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By A. D. Hughes

C. W. MERRILL*—Mr. Hughes' paper not only is very well presented but is most timely in that it covers a subject of vital interest to the United States. Tin is one of the strategic metals which has not been found here in appreciable quantities. The total United States tin output since the first recorded production over 100 years ago would not supply current consumption for a fortnight. On the consumption side, tin is extremely important in national defense because of its use in tin plate which, in the form of tin cans, makes it possible to feed properly the armies that the United States recruits from its civilian population in emergencies. Moreover, the internal combustion engines so important in powering tanks, planes, and other war machines, require large quantities of tin alloys for bearings and for soldering. These considerations, along with the fact that Malaya, historically, has been the leading source of tin to the United States, make the kind of information that Mr. Hughes has presented so ably. a matter of vital interest. Your Chairman, Mr. Romanowitz, in his introduction, referred to the fact that I had been a member of the United States delegations to the three meetings of the International Tin Study Group. Some cominents on the Group's objectives and deliberations may be of interest. When it appeared that the International Tin Committee, the prewar producer's cartel, might soon revive its operations and extend its control agreement beyond the expiration date of Dec. 31, 1946, the United States Government became interested in some kind of an international trade organization concerned with tin which would give the consumers' interest equal representation with the producers' interests. An international meeting was called in London in October 1946 to consider this problem. I did not attend that meeting hut the result of the meeting was the organization of the International 'Tin Study Group which

Jan 1, 1950

By William Firmstone

ON the 19th December, 1833, a patent was granted to F. W. Geisenheimer, for smelting iron ore with anthracite. In his claim he says: "Sixthly, though I cannot, and do not, claim am exclusive right of the use of heated air, for any kind of fuel, nevertheless I believe to have a right to claim the use of heated air, applied upon, and in connection with, the said principle and manner discovered by me, to smelt iron ore in blast-furnaces with anthracite coal, by applying a blast of air in such quantity, velocity, and density, or under such pressure, as the compactness, or density, and the continuity of the anthracite requires, as above amply and fully described and illustrated." Dr. Geisenheimer made experiments in smelting iron ore with anthracite at the Valley Furnace, near Pottsville, but he failed to carry out to good practical results the principles enunciated in his patent. In the Journal of the Franklin Institute for February, 1838, a communication was published that was made by Mr. George Crane, of the Yniscedwyn Iron Works, South Wales, to the British Association, in September, 1837. On the smelting of iron with anthracite coal, Mr. Crane states therein, that he began the use of an¬thracite with hot-blast on the 7th February, 1837, in a cupola blast-furnace, 41 feet high, and 10' feet across the boshes ; product, 34 to 36 tons a week. Mr. Crane goes on to say, "It may not be uninteresting to be informed in what matter the idea first occurred to me of applying a heated blast to anthracite coal. One evening, after I had placed a piece of it upon my parlor fire (which had before been made up with bituminous coal), and had allowed it to arrive at a red heat, upon applying as fierce a blast to this piece of coal as I could raise from a pair of bellows, I noticed a black spot or mark

Jan 1, 1875

By D. L. Ward

This paper is the result of a study, in 1919, to determine how much surplus power could be produced through the proper utilization of the entire gas flow from the two furnace stacks at the Federal Furnace Plant, South Chicago, Ill. Obviously, the problem was to measure the flow of gas through the main beyond the point where the amount necessary for stove operation was removed. In all probability, blast-furnace gas is the most difficult gas to measure, because of the high moisture and dust content, and the widely fluctuating flow from the furnaces. This wide fluctuation of flow forbids the acceptance of any one group of flow readings as indicative of normal operating conditions. A study of the conditions showed that a recording device on gas flow was necessary. As the gas at the point of measurement had passed through wet washers, and accordingly was saturated with water and contained considerable dust carried past the scrubbers in the form of sludge, no form of Pitot tube could be used, for this sludge would quickly plug the dynamic and static holes, spoiling the gage readings. An even more serious objection to the use of Pitot tubes was the impossibility of accurately measuring the cross-sectional area of the gas main on the plane of Pitot-tube installation. Given an absolutely clean gas and a perfectly circular pipe, it would be safe to assume, through measurements of the pipe diameter, that the gas main was of a certain cross-sectional area. But the continual depositing of sludge and the fact that the main was fabricated from riveted sheets led us to discard the idea of using Pitot tubes for this service. The Venturi tube was then considered, and had there been a sufficiently long straight run of gas main to accommodate a tube of the required size (72 by 28 in.) such an installation would very likely have been made.

Jan 2, 1921

By Albert McIntosh

One of the most interesting as well as important factors connected with the petroleum industry is the consumption of motor fuel. A few years ago we always spoke of "gasoline," but when natural gasoline and benzol became more important it seemed desirable to include all of these products in the petroleum statistics and so there was adopted the term "motor fuel," which embraces these three products in their entirety. Gasoline always included all stove and motor gasolines, high-grade naphthas, cleaning naphthas, solvents, varnishmakers' and painters' naphtha and gas-machine gasoline. "Motor fuel" includes all of these products also; therefore, technically the term "motor fuel" is incorrect, but as the total quantity of these non-motor naphthas is small their inclusion does not distort the results to any appreciable extent. When the Federal Oil Conservation Board appointed its first semiannual forecasting committee early in 1930 to project the demand for gasoline and crude oil into the year 1930, it was necessary for that committee to formulate a method of forecasting. It adopted the system in use by some of the oil companies at that time, of using automobiles and per-car consumption. Six months later the American Petroleum Institute also formed a committee for forecasting, which adopted the committee principle of asking each member to produce his own forecast of demand by any method he thought best and to give a full explanation to the committee. The result of the latter method was to get the benefit of as many different methods of forecasting demand as there were members. The writer does not recall any two members ever using exactly the same method. By studying the different forecasts and their methods, there evolved a composite opinion, which was presented to the industry as the committee's estimate. The same method has been followed by the American Petroleum Institute or Planning and Coordination Committee ever since.

Jan 1, 1935

By M. A. Rigdon, R. E. Grace

The dissociation of cupric oxide to cuprous oxide and oxygen was studied with a microbalmce technique at 700" to 750°C. In this temperature range the dissociation pressure of the reaction 2CuO= Cu2O + 1/2 O2 was: The theory of near-equilibriwm reaction rates predicts a linear relationship between reaction rate and the Gibbs free-energy change for small values of AF/RT. This correlation is found to be valid for AF/RT = -0.1 or approximately 200 cal per mole away from equilibrium. THE theory of reaction rates near equilibrium as developed from classical thermodynamics suggests a small range of linear behavior between the overall reaction rate and the free-energy change accompanying the process. The extent of this linear correlation is generally unknown, even to the order of magnitude. The idea of linearity is also found in the formal mathematics of coupled transport phenomena, e.g., chemical diffusion, thermal diffusion, thermoelectricity, and so forth. The linear array of forces and fluxes which leads to various main and cross coefficients is predicated upon linearity between reaction rates and the bulk thermodynamics which govern the process. The general case in reaction kinetics is well-known: the magnitude of the free-energy change does not cor- relate with observed reaction kinetics, irrespective of whether the process occurs by diffusion or chemical reaction or both. The real need is to investigate specific reaction paths near equilibrium in order to learn of the limitations in attempting to correlate reaction rates and thermodynamics. It is the main purpose of this paper to examine the dissociation kinetics of cupric oxide under conditions of known driving force where the dissociation process is likely to occur by chemical reaction. A secondary objective is to obtain equilibrium data for the CuO-Cu20-O2 system. In a prior paper Edmiston and race' investigated reduction kinetics of wustite in H2-H2O gas mixtures. The present study was carried out in oxygen according to the following reaction:

Jan 1, 1969

By M. Katzer, R. Klimpel, J. Sewell

The effect of using selective dispersants as wet grinding aids for ores is demonstrated on laboratory scale batch and continuous grinding equipment. A complete characterization of behavior is performed on a given ore to demonstrate correlations involving torque, % solids, net production rate, and slurry weight and volume loading. The relationship between such laboratory data and industrial scale testing results is very consistent.

Jan 1, 1982

By Stewart L. Toleman, Robert H. Hafner, Irvin R. Kramer

In his paper on the calculation of harden-ability from chemical composition, Gross-mannl discussed the effect of most of the alloying elements used commercially. The purpose of the work reported in this paper was to determine the effect of several other elements on hardenability—arsenic, antimony, beryllium, cobalt, columbium, germanium, tellurium, tin, aluminum, and titanium—and to extend the range of composition of some of the elements studied by Grossmann—chromium, copper, manganese, molybdenum, nickel and silicon. Experimental Methods To determine the effect on hardenability, suitable amounts of the alloying elements were added to experimental heats and the hardenability determined by means of end-quenched hardenability specimens. The steels were melted in a high-frequency induction furnace with a basic crucible, using ingot iron as a base for some of the heats and S.A.E. 1015 for others. The alloying additions were made as ferroalloys or as metal, depending on the alloying element. Hundred-pound heats were split and poured into square, tapered, cast-iron ingot molds with hot tops. Aluminum was not used as a deoxidizer in most of the heats. The ingots were homogenized for 12 hr. at 1260°C. (23oo°F.) and forged into rounds of I½ -in. diameter. These bars were normalized twice from 840°C. (I55o°F.) before machining into Jominy bars. mined in most Cases by samples taken from the end-quench hardenability spedmen. AS suggested by Crafts,2 acid-soluble (8

Jan 1, 1944

By Robert H. Hafner, Irvin R. Kramer, Stewart L. Toleman

In his paper on the calculation of harden-ability from chemical composition, Gross-mannl discussed the effect of most of the alloying elements used commercially. The purpose of the work reported in this paper was to determine the effect of several other elements on hardenability—arsenic, antimony, beryllium, cobalt, columbium, germanium, tellurium, tin, aluminum, and titanium—and to extend the range of composition of some of the elements studied by Grossmann—chromium, copper, manganese, molybdenum, nickel and silicon. Experimental Methods To determine the effect on hardenability, suitable amounts of the alloying elements were added to experimental heats and the hardenability determined by means of end-quenched hardenability specimens. The steels were melted in a high-frequency induction furnace with a basic crucible, using ingot iron as a base for some of the heats and S.A.E. 1015 for others. The alloying additions were made as ferroalloys or as metal, depending on the alloying element. Hundred-pound heats were split and poured into square, tapered, cast-iron ingot molds with hot tops. Aluminum was not used as a deoxidizer in most of the heats. The ingots were homogenized for 12 hr. at 1260°C. (23oo°F.) and forged into rounds of I½ -in. diameter. These bars were normalized twice from 840°C. (I55o°F.) before machining into Jominy bars. mined in most Cases by samples taken from the end-quench hardenability spedmen. AS suggested by Crafts,2 acid-soluble (8

Jan 1, 1944

By W. H. Adams

I doubt if many of our engineers know of the existence of coalfields extending over hundreds of miles of territory bordering on and lying contiguous to the Rio Grande River in Mexico. Essential as these facts are to those contemplating the starting of industrial works along our frontier, 1 have not been able to learn that any surveys or examinations have been made of these deposits, arid I trust the preliminary and unofficial investigations lately made by myself may be found of interest, especially to those of our members whose experience has been with poor fuel, or in districts remote from railway facilities. While it is true that Northern Mexico is generally bare of charcoal-making timber, yet no greater mistake can be made than to condemn the light, quick-growing woods found in profusion, and which cannot be excelled in flame or heat-pruducing qualities for boilers, reverberatory furnaces, or hearths. No country could be surer of a full supply of wood if wise legislation in regard to irrigation and preservation of young timber were adopted and enforced, but the beneficiation of the low-grade ores of Mexico demands a more dense fuel for furnace work, and, fortunately for metallurgists, who will hereafter make this frontier a base of operations, there have been disclosed, near the surface, seemingly inexhaustible beds of semi-anthracite and bituminous coals. No extensive openings have as yet been made, and my own workings at the Cedral mines are all that can yet be said to prove the quantity and quality of the coal, other openings furnishing only corroborative evidence. Our location (one hundred and ten miles west of the Rio Grande River) is on the western line of the depository basin, as it has existed since the period of activity along the volcanic line. The region farther inland I have not examined, but the elevations, as a rule, are much greater, though from the nature of the formation, they are not necessarily barren ground. Beginning at the base of the Santa Rosa Mountains (location of the Cedral mines), we find very interesting breaks in the foot-hills, disclosing the stratified rocks from the volcanic centres to the valleys.

Jan 1, 1882

By W. H. Adams

I DOUBT if many of our engineers know of the existence of coal-fields extending over hundreds of miles of territory bordering on and lying contiguous to the Rio Grande River in Mexico. Essential as these facts are to those contemplating the starting of industrial works along our frontier, I have not been able to learn that any surveys or examinations have been made of these deposits, and I trust the preliminary and unofficial investigations lately made by myself may be found of interest, especially to those of our members whose experience has been with poor fuel, or in districts remote from railway facilities. While it is true that Northern Mexico is generally bare of charcoal-making timber, yet no greater mistake can be made than to condemn the light, quick-growing woods found in profusion, and which cannot be excelled in flame or heat-producing qualities for boilers, reverberatory furnaces, or hearths. No country could be surer of a full supply of wood if wise legislation in regard to irrigation and preservation of young timber were adopted and enforced, but the beneficiation of the low-grade ores of Mexico demands a more dense fuel for furnace work, and, fortunately for metallurgists, who will hereafter make this frontier a base of operations, there have been disclosed, near the surface, seemingly inexhaustible beds of semi-anthracite and bituminous coals. No extensive openings have as yet been made, and my own workings at the Cedral mines are all that can yet be said to prove the quantity and quality of the coal, other openings furnishing only corroborative evidence. Our location (one hundred and ten miles west of the Rio Grande River) is on the western line of the depository basin, as it has existed since the period of activity along the volcanic line. The region farther inland I have not examined, but the elevations, as a rule, are much greater, though from the nature of the formation, they are not necessarily barren-ground. Beginning at the base of the Santa Rosa Mountains (location of the Cedral mines), we find very interesting breaks in the foot-hills, disclosing the stratified rocks from the volcanic centres to the valleys.

Jan 1, 1882

By William Kelly, Frederick Laist

The slow, tedious and costly method of reducing copper matte to metallic copper in the reverberatory furnace, commonly known as the Welsh process, was displaced by the rapid and inexpensive converter process about fifty years ago. The art of refining copper was for many generations a carefully guarded secret among the Welsh furnacemen and was handed down among them from father to son. An attempt was made to apply it at Butte when the smelting of copper ore first started there but it proved too difficult and expensive under local conditions, and until the introduction of the converter process the entire output of copper was shipped to Swansea in the form of high-grade (60 per cent) matte. Before the construction of the Manhes converter, attempts had been made to reduce copper matte in the bessemer steel converter, but these failed, chiefly because the air was blown through the bottom of the vessel. The air holes became clogged with chilled copper as soon as the reduction started. Manhes partially overcame this difficulty by placing the tuyeres in the side of the vessel, some, distance above the bottom, thus allowing space beneath them for the copper to accumulate. Nevertheless the first attempts to operate such a converter at Butte were not successful, as no means had been provided for clearing away obstructions, which formed to some extent in front of the tuyeres. This difficulty was overcome by drilling holes in the outside wall of the air chamber directly opposite the holes in the shell and lining, so that these could be punched

Jan 1, 1934

By Gregory J. Comstock

THERE is a growing interest in the possibilities presented by the manipulation of metal powders, which justifies an attempt to summarize their character and potential value. A summary of this kind presents an opportunity for making a classification of metal powder products into several general types. Our present knowledge of the finer and more abstract aspects of many of the principles involved in metal powder technique is extremely limited. Any conclusions as to the ultimate value of the process will, therefore, for the present at least, be of doubtful value unless they are substantiated by its products. The number of such products is increasing. A study of their diverse and unusual characteristics; an examination of the methods by which they are made, and a consideration of the reactions that take place during their fabrication, in so far as we can define them, should afford as good an evaluation of this interesting development as it is possible to make at this time. A critical study of this kind results in a formidable list of special attributes, which apparently ate characteristic of applied powder metallurgy. A comparison of these special effects with the end products and well defined limitations of the melting and casting process indicate that often they may very well be considered as being special advantages. They are subject, of course, to certain not as yet so well defined limitations of their own. Based on current products only, a necessarily condensed summary of the more striking special attributes of the metal powder process follows. MANIPULATION OF HIGHLY REFRACTORY METALS The powder process presents a means of manipulating highly refractory metals, which cannot be cast and formed in the usual melting and casting process. Tungsten, molybdenum and tantalum are the classic examples of the adequacy of the metal powder process for meeting unusual conditions of this character. The development and application of these metals by means of it, and their importance in the electrical

Jan 1, 1938

By T. Olrog

Dissemination of technical data on developments in rock-blasting techniques in Sweden initially takes place as personal contacts and contacts between companies. In addition to these informal contacts, contacts occur in Sweden in a somewhat more organized form. There exists an informal working group--the Rock Blasting Committee--which consists of a number of personal representatives from various companies that perform rock blasting on a large scale and from firms manufacturing the equipment that is used. This means that people from both mining and construction companies get together, plus the manufacturers of explosives, drill steel, drilling machines, and loading equipment. This working group has, so far, succeeded very well in ignoring the purely commercial interests of the companies concerned. Cooperation in this form was started in the 1940's when the tungsten-carbide drill steel was invented-the group originally concentrated entirely on the development of that product. Their activities have been broadened since that time and now a meeting is held every year, at which practical experiences are reported. Only in the past five years have subjects relating to blasting procedures to avoid rock damage been treated at such meetings. This, of course, does not mean that such techniques had been neglected previously. It does, however, reflect the fact that practice in this field is still under development. Why do we try to be careful about the rock surfaces? Obviously, it is a question of economic evaluation. An even rock surface provides, in certain cases, the conditions for more favorable maintainance costs later on, greater strength, and a diminished risk of slides. The economic connections in this field, however, are neither simple or clear. A well-controlled blasted rock surface limits the need for concrete when you later build the concrete constructions. In this respect, the connections are all the more clear. In certain situations, such as tunnels for hydroeletric power plants, a good rock surface that is not lined is hydraulically more favorable than a more coarsely blasted surface. This permits a gain in the height of fall, but the

Jan 1, 1970

By David Keys

APPLIED geophysics is the youngest child of that old branch of learning, that has been known from Aristotle's time as physics-the constitution and laws of nature. The mother science, with the help of mathematics, has given birth to many children, who, on becoming of age in the scientific sense, wedded more practical applications which later became known as electrical engineering, physical chemistry and acoustical engineering. Some vigorous sons still retain the family name, among which the most recent to take its place as a division of science is geophysics, which deals with the physics of the earth. Geophysics in its broad sense has many departments-meteorology, oceanography and seismology, to mention only three. Within the past 20 years, however, a special interest has arisen in the application of physical principles to, problems in geology, mining and civil engineering, with the consequent rapid growth of what has now been called "applied geophysics." Applied geophysics in this narrower sense is the application of experi-mental and theoretical physics to determine variations: and discontinuities in underground structures that cannot be ascertained from surface inspec-tion. It seems evident, then, that the physics department is the natural place in a university where the principles and methods involved should be taught and developed, for the physicist will also have had the requisite training in mathematics that the proper understanding of many methods now used will require. A knowledge of the procedure and principles, however, is not sufficient for the successful application of geophysical, methods. One may know the dynamics of flight of golf balls and of impact and yet not play a par game of golf ! The proper selection and use of the right club to suit the circumstances of the lay of the ball and an acquaintance with the possibilities and limitations of the strokes as well as the practical execution of the play is essential to a successful game. So, also, in the application of geophysical methods, it is important for the geophysicist to use the best device under the conditions presented, to know the limitations of the conclusions deduced from his physical measurements and to make the proper interpretation of the results. A knowledge of geology will be of great aid in coming to the correct con-

Jan 1, 1938

By George Hulst

PRIOR to 1914, there was little demand for antimony in this country; its use was limited almost entirely to the manufacture of type and bearing metals. Practically no antimony ore was mined here, the market being supplied principally from China, and the alloy was produced by a direct mixing of lead and antimony. The great world war, with its demand for shrapnel in hitherto undreamed of quantities, precipitated a great boom in the price of antimony. Nominally quoted at 6 c. to 7 c. in 1914, the price increased by leaps and bounds to 45 c. in March, 1916. Under the stimulus of high prices many shall mines were opened, for it became profitable to work ores containing as low as 20 percent. antimony. High-grade sulfide ores (stibnite), containing 55 per cent. to 60 per cent. antimony, were received from Bolivia, China, and Alaska. Low-grade sulfide ores, running from 20 per cent. to 45 per cent., were produced in Nevada, California, Idaho, Utah, and Mexico; much of this ore was fairly rich in silver. The principal oxide ores came from Mexico and Oregon. The following analyses are representative of various types of antimony ore: Se Pn Cu Ao Au SIC), Fe S CAO ZN As Oxide Ore 25.09 46.02 0.95 0.40 10.98 0.30 0.22 Sulfide ore 5.5.20. 15.12 1.05 19.87 ? 0.40 0.25 Sulfide Ore 37.16 11.30 0.10 34.0 7.60 0.50 17.05 7.40 0.36 0.10 Sulfide Ore 41.55 15.00 0.20 76.0 0.04 5.60 0.25 18.17 0.85 0.25 0.10 The International Lead Refining Co. fortunately was equipped to handle these ores through residue and blast furnaces. The charge consisted of a variety of sulfide ores containing Sb 20 to 60 per cent. and Si02 6 to 45 per cent., oxide ores containing Sb 20 to 40 per cent. and SiO2 10 to 45 per cent. Secondary materials, such as battery plates, battery mud, lead oxide, paint, etc., together with refinery skims, softener skims, and other refinery byproducts, were treated along with the antimony ore to furnish the lead required. All silver-bearing antimony ores were treated in the residue furnace, the sulfur, iron, and copper forming matte that carried part of the silver, the balance going into lead bullion. The

Jan 9, 1919

By Basil Prescott

In the science of evolution of the species, there is a law which, simply stated, avers that the history of the individual repeats the history of the race. Similarly, if unassisted by the experience of others, each SUCcessful engineer would perfect and develop his methods and technique from the rough grab sample up to the carefully taken, recorded and studied samples and observations which now determine and decide the expenditure of the large sums required for modern mining. Hence real progress results from the interchange of experience, as in that way the entire experience of the profession can be made available to every engineer. The literature of this subject is already voluminous, but some progress has been made in the gathering of data and in their compilation or presentation. More Romance than Developed Ore in Limestone Deposits In certain types of deposits, methods little known 25 yews ago have been developed, perfected and standardized to a degree that lifts sampling from the field of manual labor to the plane of an applied science; for instance, the modern methods of estimating the so-called porphyry coppers. With some types of orebodies, we have become familiar, and sometimes on too easy speaking terms, with millions of tons of ore in reserve and tens of millions of dollars; while with others even these once marvelous figures sink into insignificance before the array of ciphers that are presented. .In such company, the average limestone replacement orebody is entirely out of place, for its reserves seldom reach a figure to arrest the attention of the modern engineer, and more often are insignificant. It is only when the records of the production of some of the older camps are studied, which show them to have continuously produced over very extended periods, that a realization is borne home that occasionally this type is worthy of consideration even in these days of gigantic tonnage.

Jan 1, 1925

By John Birkinbine

A RETROSPECT of the growth of the production of pig-iron for the past half century would be the history of the invention and introduction of heated blast as applied to the smelting of iron ores. As the apparatus employed was improved in conception and construction, the economical operation of the furnaces to which it was attached was the more marked, and the production correspondingly increased. To compare the original iron box placed over a coal fire with the modern hot-blast stove, with its combustion-chamber, gas-burners, and air-regulators, would be as unfavorable to the former as to contrast the product of the little Blauöfen with the yield of the improved furnaces of to-day. But, as these little Blauöfen were the germs from which the larger plants have grown, so from the crude apparatus invented and applied by Neilson has grown, in the face of great opposition, the more economical hot-blast stoves now in use. It is not surprising that an innovation like heated blast should have received a large amount of attention from metallurgists, nor that men of recognized ability should formerly have been found both among its champions and opponents, but it is remarkable that, at the present day, with the results of careful research and thorough experiment compiled in convenient shape for perusal, there are iron¬masters who still consider it economy to allow the products of combustion to escape into the atmosphere, rather than utilize them in heating the blast, because of a supposed injury to the quality of the product. In the present state of knowledge and practice, it is proper to express as an axiom, that a well-constructed hot-blast apparatus is essential to the economic operation of an iron-producing plant. Of the interpretation of proper construction there is of necessity a variety of opinions, and, with the view of solving the problem, the apparatus for heating blast has from time to time assumed various forms. Boxes, cylinders, and pipes, placed horizontally, vertically, inclined, or in circles and spirals, have been tried ; there have been pistol-shaped pipes, double pipes, divided or diaphragm pipes, siphon pipes, and as much variety in the mains, connections, flues, and setting. It is probable that, to the introduction of the bell and hopper in

Jan 1, 1876

By R. J. Franklin, G. W. Beckman, D. Warren, E. Both, J. F. Libsch

BINARY and ternary alloys of iron, nickel and cobalt respond to annealing in a magnetic field by a characteristic change in the shape of their hysteresis 100p.l,2 An increase in retentivity and a decrease in coercive force produced by the magnetic treatment cause the hysteresis loop to approach the appearance of a rectangle. Materials with a rectangular hysteresis loop have made possible the contact-rectifier³ and have greatly improved the performance of pulse transformers4 and magnetic amplifiers." In the best material presently available for these applications, a 50 pct nickel-iron alloy," the desired characteristics are achieved by aligning the preferred crystallographic directions of magnetization along the rolling direction of the tape. The objective of the present study has been to produce rectangular hysteresis characteristics in materials with inherently high saturation. Iron-cobalt alloys, exhibiting saturation values up to 24,000 gausses' appeared to offer promise for the magnetic annealing technique, because they remain magnetic to very high temperatures,8 exhibit favorable magnetostriction properties: and show zero crystal energy at 42 pct cobalt.10 Among the ternary iron-cobalt-nickel alloys,7,11 response to heat treatment in a magnetic field is unfortunately limited to alloys having rather low saturation values.' It appeared interesting nevertheless, to study a series of compositions connecting the optimum composition (50/50) of the binary iron-cobalt system with the "Perminvar" composition (30 pct Fe, 25 pct Co, and 45 pct Ni). Very recently, R. Smoluchowski and R. W. Turner," have shown that under certain circumstances magnetic annealing can produce oriented recrystallization. A combination of this technique with the domain orientation utilized in the present study might well result in further improvements. The advantages of the powder metallurgy technique in preparing magnetic alloys for study have

Jan 1, 1951

By P. Hadzeriga

There are two places in the world where potash, trade name for potassium chloride, is economically recovered from naturally occurring brines by solar evaporation. One is at the Dead Sea and the other at Wendover, Utah. American Potash and Chemical at Trona, Calif. recovers potash from natural brines, but uses fuel to accomplish evaporation. Solar evaporation is always desirable, because of low costs, however artificial evaporation may be economical if a group of very valuable salts are recovered. This is the case for the American Potash operations at Trona. Solar evaporation is limited by low working temperatures, which in most areas of the world is between 18 and 45°C. In many cases the average working temperature is about 25°C. However, solar evaporation will have to accommodate itself to the highs and lows of each 24 hour period, and to the different average temperatures during the months of the year. Therefore, solar evaporation, although more economical than artificial evaporation, has a tem- perature limit which greatly reduces the chances of its application. The feasibility of solar evaporation as a means of recovery of values from a particular brine, may be evaluated by the use of phase diagrams showing the several components present. This paper is restricted to the five component system: C1-, SO4=, Na+, K+, Mg++, and H2O, which correspond to brines found at Wendover, Utah, the Great Salt Lake, and sea water bitterns. THE BONNEVILLE OPERATION AT WENDOVER, UTAH For more than 25 years Bonneville, Ltd., now a division of Standard Magnesium and Chemical Co. (recently acquired by Kaiser Aluminum and Chemical Corp.), has been recovering potassium chloride from the brines found in the desert area just east of Wendover, Utah. Solar evaporation of the brines is possible as a consequence of relatively low precipitations (year average: 4.8 in.), and of dry and hot summer months. The brine, collected by a series of approximately 67 mi. of ditches crossing the desert, is fed into solar evaporation ponds. Evaporation which takes place from around the middle of May to about the end of September, permits the crystallization of approximately 90% of the originally present NaCl on what is called the "General Pond Area". Further evaporation,

Jan 1, 1964

By Daniel M. Bass, Paul B. Crawford

Laboratory investigations have been made to study the effect of variations in fluid characteristics, gas saturation, water saturation, and water injection rate on oil recovery by water flooding. Three synthetic gas-saturated crude oils having bubble points of 860, 1,540 and 1,885 psi were used as reservoir fluids. Repeated tests were made in which a and pack, saturated with water and synthetic oil, was produced by solution gas drive followed by water flooding at various pressure levels. Oil recovery by solution gas drive and subsequent water injection is shown to vary with the pressure and rate at which the water flood is conducted. The pressure at which optimum flooding conditions exist is shown to be a functiotl of the physical characteristics of the reservoir fluid. For the systems studied, increases in oil recoveries of near 10 per cent were obtained by flooding at the most desirable conditions. Va- riations in initial water saturations gave results similar to those in the literature. INTRODUCTION Most of the waterflooding studies investigating means of improving present exploitation processes have been conducted at low pressures with little effort to simulate reservoir conditions. Holmgren and Morse' performed a waterflooding study at 300 to 500 psi wherein the gas saturation was created by injecting gas, letting dissolved gas evolve from the oil, and then flushing the core with "live" oil until the desired gas saturation was obtained. Their results show increasing oil recoveries with increasing gas saturations. Data presented by Guerrero' and Kennedy, et al, indicate that in some instances water flooding at approximately 500 psi below the original bubble point results in a lower residual oil saturation than is obtained when water flooding above the bubble point. In their work gas saturations were created by primary depletion. By correcting low pressure flooding data for fluid shrinkage, Dyes found that a maximum oil recovery may be obtained by flooding with initial gas saturations of from 7 to 12 per cent. The purpose of this work was to determine the variations in oil recovery caused by initiating a waterflooding program at various stages of primary depletion of a core. This is a part of a more comprehensive study of obtaining criteria for determining when to initiate a pressure maintenance program and what fluids to in-ject. EQUIPMENT A schematic diagram of the apparatus is shown in Fig. 1. Fluid transfer was accomplished with metering pumps. Pressure control was ob-

Jan 1, 1957