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By R. Blosser

Phelps Dodge introduced a process improvement model known as Quest for Zero in 2001. In 2004, the focus of Quest for Zero shifted from corporate-led initiatives to projects led by site personnel. The Hydrometallurgical Division at Morenci focused on two (2) significant process improvements: reducing electrolyte bleed and organic losses. In September 2004, Morenci kicked off a bleed reduction project to reduce electrolyte bleed by 45%. By the end 2005, electrolyte bleed was reduced by 55% through understanding and reduction of variance. Significant process changes made during this time period include changes in acid-addition strategy, reduction of uncontrolled bleed, and optimization of bleed placement. In April 2005, the organic reduction project began with the goal of reducing losses by 15%. Operational improvements during this project included improved organic recovery systems, mixer speed optimization, and picket fence installation. By the end 2005, this project reduced organic losses by 35% and current losses are 48% lower than at the start of the project. These projects and smaller Questfor Zero projects have resulted in sustainable annualized savings of $13 million in Morenci hydrometallurgical operations. Through the use of Six Sigma tools, process variances can be controlled and reduced.

Jan 1, 2007

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe. INTRODUCTIONThe Katanga province in the Democratic Republic of Congo hosts the northwestern part of the Central African Copperbelt. This region abounds with large, rich deposits of sulfide and oxidized copper-cobalt ores. In general, the main valuable minerals present are malachite (CuCO3Cu(OH)2) and heterogenite (CoO(OH)). Common impurities found in heterogenite are Cu, Ni, Si, Al, Mn, and Fe. The substitution of Co by other cations (e.g., Cu, Ni, and Fe) has an influence on the crystallinity of heterogenite (Deliens, 1974). In general, well-crystallized varieties of heterogenite have lower impurity contents, whereas amorphous heterogenite types usually contain more impurities (Thys et al., 2009). Further, in heterogenite, Co can occur in the 2+ and 3+ oxidation states. The gangue generally consists of quartz (SiO2), talc (Mg3Si4O10(OH)2), kaolinite (SiO2·Al2O3·2H2O), limonite (Fe2O3·3H2O), and goethite (FeO(OH)). Oxidized copper-cobalt ores are often treated by hydrometallurgical methods, whereas sulfide ores are often treated by flotation or pyrometallurgy, depending on their grades. Hydrometallurgical methods typically entail selectively dissolving the metals of interest (Cu, Co, and Ni) in aqueous solutions (leaching), transferring the dissolved metals to an organic solution, and retransferring these to a second aqueous solution (solvent extraction). Copper and nickel are readily dissolved in an acidic aqueous media. In contrast, cobalt is difficult to dissolve, especially if it is present in the third oxidation state; however, this species becomes soluble after it is reduced to Co2+ (Mwema, Mpoyo, & Kafumbila, 2002; Kime & Makgoale, 2016)."

Jan 1, 2017

By Abu Syed H. Kabir, Mehdi Sanjari, Steve Yue, Jing Su, In-ho Jung

AZ31 magnesium alloy sheets were produced by high speed rolling (HSR) at 1000 m/min at a low temperature of 100 ?. A high reduction of 72% can be achieved in single pass. At the reduction of 30%, the microstructure was covered by shear bands and twins. When the reduction was increased to 49%, dynamic recrystallization (DRX) was clearly observed in the vicinity of shear bands and twins and the full recrystallization was seen at a reduction of 72%. In order to study the static recrystallization (SRX) behavior on the heavily twinned structure, annealing was then carried out at 200 ? on the as-rolled specimens at the reduction of 30% for different times. Static recrystallized grains were also firstly observed on shear bands and twins after 45 s and the microstructure was mostly fully recrystallized after 1 h annealing with a few retained large elongated un-recrystallized grains. Texture weakening was found during annealing on the heavily twinned specimens by SRX, but not during high speed rolling by DRX. In the present study, effect of DRX and SRX on microstructure and texture evolutions during rolling and annealing were compared.

Jan 1, 2015

By M. S. Badollet

INTRODUCTION THE DEMAND for general knowledge on asbestos fibres has increased considerably in recent years. A few publications have printed data showing some of the physical and chemical prupertie3 of asbestos, but in many cases this information is difficult to find and is seldom available when needed. During the past ten years, Johns-Manville have received many inquiries on the physical and chemical properties of asbestos fibres. Fortunately, we had some of the information in our files, and we willingly supplied the data. To help relieve this need, we have tried to present briefly in this paper some of the interesting and out-standing properties of asbestos. This information was obtained over a period of years by search of the literature and by experimental investigations. PROPERTIES OF ASBESTOS FIBRES Table I (1, 2) presents, in convenient form for easy comparison, data on the principal properties of the several varieties of commercial 'asbestos' -actinolite, amosite, anthophyllite, chrysotile, crocidolite, and tremolite. Under each variety of fibre is a brief statement describing the properties in terms of structure, mineral association, origin, etc. Some of the more important data in Table I are expanded and presented in Table II (3). SOLUBILITY OF ASBESTOS A report ( 4, 5) discussing the effects of acids and caustic on asbestos fibres was published in Germany in 1927.

Jan 1, 1951

By M. L. Jeremic

The design of the long-hole sublevel mining method was originally based on the traditional assumption that the principal load was due to the weight of the overlying rock, and that the horizontal stresses are equal to one-third of the vertical stress. However, as mining progressed, the virgin lateral stress was found to be equal to or greater than the vertical stress. The virgin stress in the rock mass is not uniform throughout the folded orebody and adjacent strata. From detailed investigations, three basic patterns of virgin stress in ore panels have been inferred: uniform, bent and twisted. Stresses induced by stoping are up to three times greater than original stresses in the rock mass; they cause heavy ground conditions and make extraction of ore difficult. In the last ten years, the original mining system has been modified several times in order to destress the ground and improve the extraction of ore.

Jan 1, 1978

By L. Bratek, K. Jaworek, M. Czaplicka

Methods for arsenic compound removal from aqueous solutions include processes such as: coagulation, adsorption, membrane techniques, electrochemical and biotechnology techniques. Advanced oxidation using both UV radiation and strong oxidizing agents such as ozone and hydrogen peroxide may also decompose these compounds. It is known that effluents from metallurgical processes contain inorganic arsenic compounds in addition to the organic compounds such as: dimethylarsinic acid and phenylarsonic acid. This paper presents the conditions that lead to the formation of deposits containing mainly arsenic, such as pH, the wavelength of the radiation and the type of oxidant, for this type of effluent.

Jan 1, 2014

By Jack Craft

Local Environment Atmospheric conditions (or lack thereof) Drilling fluids are impractical Cuttings removal is a major concern Heat dissipation is a major concern Some tried-and-true mechanisms need air to function properly Gravity Low gravity means low downforce Microgravity means even less downforce Regolith Local dust may be highly abrasive Packaging for Spaceflight System mass is highly constrained The drill must fit within the spacecraft?s launch envelope Power is constrained

May 1, 2013

By R. Vracar, D. Sinadinovic, Ž. Kamberovic

The paper presents a study on the oxidation of polymetallic gold ore by oxygen in an autoclave. It presents optimum parameters of autoclave leaching of sulphide refractory ore in self-generated sulphuric acid solutions aiming to get products with favourable technological characteristics from which precious and other useful metals can be recovered. A high partial oxygen pressure (1.5 MPa to 2 MPa), high leaching temperature (190°C to 200°C), pulp density 80 g/L to 240 g/L, ore fraction size 76 µm and leaching time up to 4 hours yield good results in rich ores. The full extent of copper and zinc conversion as well as a high extent of iron conversion has been achieved, while lead, gold and silver and a minor part of iron remain as a solid residue among gangue minerals.

Jan 1, 2001

By James E. Wennen

The through-put and energy efficiency of an autogenous (AG) grinding mill are adversely affected by variability in rock size and rock competency. This applies to both fully autogenous and semi-autogenous (SAG) grinding circuits. In this paper we focus on an approach to overcome the problem of inconsistent mill through-put related to variability in mill feed size and rock competency. The focus is on ores containing hard, competent rock. This approach consists of preparing feed to an autogenous mill that contains 20% coarse media rock and 80% of material crushed to pass 37 mm. Results of pilot-scale testing for two iron-ores will be presented to show that a 10% to 12% reduction in unit energy consumption is possible with prepared feed, compared with feeding the mill with conventional primary crusher discharge.

Jan 1, 2012

By A. Oja, M. Lahtinen, P. Salonen, B. Saxen

Most of the secondary and low grade zinc raw materials cannot be treated successfully by either conventional roasting - leaching - electrowinning (RLE) process or even by atmospheric direct leaching process. The problems arising especially from high impurity content of these raw materials can be effectively solved by implementation of the solvent extraction process. The utilization of solvent extraction process has been demonstrated by Outotec with raw materials like Waelz oxide, crude zinc oxide and zinc containing concentrator tailings. Based on batch and continuous test work it has been shown that SHG quality zinc can be produced even from the lowest grade raw materials. Impurity control in the solvent extraction process has been examined. The solvent extraction process is the key feature of the whole zinc plant for such raw materials. However, design of the entire zinc process including neutralization and bleed treatment is important for optimization of investment and operation costs of the plant. Very careful evaluation of the zinc process with modern simulation tools is essential. The optimized Outotec zinc process ensures a sustainable and profitable process containing minimal effluent and requiring little residue treatment.

Jan 1, 2014

By Richard J. Wardle, Ambrose F. Howse

The industrial minerals industry in Newfoundland and Labrador is a significant contributor to the provincial economy. The variety ofcommodities produced reflects the diverse geological environment from which they come. A highlight of the past decade has been the continuing development of dimension stone quarries, with producers now active in anorthosite, gabbro, granite and sandstone. Other dimension stone prospects have been identified and are in various stages of assessment and development. Western Newfoundland hosts a large resource of limestone, dolomite and marble. It provides raw material for industries that produce Portland cement, agricultural limestone and aggregate, as well as chemical-grade limestone and dolomite products. In western Labrador, dolomitic marble is quarried for use in the production of self-fluxing iron ore pellets. The recent opening of a new gypsum quarry at Fischells Brook signalled the beginning of a new era in the commercial production ofgypsum, a commodity which the province has produced since the 1950s. Hopefully it will emulate the nearby Flat Bay Quarry (now closed) which was a long-time exporter to markets along the U.S. eastern seaboard, in addition to supplying local demands. Oil production and continuing exploration in the Newfoundland offshore has renewed interest in local barite deposits for potential use in drilling fluids. Already there has been some production from the Collier Point deposit, and at Buchans, an existing plant is being refurbished to recover barite from a large tailings pond. Emerging new industries include the development of an antimony mine in central Newfoundland, the development of silica deposits near Labrador City for silicon metal production, and reactivation of the St. Lawrence fluorspar mine. The province has many deposits with development potential such as rare metals at Strange Lake, white marble at Roddickton and salt deposits near St. George's Bay region.

Jan 1, 2001

By G. R. Elliott

Foreword The office of the Supervisory Mining Engineer, a branch of the l. Federal Government, is financially interested in no oil company and has no stock to sell. This office, however, is deeply interested in the proper and efficient development of Canada's natural resources. The people of Canada are interested in the petroleum development in Turner Valley for two principal reasons: As represented by the Department of the Interior, they are the largest owners of petroleum and natural-gas rights in the field; As a nation, they are vitally interested in the development of petroleum and natural gas as a national asset, and therefore, also, in all productive property, no matter who directly controls the leases. As has been stated by Mr. Charles C. Ross, Supervisory Mining Engineer, "The Department, being responsible for the administration of these public resources, necessarily requires regulations to protect them from abuse by lessees. Our portion of this responsibility is to record a complete history of all drilling operations and to see that proper drilling methods are adopted to prevent damage and wanton waste of the valuable natural resources under discussion." Not only does our position necessitate an impartial and a judicial viewpoint, but, being day by day in touch with all operations in the western provinces, we are uniquely situated to comprehend both individual and general problems.

Jan 1, 1930

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By F. Sorenson, P. A. Castellarini, F. Garbarino, M. N. Garcia

"Recently, significant efforts to improve productivity from the tight intervals of the Mulichinco Formation within the Sierra Chata Field in the Neuquén Basin have been ongoing. Because conventional high quality reservoirs were being developed in this field, a proper reservoir understanding and completion approach was applied. After developing these high permeability reservoirs, the operator began evaluating the tight intervals and new areas within the field, but a completely different approach was necessary to achieve motivating production improvement.An extensive study to help enhance reservoir understanding and identify key factors controlling productivity of these tight intervals (which tend to be in the range of 5 µD) has been ongoing. Some of the issues discussed in this study are 1) petrophysical review, 2) rock properties calibration, 3) geomechanics understanding, 4) faulting and micro faulting/lineaments description, 5) stimulation and completions review and, 6) understanding key production drivers.As in many other tight reservoir projects, a considerable area of the reservoir must be effectively stimulated during the hydraulic fracturing process to achieve economic productivity. Two critical issues hinder these objectives. First, the low permeability in addition to a pore pressure close to or even lower than hydrostatic are critical characteristics when attempting to flow back the well and clean up fractures. Second, very high horizontal stress anisotropy resulting from a strike slip stress regime promotes the generation of simple planar bi-wing fractures. It is well-known that this fracture geometry will contact much less reservoir area compared to more complex fractures, as the operator would normally intend to create at very low permeability reservoirs.This paper discusses these issues and how they were addressed. A pilot drilling and completion program was initiated during 2012 to validate this study. Key factors include well location relative to formation unconformities, their orientation relative to the far field principal stresses, hydraulic fractures generated, and overall completion design."

Jan 1, 2015

By J. C. Allan

THE purpose of this paper is to outline the pogress made in the development o the gravity separation method o ore dressing known as Sink-and-Float, which, in the opinion of the writers, has now reached a stage justifying the claim that this new method marks a highly important advance in the technique . The essential feature of the newest development of this process is the extremely accurate separation achieved. This is responsible for higher extraction in the sink-and-float unit on coarse sizes and, in consequence, for substantially higher overall recoveries. Whilst this is the most remarkable feature of the new process, it has further important contributions to make to ore dressing under the following heads: (1) The introduction of the sink-and-float separator as a buffer helps to iron-out irregularities in the mill feed. By supplying a concentrate of constant grade to the flotation section, the process also indirectly improves overall recovery. (2) The addition of a sink-and-float unit to an existing mill results in substantial increase in capacity at low per ton capital cost. (3) Where the plant can be installed underground for the pre-treatment of low-grade ores, there is a saving in hoisting costs, and excellent 'fill' is provided near the point of use. ( 4) Low-grade mixed oxide-sulphide copper ores may be pre-concentrated, thereby producing a flotation feed sufficiently rich to render the oxide residue from such flotation economic for subsequent treatment by leaching or other methods. (5) Application of the process eliminates hard gangue constituents which cause high grinding costs, or gangue constituents which adversely affect flotation. The plant is compact and easily controlled. No highly skilled operators or expensive reagents are required, and the labour and power per ton are low. The separator is extremely flexible, working equally efficiently on any throughput up to its maximum capacity.

Jan 1, 1940

In several European countries, including Russia, it has become economically attractive to utilize peat as a fuel for power generation, the production of metallurgical coke, the production of fuel briquettes for the domestic market and low-Btu gas. Although the economic base and availability of energy supplies in Europe is much different than it is in Canada, regional economics here may warrant the development of peat as an alternative source of energy. Canadian peatlands cover several thousands of square miles and have historically been considered as waste land. Now, with the increasing costs of other energy sources, it is apparent that fuel peat should be re-evaluated as a potential energy resource. A nation-wide inventory of peat deposits has been prepared and reserves evaluated for some of these areas where field surveys have been carried out. The paper describes alternative mining methods developed to meet some of the various conditions encountered on virgin peatland . These mining techniques are generally based on current peat technology exercised in other parts of the world and would be applicable in some of the peat regions of Canada. Cost estimates have been prepared for peat production in regions of Canada, and the socio-economic aspects of a large-scale fuel peat operation are discussed. Several potential utilization schemes have been described, with particular emphasis on electric power generation. The paper makes recommendations for steps to be taken in the development of a fuel peat industry in Canada.

Jan 1, 1978

By U. Caliskan, S. Miskovic

Gravity separation is a technique that depends on the difference in density of minerals for their separation. Although this method is one of the oldest separation techniques, it is still preferred in the industry because of its low capital and operating cost while it is environmental-friendly. In this paper, we present a new numerical methodology that can be used to investigate dynamics of dense slurry flows in gravity separation systems. A simple channel with a set of riffles is selected as a test platform in order to observe the effect of the riffle shape on segregation profile of particles with different densities. It is believed that the riffle shape would affect the slurry flow and possibly cause one class of particles to segregate within the riffle zone. The turbulence, as a disturbance effect within the riffle zone, causes heavy particles to displace the light, that is, the heavy particles will be trapped in riffles, while the lighter particles are carried by water to the end of the channel, which is an example to uninterrupted suspension. MP-PIC model in OpenFOAM is used to study the effect of riffle shape and slurry percentage of solids in this simple gravity separator on particle segregation profile of four discrete mineral density classes, which are Quartz/Clay (SG 2.6), Pyrite (SG 4.2), Chalcopyrite (SG 5.1), and Gold (SG 19.32). Gold particles are found to be readily captured and retained in the riffles because of their high density, while particles with the intermediate densities are more influenced by the flow. The developed model framework has been proven robust and capable of providing physical results even for the flows with a very high percentage of solids, characteristic for mineral processing operations. INTRODUCTION Gravity-based ore concentration techniques make use of differences in density of minerals within an ore to enable separation of valuables from the gangue. As some of the oldest techniques used for ore beneficiation, they are known to offer a range of benefits such as low specific energy consumption and low capital and operating costs (Burt, 1999; Falconer, 2003; Holland-Batt, 1998), however, they suffer from low selectivity, poor separation efficiency, and low capacity. Gravity separation techniques are common practices in the mining industry and are employed widely for the precious mineral concentration, iron ore recovery and coal preparation (Kroll-Rabotin, Bourgeois, & Climent, 2013; Laplante & Spiller, 2002; Williams, 1997). For example, gravity separation systems are highly applicable for precious metal enrichment operations by being included in primary grinding circuits, shaking table tailing separation, pre-concentration of leach feed and flotation concentrate enrichment for both flash and conventional flotation purposes (Burt, 1999; Falconer, 2003; Holland-Batt, 1998; Laplante & Spiller, 2002; McAlister, 1992). Gravity separation can be employed in the copper processing circuits by being integrated into the pre-flotation circuit to capture the gravity recoverable gold (GRG) and any free copper aiming to enhance the gold and copper recovery of the plant. When native copper and GRGs are present in the deposit, this integration not only facilitates plant overall performance via removal of the valuables early in the circuit, but it also reduces downstream operational expenditures due to less retention time of coarser copper particles in the system.

Jan 1, 2019

By A. R. Sorta, D. C. Sego

ABSTRACT The settling, shear strength, and index properties of oil sands fines-sand mixture tailings (FSMT) for a wide range of solids and fines content are investigated. Results indicate that the liquid limit of FSMT obeys a linear mixture law. The fines-water ratio (FWR) governs the permeability of composite tailings (CT) and CT with comparable geotechnical behaviour can be produced from the same initial FWR mixtures. A phosphogypsum (PG) dosage > 900 mg/kg does not improve the dewatering behaviour of CT. The undrained shear strength of FSMT at the liquid limit is approximately 2.4 kPa, but is dependent on fines content at the plastic limit.

Jan 1, 2013

By Michael P. Davies

Mine waste facilities, and in particular tailings impoundments, are one of the highest risk aspects of any mining venture. There are far too many recent examples of how real and/or perceived physical or environmental impact from one of these facilities has had enormous economic impact on both the specific project and the overall parent mining company. In many cases, such dramatic impacts have followed a period where a due diligence of the mine had been carried out (e.g. in an acquisition, merger or similar) or an internal or otherwise audit had taken place. Consequently, it is suggested that there is a need for an audit/due diligence framework to assist those processes in terms of assessing mine waste facilities. This paper presents a recommended framework for completing either an audit or due diligence assessment of mine waste facilities under a number of typical scenarios. The framework will be of relevance to reviews carried out prior to mine construction, during operations and for mines that have been in a care and maintenance position and are to be re-opened. Concepts of risk management are introduced as an essential part of the recommended framework. The paper should be of value to current and prospective mine owners involved in stewarding an area of significant risk to viability of their mining venture. The paper should also interest prospective lenders to these ventures.

May 1, 2007

By A. J. Miller

Estimates of interstitial water saturation derived from capillary pres-sure data are compared with residual water saturations found by the analysis of cores out in oil-base drilling fluid. A theoretical explanation for the high-rate of water production from the Bellshill Lake Field is proposed, based on the interpretation of the capillary pressure data.

Jan 1, 1960