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By T. S. Lundy, J. I. Federer

Chemically purified Zr95and Cb95 have been used in determining self-diffusion coefficients in the bcc phase of iodide zirconium over the temperature range of 900o to 1750°C. The temperature dependence of the diffusion coefficients could not be described by the usual Arrhenius-type equation over the entire temperature range. Values of the apparent frequency factors (D0)a and activation energies (Q)A for ZR95 varied from 4.8 x 10-6 to 2.5 x 10-2 sq cm per sec and 20,700 to 46,900 cal per mole, respectively, between 900°and 1750°C. Similarly, for Cb95, values of (Do) a and (Q)A varied from about 2.4 x 10'5 to 0.25 sq cm per sec and 26,500 to 56,800 cal per mole, respectively. The data may be described in terms of the a to ß transition temperature of 1136 °K and the absolute temperature of the diffusion anneals by the following eauations: SEVERAL studies on the diffusion of Zr95 in zirconium have been reported.1"5 The values of the constants contained in the usual Arrhenius-type equation for describing the temperature dependence of the diffusion coefficient, D = Do exp [- Q/(RT)], are summarized in Table I. The reported values of Do, the frequency factor, and Q, the activation energy, are seen to vary by factors of about 60 and 1.6, respectively. Examination of the data from any one study indicated reasonable consistency of measurements. The large discrepancies of over-all results, therefore, cannot be explained on the basis of experimental scatter. One possible explanation for the differences in results could be a varying impurity content of the zirconium. Another possibility is that the radioactive daughter, Cb95, influenced the values of some of the determined diffusion coefficients. Therefore, the first of the three purposes of this study was to reconcile the large differences in diffusion results that have been obtained. Several empirical relations have been proposed to relate the diffusion coefficients in solids with physical properties, such as the absolute melting point, the heat of fusion, and the heat of sublimation.

Jan 1, 1963

By Paul Soros

There has been a steady increase in shiploading capacities in the last 20 years. One of the reasons has been the general increase in ship sizes, with the largest vessels currently around 280,000 DWT in the bulk trades. Obviously, the large vessels can accept loads faster and their economic utilization justifies higher loading rates, up to a point. The high capacity facilities have loading rates far beyond this point. The economic logic of these facilities is based on the fact that for a given annual throughput the capital and operating cost of a single high capacity system is less than that of two smaller systems. Thus, where the projected throughputs are large, there is a great incentive to reduce capital costs by maximizing capacity. Tubarao, in Brazil, designed for a 100 million ton per year throughput with one finger pier and one high capacity berth is a successful demonstration of this approach. In the current state of the art, the high capacity systems have shiploading capacities in the range of 10,000 - 16,000 TPH, for annual throughputs of 20 million tons and larger per loading berth.

Jan 1, 1982

By Walter Gervásio Ladeira

O quartzito Taboões é uma fonte potencial de matérias-primas de sílica (areias industriais), e precisa ser adequadamente caracterizado para se definir metodologias de beneficiamento que visem o seu melhor aproveitamento possível. Dois litotipos foram classificados nos quartzitos intemperizados da Formação Taboões presentes em São Joaquim de Bicas – MG: quartzito argiloso e quartzito. A principal diferença entre eles é a abundância relativa de argilominerais. Em uma amostra representativa do quartzito argiloso foram caracterizados quatro tipos de contaminações com auxílio de análises granulométricas e químicas, microscopia (óptica e eletrônica de varredura), e difração de raios-X. Estas contaminações são: incrustações no quartzo; películas de argilominerais e minerais de ferro aderidas ao quartzo; partículas de minerais de ferro liberadas em meio ao quartzito; e partículas liberadas de rochas estranhas ao quartzito. A caracterização realizada é um ponto de partida para se planejar rotas de processamento mineral visando obtenção de matérias-primas para a indústria.

Aug 8, 2018

By Erik Westman, BEN WESTON, SETAREH GHAYCHI AFROUZ, KATHRYN DEHN

This study investigates the changes in seismic velocity of rockmass before and after three major seismic events to determine any potential identifiable precursory velocity changes associated with these events. Induced stress measurement is one of the challenging tasks in deep underground mining, with extreme impacts on the safety and stability of the mine. This study used p-wave passive seismic tomography to image the velocity redistribution within a rockmass, which can indicate induced stress level changes in the rockmass and detect the velocity changes that might precede a major seismic event or a rockburst. The ultimate goal of this research focus is to develop another tool for the deep-mining community that will help to increase safety and efficiency. For this purpose, the hypothesis of conventional mechanics, which implies induced stress at the hypocenter (as inferred by the p-wave velocity) increases until the seismic event occurs, is evaluated. It is found that the p-wave velocity did not increase at any of the three hypocenters prior to the seismic event occurring; however, the p-wave velocity did increase in the closest “zone center” for two of the three events. 

By Aaron Evans, Chu E. Ho, Tom Richards

"This paper describes an innovative case history of using jet grouting to form a groundwater cutoff wall at the interface of a cut-and-cover construction and an existing tunnel. The design of the jet grouting layout was complicated by the presence of a left-in-place bulkhead of unknown dimensions abandoned by previous construction of the existing tunnel. Jet grouting was performed through predrilled holes within the narrow space between the existing bulkhead sheeting and tunnel structure. A systematic sequence of primary and secondary jet grout elements of varying diameters and panel lengths was executed to achieve an effective groundwater barrier. A key challenge in the jet grout design was the impact of potential deviations due to shadowing effects of the left-in-place bulkhead sheeting and pre-formed jet grout columns, as well as overbreak concrete in adjacent secant pile walls. The flexibility of the jet grouting methodology enabled a wide range of operational parameter combinations to be performed, allowing column diameters to be adjusted based on actual field installation measurements. Special precaution was exercised when grouting at critical locations to avoid over-pressurization and damage to the existing tunnel structure.IntroductionThe 96th Street Station box for the new Second Avenue Subway Line in Manhattan, New York included a transition tunnel, which connected the station to an existing tunnel built in the early 1970s (Figure 1). The new station and transition tunnel were both constructed using the cut-and-cover technique with bottom-up sequence (Aksman et al. 2012, Grigson et al. 2016). The main station structure incorporated permanent diaphragm walls for most of its length, except for the southern segment where high rock levels were encountered and the station box was constructed within temporary secant pile walls socketed into the rock. The permanent diaphragm walls were also utilized for temporary excavation support (Ho and Hu 2014). At the northern end of the site, the new transition tunnel was constructed within temporary secant pile walls that extended from the station diaphragm walls to the existing tunnel at the tie-in location. A temporary traffic deck spanning 60ft across the secant pile and diaphragm walls along the full excavated length of the site allowed traffic to continue operating at street level while construction of the station and transition tunnel progressed below grade."

Jan 1, 2016

By Y. S. Li

The life cycle assessment method is applied to investigate the environmental impacts of cop-per-slag and copper-ore concentration process. Some environmental load data of copper production are obtained. The result indicates that damage level of human health, ecosystem quality and re-sources respectively is 0.174, 0.0203, 0.246 in the copper-slag concentration and 0.112, 0.0136, 0.299 in the copper-ore concentration. Environmental impact of copper-slag production (0.44) is more than that of copper-ore production (0.42), but can meet the environmental protect demand. With domestic copper concentrate supply gap enlarging, recovering copper from slag will lead to a significant improving of resource utilization and development of circulation economics.

Jan 1, 2014

By Corby G. Anderson

Since 1985, the Sunshine Mining Company has used a patented nitric-sulfuric acid pressure leaching system for production of silver and copper from a refractory sulfide ore body. To better understand this novel process, a program of lab scale testing was undertaken to quantify the effect of system variables on silver recovery. Some of the factors studied include temperature, agitation, acidity, vessel pressure, particle size, percent solids and oxidizer amount. In turn, this knowledge will be applied in actual plant practice to upgrade reaction time, increase concentrate throughput, raise silver recovery and lower reagent costs. A discussion of plant process changes resulting from lab scale testing is included.

Jan 1, 1991

By José Vidalón G

El presente trabajo analiza los diversos métodos de concentración de minerales de estaño empleados en los países productores de este metal. Asimismo se describen los procesos de gravedad, se analiza la flotación de caseterita, la concentración por volatización, así como se presenta algunos diagramas de flujo ilustrativos.

Oct 14, 1980

By Helmut Thielsch

IN recent years an ever increasing amount of interest has been directed toward research studying the principles and various applications of sonic and supersonic waves. Though still in their early stages of practical development, sonic vibrations are already used in the emulsification and degasification of liquids. Metals exposed to sonic or ultrasonic vibrations while solidifying show a considerable amount of grain refinement. Often sound waves are applied instead of radiography to test engineering materials for internal cracks and flaws.1 In the field of pure research these waves are used in dispersion and also in coagulation of particles or liquids in gaseous or, under certain conditions, in other liquid systems. In the settling and thickening of slurries considerable time is necessary to compress the solid particles and to squeeze out the liquid to obtain as low a dilution (liquid to solid ratio) as possible. Various methods have been developed to increase the amount of coagulation of the very fine solids (colloidal or semicolloidal) and to shorten the over-all time. The addition of small amounts of electrolytes and the warming of the suspension represent merely the more important techniques. Some of the effects of supersonic vibrations have been reported previously.2,6 From preliminary studies, therefore, it was hoped that by application of sonic vibrations it would be possible to reduce the time required to thicken such materials to a specific dilution, as well as to thicken to lower ultimate dilutions than could be obtained by quiescent settling alone. By increasing the volume thickened per unit time-i.e., improving the plant efficiency-great savings in equipment and time would be obtained for industrial processes. Also, faster settling rates should result if coagulation of particles could be increased. Experiments have been conducted for a period of several months in the Allis-Chalmers laboratory to study the effect of sonic vibrations on settling of particles of different sizes and concentrations. APPARATUS The sedimentation apparatus used in these experiments is illustrated in Figs. I and 2. The essential features are the stationary field coil and the movable voice coil. Both windings are placed around a solid iron core. A leather diaphragm connected to the steel frame holds the voice coil in place. A brass rod is fastened to the voice coil with a metal disk connected to the other end. This disk is sealed to the lucite cylinder with a flexible rubber diaphragm. The lucite tube is 17 in. long; its inner diameter is 2 ½in. and the wall thickness is ¼ in. The tube is calibrated on the outside in 10 c.c. divisions for a total of 1000 cubic centimeters.

Jan 1, 1946

By L. R., McLeod

NO important changes in metallurgical practice are exhibited in the smelter that has been erected for treating the Morenci concentrate: the material is charged to reverberatory furnaces without roasting, and the matte subsequently blown in Peirce-Smith converters to separate the iron and sulphur from the copper. In fact the process is essentially the same, except for preliminary roasting of the concentrate, that was adopted in the new smelter that was built for the Arizona Copper Co. at Clifton, a few miles away, to treat Morenci concentrate just before the start of the first World War, and which went into service in October, 1913.

Jan 1, 1942

By H. Yen, D. E. Walsh, H. K. Lin

"Comminution circuits are widely used in nonferrous and precious metals milling. Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) fines, are unavoidably produced and report to undersize products in the classification circuit, i.e., flotation or leach feed, while tramp grinding steel (TGS) reports to classification oversize products and returns to the grinding mill, building up in the circulating load. In laboratory studies, TGS reduced grinding efficiency significantly, the impact being dependent upon the size of the TGS present in the mill. Because iron fines adsorb flotation reagents effectively, iron fines increase reagent consumption and reduce flotation recovery. Iron fines are also capable of reducing gold recovery in cyanidation circuits via a cementation reaction. When using filtered gold solution from the cyanidation circuit of an Alaskan gold mine, the gold concentration in solution was reduced by 0.2 to 2.6% over various reaction periods when iron fines were present in the solution.IntroductionComminution circuits are widely used in copper, lead, zinc, nickel, cobalt, molybdenum and precious metal mills. Flotation and leaching processes are usually preceded by comminution (crushing and grinding) circuits in order to liberate valuable minerals for effective separation, concentration or dissolution by the subsequent flotation or leaching processes.Steel crushers, grinding mills and grinding media are typically used in comminution circuits. Comminution circuit wear products, in the form of metallic iron (steel) powder, are unavoidably produced and report to undersize products in the classification circuit (flotation or leach feed), while tramp grinding steel (TGS) reports to oversize productions during classification and returns to the grinding mill, building up in the circulating load. Variables affecting the amount of metallic iron powder and TGS produced in a comminution circuit include ore hardness, grinding mill operating conditions, comminution circuit design and the metallurgy of the steel used for manufacturing crusher liners, mill liners and grinding media. As one example, a comminution circuit product of 80% passing 200 mesh at the Pogo Mine, AK is estimated to contain approximately 2 kg/t of metallic iron. A finer grind will generally produce a comminution circuit product with higher metallic iron fines content."

Jan 1, 2015

By Sastry Putcha, Santosh Mummaneni, Swamy Avasarala, Vamshi Vemula

"This paper presents the results from a case study on the comparison of two strain acquisition instrumentation technologies, Geokon rebar strainmeters and Embedded Data Collectors (EDC) for the DC Water Main Pump Station project, in Washington D.C. These two instrumentation systems were installed by AVER in a single 18-inch (0.45 m) diameter augercast pile (with one-1.25 inch (3.175 cm) dywidag bar) at critical locations to determine the load transfer mechanism and establish a comparison between strain/load measured with these two systems along the pile. A quick static load test was performed on the test pile as per ASTM D1143 standard.Prior to the installation of the pile, a 24-inch (0.6 m) diameter outer casing was installed to the proposed cutoff elevation of -22.5 feet (-6.85 m) to discount the frictional resitance within the upper overburden zone. The pile was then drilled through the outer casing to the tip elevation of -65.02 feet (-19.8 m) with inner casing within the overburden zone. Strainmeters along with EDC were installed on dywidag bar at various locations and then wet set into the concrete following auger retrieval. The loads measured with EDC and Geokon sensors were within 15% percent of each other.PROJECT BACKGROUNDProject Background & Requirements:Like any other foundation piles, augercast piles are extensively used in the public and private sector structures in the United States for many years. It is a common practice to perform static compression (ASTM D1143), tension (ASTM D3689), and lateral load tests (ASTM D3966) depending on the project requirements. In recent years, embedded strain sensors, manufactured by Smart Structures, USA has gained prominence for its use to collect both static and dynamic measurements for driven piles. In addition, AVER has successfully used EDC for collecting long term static measurements for an abutment drilled shafts for I-95 Hotlanes project in Virginia, USA.Geokon sisterbar strain gages are widely used in the foundation industry to monitor the load transfer mechanism within pile foundations throughout the world. As the Geokon strainmeters are vibrating wire and are welded to a sister bar, there is often a debate within the engineering community with regards to what modulus to use when converting measured strains to loads. EDC sensors, unlike Geokon strain gages are embedded directly into the concrete and therefore do not have the same concern."

Jan 1, 1900

By D. C. Yates, G. V. Jolliffe

In the five coalfields of Staffordshire, there have been some 43 incidents of spontaneous fires and heatings which have required special attention in the past ten years. This total excludes incidents in the Thick Coal Seam of South Staffordshire, which was worked until 1967, and which was subject to an almost continuous series of heatings. The incidents have been classified to show the sites of occurrence, the contributory factors which may have caused them and the treatments applied to them. The remedial techniques, as practised in Staffordshire, are dealt with in detail, with particular reference to standard methods of stopping-off. Precautionary measures taken are described, including a "liability to spontaneous combustion" classification of all seams, and the setting up of an emergency organization with emergency stocks of materials and equipment. The paper is concluded by a few words on the organization and control at the time of an incident.

May 23, 1905

By W. Gibson Jaworek

It has become apparent in recent years to everyone intimately concerned with the future of the American fuels industries that the growth in demand for energy has become a topic receiving considerable attention, and that investigators are leaning more and more toward a mathematical approach to deduce what pattern that growth will follow. Though coal has been included by necessity In all-studies of future energy markets, it has not been the subject of mathematical analysis or description as frequently as has been total energy or some of the other fuels, particularly petroleum, It is the intent in this particular paper, to subject bituminous coal consumption to a preliminary mathematical scrutiny which can lead to a more logical estimation of the general level of bituminous coal consumption for the next decade, as well as formulating an approach toward describing how coal consumption may vary as the result of the annual variations in activity in the United States, economy, The approach utilized is more sophisticated than the mere projection of the historical trend of bituminous coal consumption. Such a projection would lead to a continuation of the recent decline, indicating that coal consumption would reach zero some thirty years from now. On the other hand, the mathematical analysis described here is a relatively simple, straightforward approach and- is not intended to represent the-ultimate in mathematical economic analysis as now practiced, It is hoped that this will contribute to our knowledge of bituminous coal markets. Even more, it is hoped that it will help arouse a greater interestin utilizing mathematical and statistical analysis when studying the bituminous coal industry. - Since this is a preliminary study, comments and criticisms are anticipated.

Jan 1, 1960

By D. Harrington

Before the present century there existed a fairly persistent demand for the establishment of a Federal Department of Mines, but relatively little was done about it until a considerable number of very serious coal-mine disasters in 1906, 1907, 1908, and 1909 created what might almost be termed a national scandal and virtually forces the Federal. Government to take action to try to solve the problem of the cruse and prevention of such disastrous occurrences. Instead of a Department of Mines, the mining people had to accept a bureau, which was created on July l, 1910; and while the Bureau of Mines was given numerous functions, unquestionably the promotion of safety in the mineral industries was and continues to be one of its main "jobs." The Bureau's organic act was approved in 1910 and amended in 1913. Both the original and amended acts indicated that promoting; the health and safety of the mine workers constituted the chief function of the Bureau, and that this was the construction placed on its activities by those put in charge in 1910 is shown very definitely by the fact that as soon as the Bureau came into existence on July 1, 1910, both health end safety activities were started in its Mine Accidents Division. Before the end of the first fiscal year (June 30, 1911) 6 mine safety stations had been established in various parts of the United States, add 6 nine safety cars had been put into the field; by October 1910 first-aid-training work was being done in mining regions. The Bureau eras able to function so promptly in its safety work largely because sections of the Geological Survey, which had been doing some coal-mine safety work since 1907 or 1905, were transferred into the Bureau when it began to operate in July 1910. On October 30, 1911, a national First-Aid Meet was held at Pittsburgh, Pa., at which first aid and mine rescue were demonstrated. During the fiscal year 1910-11, the first year of the Bureau's existence, 509 persons were given certificates indicating completion of the Bureau's training course in first aid.

Jan 1, 1939

By Federick W. Miller

The Bureau of Mines has investigated the availability of columbium from 19 deposits (3 producers and 16 nonproducers) in 7 market economy countries (MEC?s). Brazil has the largest recoverable columbium resource, posessing approximately 2.39 million metric tons Wmt), or 69 pet of the MEC total (3.47 Mmt). The Western Hemisphere countries of Brazil, Canada and the United States contain 3.14 Mrnt of recoverable columbium or 90 pnt of the MEC total. Columbium recovered as a byproduct of tin mining is not included as part of MEC resources in this study. Currently producing mines are Araxa and Catalao in Brazil, and Niobec in Canada, These three mines have 2.42 Mmt of recoverable resources or approximately 69 pct of the MEC total. It is estimated that these mines, operating at full capacity, could satisfy cumulative MEC demand (based on an annual growth rate of 5.1 pct) for the next 20 yr. The United States is totally dependent upon foreign sources for its columbium supply. The majority of U.S. columbium is imported from Brazil in the form of steelmaking- grade ferrocolumbium. Canada has been the sole source of pyrochlore concentrates since Brazil discontinued exports in 1981. The United States also imports small (but important) quantities of columbium as columbite concentrates from Nigeria and Brazil, as columbite contained in tin slags from Thailand and Malaysia, and as synthetic concentrates from the Federal Republic of Germany.

Jan 1, 1986

By Lionel A. York

THE first application of the cementation process took place in the year 1864, according to H. Standish Ball, when a break in the brickwork lining at a depth of 270', in one of the Rhine Preussen pits near Homburg, was sealed by running in milk of cement from the surface by means of a small hand pump. At about the same time Monsieur Portier adopted the method in France for repairing breaks in shaft lining. Figure 1 is descriptive of the Portier system and is of interest when compared with modern practice. During the next thirty years numerous attempts were made to improve the process; the general method used in sinking being to put clown bore holes outside the perimeter of the shaft for the purposes of injection. The cementation process was first recognized as an important as-set to mining in 1896 when Monsieur A. Francois developed his method of boring and injecting inside the shaft below the permanent water level. The Francois cementation process rapidly attained fame on the Continent and many shafts were sunk by its use in France, Belgium and

Jan 1, 1961

By M. Yamine, R. J. Ring, D. J. Waters

"An experimental program has been carried out by the Australian Atomic Energy Commission to compare the effectiveness of Caro's acid as an alternative oxidant to pyrolusite in the leaching of uranium ores from the Alligator Rivers region of northern Australia. Batch leaching tests on Ranger, Nabarlek, Koongarra and Jabiluka ores showed that uranium extraction was unaffected by choice of oxidant, but that Caro's acid reduced acid requirements by 15 - 25%. Lime requirements for neutralization of tailings liquors were reduced by 20 - 30%.The batch studies were extended to a four-stage continuous leaching circuit with a capacity of 400 gore h-I. Comparative leaching tests confirmed the reagent savings obtained in the batch tests. Following these encouraging laboratory results, lnterox Chemicals Pty Ltd carried out plant trials using Caro's acid. Reagent savings in the mill were similar to, or better than, those obtained in laboratory test work. The trials also established that Caro's acid has a number of operational advantages over pyrolusite.IntroductionUranium is most commonly extracted from its ores by leaching in sulphuric acid. Simple hexavalent uranium oxides and compounds are readily soluble but uranium in the tetravalent form is insoluble and must be oxidized for dissolution to occur. The most commonly used oxidants have been sodium chlorate and manganese dioxide. They act indirectly by maintaining iron as the ferric ion which oxidizes uranium by a surface electro- chemical reaction. An Fe3+ concentration of about 1 - 2 g L-I is usually considered adequate for the effective dissolution of uraninite(1)."

Jan 1, 1984

By Harold L. Riley

This Bureau of Mines paper describes the methods and practices used at the Peck quarry of the Crab Orchard Stone Co., Inc., one of the leading producers of dimension stone in the Crossville, Tenn., area. The product is marketed under the registered trademark "Crab Orchard Stone". Another large producer of stone from the Crossville district sells its product under the registered trademark of "Tenn-Quartz". Both companies, and a number of other companies and individuals who quarry and process dimension stone from the same general geological formation, are members of the Quartzite Producers Association of Tennessee. The salable product is shipped throughout the country for use as architectural building stone. In 1959, 653,008 cubic feet of stone was produced in the Crossville area and was sold for $1,414,405. Terms and descriptions used in this report are those of the quarry and building trades. The offices, pitching sheds, wire saws, railroad siding, and storage areas of the Crab Orchard Stone Co., Inc., are on a side road 0.3 mile north from a point 2.2 miles east of Crossville, Tenn., on U.S. Highway 70. The quarry is on this same side road 2.0 miles south of Highway 70. Crossville is 62 miles west of Knoxville and 65 miles northeast of Chattanooga, Tenn.

Jan 1, 1962

By H. P. Hamlin, W. A. Grosh

Samples of clays , shales , and argillites from 21 locations were subjected to preliminary bench- scale tests for bloating properties , and several samples were tested for ceramic properties . Samples showing favorable bloating properties were further tested in a pilot - plant - scale rotary kiln . Physical characteristics and concrete -making properties of the bloated products were determined . The Decorah shale from one area made a suitable material for a lightweight aggregate ; however , the limestone layers in the formation must be eliminated or the resulting activated lime must be controlled by quenching .

Jan 1, 1963