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By G. A. Croes, N. Schwarz

This paper reports the results of a series of model displacement experiments carried out for measuring the efficiency of the water-drive process. This series forms a continuation and extension of that described by Engel-herts and Klinkenberg. Detailed information has been obtained on the influence of the oil/water viscosity ratio. The results are represented in the form of a diagram from which both the oil recovery and the water/oil ratio can be easily read off as a function of the total production (oil plus water) for all values of the viscosity ratio M between I and 500. These resu1ts are viewed in the light of the two existing theories on water flooding, viz. that of Buckley and Leverett and that of Dietz. It is shown that if the Buckley-Leverett theory applies, the relation between the relative permeability ratio and saturation, which plays a major role in this theory, (.an be calculated with a high degree of accuracy from the results of the model experiments. Dietz's theory is found to be in agreement with the experimental results in a certain range of circumstances. A discussion of the physical background of the Buckley- Leverett and Dietz theories makes it clear why the latter fails to agree with some of the experimental results. INTRODUCTION For an economical exploitation of oil fields both a rational control of natural (primary) recovery processes and a proper application of artificial (secondary) recovery methods are essential. These require detailed information upon the dependence of the relevant flow processes on the variables by which they are governed. Three methods are available for obtaining this information: (1) (statistical) analysis of actual field data; (2) appropriately scaled model experiments; and (3) mathematical analysis of the physical problem. If sufficient data were available, the first method would, in principle, be the most reliable one, although it has the drawback that the basic relationships between the variables involved are to a large extent obscured by the natural inhomogeneities of most reservoirs. The most profitable procedure seems to be: (a) determining the fundamental relations for idealized reservoirs by methods (2) and (3); (b) checking the consistency of the results obtained by these two methods; and (c) establishing the range of applicability of these methods to actual reservoirs by comparison with the data accumulated under (1). In this paper items (a) and (b) are dealt with for the case of homogeneous loose sands initially saturated

Jan 1, 1956

By Gilbert Thiessen

THE purposes of this paper are (1) to show that the mineral matter content of coal is satisfactorily represented by the Parr formula; that is, Mineral matter = 1.08 Ash + 0.55 Total sulfur (2) to compare ash-to-mineral-matter ratios with factors by which ash values must be multiplied in order that dry, factor-times-ash-free values shall equal Parr unit coal values; (3) to examine such ash-correction factors and to compare them with similar factors corresponding to certain simplifications or modifications of the Parr formulas and (4) to show that ash-correction factors used for simplification in calculating approximate unit coal calorific values cannot be. correctly used for the conversion of other determined values in an analysis to the unit coal basis, but that each type of calculation requires separate treatment in simplification.

Jan 1, 1934

By Hugh Marriott

MANGANESE and its ores have been recently dealt with in comprehensive papers to the Iron and Steel Institute by Sir Robert Hadfield, and in a series of papers read before the A. I. M. E. at the Cleveland meeting. I have taken the opportunity of adding this mineral, to my records of the "World's Mineral Production and Consumption," as recently pub-lished in the Economist ?. The tables bring out the following significant facts: The world's production has increased by 10 per cent since 1913. India's production has increased by 3 per cent since 1.913, the supply from this source now being 31.1 per cent of the world's output. Russia is now producing at about half its pre-war rate and yields 19 per cent of the world's production. West Africa supplies 12.5 per cent of the world's total output. Brazil's present output is 2.5 times that of the pre-war period, being 11.3 per cent of the world's output.

Jan 9, 1927

By H. Q. Golder

With the development of open-pit mines of ever increasing depth, the stability of the pit slopes in soil and rock is of growing economic importance. How is it, considering the newness of the problem that we know anything at all about the stability of man-made slopes? How much do we know and how did it all begin? We can make a reasonable estimate of the stability of a slope in soil, but we know as yet woefully little about slopes in rock because the problem is much more complex. It is only with the development of the capacity of the computer to handle wearisome calculations that any but the simplest of stability problems in rock have become possible of solution. But what we do know is a guide of immense value in the design of slopes in rock. But remember that the computer is a great elevator; it takes everyone's feet off the ground! So our study began with soils and what is now known as "Soil Mechanics", which is a translation of the German term "Bodenmechanik". It is a pity that the title of Terzaghi's book "Erdbaumechanik" was not used instead. But here the task of the translator is difficult because English lacks the facility of German to string together several words and make a new one whose meaning is unequivocal. Thus, we have the three German words 'Erde' 'Bau' and 'Mechanik'. 'Erde' means "earth" in almost all the English senses including "soil". 'Bau' and 'bauen' convey the meaning of building and construction, and 'Mechanik' means "mechanics" which includes statics and dynamics and the 'mechanics of materials', etc. So that a correct translation of the German is a phrase like "the mechanics of construction with, in or on, earth or soil." However we are stuck with 'Soil Mechanics' and that is where it all began. Now this study or subject did not begin with 'Terzaghi' although his contribution to the subject is unquestionably greater than that of any other single person. Every scientific discipline has its 'classical problem' and that of soil mechanics is 'the earth pressure problem' and it began in the 17th century. In fact, it probably began before this with the introduction of gunpowder to Western Europe in about the 15th century, but the first known reference to the problem was by Vauban, a distinguished French military engineer who lived from 1633 to 1707 and who gave rules for the dimensions of retaining walls from 6 to 80 ft. in height. The soil properties were not mentioned by Vauban probably because the rules were intended to be applied to fortifications only, but Poncelet (1840) claimed that Vauban's rules were based on a theory, and not simply on military and practical

Jan 1, 1972

By Alden B. Greninger

The study of mosaic structure of crystals1 has been confined until recently to the field of theoretical physics. Crystallographers, in general, have neglected the subject, although X-ray crystallographers constantly make use of formulas for intensities of X-ray reflection as modified by mosaic structure. Work on mosaic structure has centered chiefly on the task of proving or disproving the secondary-structure theory of Zwicky,² and very little attention has been paid to the visible imperfections of crystals. A. Goetz has been responsible for most of the supposed experimental confirmations of Zwicky's theory.3 On the other hand, Smckal,4 and Orowan,5 among others, maintain that there is neither theoretical nor experimental evidence to substantiate Zwicky's secondary structure. Lately the subject has been intensively investigated by Buerger,6 one of whose recent papers led to a symposium on mosaic structures.'

Jan 1, 1935

By Alden B. Greninger

The study of mosaic structure of crystals1 has been confined until recently to the field of theoretical physics. Crystallographers, in general, have neglected the subject, although X-ray crystallographers constantly make use of formulas for intensities of X-ray reflection as modified by mosaic structure. Work on mosaic structure has centered chiefly on the task of proving or disproving the secondary-structure theory of Zwicky,² and very little attention has been paid to the visible imperfections of crystals. A. Goetz has been responsible for most of the supposed experimental confirmations of Zwicky's theory.3 On the other hand, Smckal,4 and Orowan,5 among others, maintain that there is neither theoretical nor experimental evidence to substantiate Zwicky's secondary structure. Lately the subject has been intensively investigated by Buerger,6 one of whose recent papers led to a symposium on mosaic structures.'

Jan 1, 1935

By A. T. Beckwith

THE Lehigh Navigation Coal Company Inc. operates steep-pitch, relatively deep mines in the Panther Creek Valley, at the eastern end of the southern anthracite coal field. Commercially minable coal beds are the Mammoth,† Primrose, Orchard, and Buck Mountain,‡ their respective thicknesses average 50, 15, 1o and 12 ft. Sand slates immediately overlie and underlie these beds, though in some locations sandstone or conglomerate beds occur. Underground operations extend to a depth of 1200 ft. below the surface, and comprise a bulk of virgin work on the lower levels, and a small amount of remining on the upper levels. With increase in depth, ventilation has become a more important factor. DEVELOPMENT In early days slopes or drifts were driven in the outcropping coal on the hillsides. Subsequent development was by water-level tunnels, with portals above high water in Panther Creek. These tunnels have been maintained because they intercept and drain much water that enters the mined-out portion of the bed and otherwise would follow down to the deep workings. Below these tunnels, the coal was customarily developed by slopes. Muleways, which are zigzag chutes easy to travel, were also driven to connect lower openings with the water levels. When it became necessary to go still deeper, the slopes were abandoned, and vertical multicompartment shafts were sunk from the surface. Levels have been at vertical intervals of from 195 to 250 ft. Recent practice has been toward the latter spacing; splitting the total lift, however, by starting to mine from chutes extending halfway up to the level above. Chutes customarily are spaced at 50, 60 or 70-ft. centers along the gangways. At some mines, additional shafts have been sunk from the surface to the level containing the main pumping station, and these carry the discharge lines from the pumps. As the mines are ventilated by the exhausting system, both the hoisting and so-called water shafts serve as intakes. The main fan is always on the surface, and is connected with the return airways from the various levels by an air hole or a vertical shaft. For economy, when the present deepest levels were developed, main return-air shafts or air holes were not extended to the new level, but connections were made from the new level to that above by two or more holes. It is doubtful that this method will be continued, as complications in the system, increased resistance to flow, and other difficulties undoubtedly will counterbalance any economies this provision may afford.

Jan 1, 1942

By G. T. Murray

The aging behavior of a Cu-Ti (3.2 at. pct Ti) alloy has been followed by electrical resistivity, hardness, and metallographic changes. The resistivity data indicate two principal processes, the first causing a sharp decrease in resistivity, and the second, which occurs over a long period of time, a much smaller rate of decrease. Lamellar nodules, Widmanstätten platelets, and homogeneous continuous precipitation was observed. The Widmanstätten platelets grow at the expense of the latter. When this study was initiated, little information was available on the aging behavior of copper-base titanium alloys. Several articles'-3 that appeared in the early 1930's showed that these alloys could be strengthened by precipitation, but a detailed study was not made. Within the past year, however, two other more comprehensive studies4'5 have been reported in the literature, one consisting primarily of an investigation of mechanical properties, the other

Jan 1, 1961

By Roscoe Bell

An economic appraisal of the western phosphate industrial potentials made between 1945 and 1948 revealed possibilities for a considerable expansion in the production of high analysis phosphate fertilizer. The most significant facts are: (1) a rapidly increasing and a much larger potential market which might be reached from the western deposits, (2) the existence of large undeveloped deposits of phosphate rock, (3) potential energy from sulphuric acid, coal, or hydroelectric power in the general vicinity of the deposits. The challenge to the mining and metallurgical engineering profession is in the economical development of phosphate mines and in improving processes for utilization of the western ores and the recovery of byproducts to make the expanded western industry satisfactorily compete with the industry in the East and South in meeting the fertilizer needs of the Midwest and Far West.

Jan 4, 1950

By L. Webster Wickes

The bad effects of arsenic in commercial copper are well-known to metallurgists. The refining of copper by electrolysis eliminates practically all of the arsenic, provided certain requirements are fulfilled. The first, and most important, of these requirements is, that the voltage of the depositing current shall not be too high. It has been known for some time that the percentage of arsenic in the deposited copper increases with the voltage. To investigate the relation between the electro-motive force (e.m.f.) and the freedom of the precipitated copper from arsenic, the experiments were made, of which a brief summary is here given: I made three copper-arsenic alloys, containing respectively 3.56, 2.24 and 0.96 per cent. of arsenic. From these alloys I cast several anodes. For cathodes I used sheets of thin copper,

Jan 1, 1905

By HILLARY W.

THAT colleges and technical schools constitute a vital factor in our industrial system is being realized more and more of late years. Consequently it is desirable that there should be a constant interchange of ideas between the 'school and the industries and that there should be a more intimate contact between the student and his future employer. Business and industry demand certain proficiencies and qualifications of the student and he, in turn, sees certain rewards and advantages in the industry. . In a meeting of this kind, whose primary purpose is to promote a greater intimacy between the students and those men who are active in the mining profession, it is quite fitting that each state his demnds upon the other in order to establish a common understanding. It is probable that a student, not being conversant with actual conditions in the industry, may be unfair in what he asks of his employer. Therefore criticism, constructive or other- wise, is not only accepted, but is invited.

Jan 1, 1930

CHARLES SCHUCHERT,* New Haven, Conn. (written discussion?).- I embrace ace the opportunity to take part in a discussion of Mr. Woodruff's paper because a successful discerning of what actually constitutes pet-roliferous areas from the geologists' standpoint is worthy of our endeavors, not only from the intellectual side, but also because it may lead, as Mr. Woodruff hopes, to the more certain establishment of principles that can be applied to other continents in exploiting them for petroleum. This discussion will also embrace the results of two other recent papers, one by Alexander W. McCoy and one by Maurice G. Mehl.1 Sources of Petroleum.-Mr. Woodruff is agreed that petroleum comes from plants and animals, or possibly from both, and that it has ac-cumulated by migration into reservoir rocks. These reservoir rocks must of course be porous to become catch basins for the oil and gas, and then, too, their present structures are variable, as they occur in anticlines, domes, terraces, etc. , The structures, he states, are more widespread than are the oil pools, and the same is true for the reservoir rocks. Accordingly, there must be many good sands and structures

Jan 11, 1919

By W. C. Kerr

When Agassiz and his party of geologists commenced their exploration of the interior of Brazil and the Amazon region, one of the first and, to the last, one of the most novel and striking phenomena which met them everywhere was the great depth of decomposed or partially decayed rock in situ, which mantles, and for the most part conceals, the underlying strata. The same facts strike all geological observers from the North who happen to penetrate the middle and southern latitudes of the Atlantic States. In North Carolina, e. g., the entire middle and western regions, outside of the Quaternary clays, sands, and gravels of the East,—that is, all that portion of the State occupied by the Archæan and Mesozoic rocks,—show everywhere this peculiarity, so new to those accustomed to glaciated surfaces. Not only do the hills and slopes, the mountain chains and

Jan 1, 1880

By Francis Foley

WITH the possible exception of high-speed tool steel, the service demanded of rock-drill steel is probably more precarious than that of any other tool steel. Unaided by the helpful influence of alloys and dependent solely on the efficiency of the heat treatment applied for its ability to stand up under the abuse to which it is necessarily subjected, rock-drill steel is worthy of intensive study. For its heat treatment the smith has his fire, an oil fire perhaps, and a quenching bath; he judges' the temperature by his eye. There are shops where excellent drills are produced by this method, but there are more where the product varies between very good and very bad. Pyrometers with specially designed equipment are used in but few cases. But the responsibility for rock-drill failures does not rest entirely on the smith. Little has been published concerning the efficiency of drill steel, though the Canadian Mining Journal' published the breakage record of a large number of hollow drill steels. This record indicates that most of the breaks occur during the early life of the steel and that as a given batch of steel is used, its percentage of breakage decreases. This fact, the article points out, is at variance with the much-talked-f theory concerning failure from crystallization and fatigue. It seems to point to the fact that the greater part of drill-steel failure from breakage is traceable to faulty manufacture, resulting in defects in the bore of the hollow steel from inclusions of slag or oxides, etc. As this defective material meets with early failure, it is weeded out. In addition, some breakage may be caused by a lack of proper condition with respect to heat treatment of the steel as furnished by the manufacturer. In the article mentioned, the breakage of 1 ¼ -in. (3.17 cm.) hollow steel is given as 4.62 per cent. for the early period of use, with a decrease to 3.35 per cent. and 2.67 per cent. With time in use. For 1-in. (2.5 cm.) hexagonal hollow steel, the figures for breakage are 0.18 per cent. and 0.06 per cent.; attention is called to the "enormous decrease in breakage by the use of smaller diameter drills." The figures are given as so many "drills sharpened," but there is no way of determining the percentage of

Jan 6, 1921

By Waldemar Lindgren

CONTENTS. [ ] I. INTRODUCTION. THE precious metals, gold and silver, are the basis of the monetary systems of the world. It is, therefore, natural and inevitable that widespread interest should be manifested in their production and in the various classes of deposits in which they are contained. At times a great scarcity of the precious metals has prevailed; at other times the production has seemed so abnormally large that fears have been entertained regarding their ultimate retention as standards of value. Since most nations have adopted the gold standard, and the remaining ones appear likely to do the same in the near future, the question of available supply of gold for the present and future very naturally arises. This necessarily involves a consideration of the characteristics of the gold-deposits. After the absorption of the gold treasures of the New World by the conquistadores, the gold-placers of Brazil and Russia

Jan 1, 1913

By O. P. Arora, J. B. Darby, Paul A. Beck

LAVES and Wallbaum' reported that the phases occurring at the compositions TiFe, TiRu, and TiOs, which are stable over a wide range of temperatures and are separated from neighboring phases by wide two phase fields, have a CsC1-type ordered structure. For TiRu and TiOs, this was recently confirmed by C. B. Jordan.2 Recent results of Greenfield and Beck3 show that solid solutions with ruthenium of the body-centered-cubic elements vanadium and tantalum (and presumably also of colum-bium) in group Va of the periodic table undergo CsC1-type ordering. Although detailed phase diagrams for these systems are not yet available, it would appear that these ordered structures are separated from the neighboring body-centered-cubic solid solutions by relatively narrow two phase fields.

Jan 1, 1957

By J. I. Budnick, W. B. Ittner III, D. P. Seraphim

A reliable technique has been developed for producing single crystals of tantalum in the form of small diameter wires. By suitably heat treating these and polycrystal samples, first in an oxygen atmosphere and finally in vacuum, it has been found possible to reduce residual resistivities to 10-3 microhm-cm. The purity of these samples is thus comparable to the purities obtained in zone-refined silver, copper, and aluminum. THE growth and purification of pure single crystals of the transition metals is, in general, difficult. The high melting and annealing temperatures of these metals make it necessary to employ rather special techniques in any crystallization process. In addition, the transition metals show a great affinity for and are easily contaminated by nitrogen, oxygen, and carbon. Recently, however. a number of investigators have been successful in growing,

Jan 1, 1961

By H. E. Sadler, Prof. Silliman

The research here recorded was undertaken early in the present year, and has been prosecuted steadily for about eight months. While the work has been under my constant supervision and advice, the labor has all been performed by Mr. Sadler, to whom is chiefly due the development of the successive steps which have led to the final result. The process is better than I dared to hope, and we are able to place at the command of chemists and engineers interested in the matter an apparatus of continuous and uninterrupted action, and methods of analysis by which the daily averages of the two variable and inconstant factors of illuminating gas, ammonia and sulphur, may be determined with all needful accuracy, even by those little skilled in chemical manipulation, and with very little loss of time. This research has been carried out in the laboratory of the New Haven Gaslight Company.

R. U. Jackson (Conveyor vs. Track Haulage, P. 866) is the author of a previous work on conveyor systems, which was presented at the Annual Meeting of the Arizona Section of the AIME in December 1951. He has worked for the Carnegie Steel Co., Koppers Co., Fairmont Mining Machinery Co., and the Hewitt-Robins, Inc., the Robins Conveyor Div., for the past 30 years, as engineer, district manager, and manager of the mining div. Jackson is a graduate of Carnegie Institute of Technology, and was born in Steelton; Pa. His present residence is in Clifton, N. J., where in his spare time he devotes himself to hiking and photography interests. F. S. White (Co-author, Solids Fluidization Applied to Lime Burning, P. 903) is a Washington University, St. Louis, Graduate, who now lives in Stockbridge, Mass. He served as a technical apprentice at Mobile, Ala., for the Aluminum Ore Co., and after four years went to Bauxite, Ark, as technical superintendent of calcination and precipitation. After a year and a half, he became technical and operating superintendent of the sintering plant. White also worked for the Dorr Co., and is now with the New England Lime Co. serving as assistant to the president. For relaxation he collects stamps and plays the piano.

Jan 1, 1952

By Charles Reed

WITH the increasing importance of clay in drilling operations which demand more precise and exacting control over its behavior, there has come the realization that most of our present methods of control over many of its important properties still represent more of an art than a science. Such a situation with respect to a material of such industrial significance is unfortunate, and naturally many investigations have been conducted to improve our knowledge. In general, these investigations have revealed the complex nature of clay behavior and while sometimes they may not have seemed to contribute directly to a solution of the field operator's problems they have been of inestimable importance in bringing to light the broad fundamental scientific principles upon which must be based any effective working theory correlating the known facts of clay behavior and predicting profitable new lines of attack for its improvement.

Jan 1, 1938