Search Documents

By C Muñoz, N Ortega, J Vergara, D Avilés

Mass blasts have been the subject of extensive studies because of their potential benefits in mining operations. However, it has not been possible to advance due to the paradigm that states that the blasts near the designed final wall or to critical structures have to be low tonnage. Another reason is the absence of specialised simulation programs to more precisely determine the influence of the energy released by blasting to the rock mass. There are some studies that demonstrate the possibility of massive blasting that maintain the design of the final slope (Farias and Santander, 2014). It should be noted that these studies develop the concept that the size of the blast should not increase the peak vibration in the rock mass.The study was carried out in partnership with Los Colorados Mining Company. Analysis, reconciliation and wall control for two types of blasts were performed:blasting production: approximately 850 000 t, with special wall control considerationsblasting of approximately 950 000 t over the entire width of the bench.Monitoring systems were used in the near field and far field using examination of holes in order to obtain information to assess the impact on the rock mass and then to compare these to conventional blasting combining production and contour blasting.The results show that for a large blasted volume, production and/or those generated from toe to crest on the bench did not produce more impact in the rock mass than the conventional blasting.The conclusions drawn from this study are:an improvement in the excavation rate of 7500 t/h that is higher than the maximum rates normally obtainedthe peak vibrations of the P wave generated by both blasts did not exceed the peak particle velocity criteria (Vergara and Muñoz, 2014)holes examination indicating no difference in their entire length, in pre- and post-blast reviewover US$2 000 000 savings generated in the year (estimated by the client) (Avilés, 2014).CITATION:Vergara, J, Muñoz, C, Ortega, N and Avilés, D, 2015. Benefits related to applications of a mass blast in open cut mining, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 625–632 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By J. E. Hawley

"The zinc-lead deposit of the Lake Geneva Mining Company is on lot 7, con. VI, Hess township, Sudbury district, Ontario, about 10 miles northwest of the northern rim of the Sudbury Basin. Though a relatively small deposit, it shows some rather interesting relations to cross-cutting, pre-ore, quartz diabase dykes, which merit description.The deposit was discovered in October 1924 by J. H. Collins beneath iron-stained drift and oxidized sulphides. This proved to be the northwestern extremity of the orebody, the remainder of which extends southeast below swampy ground. Exploration began in 1927. In 1928 a vertical shaft was sunk to 250 feet and a level established at 235 feet. Later the shaft was deepened to 400 feet and new levels opened at 315 and 375 feet. In 1943 an inclined winze was sunk below the vein from the 315-foot level to a vertical depth of 640 feet, and two additional levels were opened at 525 and 615 feet respectively.The geology of the area has been described by T. T. Quirke (1), F. F. Osborne (2), F. J. Alcock (3), and Ralph Tuck (4). Private reports have also been made by Carl Tolman, J. E. Gill, and K. W. Fritzsche. Tuck's paper, covering the work completed to 1930, gives a detailed account of the character of the ore and enclosing rocks.Up to May 1944, when the property was closed, all ore above the 375-foot level and a small tonnage from below this elevation had been removed. Ore mined from 1941 to 1944 yielded the following:"

Jan 1, 1954

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By A. Ceylan

Pyrite is present as a gangue mineral in most of complex sulphide ores and most of time it is removed as a tailing. However, beneficiation of pyrite from tailings could be important because of its economical value and for the environmental concern. This paper presents a research for the enrichment of pyrite from copper plant tailings, Siirt-Madenköy/Turkey, by flotation. Siirt-Madenköy copper mine is operated by Park Electric Production Mining and Industry since 2005. In order to obtain the pyrite from Siirt-Madenköy copper plant tailings, laboratory test work has to be done to determine the type of reagents, the flowsheet, and the size of plant. The objective of the company is to develop a pyrite flotation circuit for concentration of pyrite from tailing dam to obtain 500.000 tons/year pyrite concentrate. There are about 3 million tons tailings that containing pyrite in the tailings dam. Experiments were carried out with three different types of tailings from the plant and the pyrite concentrate with 46% Fe and 90% recovery has been obtained. Therefore, this study shows that high grade pyrite with high recovery can be recovered from the tailings.

Sep 1, 2012

By Z. W. Zhang, Songsong Xu, Jinhui Li, Yun Zou, Yu Zhao

High strength low alloy (HSLA) steels with high strength, high toughness, good corrosion resistance and weldability, can be widely used in shipbuilding, automobile, construction, bridging industry, etc. The microstructure evolution and mechanical properties can be influenced by thermomechanical processing. In this study, themomechanical processing is optimized to control the matrix microstructure and nano-scale precipitates in the matrix simultaneously. It is found that the low-temperature toughness and ductility of the steels are significantly the matrix microstructure during enhancing the strength by introducing the nano-scale precipitates. The effects of alloying elements on the microstructure evolution and nano-scale precipitation are also discussed.

Jan 1, 2016

By SANDEEP KUMAR JENA

This paper reviews the recovery of potassium from different rocks and mineral sources. Global demand for potassium is rising steadily due to the growth of agricultural production. Fertilizer manufacture consumes the majority of the world’s potassium production, with other uses including those in the pharmaceutical, glass, ceramic, food and detergent industries. The availability of soluble potash (K2O) minerals, such as sylvite, kainite and carnalite, in countries like Canada, the United States, Israel and Russia makes them major potash producers, whereas agriculture-based countries like Liberia, Somalia, Central African Republic, Thailand, Indonesia, Malaysia and India meet their potassium requirements through imports only. In these countries, the huge availability of potassium-bearing rocks/minerals like nepheline syenite, feldspar, mica and glauconitic sandstone, containing around 4 to 17 percent K2O, brings up the prospect of commercial production of potassium. Potassium recovery from minerals/rocks is complicated due to the uniform distribution of potassium throughout the crystal structure. Different physico-chemical separation methods like bioleaching, chemical leaching, flotation and roast-leaching have been discussed for the successful recovery of potash values from these rocks/minerals. Although seawater is vastly available, the recovery of potassium from seawater using chemical precipitation, solvent extraction, membrane separation and ion-exchange methods is not cost-effective due to low concentration of potassium.

By Ward B

Central Colliery was developed to exploit large underground reserves in the German Creek lease. It was planned from the outset as a retreating longwall operation and is the first longwall mine in Queensland. Longwall mining is not new to Australia but all previous experience has been confined to the coalfields of New South Wales. There was no precedent for longwall extraction in the markedly different geological setting of the Bowen Basin in Central Queensland. Various investigations were thus carried out during the initial development of Central Colliery, prior to the installation of the longwall, to ascertain the geotechnical characteristics of the coal seam and the adjacent strata and to predict the performance of the heading and pillar design as mining proceeds to depth. Laboratory tests showed the coal to be weak with an unconfined compressive strength of 9.6 MN/m2. Site inspection and geophysical correlation revealed a shear zone and extensive intraformational shear planes in the seam. The latter were found to exert a controlling influence on rib reaction in the headings. This behaviour was predicted by finite element modelling of the development headings which indicated that mining induced stresses in the coal would be relieved by block movement of the ribs. A chain pillar width versus depth curve was established for yielding pillar design based on empirical and computational methods. This gave pillar widths from 25m to 48m over the proposed depth range of 150m to 300m. Finite element modelling of the 25m pillars chosen for the first gateroads confirmed the overall stability of the design but suggested that rib spall could be significant in the adjacent tailgate. (1) Chief Mining Engineer, Capricorn Coal Management Pty. Ltd., German Creek Mine, Queensland (2) Senior Engineering Geologist, Coal Division, The Shell Company of Australia Limited, Melbourne

Jan 1, 1986

By Toshiaki Tsuru, Takeshi Ohgai, Hisaaki Fukushima, Shigeo Kobayashi, Tetsuya Akiyama

"Electrodeposition behavior of Zn-Cr alloys from the methanol baths was investigated. In the methanol baths of low Cr3+ concentration, Cr (III) compound was incorporated in the deposits and no lusfrous Zn-Cr alloys was deposited. However, Cr was existed as metallic state in the deposits obtained from the baths of higher Cr3+ concentration. With an increase in water content in the baths, the chemical state of Cr in the deposits changed from metallic to trivalent state. Under the condition that metallic Cr can be electrodeposited, Zn deposition was significantly polarized to the potential of Cr deposition.INTRODUCTIONAn attention has been paid to Zn-Cr alloy plated steel sheet because of its excellent properties for body panels of automobile and electrical appliances [1]-[4]. This plating process can be operated using the sulfate solutions containing Cr3+ ion [1] - [6].In decorative single Cr plating, on the other hand, many attempts have been made to electroplate Cr from trivalent electrolytes, which is motived by environmental deficiencies of the presently used hexavalent process [7]. [8]. However, it has been reported that in the aqueous solutions the behavior of the electroreduction of 0 3+ is atypical due to the complicated nature of the chemistry and electrochemistry of cr3+ species [9]-[11]. Even in Zn-Cr alloy plating, it is difficult to codeposit metallic Cr with Zn in simple sulfate electrolytes [l]-[4], [12]. Therefore, it can be expected that the electrodeposition behaviors of Zn-Cr alloys as well as Cr are significantly changed when the electrodeposition is conducted in non-aqueous plating solutions.In this study, the electrodeposition of Zn-Cr alloy was conducted from methanol solutions to clarify the electroreduction mechanism of Cr3·-Cr0 in the alloy deposition process."

Jan 1, 2000

By R. E. Hudrlik, G. W. Preckshot

The diffusion coefficients of silver from solid silver in molten lead were measured to within ± 0.8 pet in a columnar type diffusion cell ower, the temperature range of 326° to 530°C. Fick's law describes the process up to 530°C where the laminar mechanism appareltly breaks down. These is negligible resistance at the interface as shown by mathematical analyses. The diffusion coefficients are found concentration independent. IT would seem that diffusion in liquid metals would be free of such effects as molecular structure, dissociation. polarization. and compound formation. This view was taken by Gorman and preckshot in their study of diffusion of copper from solid copper into molten lead. They reported diffusion coefficients which were independent of the concentration over the range of 478° to 750°C. They found that the Stokes-Einstein equation with constant radius of the diffusing specie represented the diffusion data better than Eyring's rate theory equation and Sheibel's correlation. The radius of diffusion was found to be that of the doubly charged copper. There appeared to be no resistance across the solid-liquid boundary. In the present work the diffusion coefficients for silver in liquid lead were measured over a range of temperatures of 350° to 505°C. The solubility of silver in lead over the range of 303° to 630°C was also obtained. These results are compared with calculated or correlated values or with data in the literature. EXPERIMENTAL Procedure—The experimental equipment techniques and procedures were those reported in detail by Gorman and preckshot9 and will not be repeated here. Measured values of WT, Co, A. L were obtained for various diffusion times and the diffusion coefficient was computed for the case of no resistance at the interface9, 11 by: WT/CoAL = 1- 8/p2 n=1 1/(2n - 1)2 exp[-(2n - 1)2p2 Dt/4L2] [1] or where there was resistance at the interface by: WT = 1- ?n=1 2h2/ap2L [sxp [-Dan2t]/[(h2 + an2) L + h] The roots an are those of the transcendental equation3 tan (an L) = Iz/cun. The diffusion coefficient is that defined by Hartley and Crank.7 The total silver in the lead cylinder and equilibrium slug was determined by a cupellation technique' with proper correction for losses. Analysis of known samples showed that this method is surprisingly accurate. The amount of silver in the lead adhering to the silver cylinder was obtained in the same fashion as shown by Gorman and preckshot.9 The small errors involved in this determination are not critical since the silver in this adhering lead layer is only 3 to 15 pet of the total diffused. Materials—Electrolytic silver containing 99.9+ pet Ag obtained from General Refineries of Minneapolis, Minn. was used for all but runs 7 and 8. For the balance of the runs this silver was reduced with hydrogen at 1100°C and its oxygen content was found to be about 0.017 pet. For the runs. 7 and 8, phosphorous-reduced silver of the same purity was obtained from Handy and Harman Co. of Chicago, Ill. The densities of the phosphorus-reduced silver and the hydrogen-reduced electrolytic silver were 10.484 and 10.487 g per cm3, respectively. These values agree with those reported for pure silver. Silver which was reduced at 900 C had an average density of 9.998 g per cm3, indicating porosity. This silver was used for a number of runs which were not tabulated in Table I. These are indicated by crosses on Fig. 2. The 99.999 pet Pb was obtained from the National Lead Co. Research Laboratory of Brooklyn, New York. DISCUSSION OF RESULTS The diffusion and solubility results are reported in Table I for eleven runs using either phosphorus-reduced electrolytic silver or hydrogen-reduced silver at 1100° C. The solubility data shown in Fig. 1 show the excellent agreement with that reported by Heycock and Neville.8 The data of Friedrichs5 apparently are in error. The experimental solubility data of this work are reported to 0.3 pet. The experimental diffusion coefficients computed from Eq. [1] are reported within 1.2 pet of the mean and are plotted in Fig. 2. These are expressed within +0.8 pet of the experimental values over the entire temperature range by: D= 8.26 x 10 -5 e-1925/RT . [3] There appears to be little difference due to the

Jan 1, 1961

By Huntington J. F, Green A. A

The quality of a photointerpreter's anno- tation of an image may be displayed by writing maps in which the pixels are shaded according to the number of times a pixel was seen to be on a feature. The map of grey tones is more valuable, if, for each grey level, a measure of quality is determined, which is the probability that a feature exists in a pixel of a given grey tone. From repeated annotations (at least four) of the same image by a single observer, it is possible to formulate a perception model which describes stochastic processes in the observer. From that model, it is possible to assign estimates of data quality for each observer to each grey tone. For two observers on the same scene, the 'mean' method of quantifying the grey levels is to assign a value equal to the mean of the ii,:lities for each of the two observers separately. For this example, the grey tones arr thus quantified at probability levels of 0.70, 0.80, 0.90 and 0.95.

Jan 1, 1977

Physical model testing at Bergbauforschung is done in two rigs, a roadway rig and a longwall rig. The loading of such models, in scale relation to the con- ditions in the collieries provides valuable guidance to the probability and nature of failures, and thus to support requirements, in structural, roofbolts and self- auvancing supports. The success of such modelling when related to subsequent underground designs put to use suggests that such methods of investigation could be extended to pillar extraction problems also.

Jan 1, 1974

By C. Dirscherl

"Declining ore grade, leading to increased material transport and plant throughput requirements, is one of the major challenges in the current mining environment. This is accompanied by rising energy and labor costs, decreasing plant productivity and the requirement for highest plant availability. Siemens’ answer is the latest gearless drive technology for grinding and conveying. Gearless drive solutions are surpassing the mechanical limits of conventional drive systems serving to utilize the principle of economies of scale. By elimination of various components of the drive train the maintenance activities and spare parts inventories are reduced. The advantages are culminating in the incomparable availability of the Siemens’ gearless drive technology of 99.46 to 99.71% - as confirmed by real operational data from the Antapaccay mine in Peru. It was the first plant worldwide to use gearless drives for both applications. KEYWORDS: Gearless Mill Drives, Gearless Conveyor Drives, Availability, SAG Mill, Ball Mill, Overland Conveyor, Antapaccay INTRODUCTION – THE GEARLESS PRINCIPLE The principle idea behind a gearless drive system is to reduce the number of components and diversity of parts. Especially those components that are at the edge of current manufacturing or power limits are eliminated. The used equipment provides the possibility to scale up and increase the power transmitted to the driven machine. This finally results in a possible increase of throughput respectively transported or processed material. In order to apply this principle of simplification we will take a look at the components of a conventional drive system consisting of: - Driven equipment (mill, conveyor, slurry pump…) - Components altering the rated speed (gearboxes, girth gear / pinion) - The electric motor - Starting devices for the motor (VSD, CCV, LRS, clutch…), which are necessary because a direct across-the-line start of high power motors with load would result in a significant drop in the line supply voltage - Alternatively a variable speed drive (VSD) or cycloconverter (CCV) to utilize the possibility of speed variation during operation - The electrical supply system (cables, switchgear, transformers, protection equipment) Intermediate gearboxes are not required when a motor is used with a rated speed that directly matches the speed requirement of the driven equipment. Furthermore the VSD can be used to smoothly start the motor and to vary speed during operation, which means that it satisfies both requirements."

Jan 1, 2015

By N. Magdalinovic

Generally speaking, erosion, as a process which entails degradation of surface layers of earth under the influence of the mechanical energy of surface waters, and from the point of view of biosphere sustainability, is a harmful process. This is absolutely true when agricultural and forest areas are concerned. However, if erosion is viewed selectively, this general definition about its harm raises serious questions. In other words, the erosion which takes place in the terrains where there is no vegetation because of the geological composition of the soil, does no harm. On the contrary, if the mineralogical composition of such terrains is characterized by a presence of precious and rare metals, erosion can be very useful. It contributes to the creation of new alluvial deposits of these metals in the waters in the plain land. It is here that torrents from hills come down and cause erosion. And finally, if there were no erosion, there would be no renewable deposits of gravel and sand.

Jan 1, 2007

By A. W. Jacob

THE shatter cut, or burn cut as it is often called, is one in which the centre of the round is almost reamed out by drilling holes so close together that the blasting of a few holes shatters the rock embraced by all of them. The idea of shattering the centre of a face by shooting holes drilled parallel to one another is not new. Some miners have used this method for years past, when drilling quartz or a face near timber. But, they followed the age-old practice of first blasting the cut, then the square-up. It was not thought possible to shoot both together. In the case of machine men, the two largest contributors to silicosis are dust from drilling and dust from blasting. It follows, then, that material reduction of exposure to either constitutes an important step in lessening the incidence o silicosis. It was? the hope of being able to do away with the necessity of the men having to return early to a face, through dust concentrations of 60,000 to 80,000 particles per cubic centimeter, that aroused interest "in the shatter cut at McIntyre. Efforts to this end were successful. Now, with this kind of cut, all holes of a round are shot simultaneously.

Jan 1, 1942

By L. Chunpongtong

One of the challenges of mine planning is to determine the most cost-effective replacement time for aging equipment. The lifespan of equipment, such as haul trucks and shovels, deployed in mining operations varies due to the nature of the material and ground conditions in which it operates. For engineering economists dealing with aging equipment, the options become an economic trade-off between higher maintenance cost versus the cost of new equipment. The discount rate plays a significant role in this decision; the higher the rate, the longer the economically optimal lifespan. Therefore, the ultimate question is: ?How can the relationship between the discount rate and the economically optimal lifespan be expressed mathematically??

Aug 1, 2013

By H. M. Kim, J. Rutqvist, D. W. Ryu

"Demand of high pressurized gas storage in underground rock caverns is increasing. Compressed natural gas (CNG) and compressed air energy storage (CAES) are one of the promising examples after since lined rock cavern (LRC) concept has been verified through in-situ pilot tests. Two key essential concerns of high pressured gas storage in underground rock caverns are mechanical stability of the cavern against high inner storage pressure and the risk of gas leakage from the caverns.In this study, we introduce our results of numerical simulations so as to investigate the potential of monitoring for gas leakage at a pilot facility for CAES in underground LRCs. The pilot facility was constructed at a comparatively shallow depth of 100 m, compared to the previous cases with several hundreds of meters, aiming at validating the feasibility of the LRC storage concept in which inner sealing liners, consisting of steel plate and concrete linings, are installed inside the excavated rock caverns (KIGAM, 2011). Compressed air may leak through either initial defects of inner containment liners such as imperfect welding regions and in-situ construction joints of the liners, or through structurally damaged points of the liners during the CAES operation where compression and decompression of the caverns are necessarily repeated and their structural robustness can be deteriorated.For this perspective, we carried out a coupled thermodynamic and geomechanical deformation analysis using TOUGH-FLAC simulator, and investigated the effectiveness of strain monitoring method in detecting mechanical failure of liners which may provide major pathways of air leakage. We therefore used an equivalent continuum model to relate the localized tangential strain to fracture permeability changes, which was developed in our early work (Rutqvist et al, 2012). In detecting and characterizing the leakage location, we tested a cross correlation technique using the synthetic pressure responses monitored in case of the failure of the inner liners. From the investigations, we showed that tangential strain, rather than radial, monitoring especially at the inner face of the sealing liners can be more effective in detecting the mechanical failure of the liners.In localizing the leakage point, we noted that the interface between the inner liners and surrounding rock may not be perfectly bonded so as to increase permeability through which any leaking air pressure may migrate more dominantly. We also demonstrated that the cross correlation of the time histories of pressure measurement especially at these interfaces can be useful in identifying the leakage point. These results may provide useful information in overall design of monitoring and alarming system of our upcoming CAES pilot facilities."

Jan 1, 2015

By Yuanbo Zhang, Zhixiong You, Li Qin, Guanghui Li, Tao Jiang

Low-grade manganese oxide ore is generally characterized by high iron content. In this work, sulfidation roasting of an iron-rich manganese oxide ore with elemental sulfur was characterized. The experimental results indicated that manganese dioxide can be selectively reduced over iron oxide by using elemental sulfur. The manganese phases in roasted product included low-valence manganese oxide, manganese sulfide and manganese sulfate, while those of iron mainly depended on the sulfur addition. Iron oxide would only be reduced or sulfidized at larger sulfur additions. The effect of roasting temperature and S/Mn mole ratio on the phase transformations was also investigated; extractions of Mn/Fe by sulfuric acid were evaluated. An extraction of Mn greater than 95% was obtained while that of Fe was controlled less than 10% under the optimal conditions.

Jan 1, 2016

By Zvi Rivlin

Classical nucleation theory states that in first order phase transformations, such as liquid to solid transition, nucleation of the product phase starts with the formation of small, unstable clusters (embryos). When the thermodynamic barrier to nucleation is overcome, the embryos grow and attain a critical size, beyond which they are stable, i.e. they become nuclei. If nucle- ation does not occur, the parent, liquid phase remains in metastable equilibrium. At temperature lowers, undercooling increase and atomic mobility decreases. The viscosity change in the undercooled liquid may result in the formation of glassy state. As demonstrated in previous papers [I-21, in solidification involving surface nucleation of the product phase, as the case is in rapid quenching by melt-spinning, both nucleation temperature and nucleation time depend upon the number of atoms available at the isothermal surface in contact with the substrate. As a result of the thinness of the melt-spun ribbons, the embryo clusters that form at the freezing temperature may not be supplied by the amount of atoms necessary for their growth to critical nuclei sizes. In such extreme conditions, the liquid does not crystallize, it forms a metallic glass. A numerical simulation method is proposed for the reactions involved in embryo cluster formation and growth, at the atomic level. The simulation enables the caIcuIation of either the nucleation or the glass transition temperatures. Calculations made for the well-known glass forming CuZr and FeB systems afford prediction of the geometrical and thermodynamically conditions necessary for the formation of either crystalline or amorphous ribbons in melt-spun ribbons.

Jan 1, 1994

By Wilbur I. Duvall

A linear array of shot and gage holes 30 feet deep in a granite outcrop was used to compare the size and shape of radial strain pulses produced in the rock when short cylindrical charges of cast composition B were detonated axially or at one end. The axially detonated charges produced radial strain pulses that had shorter rise times and larger peak strain than the strain pulses produced by end detonated charges.

Jan 1, 1965

By Pizhi Zhao, Yingdong Li, Hailong Cao, Yingjuan Feng

"Three types of anodic films (unsealed, hot water sealed and agent sealed) were prepared to study the effects of anodizing pores structure on the adhesive bonding performance of AA5754 automotive sheets. The morphology of the anodic films was examined by using scanning electron microscope (SEM) and the composition was examined by glow discharge optical emission spectroscopy (GDOES). The adhesive bonding strength and durability in corrosive environment were investigated by using single lap shear test and salt spray corrosion test (SST), respectively. The results showed that the pores structure could significantly influence the adhesive bonding performance. The unsealed sample showed porous structure and provided high bonding strength, however, the durability was poor in corrosive environment. The hot water sealed sample showed fine and loose hydrated alumin a structure on the surface and provided high durability in corrosive environment, but the bonding strength was low. In contrast, the agent sealed sample provided both high bonding strength and durability in corrosive environment.INTRODUCTIONAdhesively bonded aluminum joints by using adhesives have been widely used for the realization of lightweight design in industrial applications like automotive and aerospace industry[1, 2]. Durable bonds which are capable of taking structural loads can be created due to a careful consideration of the way in which the joint is formed, the type of adhesive and the appropriate treatment of the adherend surfaces prior to bonding[3-6]. Experiences demonstrate that the surface treatment is the most critical step which could not be disregarded, since it is essential to achieve long-term service capability [7].In structural applications, a bonded assembly is expected to maintain a significant load and may be combined with exposure to harsh environmental conditions in its service life. For this purpose, the pretreatment for structural bonding of aluminum alloy must provide not only strong tensile strength and durability but also good corrosion resistance. Chromic acid anodizing (CAA) process provides an anodized layer which has good corrosion resistance while also exhibiting useful adhesion characteristics as well as lacquer coating retaining characteristics[8].However, the use of Cr (VI) is unadvised from a health and environmental point of view since it is toxic and carcinogenic, and this process is gradually limited even prohibited. Boeing's phosphoric acid anodizing(PAA) process provides a more open pore structure allowing penetration of high molecular primers/adhesives[8]and PAA process is the most widely used pre-surface treatment suitable for adhesive bonding between aluminum alloy components. Rahimi et al. demonstrated that nanostructure can be produced by PAA process and is affected by the time of pretreatment and anodizing parameters [9]. Xu et al.investigated the influence of surface energy and roughness on adhesive bonding through PAAprocess and provided improved adhesion performance under certain anodizing parameter[10]. However, PAA process is normally not recommended for a major concern of deterioration of the mechanical performance of the joints as a result of exposure to a wet and corrosive environment. Sulfuric acid anodizing(SAA)process, recently, has been widely used for corrosion protection and good base coating for the adhesion of lacquers in aerospace manufacturing[11]. The good performance is explained by properties such as the porous morphology and high adsorptive power of the oxide film, the chemical and electrical inertness of the anodized layer. Moreover, modified sulfuric acid could also used for adhesive bonding. Lunder et al. found that anodizing in hot sulfuric acid is promising as a simple, very rapid and environmentally friendly pre-treatment for adhesive bonding[12].Saeedikhani et al. studied the process of phosphoric/boric/sulfuric acids anodizing and found it was is a promising pre-treatment for adhesive bon"

Jan 1, 2018