Nakamura, 2009) developed a new method for producing large scorodite crystalline particles with improved filtration and washability properties at normal atmospheric pressure and temperatures below 100°C. In the new method, oxygen gas (O2) is blown into solutions containing a high concentration of arsenic ions (As(V)) and ferrous ions (Fe(II)). The Fe(II) ions were subsequently oxidized to ferric ions (Fe(III)), resulting in the formation of large scorodite particles. High supersaturation of solutes such as Fe(III) will result in excessive nucleation, and the formation of poorly crystalline phases. The scorodite formation must therefore be conducted in a manner that avoids the critical supersaturation level being exceeded. It is supposed that the oxidation of Fe(II) to Fe(III) by O2 gas in the new method suppressed the supersaturation of Fe(III) during scorodite formation. The low Fe(III) supersaturation resulted in formations of highly crystalline scorodite particles of size of around 20 µm. In June 2008, based on the developed process described above, DOWA began experiments to verify the industrial capability of a plant with a capacity of 30 MT/month of As. It was successfully proven that it is possible to produce crystalline scorodite industrially on a commercial scale. This process was named and trademarked as DMSP® (Kubo, Abumiya, & Matsumoto, 2010)."

Jan 1, 2012

By C. Gosselin, M. Rheault, M. Benoit, Y. Bouroubi, V. Sarago

The last three decades have seen significant mining development in northern regions of Canada, where the freeze and thaw cycle of permafrost and the corresponding surface subsidence and heave represent a significant challenge to the design and maintenance of infrastructures. Identifying areas at risk is of great assistance to reduce the impact of this issue. Over the past ten years, Synthetic Aperture Radar Interferometry (InSAR) has been widely used to monitor ground surface deformation. With this technique, changes in phase between two SAR acquisitions are used to detect centimeter to millimeter surface displacements over a large area and with high spatial resolution. InSAR can be used as a tool to assist the siting and design of new infrastructure as well as highlighting the risk to existing structures in areas of unstable terrain. This paper presents the results of a project carried out by Effigis, which made use of SAR interferometry in the context of monitoring terrain and infrastructure stability in a northern mining environment that is affected by permafrost seasonal and long term changes. TerraSAR-X images acquired during two periods, August to November 2012 and March to October 2013, were used to measure the deformations and/or movement of ground surface, infrastructure and stockpiles caused by seasonal changes in permafrost extent in and around a mining site located in Nunavik, Quebec. The results showed that spatial and temporal distributions of surface displacements are in accordance with scientific and terrain knowledge. Some displacements were observed in loose soil areas while, as expected, none were detected in bedrock and rock outcrop areas. The areas most affected by active layer changes showed surface subsidence in the thaw settlement period. This study confirms that SAR interferometry has a great potential for operational applications related to risks induced by surface deformation in mining environments. It shows that this technique can be used to produce reliable maps of surface movement and monitor the vertical displacement of important infrastructure.

Jan 1, 2015

By Lawrence D. Hoy, Armand Savoie, Pierre Trudel, Ghislaln Tourigny, Robert Crépeau, Lao Kheang

"Recent fluid inclusion and stable isotopic studies in the Bousquet mining district have identified spatial and temporal trends in mineralization temperatures and isotopic compositions of vein forming fluids. These studies indicate that mineralizing temperatures were lower during sterile vein formation (T=200-300°C) than during auriferous vein formation (T = 300-400°C), and that 8 80 values of minerals in sterile veins are lower by 1-3 %o than in associated auriferous veins. In addition to these small differences in 8 80 within individual mineralized zones, a trend of increasing 8 80 values of vein minerals is identified from west to east across the district, with 8 80 of vein minerals increasing by4-6%o. Quantitative evaluation of potential causes of the observed oxygen isotopic shifts suggests that the best explanation for these trends is the derivation of the mineralizing fluids from an isotopically inhomogeneous terrain in which the fluid isotopic compositions are controlled by the isotopic compositions of the host lithologies due to high rock/water ratios in these source terrains. This inhomogeneous source terrain is interpreted as consisting of the Blake River Group volcanics (low 8 80 component) and the adjoining Kewagama and Cadillac Group sediments (high 8 80 component).The genesis of the hydrothermal fluids is attributed to crustal heating during metamorphism, with the fluids representing metamorphic dewatering products and/or fluids incorporated during deposition and burial of the host lithologies. Ductile deformation of the fluid source regions impeded fluid migration during metamorphism; the ultimate release of the mineralizing fluids is attributed to the penetration to depth of vertical structures (fault and shear zones) during brittle deformation of the crust under waning metamorphic conditions. Release of fluids caused by this puncturing of the closed hydrologic source regime produced a localized zone of lowered pressure, drawing fluids from adjacent lithologies toward the fault zones, feeding further hydrothermal fluid upwelling. Au mineralization resulted from chemical processes related to cooling of the hydrothermal fluids and/or interaction with lithologies encountered during fluid migration; the level of crust at which Au deposition occurred likely migrated upward with the thermal anomaly caused by hydrothermal fluid upwelling, eventually reaching the level of current exploitation. Cessation of fluid flow along the vertical structures is attributed to inadequate recharge of the hydrothermal systems as fluid contents were depleted in the lithologies proximal to the vertical structures and/or sealing of the structures by mineral deposition."

Jan 1, 1990

By Karl J. C. Harries

"11.1. INTRODUCTIONA royalty is the most common form of interest retained by an owner who is disposing of his property or by a joint venturer who ceases, voluntarily or otherwise, to participate in the joint venture.1 Rarely does a non-participating party have a direct interest in the property and/or assets of a project, except during the period when a non-participating joint venturer may be having his interest diluted.2 In fact, it is most unwise to permit a non-participating party to have such an interest. It may give rise to significant problems that could prevent or substantially delay the development of an orebody and require a considerable amount of time, effort, and money to correct.3In negotiating a royalty, it is important to be aware that there is no law or convention that says, “You just don’t do that in a royalty agreement.” As with any agreement, inventiveness and flexibility on the part of the negotiator are not just assets, but virtual necessities. It is also for this reason that it is essential to read the royalty provisions, particularly the definitions, fully and carefully, especially if you are the recipient. On the other hand, if your inventiveness and flexibility cause your accountant to question the advisability of one of your ideas, pay close attention to him.4 He will, no doubt, have had experience with many royalties, and no competent professional adviser disparages a client’s ideas without good reason. Besides, he will probably be the person who will be determining the royalty or certifying the determination of it. At the very least, he will be auditing your general financial statements, which must, of course, reflect the royalty determination. Heeding his advice not only may make the determination easier but also will probably save you money in professional fees later on. Nevertheless, do not simply accept his comments or recommendations without understanding what they mean, why they have been made with respect to your royalty agreement (sometimes professionals have comments that they make as a matter of course and, even though they may be valid, you should require them to be justified to you), and how they will affect your royalty determination.It is surprising how many corporate payors insist that their standard royalty provisions5 be used as a matter of policy, thereby effectively tying the negotiator’s hands. It is even more surprising, and to professional advisers frightening, how many of the senior employees who insist that such a policy be adhered to, virtually without variation, do not know what is in the standard provisions and would be hard-pressed to explain them to a property owner. If standard provisions are appropriate, by all means use them, but do allow experienced and sensible negotiators some flexibility and make sure that everyone within the corporation who may have to use such provisions – negotiator and supervisor alike – knows what they contain and why they are as they are. For example, there are often good and convincing reasons to describe a deduction in a certain way or to include a certain specific type of deduction. On the other hand, quite often the answer to the question “why?” is that “it has always been there”; this is, or should be, an unacceptable answer. In any event, if you, as the negotiator, appear to know what you are talking about, are familiar and comfortable with your royalty provisions, and are backed up by your boss with the same words or reasoning, a property owner cannot help but be satisfied that you are knowledgeable, even if he still does not agree with your provisions. Finally, if you do use standard provisions, make sure that they are reviewed and updated regularly."

Jan 1, 2003

By F. J. A. van Ruitenbeek, M. Dalm

In the presented study test work was performed with near-infrared hyperspectral imagery (NIR-HI) on 36 ore samples from a South-American epithermal Au-Ag mine. The aim of the test work was to investigate if NIR-HI provides information about the alteration mineralogy of samples that can be used to predict their economic value. Mineral distribution maps were produced from the hyperspectral images by using correlation coefficients between the image pixels and a set of reference spectra. These maps showed that detection of mineralogy with NIR-HI can be used to distinguish; i) ore particles with low Au and Ag grades, ii) ore particles with high carbon contents, iii) ore particles with high sulphur contents.

Jan 1, 2015

By R. C. A. Thurston

AT A FATIGUE SESSION organised by the A.S.T.M. in 1949, R. E. Peterson presented a brief introductory paper ( 1) in which lie referred to a discussion on the fatigue of metals which took place in England in 1849, and then proceeded to review some of the subsequent researches concerning the mechanism of fatigue. In the course of the review, he discussed metallograpl1ic studies with single crystals and polycrystalline materials, studies with X-ray methods, and the application of the electron microscope. During that hundred-year period considerable progress was made toward a better under-standing of the nature of fatigue, although it is probable that even greater attention was directed to the more practical aspects of the problem, such as the effects of notches, temperature, corrosion, surface treatment, residual stresses, and so on. Since then there has been an appreciable acceleration in the tempo of the fundamental work, partly influenced by the rapid development of the theory of dislocations, with the result that our knowledge of the mechanism of slip, the initiation of fatigue cracks, and their subsequent propagation, has still further advanced, although it is by no means complete as yet. The present paper is an attempt to out-line the more recent developments in these basic studies, to correlate them when possible, and to draw attention to those directions in which research might profitably be pursued.

Jan 1, 1957

By E. H. Dudgeon

In order to make increased use of automation in copper smelting, it is evident that a useful first step .world be the accurate determination of the copper end point in the converter operation. After laboratory tests, the copper end points in a copper converter at Gaspe Copper Mmes Ltd. were determined without reference to melt samples or other observations. The results indicated that the rapid measurement of the S02 level in the gas released from the converter has potential as a new and independent method of determining the copper end point in converter operation.

Jan 1, 1966

By Z. Huda

The effect of various percentages of cold-working and recrystallization on the microstructure and hardness of commercially-pure aluminum plate, has been studied. The 'A critical deformation for the aluminum, has been determined. Experimentation involved cold rolling and recrystallization processes followed by quantitative metallographic practice and the hardness measurements. The raw material chosen was a plate of commercial aluminum which was cold rolled to different percentage of cold-work and then recrystallized by heat treatment at 150°C. The critical deformation percentage of aluminum was computed to be around 30% of cold-worked.

Jan 1, 2007

By Jean-Christophe Ehrström, Fanny Mas

"A specific test set-up has been developed to study at the lab-scale the high-temperature behavior of aluminium alloys in conditions close to those experienced by thick plates during hot-rolling. A particular attention is paid to reproducing both the stress triaxiality and strain fields that exist in plate during rolling. In addition to standard ductility measurements by means of secondary tensile tests (STT), multi-step plane strain compression (PSC) tests have been performed to mimic hot-rolling pass schedules. Tool and sample geometries were adapted to allow low h/a ratios (h= average specimen thickness, a= tool width) and thus guarantee depressive stress conditions at the center of the specimen during most of the test. Such conditions resulting in porosity opening can then be used to investigate the impact of rolling conditions on damage evolution. The mechanical testing was combined with post-mortem high-resolution ultrasonic scans allowing to detect small amounts of damage and quantify its evolution as a function of processing parameters such as strain and temperature. The test set-up was validated on two 2050-type AlCuLi alloys with different susceptibilities to high temperature embrittlement.INTRODUCTION Aluminium thick plates are widely used in the aerospace industry, mainly as semi-products to be machined for internal structure parts of wings (spars, ribs) and fuselage (frame). The conversion route of such products always involves a hot-rolling step, the conditions of which (temperature, speed, pass schedule) have to be optimized to maximize both mechanical properties and final plate quality. This goal cannot always be efficiently achieved by full-scale industrial trials as (a) cost limits the number of possible test conditions and (b) it is often difficult to change one parameter alone. That is why there is a need for laboratory-scale tests able to mimic the rolling process in terms of temperature, strain rate, stress triaxiality and deformation. Most laboratory hot-rolling mills do not adequately simulate industrial processing routes, especially in terms of heat loss, deformation speed and rolling geometry (maximum roll gap vs. work roll diameter). Concerning thick plate, it is of interest to achieve both similar deformation and L/h ratio (L=arc of contact, h=mean gauge) per pass as the industrial schedule because they are simultaneously involved in damage evolution and void closure during hot forming processes (Saby, 2014)."

Jan 1, 2018

By L. R. Wilkinson, W. J. Howarth, G. J. Wenk

Over a period of three years, a cooperative program in Australia has resulted in the development of radioisotope immersion probes for the on-stream analysis of mineral slurries. Two basic probe types are now available on a commercial basis - fluorescence and absorption probes - and within each type there are a number of variations so that optimum sensitivities can be obtained for elements with atomic number greater than titanium (22), thus covering most metals of interest to modern metallurgy.

Jan 1, 1973

By Q. Li

"The precursor of In2O3 was prepared by hydrolysis precipitation/hydrothermal method using In(NO3)3 solution as the feed material and ammonium hydroxide as the neutralizing agent. The crystallinity, morphology and particle size of the products were characterized by SEM, XRD, BET and LPSA. The results showed that the hydrolysis product consists of an aggregate of cubic In(OH)3 particles with a short rod morphology. In the hydrothermal process, the structure, morphology and size of the particles changes through the mechanisms of Ostwald ripening and phase transition, respectively. When the hydrothermal temperature was less than 280 ?, the Ostwald ripening process took place, which changed the morphology of the particles from short rods to cuboids through dissolution-recrystallization. When the hydrothermal temperature was higher than 280 ?, the processes of Ostwald ripening and phase transition took place successively. Firstly, the morphology of the particles changed from short rods to cuboids through Ostwald ripening, and then, the phase transition from cubic In(OH)3 to orthorhombic InOOH occurred and the morphology of the particles changed from cuboids to polyhedron. INTRODUCTIONDue to its excellent electrical conductivity and optical transparency, indium tin oxide (ITO) film has been wildly used in flat-panel display, solar cell, antistatic coating and EMI shielding (Medvedovski et al., 2008). Indium oxide powder is one of the fundamental materials for preparing ITO film. Along with the development of ITO targets of both high density and large size, high quality indium oxide powders, such as single phase, nano-size, spherical morphology and mono-disperse, have been in high demand (Nakashima and Kumahara, 2002; Betz et al., 2006; Kim et al., 2007). The main preparation methods for indium tin oxide or indium oxide powders include chemical precipitation (Nam et al., 2001; Xu and Yu, 2007), melt atomizing-combustion (Chen et al., 2000) and spray pyrolysis (Ogi et al., 2009). Among them, chemical precipitation has been preferred, since it is simple, easy to control and suitable for industrial scale-up. In chemical precipitation method, indium oxide powders were prepared through the following steps: firstly, indium hydrate precursor was precipitated from an indium salt solution by neutralization using an alkali, such as ammonia; and then, indium oxide (In2O3) powders can be obtained from the precursor through calcination (Li et al., 2006), or solvothermal method (Lee and Choi, 2005), or hydrothermal processing/roasting (Xu et al., 2005; Chen and Li, 2007), respectively. However, the indium oxide powders obtained by direct roasting are polycrystalline, dispersable with a wide size distribution (Liao, 2006). The disadvantages of the solvothermal method are high cost, complicated after-treatment processes, as well as bad performances of the powders (Udawatte and Yanagisawa, 2000). Therefore, among three methods of obtaining indium oxide from the hydrolysis precursor, the hydrothermal process/roasting method is the most feasible to synthesize high quality In2O3 powder with uniform crystallinity and size (Kim et al., 2002; Zhu et al., 2004; Xu et al., 2005; Xu et al., 2005; Chen and Li, 2007; Seetha et al., 2009). However, current research on hydrothermal process-roasting method has been limited to the synthesis of a certain ITO or In2O3 powders under specific conditions. A systematic study on the phase transition, as well as the change of the morphology and size of the particles in the hydrothermal process is still missing. In this paper, the effects of hydrothermal processing on the mineralogy, morphology and size of products were investigated. The results showed that the evolution of crystal structure, morphology and size in the hydrothermal process was affected through the mechanisms of Ostwald ripening and phase transition successively. These results are novel and have guidance for improving the hydrothermal process for In2O3"

Jan 1, 2012

By G. H. Charlewood, J. W. McBean

"One hundred years after being developed, the diamond drill is still an essential tool in mineral exploration. The basic principle is unchanged, but the technique has been revolutionized, particularly in the past fifteen years. The cost of core drilling has not kept pace with the rising cost of living. The price of machinery, supplies and labour in drilling has doubled and trebled since 1946. Some of the techniques which have made it possible to hold the price line are described."

Jan 1, 1967