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By G. Bjorling

The opening oxidation of a hydrometallurgical treatment of natural sulphides must for several reasons be so controlled that a maximum of the sulphide sulphur is transformed into elemental. If the oxidation is performed at low pressure and moderate temperatures and with mild reagents such as diluted nitric acid (or ferric or cupric chloride) the just mentioned condition is realized and it has been found possible to conduct the reaction so that solutions are obtained from which the metals can be recovered and the reagents required for the dissolution are regenerated. Experiments in laboratory scale with nitric-acid promoted oxidation have shown that this method is applicable to several types of raw materials, and in combination with electrodialysis both for partial neutralization and for final regeneration of the circulating acid can the requirements of low consumption of chemical reagents and formation of harmless residues be well fulfilled. The metals can be recovered as cathodic deposits or as hydroxides, and the method should be applicable also for low grade ores and concentrates. Although oxidation of sulphides by ferric or cupric ions has the advantage that it can be performed in open vessels it seems well worth the complication of working with nitric acid promotion in a low-pressure autoclave. Also complex sulphidic, oxidic and metallic materials can be treated.

Jan 1, 1973

A bibliography of the use of pulverized coal for the years 1917 and 1918 has been compiled by the Library for the Institute. It comprises three typewritten sheets. Copies may be obtained by those interested at $2 per copy.

Jan 5, 1919

By Cadwallader Jr. Evans

THE Hudson Coal Co. is an anthracite concern with 22 mines, employing, when operating full, something around 18,000 men. We have, there-fore, necessity for a large number of subordinate officials and for a considerable number of major officials, and we carry on two separate courses of training in our endeavor to develop these two groups. The one in which college professors will be most interested is that which we call our two-year course. A man to be eligible for it must have completed a college course at one of several institutions from which we regularly seek our men, but he need not necessarily be a graduate of the course in mining, although we have been giving prefer-ence to graduates of schools of mines. Each year we take a number of men from these col-leges, sometimes five, six or seven, and put them through this two-year course, which is carefully. laid out so as to give them experience in the various details of our business. A schedule of the typical two-year course laid out for a man who started in July, 1925 shows that he was employed in the mining engineering department first for a period of four months, then for six months in inside mine work, three months in the mechanical and electrical departments, two months in "preparation," which with us means the cleaning of our product for market, one month in the study of statistics, one month on transportation and safety, and seven months in loading coal at the face, working with a shovel, making twenty-four months in all. We started this training in 1915 and in the first year we gave six months in the mining engineering depart-ment. We have now cut that to four. We gave six months in inside mine work and have continued that. We gave four months in the mechanical department, which is now cut to three; five months in preparation, now cut to two; two months in statistics, now cut to one; one month on transportation and safety which re-mains, and we have added seven months in loading coal. This last class of work gives them experience with the miner at the mining face.

Jan 7, 1928

By C. F. Willis

The time is no longer when a man can act as an independent unit; the appreciation of the interdependence of one man upon another has emphasized the importance of the social unit. Epidemics have made us recognize that even a man's health is not distinctly his own to control as he pleases. The physical examination of workmen previous to employment started with an effort to prevent the spread of tuberculosis, for tuberculosis may be detected in its early stages and cured. But it was soon found that many other diseases were detected and the saving of lives made possible. The physical examination does not mean the elimination of the unfit—on that basis it would utterly fail—but rather the measuring of a man's physical fitness and placing the man where he can do the best for himself, his fellow worker, and the company. Industry as a whole cannot expect to live up to the standard of physical examination set for the army, nor should it expect to do so, for in all branches of industry there are types of work that do not require the same amount of endurance as does army work, and the lacing of men with physical limitations in the work for which they are capable permits a higher average of physical fitness for the work requiring physical excellence. Objects of Physical Examination The objects of physical examination are: The early detection of illness, particularly at a time when a full restoration of health is possible; the protection of employees from infection caused by working in contact with contagious diseases; the discovery of a man's physical limitations, in so far as his possibility for rendering good service is concerned; assistance to the safety movement by eliminating association in hazardous occupations with men whose physical condition renders them likely to accident to themselves and others; and the lessening of time lost by sickness. Statistics issued by the United States Department of Labor show that 22.54 per cent. of idleness is caused by sickness, with an average number of 7.71 weeks idle; whereas only 1.66 per cent. is caused by acci-

Jan 1, 1920

By B. Fernow

The question of preserving the forests in this country is an impor tant one, not only to trades using wood but to the whole nation, and though agitated for many years has not received that general consid eration which its broad bearing demands. Those who are interested in and working for reform in the treat ment of American forests are looking to the government for help, suggesting the creation of a commission to study the conditions of forests at home and abroad, and hope that a sound system of manag ing the woodlands will be thereby inaugurated. This reform will cost time and money, all the more because the government can bring to bear upon private owners hardly any power but that of good example and encouragement. There is, however, another aspect of the question to which I wish to draw your attention, namely; the more economical use of the valuable material which our forests offer, a more careful and ex haustive utilization of its constituents in all cases where wood or its products are applied. The wasteful consumption of wood in the United States is in every way so enormous as to justify the statement that by merely adopting an economical husbandry in this particular the destruction of forests might be delayed for many years, while the neglect of this imperatively needed and immediately practicable reform deprives legislative remedies of much of their value. In this regard I wish to draw the attention of metallurgists, especially those who are in terested in the manufacture of charcoal iron, to a more economical and profitable use of wood in iron manufacture. For thousands of years of human history wood was the main, nay, the only material used for fuel. Mineral coal came into use only in the fourteenth century, and it is only recently that it has largely displaced its less carbonaceous predecessor as fuel. The art of concentrating carbon in the form of charcoal for easier transportation and readier use in distant places was, according to Pliny, known to the ancients long before Christ., and was practiced in all countries, especially in connection with the iron-manufacture.

Jan 1, 1879

By John Birkinbine

In a former paper* attention was directed to the various forms of pumping machines employed for permanent work in mining and metallurgical processes. The following is simply a collection of memoranda of work done of a temporary character, and is presented by way of comparison with other work of similar nature. In close proximity to the charcoal fnrnace at Pine Grove, Cumberland County, Pa., is a large deposit of superior hematite iron ore, which has been worked for a number of years, and from which many thousand tons of ore have been taken by open pit workings. In July, 1874, the furnace was blown out and operations at the bank suspended, the machinery for draining being removed except a plunger pump, 18 inches in diameter and 66 inches stroke, operated by a steam-engine by means of rods. The pit was allowed to fill with water, and no steps towards its reclamation were taken until November, 1877. At that time the pit was a pond of water at the base of the mountain, having an area of about four acres and a depth of seventy feet. As the pumps, rods, etc., had been submerged for over three years, and partially buried by the mud washed down from the banks, and as it was determined to change the location of the pump for future operations and drive it by water-power, a temporary pumping apparatus was determined upon for reclaiming the pit and keeping it drained until the permanent arrangements could be completed. By opening an old adit about 10 feet of the water was removed, and the area decreased to three acres. The inflow of springs was found to be 250 gallons per minute, and the amount of water contained in the pit was computed to be 45,000,000 gallons. As the inflow would undoubtedly increase while the water sank in the pit, provision was made for removing at least 60,000,000 gallons, at the rate of 1,500,000 to 2,000,000 gallons per day. The company determined to employ a Heald and Cisco centrifugal pump driven by an oscillatinig engine by means of a belt. Steam was supplied by four plain cylinder boilers, each 36 inches diameter

Jan 1, 1879

By N. W. Ratliff, P. J. Closmann

Production of oil by expansion from a cylindrical reservoir composed of two concentric regions of different properties has been determined as a function of time for a reservoir producing at constant terminal pressure. The parameters involved are permeability, porosity, compressibility and oil viscosity. Results agree with those of a generally accepted method for uniform reservoirs when all parameters are taken as uniform. Cumulative production at any given time is reduced below that of the uniform reservoir when a region of considerably lower permeability adjoins the well; cumulative production increases when a high-permeability region adjoins the well. Curves are presented illustrating quantitative effects of these variations. INTRODUCTION Most petroleum reservoirs can be exploited by release of pressure and consequent expansion of underground fluid. During part of the production history of certain reservoirs by this mechanism, fluid compressibility can be considered small and constant. Cumulative fluid produced by this means as a function of time was calculated for a uniform reservoir by van Everdingen and Hurst.l For certain cases where a production well has been damaged or where an acid treatment has been used, a zone of properties different from those of the reservoir may be created around the production well. In such a case, expansion of the reservoir fluid takes place in a system composed of two concentric cylindrica1 regions of different reservoir properties. Such composite systems were studied in connection with heat flow by Jaeger2 who presented a solution for temperature distribution in a radial system with an infinitely large outer radius. Similar heat flow problems have been studied by other authors Oil production from composite reservoirs was studied for constant production rate by Hurst,4 Loucks and Guerrero,5 and Carter.6 THEORY This work considers constant terminal pressure. Cumulative flow is calculated for a composite bounded system in which no flow takes place across the outer boundary (Fig. 1). Since the flow is considered to be purely radial, the problem involves only one space dimension and time. It is convenient to define the following dimen-sionless pressure drops (Fig. 1).

Oklahoma Geological Survey, Faculty Exchange, Norman, Okla The Oklahoma Geological Survey was closed for lack of funds July 1, 1931. However, a list of publications "will be sent and requests for publications will be filled in so far as possible Address the above.

Jan 1, 1933

By Ernest F. Burchard

In connection with the work of testing structural materials for the use of the U. S. government at the laboratories of the technologic branch of the U. S. Geological Survey at St. Louis, Mo., from September, 1904, to April, 1909, and since then at Pittsburg, Pa., large quantities of sand, gravel, and crushed stone have been needed from time to time, besides samples of building-stone, clays, and other quarry-products. In many instances it has been necessary to obtain single samples of sand, gravel, or crushed stone in lots of a car-load or more. For obvious reasons all these collections have had to be made by a representative of the Survey. As the work progressed it was found essential that numerous geologic data should be gathered regarding the materials collected, in order that they might be properly classified as to kind of material, source, geologic age, etc., and that they might be rated according to quantity available, accessibility to transportation facilities, approximate costs, suitability for special purposes, etc., and that notes might be taken regarding undeveloped deposits of possible value. Furthermore, it mas desired that the selection of materials for tests should be made broadly, so as to cover, first, the representative types of material, and later, if possible, the typical materials of the more important building-centers in the United States. In order to insure a certain degree of uniformity in this work and economy of effort and expense, it was decided that as much of the sampling as was practicable should be done by a member of the geologic branch, whose regular field-trips could be combined conveniently with those necessary for procuring materials for the laboratory. During parts of the last three years 1 have been engaged in field-work of this sort.

Jan 1, 1911

AMERICANIZE THE MINING INDUSTRY Americanization is the snaking of American citizens; men and women controlled by the ideals of American citizenship, which have been built up by this country's heritage and its unceasing struggle for freedom and democracy and opportunity. That means, first of all, a necessary understanding of what those ideals are and what they mean for the newly arrived foreigner. It means that every kind of anti-American propaganda must be stamped out; that racial prejudices and the misunder-standings which lead to unrest and disloyalty and make fruitful soil for anti-American propaganda must be overcome. The foreigner must understand. He must understand what we are trying to do here in America; he must understand something, at least, of the kind of government we have built up in our efforts to, accomplish our particular aims; he must understand how lie can fit into it all, not only to help America, but to help himself-to make it possible for hint to get from this country what he carne here seeking. First of all, he must learn the American language. He must be able to talk with his fellow Americans-those who were born here and those who have recently cone, like himself, but from a different land. The most dramatic, the most crucial demonstration of the urgency of the need of all this is given to us right now. At the time when it is most essential for this country to be solidly American, enemy propagandists are winning an occasional success here because they give their message to men and women and boys and girls who do not understand our language and consequently do not understand us. These foreigners, whom the enemy is trying to make disloyal, are really in our army, the big army that is fighting the war for America. Most of them are not among the soldiers who will fight on the battle front, but they are in the lines back of these soldiers. The worker in the shipyards and in the mines is just as important a soldier in this war as the man in the trenches. That has been said over and over, but it cannot be said too often. It is just as vital for that man in the mine to know why we are at war as it is for the soldier. His employer has just as great a responsibility to the country as has any general, and it is the same responsibility.

Jan 8, 1918

MAJOR AWARDS JAMES DOUGLAS GOLD MEDAL 1960-Augustus B Kinzel "For outstanding contributions and inspiring leadership in the field of electrolytic and electrothermic winning of nonferrous metals and for his notable administrative ability " BENJAMIN F FAIRLESS AWARD 1960-Charles McElroy White "His ability, energy and determination in starting the top-pressure blast furnace and foresight in providing it with prepared burdens have created the world's dominant metal producer " HAL WILLIAMS HARDINGE AWARD 1960-Samuel H Dolbear "Eminent mineral consultant and engineer-first chairman, Industrial Minerals Division of AIME-first editor, 'Industrial Minerals and Rocks'-for the improvement and increase of industrial mineral knowledge "

Jan 1, 1960

By C. Richard Tinsley

As discussed in the economics section of this article, the main processing consideration is whether manganese will be recovered, as this has major implications for reagent consumption. Nodule processing can be classified into three sections; smelting, roasting, and leaching. Many patents have been issued for various stages of these techniques. Since extensive laboratory and pilot plant testing is continuing, it is certain that some companies are close to full-scale commercial processes. Published data does not include all of the possible concepts for nodule treatment. In fact, one may suspect that published flowsheets are those that have been rejected or have since been extensively modified.

Jan 4, 1975

By W. J. West, T. D. Mueller, J. E. Warren

Two methods are used to obtain the relatiorlship between ratio of gas to oil permeability and gas saturation. One method is to calculate a curve from field measurements of reservoir behavior: the other is to measure the relationship on a core .sample in the laboratory. The curves resulting from these TWO methods arc often comparer1 and seldom found to agree. The most important reason for the nonagreement is often overlooked. This reason is that the performance k9/k0 curve is calculated with the assumption of uniform pressure and saturution throughout the reservoir. To show the differerence between performance type kg/k0 curves and laboratory type kg/k0 curves. two performance type kg/k0 curves for two different production rates were calculaled from the production perforrnance of a hypothetical reservoir for which a laboratory type curve was assumed. Production performance of the hypothetical reservoir bras calcu- lated by use of international Business Machine's 701 Computer. The perfortnance type kg/k0 curves differed from the laboratory curve for the hypothetical reservoir. The performance type crrrve for the lowest production rate most nearly coincided with the laboratory curve. INTRODUCTION Predictions of oil reservoir performance are often made with the aid of complex numerical calculations. An important quantity required in these calculations is the ratio of gas permeability to oil permeability (kg/k0 )at a particular gas saturation. Two methods arc used to obtain a relationship between this ratio and gas saturation. The curves resulting from these two methods are called performance kg/k0 curves and laboratory kg/k0 curves. The performance curve is obtained from field measurements of reservoir behavior. Particular kg/k0 values are calculated from the producing gas-oil ratio, the cumulative reservoir withdrawals, the original oil in place, the average reservoir pressure, and the PVT properties of the reservoir fluids. The particular kg/k0 values are then plotted against the average rcservoir gas saturations for the entire history period. In order to use this derived kg/k0 relationship for performance predictions, a curve through these points is extrapolated to higher gas saturations. The laboratory kg/k0 curve is obtained from measurements made on core samples. Saturation is maintained uniform throughout the core during these measurements. The kg/k0 curves obtained with these two independent methods are often compared and seldom are found to be the same. Various reasons have been offered for the lack of correlation. One is that insufficient core? were obtained to derive a curve representative of the reservoir rock. Another is that laboratory methods have failed to reproduce reservoir conditions. The most important reason for the noncorrelation has been often overlooked because of the difficulty in evaluating its effect. This reason is that the performance or field kg/k0 curve is calculated with the assumption of uniform pressure and saturation throughout the reservoir. In any

Jan 1, 1956

By Leonard Bernstein, Harry Bartholomew

MANY of the properties of metals and alloys are structure dependent. Not the least of these is the grain structure. For example, in producing alloy bonds between silicon or germanium and gold-alloy foil at temperatures above their eutectics (which are, respectively, at 370" and 356°C) but below the melting points of the individual constituents, it was found that wetting was more complete with a fine-grain structure than with a coarse-grain structure. In cases where the assemblies were held together for long periods of time at elevated temperatures, wetting was not as critically dependent on the grain structure as was the case for shorter periods of time. When liquid phase forms, it first forms in the grain boundaries due to the fact that most of the impurities are concentrated at the grain boundaries and that most impurities tend to lower the melting point of the gold alloy somewhat. In addition, grain boundaries are at high-surface free-energy levels and are thus in a more favorable condition to initiate good wetting. A fine-grain structure will have more grain boundaries per unit area than coarse-grain structure thereby making wetting somewhat easier. To make the grain structure of an alloy sys- tem visible, a satisfactory method for differentiating between the different grains of which the system is composed must be employed. For the alloy bonding system previously described, the grain structure on the foil surface is of primary interest. Conventionally used etchants for the gold-alloy system will not adequately delineate grain boundaries in their structures. For this reason an alternate method is proposed for those cases where such a determination is necessary. Foil between 0.0005 and 0.005 in. thick has been used in this determination. The equipment used in this investigation was described in a previous publication.' Essentially, it employs a resistance-type filament which can be heated up very rapidly and cooled very rapidly. A thin refractory material is placed on top of the heating element. This refractory material may be molybdenum, tantalum, tungsten, or even ceramic but its thickness should be less than 0.010 in. to minimize the temperature gradient across it. The gold-alloy foil is placed on top of this refractory material. The temperature of the heating filament is raised to 900°C and cooled down to below 100°C in 5 to 10 sec. During this cycle, the foil can be observed to plastically deform due to its own weight. With no further chemical etching, this assembly is then viewed under a standard metallurgical microscope and the grain size measured. Fig. 1 is a Au-1 pct Sb alloy at 400X magnification and Fig. 2 is a Au-1 pct Ga alloy at 130X. This technique has proved to be an adequate means for controlling processing conditions in producing large quantities of gold alloy foil.

Jan 1, 1963

By N. M. Langdon

ON account of its greater economy and cleanliness, and the extent to which iuferior fuels can be utilized for its generation, there has been of late a rapidly increasing tendency to substitute gaseous for solid fuel for metallurgical and other industrial purposes, which has led to various improvements both in the process and apparatus for its manufacture, notably among which may IN mentioned the Tessie Gas Producer* described by Mr. A. L. Holley. A considerable experience by the author with producers of various kinds using anthracite fuel, in connection with the Taylor ore-roast ing furnace at Chester, N. J., with more or less unsatisfactory resnlts, finally led to the erection of the experimental producer described below, which combines in its construction, simplicity, dorability, and accessibility for cleaning and removing the ash and manipulating the fuel. It is adapted to the use of various kinds of fuel, and is capa ble of generating a steady and uniform supply of gas at a minimum cost. It has been in constant use day and night for about five months, and has given very satisfactory results. The producer, as shown in the accompanying sketch, consists of a cylindrieal furnace, preferably inclosed in an iron jacket or casing, having a bosh or inverted cone-shaped base as in a blast furnace. It is provided with a bell and hopper, the bell being hung to a forked lever, and having guide flanges to prevent it from swing ing, and an opening at its apex through which to insert a bar for manipulating the fuel, which when not in use is closed with a plug or stopper. Cleaning is effected through two small doors placed opposite each other at the hearth level, which in order to facilitate the operation is elevated above the floor. The doors are removable, and when closed are by their own weight and by means of bevelled lugs held tightly against their frames, forming a practically tight joint. A blast of commingled steam and air is injected into the fuel through a series of tuyeres underneath the bosh communicating with steam jet injectors. A small flue also connects the door

Jan 1, 1884

By A. M. Gaudin, D. W. Fuerstenau, M. M. Turkanis

SOLUBLE silver salts are effective activators for flotation of sphalerite with potassium ethyl xanthate as collector.' Since sphalerite takes up large quantities of silver ions rapidly," investigation of this system appeared fruitful for studying the mechanism of sphalerite activation and deactivation. Experimental data presented here comprise studies of the mechanism and rates of activation and deactivation of sphalerite with silver and cyanide ions. A 20-lb sample of sphalerite from Ottawa County, Oklahoma, was handpicked, crushed, screened, hydrosized to produce a 65/100-mesh fraction, and purified by electrostatic separation. The sphalerite was then leached with benzene and absolute ethyl alcohol to remove possible organic contaminants and with 0.1 M NaCN to remove any copper that might have been picked up during screening. The benzene had been specially purified by grinding with fine sphalerite for 12 hr to remove trace impurities that might have had a specific affinity for sphalerite. Finally, the mineral was washed, dried in flowing nitrogen, and stored in large ground-glass stoppered weighing bottles under a small nitrogen pressure.

Jan 1, 1957

By John M. Dale

Sulfur has attractive features as a base material for coating systems. It melts at 246ºF and can be applied as a liquid above this temperature. Its melting point is just above the environmental stress level, 180°F, for most coatings and yet it is low enough to be easy to work with in comparison to many hot melt systems. The viscosity characteristics are such that sulfur lends itself to spray applications. The oxidation rate of sulfur in the atmosphere is very low and sulfur has outstanding chemical resistance characteristics, particularly in acid environments. One of the greatest potentials for these coatings appears to be in the protection of other materials. At one time, most acid tanks and pits were constructed with acid- proof brick and sulfur based mortars. This type of construction is much more expensive than sulfur based spray coatings. An attractive sulfur based coating composed of sulfur, talc, milled glass fibers and dicyclopentadiene,1 developed by the Institute for the Bureau of Mines has excellent acid assistance and can be used to protect concrete from acid attack.

Jan 10, 1973

An unexpected demand having entirely exhausted the Institute's supply of the Bulletins for January and February, 1916, the sum of $0.50 each will be paid for. a limited number of copies of these Bulletins, which send to the Secretary of the Institute.

Jan 5, 1916

By A. Bruce Matthews

Of the many opportunities in the mining industry to invest funds to improve operations, there is always some limit in every company as to how much can be spent each year for the acquisition of capital assets. Generally, there are many more opportunities for investment than funds to make the investments. As such, one of management's goals is to select the most profitable of all the opportunities available. Each opportunity must be carefully analyzed for its potential percentage rate of return. This percentage return or return on investment concept is an accepted financial yardstick of business profit- ability. For today's mining engineers, this problem resolves itself in the job of determining how to in- vest most productively the cash that is flowing from their operations so that it will multiply in value. There are four basic types of capital investments: Strategic investments, such as selecting a plant site, are those that affect virtually all long-run plans of a company. Change in a company's product line and expansion of company facilities are two other types of capital investments.

Jan 3, 1963

By W. A. Boyer

HOISTS for metal mines are seldom designed for H one particular depth. They are intended for an ultimate load and depth with a given speed but are first used to hoist from a shallower depth, gradually working to the ultimate as development progresses. Sometimes the mine is not worked on the upper levels because of the kind and grade of ore, the mining of which depends on market conditions. In this case the hoist may be used in the same working shift to lift ore, for example, from the 1200 and the 4400-ft level. This means that the safety factor of the rope should be considered not only when it hoists from the greatest depth, but also when it hoists from the upper levels. According to present safety factor standards, a hoisting rope can have ample safety margin when hoisting from the lower or lowest level and still be shy of sufficient safety margin when hoisting from the upper levels. This will be shown by curves presented in this paper.

Jan 10, 1954