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By S. B. Flagg

Advancement in the art of burning fuels for steam generation has been so marked and so rapid in the last 10 or 15 years that one may well hesitate to classify as unsuitable for stationary steam boiler firing any material having a fuel value. This statement should not be interpreted to mean that any existing boiler plant can successfully utilize any fuel with which it might be supplied. It does mean, however, that almost without exception it is possible to design and construct stationary boiler plants so that they can be operated with whatever coal is the economic supply therefor. In considering the subject of the use classification of coals, it must be recognized, first, that the suitability or unsuitability of a coal for certain uses or conditions may be largely a matter of opinion and, second, that as advancement in the art of burning fuels continues, fuels that may have been considered unsuitable may later be regarded as entirely suitable. This is well illustrated in the creation of a market for slack bituminous coal and for the finer sizes of anthracite that resulted from the development of mechanical stokers adapted thereto. Coke breeze is another fuel of which large tonnages were formerly wasted, that has now been found suitable for use in properly designed furnaces. Again, results that would have been thought quite impossible a generation ago are being obtained in steam boiler plants today with lignites of high moisture content and with coals of excessive ash content. It must, however, be admitted that oftentimes an existing boiler plant can be successfully operated with only a limited number of the coals that are available as possible supplies. We may briefly consider some of the more important factors that may affect the suitability of coals for such a plant. Insufficient or barely sufficient draft to meet peak steam demands is often a limiting factor, and the permissible frequency of fire-cleaning periods is another. In some cases, the action of the molten coal ash on refractory furnace linings prohibits or makes inadvisable the use of certain coals. Again, clinker conditions in the fuel bed or slag conditions on the boiler-heating surface may be much worse with some coals than with

Jan 1, 1930

By Willard S. Morse

Referring to Mr. Rickard's paper on " The Limitations of the Gold Stamp-Mill" (Trans., xxiii., 137), and the discussions that have followed, and without entering into any controversy as to the relative merits of the " California " and " Colorado " types of stamp-mills, I wish to give the results obtained on ores from Lynx Creek district, near Prescott, Arizona, with a stampmill of the Colorado, or, more precisely, the Gilpin county, Colo., type. The mines of the district have been worked for nearly thirty

Jan 1, 1896

By Henry Engelmann

ORes are generally found in the mines mixed with more or less base matter, which renders their treatment by smelting or milling unnecessarily costly. They have to be sorted. Those of a higher grade remain often mixed with substances which might, with hardly a loss of metal and at small expense, be removed by dressing machinery, and a concentrated and purified ore thus obtained, which would bring a far higher price, because it can be reduced by cheaper methods, and, at any rate, at less expense, besides affording a saving of transportation, which in our territories is often an item of no small magnitude. The ores of a lower grade have often to be

By Henry Engelmann

ORES are generally found in the mines mixed with more or less base matter, which renders their treatment by smelting or milling unnecessarily costly. They have to be sorted. Those of a higher grade remain often mixed with substances which might, with hardly a loss of metal and at small expense, be removed by dressing machinery, and a concentrated and purified ore thus obtained, which would bring a far higher price, because it can be reduced by cheaper methods, and, at any rate, at less expense, besides affording a saving of transportation, which in our territories is often an item of no small magnitude. The ores of a lower grade have often to be

Jan 1, 1874

By Roger Thunvik, Carol Braester

Excavation of cavities below the ground water level induces water influx from the surrounding aquifer. An estimate of the rates of flow prior to excavation operations may be of valuable information for the mining engineer. The present paper deals with water influx into cavities of the tunnel type, e.g., mine galleries, tunnels, etc. The solution of the flow problem was obtained by a numerical finite difference method. The results are presented in dimensionless form as a function of the parameters characterizing the location of the cavity in the aquifer.

Jan 1, 1981

During the latter part of the Civil War an income tax was placed upon coal and the production of coal in the various collection districts during the life of this tax is shown in the tabulation that follows. The counties that include coal deposits are shown for each district. No record exists now of the production by counties, but it is calculated here on the basis of tax collected. The table, of course, does not include any territory not under the control of the northern armies, and not all of that in some cases.

Jan 1, 1942

By D. Malhotra, R. M. Hoover

The effect of a surfactant, designated Syntex, on the wetting and spreading of hydrocarbon oil on molybdenite surfaces (faces) has been investigated experimentally through measurements of zeta potentials and factorially designed flotation tests. These studies indicate that Syntex has a positive effect in increasing molybdenite recovery in the rougher flotation circuit at the Climax mill. The analysis of experimental data using DLVO theory shows that the controlling factor in determining the magnitude of the repulsive energy barrier preventing oil from wetting and spreading on the molybdenite faces is the MoS2 zeta potential and the vapor oil droplet size. The role of Syntex in this case seems to be related to the decrease and stabilization of MoS2 zeta potential by Syntex adsorption and also to the emulsifying action of Syntex on vapor oil to provide a more favorable oil particle size.

Jan 1, 1976

By Terkel Rosenqvist

J. Chipman (Massachusetts Institute of Technology, Cambridge, Mass.)—The fact that the experimental work has been applied to copper rather than iron and that the paper is presented to the Iron and Steel Division, I regard as rather significant. It shows the unity of metallurgy and the fallacy of trying to cut it up by metals. This result for the solubility of sulphur in molten copper correlates with Professor Schuhmann's finding that the published data on the other side of the copper-sulphur miscibility gap are also in error. I should like to ask the author to say a little bit more about the sulphur capacity of the slag. T. Rosenqvist (author's reply)-—I hope that Dr. Chipman will find the derivation of the expression for sulphur capacity more clearly explained in the printed version of the paper than in the oral discussion at the meeting. I feel that this quantity, which actually is the ratio of two activities, can be measured more easily than the individual activities. Even if the ratio CaO/CaS is chosen as the standard state, the expression can be used for any slag, even for slags completely free of lime, and it represents a way to put the desulphurizing power of all slag constituents into one bag. Some doubt has been expressed as to whether oxygen ions really exist in calcium oxide and in molten slags. From a thermodynamic view point that question is of minor importance. The term oxygen ion activity, or any activity for that matter, is defined rigorously by the equation: activity = exp p/RT, where p is the change in free energy connected with the transfer of one mol of ions from the standard state into the slag. Whatever happens to the ion in the slag is of no concern to the thermodynamicist. Regardless of whether the ion is "free" in the slag or not, or whether it is present in a very small amount, its activity can always be expressed, and for a thermo- dynamic calculation that is all we need. However, ionic activities will only be of some real value if they are simple functions of the slag composition, or can be measured easily. Concerning the real nature of the oxygen in the slag, my feeling is that the oxygen atom has a rather multiplex nature depending on how strongly it is tied by covalent forces or polarized by the other atoms or ions present. The oxides of iron, cobalt, and nickel differ from calcium oxide and blast furnace slags as to the amount of free electrons that can give rise to electronic conductivity. In slags we know that the conductivity is mostly ionic. The fact that reversible emf's can be obtained with oxygen electrodes in certain salt melts, indicates a significant amount of oxygen ions in these melts. But extended work, e.g. polaragraphic studies and measurements of transference number; are needed to obtain quantitative information about the real structure of the slags. D. E. Babcock (Republic Steel Corp., Youngstown, Ohio)—-With reference to the ion, it might be well to remember Dr. Moses Gomberg. All of his life he had no use for the ionization theory and he contributed greatly to the field of chemistry on the assumption there was no such thing as ions. I do not think we have to worry about whether the oxygen is ionic or not. I think one thing specifically should be brought to your attention and this I think is one of the important contributions of Dr. Rosenqvist. He pointed out what we know as oxygen potentials or what is described as oxygen potentials. I have used this concept for a long period of time and I want to state that if this concept is properly applied, it vitiates much of what we have in the literature, or makes our usual ideas regarding oxidation seem primitive. That one thing is more valuable than almost all the rest of the discussion as a fundamental basis on which to build a reasonable in-

Jan 1, 1952

STANFORD UNIVERSITY, CALIFORNIA Our activities for the year 1918-19 have closed with the coming of summer. It has been a most successful year in many respects, especially in the reorganization necessary after the war conditions had passed. An INITIATION SCENE AT STANFORD UNIVERSITY. "old-days" initiation was held on the Stanford campus by the Society a few weeks ago. The accompanying picture explains some of what took place when the following men were taken into the membership: W. P. Winham, Salinas, Calif. ; T. L. Wark, Long Beach, Calif.; P. L. Henderson, Greeley, Colo.; T. E. Bassett, Palo Alto, Calif.; and R. G. Wheelton, Long Beach, Calif. CHAS. A. DOBBEL, Secretary.

Jan 8, 1919

By J. P. Carson

(Read at the Wilkes-Barre Meeting, May, 1877.) THE works of the Tula Iron Company are in the Republic of Mexico, State of Jalisco, twenty-eight leagues southwest of Guadal¬ajara, ten leagues northwest of the town of Sayula, through which passes the projected line of the Mexican National Railroad. Its geographical position would be about: latitude, 20° 10' N., longi¬tude, 4° 35' W. of Mexico City. The surrounding country is a roll¬ing plateau, 6000 feet above the sea, enjoying the most magnificent climate in the world, the average temperature being about 70°. The works were commenced in 1850 by a company with very small capital, having not the least idea of the undertaking. They soon fell into the hands of the money-lenders, and after changing

Jan 1, 1878

By Francis T. Freeland

The deeper workings of the Leadville mines show refractory ores, consisting principally of sulphides of iron, lead, and zinc, carrying silver, in place of the easily reduced carbonate ores lying nearer the surface. The largest and most extensively developed deposit is that of South Iron Hill.* It lies on the north side of California Gulch,

Jan 1, 1886

By D. E. Furman

The thermal coefficients of linear expansion for several stainless steels have been determined over the temperature range from —300° to 1000°F. The steels studied include types 301, 304, 316, 347, 310 and 330. This wide selection of compositions allows an insight into the effects of austenite stability and alloy content on the expansion characteristics. THE recent increased use of materials in low temperature applications has created a field for which the properties of austenitic iron, chromium, nickel alloys are particularly suited. Tensile and impact values of stainless steels at subzero temperatures have been made available in the technical literature but, as yet, little information has been published with respect to expansion characteristics. In order to supply this need, a study was made of several of the more common compositions. Those selected were types 301, 304, 316, 347, 310 and 330 stainless steel. Both the mean and instantaneous coefficients of linear expansion were determined over the temperature range from —300°F to 1000°F. Procedure The materials used were commercial grades with the exception of type 301 which was made in a 10# high frequency furnace. The compositions are listed in table I. All steels were given an anneal at 1950°F for 30 min and water quenched prior to machining the expansion specimens. Expansion readings were taken on specimens 0.250 in. in diam by 4.000 in. long with a fused quartz tube expansion apparatus similar to that described by Hidnert and Souder.1 Temperature measurements were made with a chromel-alurnel thermocouple calibrated for use at subzero temperatures. A bath of propane was used for temperatures from —300° to —100°F and one of alcohol from —100°F to room temperature. These baths were contained in large mouthed Dewar flasks and cooled to the desired temperature levels by passing liquid nitrogen through glass cooling coils placed in the flasks. The baths were stirred constantly for temperature equalization and were heated by immersing metal rods which were replaced frequently enough to give a heating rate of approximately 150°F per hr. A resistance wound furnace was used for heating from room temperature to 1000°F and throughout this range rates of about 450°F per hr were maintained. The furnace was designed so that the temperature gradient over the specimen was within 5°F. In most instances, the expansion readings were taken during heating from —300° to +300°F at

Jan 1, 1951

By A. L. Mular. Discussion by G. A. Parks

G. A. Parks (Associate Professor, Dept. of Mineral Engineering, Stanford Univ., Stanford, Calif.) - Professor A. L. Mular in his paper Effect of Impurities on the Flotation Behavior of Zinc Oxide (T.P. 65B206) has made a most interesting and thought provoking contribution. In view of his recognized lack of measurements of the ZPC's of the doped samples and lack of direct evidence for participation of semi-conducting electrons in collector adsorption an alternate explanation should be considered. The alternate also

Jan 1, 1967

By Alden Greninger

ALTHOUGH the crystallography of lattice transformations has been studied extensively during the past few years, these studies have been limited, with few exceptions1,2, to specimens in which the transformed lattice appears as a, segregate phase. A realization of the technical importance of the segregation mechanism, especially in the formation of martensitic structures and in age-hardening phenomena, has undoubtedly stimulated research in this direction. In the crystallographic studies of segregation, the general problem has been to relate the orientation of the parent crystal to that of the segregate crystals. The technique has been complicated by the fact that it has been necessary to deal with the presence of as many as 24 ideal segregate orientations within one parent lattice; furthermore, the segregate lattices are invariably scattered (seldom less than ±2°, often as much as 15° or 20°) about these ideal positions. It is probable that a more complete picture of phase transformations may result from a study in which complete lattice relationships between individual grains are evaluated, thereby providing an additional param-eter which, when it is necessary to work with multiple segregate-orienta-tions, cannot be evaluated. The present paper presents the results of such a study, ? wherein a peritectic reaction is made use of to produce the transformed lattices.

Jan 1, 1937

By George M. Fowler, R. E. Illidge

Part I. Developing BY GEORGE M. FOWL INTRODUCTION The Tri-State district comprises an area of about 2000 square miles in southwestern Missouri, southeastern Kansas, and north [ ] eastern Oklahoma. The part that is in and contiguous to Missouri is still sometimes designated as the Joplin district (Fig. I). EARLY OPERATIONS Mining operations in what is now the Tri-State district date from about 1848 and have been continuous to the present. Apparently the first discoveries of ore were made about the same time near the present sites of Joplin, Oronogo, and Granby. Lead minerals were found at grass roots, probably in shattered rock in shallow excavations, then these minerals were followed in shear zones to deeper horizons. The mining of zinc followed. Before 1874, zinc ore was worthless and discarded as waste. According to published records, the total production of lead to that date was 49,000 tons of metal from 70,000 tons of concentrates. PRODUCTION The aggregate ore production from the Tri-State district was recorded at interval

Jan 1, 1943

By J. E. Kemp

1. Situation.—From Monterey in the State of Nuevo Leon, the Sierra Madre mountains stretch away to the southeast and present a steep front to the northeast. The Monterey and Mexican Gulf railway. which connects Monterey with Tampico. follows their general line with its road-bed a few miles out from the foothills. At a distance of 100 miles from Monterey it passes through the town of Linares. and from Linares one can see far away to the southeast the peaks of another group of mountains rising from the general plateau and forming a more eastern

Jan 1, 1906

H. F. MOORE and W. J. PUTNAM (author's reply to discussion?).-The writers are inclined to question whether it has been experimentally established that steels will endure an indefinite number of repetitions of low range of stress. It is difficult to see how such a conclusion can be reached except by extrapolation from test data,. and such extrapolation always gives results of questionable value. From the viewpoint of the designer and the user of steel the writers believe that the exponential formula, which gives results on the safe side of what test. data we have, for steel subjected to tens or hundreds of millions of repetitions is a safer

Jan 7, 1919

By R. R. Odman, O. N. Lofgren

At the planning stage for this plant it was scheduled that the plant operate at a low energy consumption. After start up in 1973 it was established that outcome was even better than the forecast. In view of the 1977 ore market it was decided to operate the plant at half capacity. This initiated efforts to reoptimize the process in order to hold back expected increase in energy consumption. The result from this work proves that a detailed study and tuning of the process can not only avoid expected increase, but also reduce specific energy consumption.

Jan 1, 1983

By George W. Mansfield

My plan in this paper is, first, to prove three general points, and then to take up the specific applications of the electric motor to nining work. The three poinb are: 1. The electric system is the simplest method known for transmitting and distributing any amount of energy from one locality to another, irrespective of the intervening distance. 2. The electric system with its applications is not in its infancy.

Jan 1, 1888

By R. L. Fleischer, R. S. Davis

BICRYSTAL specimens grown from the melt have been used extensively for investigations of the influence of grain boundaries on plastic deformation. The bicrystals are usually of predetermined orientation prepared by seeded growth from the melt in milled graphite boats. This technique has been described in detail by Chalmers.' Since the direction that the grain boundary follows during growth is affected by both thermal conditions and crystallography, a difficulty arises in maintaining the grain boundary position constant along the length of the specimen. This problem is particularly

Jan 1, 1960