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By H. S. Price, F. N. Kissell, R. C. McCulloch, J. C. Edwards

"The methane em1ss10n from deep coalbeds which are actively mined is a serious problem facing the mining industry today. Pinpointing the source of methane and predicting the emission of this gas from these coalbeds is necessary if preventive techniques are to be effectively used to control methane emission. In general, because most coalbeds have water associated with them, the system to be studied may be either single-phase (methane gas) or two-phase (methane and water). Because coal mine geometry is complex and the fluids have variable properties as functions of pressure and methane concentration, the differential equations describing the flow of methane and water are not amenable to analytic solution, but must be solved numerically using high-speed computers. This paper presents the development of such a complex mathematical model along with some preliminary applications of the model to methane emission from one- and two-dimensional coalbeds with and without water present."

Jan 1, 1973

By William M. Luff

This paper outlines the regional geology and history of the area, and summarizes the stratigraphy, structure and geology of the Brunswick No. 12 mine area. The Brunswick No. 12 deposit is a stratiform massive sulphide body. It occurs in rocks of the Tetagouche Group, which is believed to range in age from Lower to Middle Ordovician. The stratigraphic sequence, including the stratiform orebody, in ascending order consists of older metasedimentary rocks, augen schist, metasediments, augen. schist, footwall metasediments, the -massive sulphide body, iron formation, hanging-wall metasediments, siliceous tuff, basic volcanic rocks , basic iron formation and a porphyry dyke. This sequence is similar to that at some other deposits in the area. Four phases of structural deformation are known to be present in the Brunswick No. 12 mine area. The first deformation folds (F1 ) and associated faulting are the most important factors in determining the distribution of the massive sulphides. This deformation has resulted in the massive sulphides being separated into four zones: the Main Zone, the West Zone, the East Zone and the V-2 Zone. Brunswick Mining and Smelting Corporation Limited is actively mining, developing and exploring the deposit.

Jan 1, 1977

By K. Hashiba, Y. Z. Liang, K. Fukui, M. Koizumi

"Efficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Development and modification of the rock drills based on test data are timeconsuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved. The objective of our research project is to construct a new realistic numerical model of continuous percussive drilling, which is based on the previous Okubo-Nishimatsu’s model. In this study, the parts of the previous model involved in stress wave propagation and attenuation were modified. The two models were prepared for HD712 hydraulic rock drill mounted on crawler drills and HD210 hydraulic rock drill mounted on drilling jumbos. Stress wave propagation was computed with the discretized one-dimensional wave equation. The calculated results were compared to the stress waves measured on a rod during percussive drilling. In both models for HD712 and HD210, the measured stress waves can be reproduced with the one-dimensional model of the same acoustic impedance as the actual piston, shank rod and rod combined with the CI+spring model as a rod joint. The calculated results indicate that the spring constant in the model of a rod joint needs to be set appropriately depending on drilling conditions. INTRODUCTIONEfficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Components related to the percussive drilling are a drill body, a piston, a shank rod, rods, rod joints, a bit and rock. The piston in the drill body is reciprocated by hydraulic pressure and collides with the shank rod a few thousand times per minute. Stress waves generated by the collision propagate and attenuate in the rods and rod joints, and then reach the bit. The bit penetrates and crushes rock. During percussive drilling, the components mutually affect each other and self-induced oscillation occurs. The number of blows and the rate of penetration are determined by the practical drilling conditions such as hydraulic pressure, thrust force, number of rods and mechanical properties of rock. Development and modification of the rock drills based on test data are time-consuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved."

Jan 1, 2015

By A. S. Romaniuk

More than a decade ago, CANMET management recognized the need to make better use of existing technological information in mining and extractive metallurgy-two fields basic to the economic well-being of Canada. There were at that time no indexes or files dedicated to disseminating technical information for the many minerals mined and processed in Canada, including coal. CANMET, with the nation's largest research and library resources in the minerals field, was in a unique position to fill this need. Initial efforts were concentrated on building a mining file, beginning with identification of world sources of published information, development of a special thesaurus of terms for language control and adoption of a manual indexing/retrieval system. By early 1973, this file held 8,300 references, with source, abstract and keywords given for each reference. In mid-1973, operations were computerized. Software for indexing and retrieval by batch mode was written by CANMET staff to utilize the hardware facilities of EMR's Computer Science Centre. The resulting MINTEC file-one of the few files of technological information produced in Canada-is the basis for the national literature search service in mining offered by CANMET. Attention is now focussed on building a sister-file in extractive metallurgy using the system already developed. Published information sources have been identified and a thesaurus of terms is being compiled and tested. The software developed for CANMET's file-building operations has several features, including the selective dissemination of information and production from magnetic tape of photo ready copy for publication, as in a bi-monthly abstracts journal.

Jan 1, 1979

By J. -P. Lempainen, K. Haavanlammi, K. Valkama

The Outotec nickel matte chloride leaching process is especially suitable for small capacity standalone nickel refineries. The matte is leached with hydrochloric acid and oxygen in multiple steps in atmospheric OKTOP® reactors. Oxygen feed prevents reductive conditions and hydrogen formation in the leaching process. A sufficiently high acid concentration keeps the iron dissolved in the solution. The iron is removed after leaching by precipitation and the pregnant leach solution continues to metals recovery. The metals recovery from the chloride solution is done by solvent extractions, where ammonia is used for pH control. Copper and nickel are stripped from the organic phases into sulphate solutions. Metals can be recovered from the purified solution by conventional electrowinning. Other alternatives are precipitation or hydrogen reduction processes. The ammonium chloride in the solvent extraction raffinate is regenerated into ammonia. The calcium chloride solution from ammonia regeneration is routed to acid regeneration where sulphuric acid is added and ultra-pure gypsum is precipitated. The hydrochloric acid solution from this step is recycled back to leaching. The process yields good overall metal recoveries and expensive

Jan 1, 2014

By M. Askari, A. Ahmadi

"This study was conducted to establish the possible application of bioleaching in the pilot scale to recover valuable metals from the sulfidic tailings of Golgohar Iron Mine (Kerman, Iran). Using bioleaching processes, solvent extraction and sulfide precipitation recovery of valuable metals including, copper, cobalt and nickel from the tailing was investigated. The results showed that the optimum pH and temperature conditions relative to the bioleaching step was 1.5 and 45°C. The extraction of the metals from the low grade polymetal resource with complex mineralogy is very important from economic, environmental and technical point of views. Moreover, the proposed method has some advantages from energy saving, tailing management and creating added value from waste materials aspects.INTRODUCTION The growing demand for base metals and strategic such as: copper, nickel and cobalt as well as high-grade resource depletion has caused them, the mining industry to extract metals from low-grade resources and driven by complex mineralogy (Xie et al., 2005). Economic extraction of metals with low grade sources requires low-cost and efficient processing methods. A source with enormous potential for metals in future, secondary sources, such as: tailings mineral industries which the lack of appropriate technology and the high cost of processing weren't recoverable with previous procedures in the past. But it is possible that with develop new and efficient technologies have the economic exploitation ability. Recovery of metals from tailings resources is very important not only in terms of precious metals but also in terms of reducing environmental problems (due to heavy metals). The metals of copper, nickel and cobalt are mainly like sulfide compounds in the nature, usually for their recovery, first they make ore with flotation method to obtain the sulfide concentrate that containing valuable metals. then for the metal production, it will be melt and purification. Due to the environmental aspects, technical problems in the recovery of base metals from low grade ore and mixes, the presence of small reserves, in the past three decades they pay much attention to the use of hydrometallurgical processes for the recovery of base metals from these resources. These processes are classified according to the solver agent to leaching sulfates, chlorides, nitrates and amines (Hackl, 1995). Early, chloride leaching under oxidation condition in acidic or alkaline solutions was recognized the best process to produce sulfide concentrates. But then the basic processes sulfates was considered as the superior process because of being easier, a better understanding of the chemistry of leaching and recovery of base metals, especially copper from the environment easier sulfate solution with an organic solvent extraction and electro winning. The bioleaching is shown its ability on a commercial scale of low-grade sulfide minerals and ore that because of environmental reasons, the possibility of melting is not possible to them. The existing industrial base factories are based on primarily on the bioleaching and pressure leaching and recovery of cathode copper sulfate solution by extraction with organic solvents (SX) and electrowinning (EW) (Wang, 2005). Preliminary analysis has shown that valuable elements such as copper, nickel and cobalt are in the float flotation unit. Hence the plan to extract these metals from the wet tailing stream has been done."

Jan 1, 2017

By G. M. Dunn

Pressure leach autoclave circuits are employed in the leaching of ores, concentrates, mattes, alloys and intermediates for the recovery of metals into solution. Once the metals are extracted into solution the value metals can be recovered by hydrometallurgical means such as by purification followed by electrowinning, hydrogen reduction, pyrohydrolysis, crystallisation and other unit operations. In many of these integrated flowsheets the pressure leach step is pivotal to the recovery of the value metals from the host material. In an expansion or a new project, a large component of the capital cost can be associated with the pressure leach step and process engineers frequently look for opportunities to mitigate costs. This paper examines a new route for increasing the capacity of an exothermic pressure oxidation leach for sulphide concentrates, sulphide and phosphide mattes and alloys.

Jan 1, 2004

By W. A. Roliff

The renewed interest of the past few years in the Appalachian and Michigan oil provinces has not, as yet, created any marked increase in activity in Southwestern Ontario. During 1960 development drilling in-creased somewhat over 1959, but exploratory drilling decreased slightly. More attention was devoted to the deeper horizons, but lake drilling de-creased considerably. Oil production reached a new peak and gas production increased slightly. During 1960 an interesting oil and gas discovery was made in the Cambrian and gas discoveries six miles off-shore in the eastern part of Lake Erie were made in the Clinton-Cataract zone of the Silurian. This paper reviews activities during 1960, summarizes the discoveries made to-date and the pertinent exploration data relating to the prospects of the region and discusses some of the economic aspects of exploration and development. D URING the last few years there has •been a marked renewal of interest in the old petroleum

Jan 1, 1961

By Gordon Jackson

"There are two accomplishments of air and gas drilling: a new series of economic and mechanical challenges; and, acceptance as a standard drilling and completion tool.The new challenges are related to the concept of using a gaseous circulating medium in drilling for oil or gas. For purposes of discussion, a two part division has been made: the challenge of fluid invasion control and that of equipment and tools. Great strides have been made in the development of materials and techniques to combat formation fluid invasion. Chemicals and the ""mist drilling"" technique, now in use, have the versatility to cope with a wide range of downhole fluid entry conditions.Equipment and tools have been developed to meet the challenges of better, more economic drilling and completion possible with a gaseous circulating fluid. Economic and operational challenges remain.Acceptance of air and gas drilling as a normal operating tool was reached with difficulty. It is now established as a means of reducing costs in exploratory and develop-mental well drilling, exemplified in a recent study of 226 wells covering 419,407 feet of hole in the United States. Air reached the projected depth in 85 per cent of the operations, although formation water was encountered in 48.7 per cent of the holes. Slim hole bit performance and cost all compared for overall bit averages as part of analysis."

Jan 1, 1961

By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By A. Staley, W. J. Cashwell, M. S. Moats

In the 1990’s, Técnicas Reunidas developed the Modified ZINCEX® Process to recover zinc from ores and secondary materials. The heart of this process was the use of solvent extraction to produce purified zinc electrolyte instead of traditional zinc dust cementation. This development was commercialized by Reunion Mining and Anglo American for primary ore at the Skorpion mine in Namibia with the first SHG zinc produced in May 2003. Horsehead Corporation through Horsehead Metal Products, Inc., its wholly owned subsidiary, is presently commercializing the MZP for the treatment of Waelz oxide. This paper will review open source information about the lessons learned and process modifications that have occurred at Skorpion over the past decade. It will also provide an update on Horsehead’s facility being constructed in Rutherford County, North Carolina.

Jan 1, 2014

By V. C. Pandolfelli, L. Paulino, C. E. Zangiacomi

The continuous improvement in aluminum industry over the last years has increased metal output at lower cost. The potlining plays an important role in this regard due to high cost involved and more recently in its environmental aspects. In order to increase potlife and thus minimize the aluminum cash cost, a systemic approach is needed, through investigating the main cathode failure mechanisms by using a pot autopsy as a powerful tool, and then making the necessary chances to achieve extended potlife. In addition, preheating and pot start-up may also damage the cathode if not performed with an appropriate technique or even if the lining materials are not specified correctly, among other factors. All these aspects will be presented and discussed in this paper. Increased potlife, especially now that the current is reaching values up to 300kA, will allow aluminum plants to match their goals more efficiently at lower costs.

Jan 1, 2006

By David Burchell

Duckbill mining is probably the simplest method of loading coal mechanically at the face in underground mines. It is a means of reducing the amount of physical labour required to produce a ton of coal. In effect, it is merely shaker conveyor mining brought up to date with the addition of a self-loading head or 'duckbill' on the end of the conveyor line. Any mechanical device used to load coal is a means of supplanting the human muscles as the medium for getting the coal off the floor into the transportation equipment. There can be no argument with the conclusion that a man can lift so much and no more. He can load more tons of coal on a low conveyor, because the lift is less, than he can in a pit car two, three, or even four feet high. Thus it follows that, if the lifting operation is entirely eliminated, the man should be able to produce even more coal. A mechanical operation is essentially a multiplication of physical strength. Although there are various ways in which coal can be loaded at the face by mechanical means, there is, perhaps, none more adaptable than shakers equipped with duckbills. This is particularly true for thin seams and in mines having heavy, tender top conditions which require close timbering. However, as we are discussing duckbill mining, we will make no further reference to any other type of equipment. The first, and to date the only, mine in eastern Canada to adopt a system of mechanical loading at the face is the Franklin mine of the Bras d'Or Coal Company, Ltd., at Bras d'Or, N.S. An experimental Goodman shaker conveyor with a self-loading head, or duckbill, was installed in this mine in 1940. Since that time other units have been placed in operation so that, today, this mine is completely mechanized. The method of operation 1s room-and-pillar. The operation is carried on in a 42-in. seam, which lies 420 feet beneath the Sydney Main or Harbour seam in the Sydney Mines basin. The slopes bear N.25 30'E., dip 10 per cent seaward, and are about 6,000 feet in length. The physical conditions of this seam do not make it particularly adaptable for complete mechanization as it contains a large amount of foreign material, such as clay intrusions or wash-outs and iron pyrites. These clay intrusions, known locally as 'troubles', vary in thickness from a few inches to as thick as eighteen feet and usually replace the coal to the full height of the seam.

Jan 1, 1947

By M. B. Shongwe, R. K. K. Mbaya, C. K. Thubakgale, P. Mendonidis

"A low-grade nickel-bearing ore was pre-concentrated on a SB40 laboratory model Falcon Concentrator. Three size fractions, -212+125, -125+75 and -75 µm were tested with the intent to upgrade the nickel content by reducing their content of fine silica, which becomes amorphous during leaching. Separation of silica from nickel-bearing magnesium silicate minerals; hornblende, clinochlore and talc, was more efficient in the finer particle sizes, -125+75 and -75 µm, and at high G-forces. For these two size fractions, nickel was upgraded from 0.06 to 0.07%, with a reduction in silica content from 52.12 to 50.71%. Leaching of feed samples prior to pre-concentration resulted in the formation of amorphous silica, indicative of the presence of fine silica in the samples. Leaching of nickel from the -125+75 µm fraction increased with increasing G-force and feed pulp percent solids, while that of -75 µm was not influenced. The optimum nickel recovery was 15.68% to the Falcon underflow, using the feed size fraction of -75 µm, 30 G and a feed pulp solids content of 10% solids, after 120 minutes of treatment.INTRODUCTION A low-grade South African nickel-bearing ore with about 0.06% Ni was previously studied for atmospheric pressure acid leaching using sulphuric acid. The study was motivated by the continuing search for methods to treat of low-grade ores, which appear to be an increasingly important source of valuable metals as a result of a declining production from rich sulphide ores. Nickel is a base metal that is used as an alloy in steelmaking and chemical industries because of its resistance to corrosion (Haudet et al., 2015). Nickel laterite ores with grades lower than 1.50% Ni are considered to be complex ores, accounting for 70% of the global nickel reserves (MacCarthy et al., 2016). Their complex nature may be attributed to the indefinite mineralogy of these ores, in which nickel may occur in more than one mineral host. In some cases, nickel may be finely disseminated in the ore. The grade of such an ore and complex mineralogy do not justify the application of pyrometallurgical methods for extraction of nickel (Zhu et al., 2012). This suggests that there is a need for less expensive alternative methods of extraction. This study investigates the application of centrifugal gravity concentration, using the Falcon concentrator, followed by leaching to determine the effect of pre-concentration of the ore prior to extraction by atmospheric pressure leaching with sulphuric acid."

Jan 1, 2017

By Janice Zinck, Maziar E. Sauber

"To counter the recent uncertainty in the rare earths market, diversify the supply source, and help meet the future demand in this sector Canada initiated development of several new rare earth deposits. In the past few years, a number of various studies on rare earths plant design have taken place mainly covering process development, process selection, and flowsheet design. The purpose of this paper is to provide an overview of known domestic and potential resources and reserves of rare earths and their status quo with a focus on the metallurgical processes using the information available in the public domain. Plant designs currently under consideration in Canada are reviewed and evaluated. An outline of the areas of opportunity for selective innovation and technology development in the rare earths flowsheet development and the associated risks and rewards is provided.INTRODUCTIONThe rare earth elements (REE) have a very small annual market, but they are categorized as very strategic metals vital to global economic growth due to their indispensability to the development of modern defence system, green technologies and electronic applications. The International Union of Applied and Pure Chemistry (IUPAC) defines the REE as the 15 elements on the lanthanide series on periodic table of elements, plus yttrium and scandium. REE are classified as light rare earth elements (LREE; La to Gd), and heavy rare earth elements (HREE; Tb to Lu). Physical properties and chemical reactivity of yttrium is similar to those of HREE, thus it is categorized as such. Properties of scandium are not similar enough to classify it as either a LREE or HREE (Weng et al., 2015; Sappin & Beaudoin, 2015). However, the mining industry does not always abide to this definitive classification of the split between LREE and HREE. Therefore, in a comparative study of projects, there is a need to pay attention to how the elements are classified."

Jan 1, 2016

"The pressure leaching of alkali-pretreated limonitic laterite ore in nitric acid was studied. The optimal leaching conditions are as follows: leaching temperature of 458 K, initial nitric acid of 2.44 mol/L, leaching time of 60 min, liquid to solid ratio of 2:1 mL/g, agitation speed of 500 RPM. Under the above conditions, the extraction of nickel and cobalt can be achieved as approximate 95% and 80% respectively while that of iron is as lower as 1%. The leaching residue containing 70% of iron in the form of hematite and trace amount of chromium is suitable as the raw material for iron-making. The nitric acid in the leaching solution can be regenerated and further recycled to leach. INTRODUCTIONIt has been estimated that 60%-70% of the world land-based nickel resources presented in nickel laterites containing 130 million tons of nickel although these only accounted for about 42% of the world nickel production (Sudol, 2005; Luo et al., 2010). The nickel resource of laterite has not yet been fully utilized. Due to the increasing global demand of nickel and the declining global reserves of nickel sulphides, there is an increasing focus on the processing of the huge reserves of laterite ores today. Nickel laterite ores can be simply divided into two types, namely, silicate-rich and limonite. The former can be treated effectively by pyrometallurgical process in which the ferronickel product or nickel/iron sulphide matte is produced (Monhemius, 1987). The limonitic laterite is rich in iron in the form of goethite which is the main nickel-bearing mineral and usually contains cobalt associated with a manganese phase (Chang et al., 2010; Georgiou and Papangelakis, 2004). The limonitic laterite is usually processed by hydrometallurgical methods, such as atmosphere acid leaching (AL) (Xu et al., 2005; McDonald and Whittington, 2008), high pressure acid leaching (HPAL) (Chou et al., 1977; Georgiou and Papangelakis, 1998; Rubisov et al., 2000; Whittington and Muir, 2000) and reductive roasting-ammonia leaching (Caron Process) (Whittington and Muir, 2000; Valix and Cheung, 2002). The AL process can proceed at lower temperature, thus the operation costs may be very low. But two biggest problems associate with the AL process, namely, the slow rates of nickel extraction and potentially the significant amount of impurities such as iron and aluminum in the leaching solutions, which hampers the wide application of the AL process. The Caron Process uses the pyrometallurgical and hydrometallurgical methods together to obtain the metallic values, but the overall metal recovery is relatively low, especially for cobalt. In recent years, the environment-friendly process of HPAL has become increasingly important because it is most suitable for low-grade ores and leads to high extraction of the valuables. However, the HPAL process needs a much higher temperature and pressure (503-533 K, 4-5 MPa) to maintain a relatively fast leaching rates, which results in higher operation costs. Moreover, another serious problem of scale formation in autoclaves occurs in the HPAL process, for example, in Moa Bay, up to 20 cm scale may build up resulting in 5 days descale downtime per month. In addition, the iron residues cannot be utilized for ironmaking due to the presence of high content chromium (Ema and Harada, 1987; Owada and Harada, 1987; Takagi and Furui, 1987)."

Jan 1, 2012

By W. G. McBride

INTRODUCTION Preparation of this article, at the request of the Committee on papers, has been undertaken in the hope that it may stir up helpful discussion and constructive criticism. The Canadian mining industry is in the dumps and there is no use trying to deny the fact; nor does it help to say that other industries are in as bad or a worse condition. Let us face the situation honestly and see just how serious it is. The entire financial and industrial world is in a state of depression. The gravity of the case is no doubt exaggerated by contrast with the wave of optimism and false prosperity which pre-ceded it. The prevailing gloom and pessimism are just as irrational as was the former super-optimism. As far as we mining engineers are concerned, the causes are quite beyond our control, and it is the effect upon our own industry which interests us most. This effect is an accumulation of mineral products with consequent depression in price to a point where profits have almost, if not quite, disappeared. Whether this accumulation of stocks is the result of over-production or under-consumption is difficult to say, but it would seem likely that there is a combination of the two. The introduction of selective flotation has brought about a large increase in the production of zinc, a moderate increase in the production of lead, and a comparatively small increase in copper. It has turned relatively small mines into great producers, as in the case of the Sullivan, revived expiring mines like La Cananea, and brought-in new ones like Flin Flon

Jan 1, 1931

By P. Cheung, J. Gulyas, R. Clary

Over the past 50 years, the use of autoclaves in the metallurgical industry has evolved from final metal recovery (hydrogen reduction) and purification (sulphide precipitate oxidation) to treating whole ores and concentrates. Recent process developments, such as the use of autoclaves for laterite leaching, have necessitated higher temperature and pressure operations, which in turn have seen marked advancements in technology and manufacturing capabilities to keep in step with process demands. This paper will discuss the advances in technology in terms of design, materials and construction of autoclaves and liners, typical dip tube design and geometric layout. This paper will also address specific auxiliary equipment, such as acid and steam injection systems, and components, such as agitator seal systems.

Jan 1, 2004

By G. B. Harris, C. W. White

A study to investigate the recovery of base metals, notably copper, nickel, cobalt, zinc and manganese from iron-free concentrated chloride solutions using ion exchange was undertaken. In such solutions, apart from nickel and, to a lesser extent manganese, these metals are present predominantly as complex anions, and therefore conventional separation techniques based on cationic resins are not applicable. The results demonstrated that zinc, copper and cobalt can all be separately recovered leaving nickel and manganese behind. Specifically, zinc is a major nuisance element in nickel and cobalt processing, and the testwork showed that it can be preferentially removed prior to copper and cobalt. Selective resins for both copper and cobalt were identified, and it was demonstrated that the strength of the chloride background matrix has a significant effect on the efficiency of separation. An additional major advantage in such systems is that stripping can mostly be effected with water. Finally, some observations are made on the hurdles that must be overcome when attempting to introduce and commercialise new technologies.

Jan 1, 2015

By Robert Maquil, Gilles Didier, Walter Steiner

"The 1580 m long dual-tube motorway tunnel Markusberg near Schengen, Luxembourg experiences strong swelling phenomena in each tube related to a 35 m wide diagonally crossing rock layer, some150 to 200m from the east portals. Overburden over the roadway is 26 to 30 meters. Tunnel construction started in 1998 and the tunnel was opened in 2003. The tunnel was driven downgrade from the West, the heave phenomenon started to occur as the tunnel approached completion. No indications of the presence of anhydrite and dissolved sulphates were known prior to tunnelling. Water samples had been taken from the beginning of construction and the concentration of anions and cat ions determined. Sulfate content was substantial, in one well it reached 22 mg/l, this high concentration requires the presence of other ions, in particular sodium and chlorine. Based on the knowledge at the time of construction heaving ground was removed from the tunnel invert and a free space was left below the roadway that is covered by a transversely spanned slab. In addition a series of posttensioned tiebacks were installed below the sidewalls. The void left in 2003 was 1.7m high and closed to less than 0.5 meters in 2007 then it became necessary to widen the free space. A central trench was dug with a height of about 2.5 meters and the benches were lowered.Level surveying had been carried out since 2002. In 2006 two extensometers were installed, one in the zone of strongest heave, the second at the edge of the swelling zone. The extensometer in the center of the swelling zone indicated heave with an essential constant rate with seasonal variations, the heave is concentrated in layer from 2 to 5 meters that heaved by nearly 300 millimeters within 5 years or 60 mm/year, which equals to approx. 1% extension per year. At the abutments heave rates of 20 mm/year where the support resistance is higher were observed. With data from other case histories a relation of heave rate with support resistance was established. Based on the numerous field observations hypotheses for the complex in-situ swelling processes, involving rock mechanics, mineralogical, soil mechanics and hydrogeological aspects were developed"

Jan 1, 2015