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By Elliot B. J

Cobalt is principally produced by hydrometallurgical means from the copper-cobalt ores of Zambia and Zaire. In addition cobalt is commonly found in minor quantities in association with nickel and copper-nickel orebodies. Generally the level of cobalt common to these latter orebodies does not warrant separate processing unless the metal price reaches levels last achieved in 1979 and 1980. For pyrometallurgical processing the distribution of cobalt and the factors which affect the distribution of cobalt between matte and slag are not well understood. A limited amount of fundamental research has been completed on cobalt distribution both for simple oxide and matte systems. The paper briefly reviews the relevant literature on theoretical aspects of cobalt distribution between metal and slag and the deportment of cobalt in sulphide smelting circuits. The deportment of cobalt in the Kalgoorlie Nickel Smelter circuit is critically analysed and areas where recovery improvements may be achieved are highlighted.

Jan 1, 1989

A method is proposed for the determination of antimony in ores. Antimony is volatilized as antimony iodide by heating with ammonium iodide at a controlled temperature.The fusion mixture is extracted with hydrochloric acid and the antimony content is measured by atomic absorption spectrophotometry using an air/ acetylene flame. The time taken for analysis when comparedwith existing fusion and separation procedures is considerably reduced. Cations and anions likely to be present in antimony ores were also studied for possible interference effects but were not found to interfere.

Jan 1, 1972

By Hemingway J, Read T. A, Anderson V. G

IN the determination of very small amounts of lead, the usual analytical methods are far from being satisfactory. Small amounts of lead may be present in the reagents empioyed, and it is customary to run a blank experiment to correct the error arising in this way. When the correction is of small magnitude compared with the amount of lead in the sample, this procedure may be adopted; but when very small amounts of lead are being determined it may happen that the lead found in the blank is as much, or even more, than the lead actually present in the sample, and the analysis has to be rejected. Moreover, the blank experiment cannot check errors which are not common to the blank and the analysis itself eg, the apparatus used in the parallel experiments, etc. It seemed to be desirable, tl;l.erefore, to make an investigation of the problem to ascertain, as far as possible, the nature of the errors arising from the introduction or loss of lead during the analysis, and how far these could be eliminated or corrected for; also, to determine the limits of accuracy of the improved method and the minimum amount of lead that could be reliably estimated.In the investigation, reliability and sensitiveness were regarded as essential features. Speed of operation, on the other hand, was considered of less importance. The amounts of lead dealt with being usually less than 1 mg, there is no alternative to the use of a colorimetric method. The latter, depending as it does upon the development of a brown coloration when ammonium sulphide is added to a very dilute -solution of a lead salt, is far from being a characteristic test for lead. Indeed, it is well known that the salts of most of the commonly occurring metals interfere with this test. Hence it is of vital importance that the lead should be isolated in the form of a pure compound possessing quite definite and characteristic properties before the colorimetric estimation is proceeded with...

Jan 1, 1921

The purpose, basic data requirements and various analysis/modelling tools employed for geomechanical evaluation of mine-site conditions are overviewed. The impact and application of computer technology are dis- cussed. Broad guidelines and criteria are presented for establishment of a practical geomechanics data-base system to yield infor- mation suitable for mine design purposes. Future needs of the Australian mining in- dustry are examined.

Jan 1, 1983

By Ward S. C, Gardner J. H

In 1990, Alcoa of Australia Limited was elected to the Global 500 Roll of Honour of the United Nations Environment Program for the environmental management and rehabilitation of the bauxite mines in Western Australia. This award placed Alcoa in the international best practice category. The story of constant improvement spans more than 20 years from a 'trial and error' start to a strategically focussed and research driven program today. The main driving force has come from within the company, against a set of strong corporate values and a well publicised Vision based on 'excellence through quality'. Along the way public opinion, action group protests, increased legislative controls together with the professional competence of internal and external environmental resources have all played a part in arriving at the level of current environmental management and mine rehabilitation performance. There were numerous lessons learned here during the evolution and maintenance of best practice. These included: I . To work diligently in obtaining a vision or strategic intent on mine site rehabilitation and environmental management - don't be easily dissuaded.

Jan 1, 1995

By K Gottliebsen

Many hydrometallurgical and chemical processes produce large amounts of acid waste. This is illustrated by the copper S/X-E/W process used at the Mount Gordon mine in North Queensland, which produces a tank house bleed in the form of a concentrated sulphuric acid stream. The bleed stream is necessary to remove impurities such as iron that decrease the efficiency of the electrowinning process. However, this bleed stream comes at a high financial cost due to large quantities of make up sulphuric acid required as well as the need to neutralise the bleed stream prior to disposal. The present work describes the approach taken to develop a solvent extraction process for the selective recovery of sulphuric acid from copper tank house bleed liquor. The proposed extraction system was investigated using a branched long chain aliphatic tertiary amine tris(2-ethylhexyl)amine (TEHA) as the extractant, Shellsol 2046 as the diluent and octanol as a modifier. Computer simulations were used to determine the optimum operating conditions for the recovery process. It was found that the process was able to selectively recover up to 90 per cent of the sulphuric acid from the copper electrolyte. This is recovered as a pure aqueous acid stream at a concentration of up to 130 g/L that can be recycled back into the tank house circuit or other areas of the process. The raffinate acid concentration was reduced from 180 g/L to as low as 18 g/L, significantly reducing waste disposal and the environmental impact of the copper process. The equilibrium data and simulation results were also compared with an alternative extractant, CYANEXR 923. Finally the efficiency of the TEHA extraction system was investigated on a pilot-scale in a pulsed perforated plate column. This information was used in order to scale the process for an industrial application. The same methodology applied in this case study could be used to provide innovative and cost-effective solutions to waste streams encountered in other hydrometallurgical or chemical processes.

Jan 1, 2000

By Weber D, Knox PR

The criteria developed for the Argyle Diamond Mine process plant control system are reviewed. The control system installed is described along with a discussion of the method of implementation adopted. The control system was extensively tested prior to instal- lation at site. This approach led to signi- ficant time savings during plant commissioning and facilitated rapid escalation of plant production. The control system has performed satisfactorily with a high level of operator acceptance and basically satisfies the criteria Developed.

Jan 1, 1986

By Phillips D. N, Herbert H. K, Fletcher A. C, Lewis R. K

Quartzite is a common feedstock used for the production of silicon by reduction at high temperatures in a submerged electric arc furnace. Silica fume, formed as a by-product in this process, contains crystalline silica in the respirable fraction. The crystalline silica in the fume represents entrained quartz derived from unreacted quartzite raw material within the furnace. A knowledge of the fragmentation of quartzite feedstock, in response to thermal disaggregation in the furnace, is important in feedstock selection to help minimise (a) the amount of crystalline silica in fume, critical from an occupational health and safety perspective, and (b) impurity levels necessary to achieve the highest possible purity of product silicon. In this study, a series of quartzites has been assessed in terms of the above requirements and correlations drawn between mineralogical and chemical characteristics. Alkaline solubility correlates with grain-size and level of stored strain in the quartz matrix. Grain-size affects the surface area available for attack while stored strain enhances the chemical reactivity of the strained matrix as well as profoundly influencing the disaggregation and microfracturing characteristics of strained grains and, hence, available surface area for chemical reaction.

Jan 1, 1995

By N Boughen, P Ashworth, S Johns, C J. Yeats, A Littleboy

The ocean floor, often called the last frontier, is increasingly discussed in terms of its resource potential û from near shore building aggregate and placer deposits to massive sulfide orebodies in the deeper ocean. Consequently there is an increasing incentive to mine the seafloor. But, do we have the social license to explore and mine the seafloor? Does this nascent industry have support amongst the wider community? If not, why not? And what should be done? To answer some of these questions, the Wealth from Oceans National Research Flagship has explored the social viability of an expanded seafloor exploration and mining (SEM) industry inAustralia. The results show that there are significant geological and environmental data gaps and that, in the absence of sufficient information, stakeholder reaction to the prospect of an SEM industry expansion may be reactionary and negative. This uncertainty means that the perception of risk from the industry is variable and often dependent on individual values. The acceptability of an expansion to the SEM industry is currently precarious, in particular due to the high levels of uncertainty regarding the environmental impacts of seafloor activity. While there are existing federal regulatory frameworks and government processes for the licensing of seafloor mineral exploration and extraction, there is little precedent in the application and implementation of these regulations. The future viability of the industry will be highly dependant on AustraliaÆs ability to improve the knowledge-base underpinning its regulatory regime and also to generate open and transparent communication channels between stakeholders. It will also be dependent on the SEM industryÆs ability to communicate an acceptable value proposition to society. This proposition will need to include the relative impacts of terrestrial and marine mining, the alternative potential uses of the ocean and the multi-use conflict that SEM might engender. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Gray J, Krouse HR, Changkakoti A, Morton RD

A group of stratabound-stratiform Fe-Ba-Zn-Pb-Ag deposits within the La Minita mining district of Michoacan, southwest Mexico have been investigated. The results of the study show that these deposits were generated around submarine hot-springs issuing in a Cretaceous island-arc environment. The exhalative mineralization, which is both epigenetic and syngenetic in character, was developed above fault-systems which constituted the loci of both volcanism and subsequent hydrothermal systems.Fluid inclusion data suggest two hydrothermal events during ore mineralization, one at 240¦C and the other at 161 to 205¦C, with salinities between 2.1 and 12.8 wt.% NaCl equivalent. Stable isotope data support a marine origin for the ore-fluids, as well as, for carbon and sulfur. Strontium isotope data suggest that Sr in the barites was extracted from the volcanics and limestones by circulating seawater. The ore-depositional environment was one of shallow, sub-tropical marine character, where mineralization was in part geochemically controlled by carbonate reefal facies within the volcanic/pyroclastic suite.

Jan 1, 1990

By Deverux M

Heavy mineral deposits accumulate on shorelines with interrupted sediment input. Beach deposits, which form on shallowly dipping coastal plains, are most favourable. However, shallow shelves seaward of cliffed coastlines are known to contain economic deposits. Significantgeologicalconditions are defined, from review of the stratigraphic and geomorphic controls on known deposits , for heavy mineral accumulation on the Swan Coastal Plain.

Jan 1, 1986

The first continuous pressure disk filter took up industrial-scale operation in Germany in 1976. This paper comments on major components of pressure filter facilities from the point of view of industrial-plant suppliers. For lack of time aspects of economy have not been commented upon. The paper elucidates a number of process-engineering inter-relations. It outlines important development trends from the angle of a machine-building company.

Jan 1, 1989

By J E. Everett

When ore is being selected from a regularised block model, a common procedure is to accept as ore any block whose iron content exceeds a cut-off value, and whose content in each contaminant analyte is below an appropriate cut-off value. This method defines a quadrant within the multidimensional analyte space, such that any block lying within the quadrant is accepted as ore and any block lying outside the quadrant is rejected as waste. The cut-off levels can be adjusted to maximise ore tonnage at a target grade (or analyte vector). When the method is applied to a project comprising multiple pits with systematically differing grades, it is found that ore tonnage at target grade is maximised if different cut-off quadrants are used for the different pits. This is apparently illogical, because it implies that an ore block from one pit may be accepted as ore, but an identical block from another pit is rejected as waste, even when ore from both pits is to be blended into the same product and there are no production cost differences between the pits. The paradox is an example of the ætheory of the second bestÆ: if there are multiple conditions for optimality and one condition is broken, then obeying the other conditions may not be the best policy. The problem lies with the quadrant cut-off method, which is shown to be inconsistent even for selecting ore from a single pit. A criterion that is inconsistent cannot be optimal. It is shown that a linear composite cut-off function provides maximum ore tonnage, and that a single composite cut-off criterion is consistent and optimal over multiple pits. Further, it is shown that a composite cut-off function not only maximises ore tonnage at a specified composition, but also can be used to select ore so as to maximise project value, if marginal costs and values are available.CITATION:Everett, J E, 2013. Selection of ore from multiple pits, in Proceedings Iron Ore 2013 , pp 185-192 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

Hindustan Zinc Limited has successfully installed an In-Stream Analysis and Process Control System in the flotation section of the Balaria Lead-Zinc concentrator at Zawar Mines. The system comprises In-Stream Analysis to continuously monitor lead and zinc levels in feed, concentrates and tailings streams, field instrumentation for reagent distribution and flotation cell level control linked to a central Distributed Control System for supervisory control functions. An intensive training scheme was conducted by the system supplier for concentrator metallurgical and instrumentation engineers. Since commissioning of the system in April 1989, Hindustan Zinc has enjoyed the benefits of improved lead, zinc and silver recoveries, improved concentrate grade control and reduced reagent costs.

Jan 1, 1991

By Just G. D

The results of a geostatistical analysis of geochemical data obtained from field measurements are described in the paper. Q values derived from seismic signal rise times for different travel paths in the rock masses were used in the study. Cross-hole seismic measurements made at surface and underground sites formed the basis for the work. Geostatistical estimation of average l/Q values for area of the rock were compared with geological interpretions of rock type distributions. Reasonable correlations were obtained between the two methods of rock quality estimation.

Jan 1, 1988

By Floyd JM

Pilot plant trials showed the effective ness of the submerged lance SIROSMELT technology for altering the composition of iron blast furnace slags as a preliminary step to produc- tion of formed materials. Mixtures of oil and air were injected into a bath of liquid slag to provide the heat required for melting the additives and to provide very turbulent conditions which resulted in complete dissol- ution of added fluorspar within one minute and almost complete dissolution of silica in two minutes. Sulphur lost during injection was readily made up by addition of pyrite or pyrrhotite. A stable foam could be readily made and broken down and the foamed slag appeared suitable for extrusion or forming into shapes.

Jan 1, 1979

By Barnett LJ

The Kellogg slag fuming model is extended to apply to the Port Pirie plant which uses recuperative heating of secondary air. Exten- sive investigations of plant operations pro- vide parameters for use with the model, and verification that the resulting model provides simulation which is very close to actual plant performance. The model is used to_deter- mine optimum slag fuming operating conditions, and the results of several other investigations with the model are briefly described.

Jan 1, 1975

By Skinner A. J, Thoman B. C

The general structure of microprocessors and their method of use is described, and de- tails given of their application in two parti- cular examples of instrumentation for mineral concentrators. One is in a pulp density gauge, and using this example, the way in which a microprocessor-based unit can be made to be self-calibrating is described. The other is in an on-stream analysis detector for uranium in solvent, where a microprocessor is used to re- place a mini-computer.

Jan 1, 1977

By Teague JWS, Jung RF, Kadletz O, Jones DR, Jones CJ

A study of the passive treatment system for Hilton minewater revealed that it consists of four main process steps. The water, which contains soluble and particulate iron and zinc and is supersaturated with CO , is pumped to the surface and then passes throuqh a degassinq unit into settling ponds where larger particles of iron hydroxide, containing some adsorbed zinc, can settle out. The still turbid supernatant is pumped to the top of a hill, from where it is allowed to trickle in a broad sheet, releasing CO , towards an earthen channel in the valley below. Consequently the pArises from around 6 to 7.5. This in turn promotes further decrease in the concentration of soluble zinc by increased adsorption of zinc on to iron hydroxide particles. The channel then transports the water to the third process in the system - a 53 ML pond acting primarily as a flocculation-sedimentation basin. The clarified water overflows into a second channel, downstream of the pond, which constitutes the fourth process in the system. Here, copious quantities of filamentous algae further reduce zinc concentrations to acceptable levels before the water is collected for recycle into mine operations. The work reported here represents a detailed study of this system and describes the optimisation of the operation of each of the individual steps involved.

Jan 1, 1988

By M Biesinger, R St C Smart

Diagnosis of the surface chemical factors playing a part in flotation separation of a value sulfide phase requires measurement of the hydrophobic and hydrophilic species that are statistically different between the concentrate and tail streams. Statistical methods, based on the monolayer-sensitive time of flight secondary ion mass spectrometry (ToF-SIMS) technique, have been developed towards this ultimate aim by measuring hydrophobic species (collector ions, dimers and metal complexes, polysulfides) as well as hydrophobic metal ions, precipitates and added depressant species. Reliable identification of specific mineral particles is central to this statistical analysis. A chalcopyrite/pyrite/ sphalerite mineral mixture conditioned at pH 9 for 20 minutes to study transfer of Cu from chalcopyrite via solution to the other two mineral surfaces, since this mechanism can be responsible for their inadvertent flotation in copper recovery, showed no statistical difference in the copper intensities on pyrite and sphalerite (selected from Fe and Zn images) after this conditioning. Principal component analysis (PCA) identifies combinations of factors strongly correlated (positively or negatively) in images or spectra from sets of data. In images, PCA selects these correlations from the mass spectra recorded at each of 256 ¦ 256 pixels in a selected area of particles. In the image mode, PCA has proved to be a much better method of selecting particles by mineral phase with clearer definition of particle boundaries due to multi-variable recognition. It has clearly separated a statistical difference in copper intensities between the sphalerite and pyrite phases. The PCA method has been applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrating extensive CuOH and NiOH transfer between the chalcocite (Cc) and heazlewoodite (Hz) minerals. Statistical differences illustrate the important discriminating depressant action of NiOH in flotation despite the activation of Hz by Cu transfer. The adsorption of the collector at specifically-identified Cu sites has been elucidated by the study. Importantly, the statistical analysis has been able to confirm some mechanisms and deny others proposed to control recovery and selectivity giving more focus on the control factors.

Jan 1, 2005