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By R. S. Shoemaker

Mines are closed for two reasons; exhaustion of ore or insufficient price for the mineral. On the other hand, the reopening of an old mine can be the result of any one of three events; the discovery of more ore, a sudden rise in the price of the product or the use of a new low-cost method of mining or milling the ore. Examples of the latter would be the open-pitting of an orebody previously mined underground as recently happened at Tyrone, N.M., or the adoption of acid leaching of an old pit as has been done at Miami, Ariz. The unique native copper mines of the Keweenaw Peninsula of upper Michigan have not been so fortunate. These deposits, which were first worked by prehistoric Indians, have been mined continuously from the early 1840's to 1968 when the last mines of Calumet and Hecla were closed and the Ahmeek mill. still using eight Nordberg steam stamps, was shut down. There are two types of deposits from which native copper is obtained; amygdaloid, which is a lava flow, and conglomerate, a sedimentary deposit of sand, rock fragments and pebbles cemented together. "In the amygdaloid, the copper is disseminated, or distributed much like the raisins in a cake; but in the rich Calumet conglomerate, the copper is more like a malleable rope or thread cementing the pebbles together." (C. Harry Benedict. Red Metal: The Calumet and Hecla Story, (Ann Arbor, Michigan, 1952), p. 42.) These deposits produced almost all of the copper used by the North in the Civil War and were substantial contributors to the copper needs of the United States in both World Wars. Some were mined to depths of as much as 9500 ft along the dip of the vein structure and 7500 ft vertically. Few of the mines ever really became worked out, but became uneconomical because of depth, pinching of veins or grades which dropped to about 1%.

Jan 5, 1972

By Gerald V. Jergensen

Does an idea have merit? What does it cost to implement? Can the concept be implemented successfully? The ultimate proof is to try, then see. However, when there are many millions of dollars at stake, blindly building and trying requires considerable courage. Owners and investors in retrospect might choose other less complimentary words. So we might ask, "How might we establish the feasibility of an idea or concept before committing large sums of money to the ultimate test?" From this basic and prudent question, has evolved the engineering concept of the feasibility study. A feasibility study is simply a systematic evaluation of an idea or concept to determine the prospects for success. In a literal sense, a feasibility study considers an idea in terms of its data base, "builds" the idea on paper, "operates" that idea, calculates the cost and benefits, then measures the probable success in terms of some economic, technical or financial standard. Feasibility studies can be quite modest in scope yet provide useful insights as to the viability of an idea. A study might be initiated only to examine the completeness or validity of the metallurgical data base. Another study could be a search for a workable idea or solution to an already-identified possibly troublesome problem. In this latter case, the question, "Will it work?" may be far more important than, "How much will it cost?" Feasibility studies are sometimes global in scope, involving several dozens of specialists and examining an entire "grass roots" mining complex. Other studies may be less ambitious but equally important in examining an expansion proposal or developing new operating techniques. Studies may be commissioned to remove plant bottle-necks, solve maintenance problems and so on. The terms study and feasibility study are used interchangeably in this chapter. They denote a systematic method to examine a proposed concept or idea. DATA BASE Typically, studies are initiated with a minimum amount of specific information and a maximum number of assumptions. As the work proceeds and the data base expands, assumptions are replaced

Jan 1, 1982

By Tormod Forland

FROM equilibrium measurements on the system NaF-Na 3A l Fo-A 1 2 O 3-Na CO 3-CO 2 with high contents of NaF, Forland, Storegraven, and Urnesl concluded that complexes are formed containing two oxygen, three aluminum, and a less defined number of fluorine per complex. The same number of oxygen atoms per complex was also found by cryoscopic measurements for mixtures high in NaALF 6. In a recent paper by Stokes: some other complex ions, Al2O2F42- and AlOF2-, have been suggested. Here an additional argument in favor of the complex ALO2F. suggested by Forland, Storegraven, and Urnes will be given. When fused Na3AlF6 containing some A12O3, is cooled slowly, the solid phase will consist of the two components as separate phases. The melting point and the heat of fusion of Al2O3 are so high that this component will form the stable solid phase even though in the liquid state the complex may have a high stability. If, however, the fused mixture is quenched, the decomposition of the oxygen-containing complex and the formation of solid Al2O3 does not proceed fast enough, and a solid solution of A12O3 in Na3AlF6 is obtained. Zintel and Morawietz3 obtained cryolite containing 10 pct AL2O3 in this way. The density and the lattice parameters of the A12O3 containing cryolite were also measured, and from this it was concluded that the Al2O3 enters the cryolite lattice as Al3AlO0 groups replacing Na3AlF6 groups. However, the experimental data could as well be explained by assuming that one Na+ ion and two of its neighboring F- ions are replaced by one Al3+ ion and two O2- ions. This may be pictured schematically as: F F F F F F F Al F Na F Al F ,-Na+ + Al8+ F Al 0 A1 0 A1 F F F F —2 F- + 2O2- F F F solid cryolite cryolite-alumina solid solution This means that the complex in the solid solution, derived from X-ray and density measurements, is the same as that which Forland, Storegraven, and Urnes derived from equilibrium measurements in the liquid state. References IT. Forland, H. Storegraven, and S. Urnes: Ztsch. fur anorgan-ische und allgemeine Chemie, 1955, vol. 279, p. 205. 2J. J. Stokes: AIME Trans. To be pubhshed. s E. Zintel and W. Morawietz: Ztsch. pubhshed.fur anorganische und allgemeine Chemie, 1939, vol. 240, p. 145.

Jan 1, 1958

By T. R. Braithwaite

The brief comments made in this chapter deal mainly with shaft sinking, but don't assume that freezing techniques apply only to shaft sinking. They can be used on tunnel work, on such things as liquid gas storage in sediment, and I think you will probably see other applications for it as we go along. The method was first developed in 1883 and was used to sink shallow shafts through water-bearing overburden in Germany and in England. One of the early shafts was in Germany and was sunk by freezing to 310-ft depth. The project required 17 months for drilling, roughly 5 1/2 months for freezing, and another 7 months for sinking, giving an average progress of 10 ½ fpm. Fortunately there have been numerous improvements and new developments in this technique through the years. With equipment and techniques available today, we can take a 20-ft-diam shaft down through 2000 ft of water-saturated overburden and the time schedule runs roughly 4 months for site preparation, freeze-hole drilling, installing the casings, and setting up the plant; 4 ½ months for freezing; and 6 months for excavating and installing permanent linings. This gives a progress rate of about 140 fpm, on average. I might qualify that a little in that the special linings that are required for some formations can affect the time. If it's straightforward sinking where one can use a heavy concrete lining, up to 630-640 fpm may be achieved in a shaft; but with special cast-iron tubbing or types like that, 5 fpd is pretty good progress, so the lining does affect the time. The freezing method is used mainly for sinking shafts through unstable water-bearing formations which cannot be grouted either effectively or economically and which are too deep to enclose in pile casing. Even with overburden, grouting methods available today can handle roughly 100 lb water pressure; in the range of, say, 100 to 150 ft from the surface, it's very often best to grout 40 or 50 ft. You normally drive a pile casing and go through it. Below that range, freezing is very often the economical

Jan 1, 1970

By Lauren A. Wright

SINCE the early nineteen-thirties the production of talc* in California has increased five-fold to a yield in 1947 of about 76,000 tons (fig. 1); conse- .' Unless otherwise qualified, the term "talc" in this paper will imply a mixture of the pure talc with such related minerals as commonly occur in the commercial material. quently the state is now one of the nation's three principal talc producers. The 1947 output, which represented about one-sixth of the national total for that year, was approximately equal to production from Vermont, and was second in value to that from New York. New York has an annual output of about 130,000 tons. Three factors have been mainly responsible for the expansion of talc production in California. (1) Technical advances and innovations, particularly in the ceramic industry, have increased the demand for certain California talcs. The nation's high-qual- LAUREN A. WRIGHT, Junior Member AIME, is Associate Geologist, California Division of Mines, San Francisco, Calif. Los Angeles Meeting, October 1948. San Francisco Meeting, February 1949. TP 2622 H. Discussion of this paper (2 copies) may be sent to Transactions AIME before Feb. 28, 1950. Manuscripts received Dec. 7, 1948; revision received Aug. 29, 1949. This paper is Contribution No. 508 of the Division of Geological Sciences, California Institute of Technology, Pasadena, Calif. the industry, mainly through demand for the urgently needed steatite. Fibrous talc, used as a paint extender by the armed forces, also was produced in quantity. (3) Expanding western industry has continued to draw heavily on California talc deposits, and has extended the upward production trend into the postwar period. Considerably more than half of California's current talc output is used as ceramic raw material. The paint, rubber, paper, and textile industries are the more important consumers of the remainder. Smaller amounts are used as insecticide carriers, and in cosmetics, and various minor industrial applications. During World War I1 the principal steatite deposits were studied in detail by members of the U. S. Geological Survey; other sources of commercial talc in the state have in the past received but scant geologic attention. The following discussion is essentially a preliminary report based on research currently in progress by the California Division of Mines, and includes a brief outline of previous steatite studies by the U. S. Geological Survey. Distribution of California Talc Deposits: The principal talc resources of both California and Nevada are confined to an elongate belt that extends from the vicinity of Baker, in north-central San Bernardino County, northwestward to include the southern Death Valley region, the Inyo Range, and the Palmetto-Oasis district of western Nevada (fig. 2). This belt, of which all but the northernmost tip lies in California, is approximately 200 miles long and 30 miles in average width. Included in the belt are four contrasting areas. The deposits within each area are geologically similar and yield talcs that have characteristic properties and applications. Three of these local "talc provinces" lie within California's portion of the talc-

Jan 1, 1951

By Lauren A. Wright

SINCE the early nineteen-thirties the production of talc* in California has increased five-fold to a yield in 1947 of about 76,000 tons (fig. 1); conse- .' Unless otherwise qualified, the term "talc" in this paper will imply a mixture of the pure talc with such related minerals as commonly occur in the commercial material. quently the state is now one of the nation's three principal talc producers. The 1947 output, which represented about one-sixth of the national total for that year, was approximately equal to production from Vermont, and was second in value to that from New York. New York has an annual output of about 130,000 tons. Three factors have been mainly responsible for the expansion of talc production in California. (1) Technical advances and innovations, particularly in the ceramic industry, have increased the demand for certain California talcs. The nation's high-qual- LAUREN A. WRIGHT, Junior Member AIME, is Associate Geologist, California Division of Mines, San Francisco, Calif. Los Angeles Meeting, October 1948. San Francisco Meeting, February 1949. TP 2622 H. Discussion of this paper (2 copies) may be sent to Transactions AIME before Feb. 28, 1950. Manuscripts received Dec. 7, 1948; revision received Aug. 29, 1949. This paper is Contribution No. 508 of the Division of Geological Sciences, California Institute of Technology, Pasadena, Calif. the industry, mainly through demand for the urgently needed steatite. Fibrous talc, used as a paint extender by the armed forces, also was produced in quantity. (3) Expanding western industry has continued to draw heavily on California talc deposits, and has extended the upward production trend into the postwar period. Considerably more than half of California's current talc output is used as ceramic raw material. The paint, rubber, paper, and textile industries are the more important consumers of the remainder. Smaller amounts are used as insecticide carriers, and in cosmetics, and various minor industrial applications. During World War I1 the principal steatite deposits were studied in detail by members of the U. S. Geological Survey; other sources of commercial talc in the state have in the past received but scant geologic attention. The following discussion is essentially a preliminary report based on research currently in progress by the California Division of Mines, and includes a brief outline of previous steatite studies by the U. S. Geological Survey. Distribution of California Talc Deposits: The principal talc resources of both California and Nevada are confined to an elongate belt that extends from the vicinity of Baker, in north-central San Bernardino County, northwestward to include the southern Death Valley region, the Inyo Range, and the Palmetto-Oasis district of western Nevada (fig. 2). This belt, of which all but the northernmost tip lies in California, is approximately 200 miles long and 30 miles in average width. Included in the belt are four contrasting areas. The deposits within each area are geologically similar and yield talcs that have characteristic properties and applications. Three of these local "talc provinces" lie within California's portion of the talc-

Jan 1, 1951

By Merrill F. McCarty, Robert S. Olson

New organic flocculants of high-molecular weight are replacing lime, glue, and starch in liquid- solid separation. Of these synthetic materials, polyacrylamides are outstanding. Polyacrylamides form a class of compounds varying widely in composition and activity. Separan 2610H, one of the first of these flocculants' released to the mining industry in 1954, is described' as a high- molecular weight polymer of acrylamide with or without a copolymer material and with some replacement of amide by carboxylic groups.

Jan 1, 1959

By E. W. Newman

DURING 1943 and 1944, there was an urgent need for certain grades of optical calcite (Iceland spar) for instruments for military uses. To find a supply of this material, prospecting was carried out in Montana, California and Colorado. Although some production was obtained by the work in California, the best results were from prospecting the large calcite veins of south central Montana. The bulk of the optical calcite mined during World War II has come from that area. The Bureau of Mines took an active part in the search for optical calcite in Montana. It examined most of the known calcite veins in the 70-mile distance between Wilsall, on the Shields River, and Absarokee, on the Stillwater River, and conducted exploration on several of the deposits. The Geological Survey also took an active part by mapping many of the veins. Actual mining of the calcite was performed at first by Calcite Operators, Inc., and later by the Metals Reserve Co., through an agent. A sorting plant was established at Clyde Park, where custom material could be sold. These activities stimulated mining by private operators. To be suitable for military uses, the calcite mined had to meet rigid specifications as to both size and quality. Individual crystals had to be clear and transparent and if in the form of rhombs had to measure at least 7/8 in. on each edge. Some color and a few inclusions in the calcite were allowable, but material with incipient or developed cleavages, or showing twinning other than parallel to the base, was unacceptable. HISTORY OF DEPOSITS The existence of large veins of calcite in south central Montana has long been known, and for many years the farmers of this region have used the common vein calcite for producing grit for chicken feed. According to reports, the first optical calcite produced from Montana came from the Cartwright deposit near Greycliff,1 but until recently the mining of optical calcite in Montana has been limited to spasmodic searching for small crystals suitable for making nicol prisms for saccharimeters and microscopes, or for mineral specimens. The possible need of substantial amounts of optical calcite for military uses began to appear late in 1942 and early in 1943, therefore the Polaroid company began searching for a source of supply in Montana and California. Work on the Wade property near Clyde Park was started on a small scale in the fall of 1942, by A. H. Hansen, of Clyde Park. During the winter and spring of 1943, a modest quantity of optical calcite was mined and shipped to the Polaroid Corporation, Cambridge, Mass. Most of this was produced from the "Hansen vug," which was found close to the surface. Early in the summer of 1943, mining on the Wade property was undertaken by Calcite Operators, Inc., a company organized for mining optical calcite from the Montana and California deposits. This com-

Jan 1, 1945

By Stanley M. Miller

The probabilistic nature of appropriate geologic variables can be included in analyzing the stability of potential slope failure modes. Random variables in the two-dimensional plane shear analysis of a specified structural discontinuity include the shear strength and waviness angle of the discontinuity and, in some cases, the rock mass density. Estimated probability density functions that describe these random variables are combined by Fourier analysis to produce an estimate of the safety factor probability density function, which appears to approximate a gamma distribution. The probability that sliding will occur along the specified structure is equal to the area under this density function where the safety factor is less than one.

Jan 1, 1982

By R. W. Raymond

AT the Pittsburg meeting of the Institute, in March, 1910, the death of Mr. Metcalf was announced, and Col. H. P. Bope, of Pittsburg, delivered in memory of him a brief but eloquent address, which, though expressing the sorrow of Mr. Metcalf's friends, and, in general terms,. the debt of gratitude which his country and his profession owed to him, was not intended to be a complete survey of his life and work. With Colonel Bope's permission, and with the aid of some of the statements in his address, I substitute for it, in our Transactions, this more detailed, yet still inadequate memorial. As Colonel Bope justly remarked, the men who could do justice to this theme-such men, as Jones, Chalfant, Bennett, Oliver, and Park-passed away before Metcalf, leaving him almost the last of the generation of great steel-makers who made Pittsburg the Sheffield of America, and who discharged a double function, as the rear-guard of the old metallurgical practice and the van-guard of the new. I knew many of them; would that I were better qualified to celebrate their achievements. William Metcalf was born Sept. 3, 1838, at Pittsburg, Pa., where his father, Orlando Metcalf, was an eminent member of the bar. At the age, of sixteen, he entered the Rensselaer Polytechnic Institute, at Troy, N. Y., from which he was graduated in June, 1858. Returning to his native city, he became an assistant engineer in the Fort Pitt Foundry, of which. he was made Superintendent in 1859. This famous establishment produced the largest castings and heaviest machinery then known in the United States;-and Mr. Metcalf's intense, intelligent and incessant study of his business prepared him as a manufacturer for a patriotic service to his country more valuable than, as a soldier, he could have rendered in the field. The call came in 1862, when the government needed, above all things, a supply of field, naval and siege artillery. The

Apr 1, 1911

By Clemens Jones

The peculiar property of the lode-stone has been known for many centuries. It was very early observed that, by contact with it, iron is magnetized; and it is needless to dwell here upon the history allied to this discovery, now constituting the wonderful science of magnetism. Deposits of magnetic ore are distributed all over the world. The ore is sometimes very rich and comparatively free from gangue, sometimes sparsely disseminated in the native rock. These bodies of lean ore often cover large areas. Modern ingenuity has utilized the principle of the magrtet, originally derived from the ore itself, and really belonging to the time of Plato and Theophrastus, to separate the magnetic ore-particles from the rock which has previously been crushed. This process recovers the ore in the state of a concentrate very rich in iron and, in some cases, desirable for Bessemer purposes. The magnetic separator is no longer a novelty. It was only at the last meeting of the Institute in New York, that Messrs. Birkinbine and Edison (Trans., xvii., 728) and Mr. Robert Cook (Ib., 599) described some of' the principal designs of apparatus in use. E. S. Dana classifies the natural magnetic minerals in the following order: magnetite, pyrrhotite, franklinite, almandite and minerals " containing considerable FeO." Of these, ferroso-ferric oxide, or magnetite, is the type. The proportionate amount of ferrous oxide essential to magnetize the compound, is not established. Ferrous oxide appears to be the only magnetic oxide of iron. Tissandier (Compt. Rend., lxxiv., 531) produced ferrous oxide in the anhydrous state, by the action of carbon dioxide on pure iron at a red heat, according to the equation : Fe + CO2 = FeO + CO. This is black, crystalline and magnetic. Heated to redness in the air, it is converted into Fe3O4. Sidot (Compt. Rend., lxvii., 175) has also produced an oxide exhibiting magnetic polarity, by heating ferric oxide to a temperature

Jan 1, 1891

As 1970 develops and industrial minerals stand at a crucial point in their progress, research and development programs appear to be the key needed to open up new uses for each mineral's future growth. Radically new processes are needed for making a host of new synthetic products from mineral raw materials which will more nearly meet the demanding specifications required for high performance in space, nuclear and defense applications. Consumer applications for high temperature environments will be needed and are important for continuing the nations economic mineral position. In addition, an acute materials problem limits the effectiveness of some of the newer concepts for controlling ail pollution. What is needed then, according to a report printed by the National Academy of Sciences, is the carefully planned development of a limited number of major centers at universities to provide for both basic research and training of personnel; the nurturing of interdisciplinary mechanisms for research and problem solving within these centers; the achieving of a better balance between physics and chemistry within research, emphasizing the chemical aspects of the material sciences; and the enhancement of a broader professional identity by unifying the various disciplines involved into a possible federation of existing societies which have an interest in the problems. [EE] presents its 1969 annual industrial minerals review, where individual authors evaluate the status of each industrial mineral and recount the major developments which occurred during the year.

Jan 1, 1970

By L. D. Frink

THOSE actively interested in mining are fully aware of the ever-increasing difficulty of making conditions such that efficient work can be clone in underground openings, especially as higher rock temperatures are encountered in depth. This is also true where an effort is being made to cut down the burden of overhead expense by working headings 24 hr. in a day if blasting is done as often as is possible in that time. That the conditions resulting from both these causes have driven the native-born Americans from the mines and that their places have been taken by less efficient foreigners is a fact that we must all admit. The great war now being fought in Europe and the educational qualification clause written into our immigration law by the last Congress will probably limit very materially the supply of labor, such as we are now using in our mines, and will force upon mine operators the necessity of making this work appeal again to Americans. Metal tubing, with blower or exhaust fans, has long been used in supplying air to dead ends where natural ventilation is impossible, or in driving the smoke from such places, or in doing both, as the need might be. Here in Butte we have now come to use canvas tubing very extensively and find that it has many advantages not possessed by the metal. The use of flexible tubing is not new, but it has not been generally used in mining operations. Recent improvements, however, in the canvas itself and in the jointing of sections and manner of suspension have so increased its usefulness that it promises to add much to the efficiency of mining. There is now on the market a product that is impervious to air, is fireproof, and has a system of jointing which, permits it to be put up or taken clown in a few seconds. In this article an effort will be made to explain the manner in which canvas tubing is being used in the North Butte company's operations at Butte, Mont. The accompanying photographs will, I hope, help make clear what may be done with this material.

Jan 1, 1918

By John P. Goheen

Considerable work has been done in developing a pyrometer to measure the temperature of molten brasses, bronzes, and aluminum in the crucible. On account of the high melting points and the amount of zinc and sulfurous fumes given off from molten brasses, the conditions are somewhat severe for a thermocouple of standard design; but satisfactory results are obtained with a portable pyrometer, 3 ft. (0.9 m.) of connecting lead wire, and a special 5-ft. nickel-nickel chromium thermocouple, composed of rods 1/4in. (6.35 mm.) in diameter. The lower 12 or 24 in., as desired, may be made detachable so that new tips may be connected at little trouble or expense. The portable instrument need not be of the extreme high-resistance type, as the movable parts of the galvanometer of a lower resistance instrument may be better constxucted to withstand the continuous handling such an instrument receives. Platinum-platinum rhodium thermocouples, protected with porcelain and graphite tubes, have been used, but the lag in registering the temperature is too great. It has been found that the range of temperature for various brasses is as follows: Red brasses...............2200-2250" F. (1205-1234" C.) Yellow brasses............2250-2400" F. (1234-1318' C.) Bronzes..................2300-2550" F. (1260-1400" C.) A recent test with a portable pyrometer having a range of 2600" F. with a bare 1/4 in. heavy exposed couple 5 it. long and a handle attached at the upper end showed that the temperatures of molten aluminum under varying conditions in an oil-fired crucible furnace and one of the Simplex type were as follows: CRUCIBLE, OIL-FIRED FURNACE SIMPLEX FURNACE Temperature of metal in furnace....... 1540" F. (837" C.) 1530" F. (834" C.) Temperature in ladle after skimming at furnace......................... 1480" F. (805" C.) 1440" F. (784" C.) Temperature in ladle after skimming at floor near mold................... 1440" F. (784" C.) 1430' F. (778" C.)

Jan 1, 1923

By John P. Goheen

Considerable work has been done in developing a pyrometer to measure the temperature of molten brasses, bronzes, and aluminum in the crucible. On account of the high melting points and the amount of zinc and sulfurous fumes given off from molten brasses, the conditions are somewhat severe for a thermocouple of standard design; but satisfactory results are obtained with a portable pyrometer, 3 ft. (0.9 m.) of connecting lead wire, and a special 5-ft. nickel-nickel chromium thermocouple, composed of rods 1/4in. (6.35 mm.) in diameter. The lower 12 or 24 in., as desired, may be made detachable so that new tips may be connected at little trouble or expense. The portable instrument need not be of the extreme high-resistance type, as the movable parts of the galvanometer of a lower resistance instrument may be better constxucted to withstand the continuous handling such an instrument receives. Platinum-platinum rhodium thermocouples, protected with porcelain and graphite tubes, have been used, but the lag in registering the temperature is too great. It has been found that the range of temperature for various brasses is as follows: Red brasses...............2200-2250" F. (1205-1234" C.) Yellow brasses............2250-2400" F. (1234-1318' C.) Bronzes..................2300-2550" F. (1260-1400" C.) A recent test with a portable pyrometer having a range of 2600" F. with a bare 1/4 in. heavy exposed couple 5 it. long and a handle attached at the upper end showed that the temperatures of molten aluminum under varying conditions in an oil-fired crucible furnace and one of the Simplex type were as follows: CRUCIBLE, OIL-FIRED FURNACE SIMPLEX FURNACE Temperature of metal in furnace....... 1540" F. (837" C.) 1530" F. (834" C.) Temperature in ladle after skimming at furnace......................... 1480" F. (805" C.) 1440" F. (784" C.) Temperature in ladle after skimming at floor near mold................... 1440" F. (784" C.) 1430' F. (778" C.)

Jan 1, 1923

By Charles Pack

Die castings may be defined as metal castings made by forcing molten metal, under pressure, into a metallic mold or die. It is necessary to keep this definition in mind to avoid confusing this process with other permanent-mold casting processes. The fundamental principles of the process have been known and practised many years. The simplest application is embodied in the modern linotype machine in which molten metal (usually tin-lead alloy) is forced under pressure into a metallic mold. The pressure is derived from a piston and cylinder immersed in the molten metal. Progress in the art of die casting may conveniently be divided into three groups: Machine for imparting pressure to the metal, material for the die or mold, casting alloys. The problem of delivering molten metal under pressure into a die is comparatively simple, when dealing with low-fusing-point alloys, as the alloys of lead and tin, but it is much more complicated when dealing with metals of higher fusing points, such as the alloys of zinc, aluminum, and copper. Although the art of die casting is comparatively new and, to a large extent, unknown, the records of the patent office are replete with patents on the subject. Fig. 1 shows the Underwood machine patented in 1902; this is probably one of the first machines designed for the production of commercial die castings. The relation of this machine to the linotype casting machine is clearly apparent. A cylinder and piston are immersed in the molten metal, the application of power to this piston forcing the molten metal, under pressure, into the mold or die. The Doehler machine, Fig. 2, patented in 1907, is based on the same general principles. This machine is used to a large extent at the present time, throughout the United States, for the production of zinc, tin, and lead alloy die castings. In the machine shown in Fig. 3, patented by Doehler in 1910, compressed air is used for forcing the metal into the die. In Fig. 4 is shown another of this type of machine. Here compressed air is applied to the surface of the molten metal to force it into the die. In a machine patented by Chandler in 1914, shown in Fig. 5, the

Jan 1, 1919

By Donald R. Mason, Daniel F. O’Kane

DIFFERENTIAL thermal analysis measurements have been used to determine the ZnTe-In2Te3 pseudo-binary phase diagram. Since ZnTe and In2Te3 are both semiconductors, any intermediate compounds formed in this system should also be semiconductors according to the rules delineated by Mooser and pearson.1 The compound ZnIn2Te4 was first reported by Hahn et a1.2 and it has subsequently been prepared and characterized electrically by several workers. A brief summary of this work has been presented by Mason and O'Kane3 who also report that the compound appeared to melt peritec-tically. The Zn-Te phase diagram has been investigated by Kulwicki4 who found that ZnTe has a melting point of 1290° + 2°C. The In-Te diagram published in Hansen' contains significant errors, and has been redetermined by Grochowski et al.6 However, both sources agree that the melting point of In2Te3 is 667°C, with the latter authors reporting the previously observed solid-solid transformation occurring at about 550°C. Hahn ef al.2 reported lattice-parameter values for the ZnTe-In2Te3 system. The 67 mole pct ZnTe-33 mole pct In2Te3 composition was the only

Jan 1, 1965

By Charles Barrett

RECRYSTALLIZATION textures-the orientations of grains after recrys-tallization-have been studied extensively not only because of their metallurgical importance but also because of the information they yield regarding the atomic movements during recrystallization. Recrystallized grains must possess the same orientations as the submicroscopic nuclei from which they have grown, and thus they offer a direct road by which experimenters can penetrate the submicroscopic realm. Many perplexing results have come of these studies, but one of the most striking has been the apparent difference in behavior between single crystals and polycrystalline grains. For example, Burgers and Louwerse have shown' that when single crystals of aluminum are deformed by compression and are recrystallized (at 600° C.) the new grains appear with orientations that are different from the orientations of the deformed crystal in which they grew; but polycrystalline specimens, on the other hand, appear to have a [110] fiber texture both before and after recrystal-lization and thus to retain their texture during recrystallization. This apparent difference between the habits of single crystals and small grains is the subject of the first part of the present research and has been explained by findings reported herein. A similar situation appears to exist for aluminum when elongated or drawn into wires, for single crystals alter their orientation2,3 and polycrystalline wires retain their texture 4,1 6 upon recrystallization after elongation (at least with high-purity alumi-num), and it is possible that the explanation found in this paper for compression can be extended to cover elongation and other types of deformation as well. The second part of this paper deals with the theory of recrystallization textures. In the most successful theory for aluminum recrystallized after compression,1 much weight is given to the orientation of highly stressed nuclei in the deformed material. Taylor's "local distortions" are assumed to exist along the slip planes where displacement has occurred, consisting of fragments rotated in a specific way with reference to the slip plane and slip direction; namely, about an axis lying in the slip plane perpendicular to the slip direction. 1,7,8,9

Jan 1, 1940

By Hans Lundberg, Theodor Zuschlag

Based upon an instrumental improvement, a new development has taken place in the art of electrical prospecting, and some remarkable results have already been obtained with regard to potential exploration. In order to visualize the importance of this development, it is deemed advisable to review briefly the fundamental facts about potential surveys. Potential exploration may be carried out qualitatively or quantitatively. Qualitative investigations are made by determining and plotting on a map points of equal potential, whereby any anomalies are revealed, without, however, much clue to their magnitude. Quantitative investigations determine the variations of potential or potential drop, and thus show not only the location of the anomalies, but also their magnitude. Figs. 1 to 6 illustrate the influence of simple types of ground inhomo-geneities, assuming one effective exciter potential only. Such a condition can be closely realized by connecting an electric current source to two electrodes, one of which is located at a great distance. Assuming uniform ground resistivity, the resultant potential distribution mar be represented by concentric spheres. Any change from the normal condition causes a characteristic distortion of the spheres, which becomes different for different types of resistivity variation. The series of Figs. la to 6a illustrates schematically results of qualitative investigations and series lb to 6b results of quantitative investigations. Figs. 1 and 2 picture the well-known case of local resistivity variations normally encountered in ore prospecting. Figs. 3 and 4 show the reactions caused by more or less vertical resistivity contacts and Figs. 5 and 6 refer to the problem of ground-water and bedrock investigations where the resistivity contact is horizontal or nearly SO. It is evident from Figs. 5a and 6a that qualitative measurements do not permit an identification of such general geological features as widespread horizontal strata, because the resultant contraction or expansion of the equipotential circles at the surface cannot be recognized without quantitative determinations. On the other hand, qualitative measurements are well suited for the exploration of local or lateral resistivity

Jan 1, 1932

By Charles S. Barrett

Recrystallization textures—thc orientations of grains after recrys-tallization—have been studied extensively not only because of their metallurgical importance but also because of the information they yield regarding the atomic movements during reerystallization. Recrystallized grains must possess the same orientations as the submicroscopic nuclei from which they have grown, and thus they offer a direet road by which experimenters can penetrate the submicroscopic realm. Many perplexing results have come of these studies, but one of the most striking has been the apparent difference in behavior between single crystals and polyerystalline grains. For example, Burgers and Louwerse have shown1 that when single crystals of aluminum are deformed by compression and are reerystallized (at 600' C.) the new grains appear with orientations that are different from the orientations of the deformed crystal in which they grew; but polycrystalline specimens, on the other hand, appear to have a [110] fiber texture both before and after reerystallization and thus to retain their texture during recrystallization. This apparent difference between the habits of single crystals and small grains is the subject of the first part of the present research and has been explained by findings reported herein. A similar situation appears to exist for aluminum when elongated or drawn into wires, for single crystals alter their orientation 2,3 and polycrystalline wires retain their texture"5*" upon recrystallization after elongation (at least with high-purity aluminum), and it is possible that the explanation found in this paper for compression can be extended to cover elongatioil and other types of deformation as well. The second part of this paper deals with the theory of reerystallization textures. In the most successful theory for aluminum reerystallized after compression,1 much weight is given to the orientation of highly stressed nuclei in the deformed material. Taylor's "local distortions" arc assumed to exist along the slip planes where displacement has occurred, consisting of fragments rotated in a specific way with reference to the slip plane and slip direction; namely, about an axis lying in the slip plane perpendicular to the slip direction.1,7,89

Jan 1, 1940