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By B. W. Madsen

A nearly dormant copper sulfide pilot-scale experimental leach containing 8.7 tons of are was injected with oxygen to determine its effect on the copper-leaching rate. Prior treatment of the uncrushed 0.25-percent-copper, mine-run stripping material consisted of 461 days of acid ferric sulfate leaching, which extracted 47 percent of the total copper. The permeability of the bed had decreased, and the percolation rate had decreased from an initial 20 gallons to 0.8 gallon per square foot per day. Copper extraction had nearly stopped. After injecting oxygen into the ore column and leaching for 30 days, the percolation rate was increased to 6 gallons per square foot per day. In an additional 298 days of leaching, an additional 40.7 percent of the copper was extracted. The improved leaching after the use of oxygen is attributed to stimulated bacterial action, better oxidation, and increased permeability.

Jan 1, 1975

By J. M. Stuve

Low-temperature heat capacities and the enthalpy of formation were deter-mined calorimetrically by the Bureau of Mines for CuO?CuS04. The derived standard entropy (S°298.15) was 40.36±0.04 cal/deg-mole, and the enthalpy of formation (?H°f) was -219.l±0.3 kcal/g-mole. A large thermal anomaly was observed in the heat capacity of CuO?CuS04 at 20±0.1 K. Gibbs energy of formation data are tabulated up to 1,200 K. Construction details of a precision low-temperature adiabatic calorimeter capable of determining heat capacities of solids in the temperature range 5 to 320 K are given. A calibrated miniature germanium resistance thermometer was incorporated into the calorimeter to extend the range of accurate measurements below 15 K. High-resistance dc heater windings were used throughout the cryostat to reduce heat conduction of inner connecting wires.

Jan 1, 1975

By P. Gonzalez

Minera La Parreña, S.A. de C.V., Milpillas operation is an underground mine designed to process 8 352 tons of ore per day for the recovery of copper through crushing, heap leaching, solvent extraction and electrowinning facilities. In order to optimize copper recovery during leaching, the ore is crushed to 13 mm and subjected to primary sampling every 15 minutes for metallurgical accounting. At the same particle size, primary sample goes to secondary sampling and then, the secondary sample is crushed to 2 mm before tertiary sampling. The tertiary sample is sent to laboratory where a final sample is obtained and pulverized to 106 microns for copper assay. This paper shows a review of sampling strategy focused on minimizing or eliminating sampling errors and an experiment designed to determine copper head grade profile as well as the best sampling frequency.

Jan 1, 2009

By L. Bryson, J. H. W. M. Brits, K. Voogt

"The Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) has the world’s first full deposit nickel plating tankhouse. Impurities in the nickel electrolyte can induce stresses in the electrowon nickel deposits that could lead to delamination of the deposit. Identifying the impurities that contribute to increasing internal stresses in the nickel deposit is key to successful operation and automation of the tankhouse. Impurities were introduced in the plant electrolyte and the effects on the full-scale nickel deposits evaluated. The impurity-adjusted electrolyte solutions were also analyzed using commercially available bench-scale methods to determine the induced stress. A correlation between impurity-induced deposit stress and full-scale delamination was developed. A direct correlation can now be made between feed quality, i.e. impurity concentrations, and degree of delamination in the plant. This methodology has the potential to rapidly predict the effect of new reagents, upstream process upset conditions and synergistic interactions between impurities on deposit stress and delamination of nickel deposits.INTRODUCTION Nickel electrowinning in sulphate media was first pioneered by Outokumpu in its Harjavalta refinery in 1960 (Saarinen and Seilo, 1985). The original process was very manual with starter sheets plated onto “acid resistant” steel for 36 hours and then manually stripped and cut into sheets which could be inserted into the main production cells for a further 4–5 days. The starter sheet stripping and manufacture process was later automated. The same technology was subsequently implemented on a number of plants around the world. Anglo American Platinum’s Base Metal Refinery (BMR) began nickel electrowinning in the early 1980’s. The recent expansion of Anglo American Platinum’s Base Metals Refinery necessitated the construction of a new nickel tankhouse to achieve two primary objectives. The first to increase the capacity to 32 400 tpa nickel and the second to reduce employee occupational exposure to nickel aerosols. The new tankhouse has been commissioned and is in the process of ramp-up; more details are given by Hagemann et al. (2016). Fundamental to lowering employee exposure to aerosols was automating both harvesting and final handling of cathode. In order to accomplish this a bold move was taken to plate up to 10 days on permanent titanium blanks which are harvested by automatic crane and automatically stripped. The original development work for the plating nickel on titanium blanks over a ten day cycle is given by Bryson et al. (2006)."

Jan 1, 2017

By Johne Jesus Mol Peixoto, João Victor Gomes Guimarães Ananias, Itavahn Alves da Silva, Thiago Araújo Santos de Oliveira, Weslei Viana Gabriel, Carlos Antônio da Silva, Salvatore Giuliano PeixotoTropia

O arraste de escória para o distribuidor, durante a drenagem de panelas de aço, tem grande impacto no rendimento metálico, limpidez e produtividade no processo de lingotamento contínuo. Modelamento físico e matemático foram utilizados para o estudo da formação do escoamento tipo vórtice e funil no esgotamento de panelas de aço. Em um modelo em escala 1:6,5 foi avaliada a influência da vazão de drenagem, altura inicial de líquido, temperatura do banho e estratificação da temperatura sobre a altura crítica (Hcr) de formação de vórtice. Para todas as condições experimentais, o valor de Hcr se mostrou crescente com o aumento da vazão, respeitando uma relação linear. Através da técnica de Particle Image Velocimetry – PIV observou-se o desenvolvimento do campo de velocidades sub-superficiais da água durante a drenagem em modelo de acrílico em escala 1:6,5. Os resultados das simulações fluidodinâmicas obtiveram bom acordo com os experimentos físicos, e foram capazes de representar a influência da vazão e da temperatura sobre o valor de Hcr.

Oct 1, 2019

By L Q. Amorim

The mining district of the Quadrilátero Ferrífero (QF) in southeastern Brazil contributes to 70 per cent of the Brazilian iron ore production, which reached 370 Mt in 2010. Traditionally, four iron ore types were mined in the QF region:1. soft haematite,2. hard haematite,3. friable ‘itabirite’ (the Brazilian name for metamorphosed banded iron formation), and4. canga (an indurated iron-rich crust).With the exception of the hard haematite, these categories derive from supergene enrichment of the Paleoproterozoic Cauê Itabirite. High current iron ore demand means that the QF high grade supergene ores will be depleted in a few decades. Consequently, several mining projects are being developed to exploit unenriched, fresh itabirite. Among them, the Mineração Usiminas Serra Azul project in northwestern QF is one of the most advanced. Four major itabirite types occur in the QF region:1. siliceous (or standard),2. dolomitic,3. amphibolitic, and4. magnetitic.The dominant type in Serra Azul region is a fresh siliceous itabirite, composed essentially of haematite, martite and quartz that averages 36 per cent Fe (51.5 per cent Fe2O3) and 47 per cent SiO2. The second type, the magnetitic itabirite, consisting of magnetite, martite, gruneritecummingtonite, quartz, dolomite, stilpnomelane, and subordinate haematite, is typically a strongly magnetic greenish banded iron formation with the iron grade varying between 25 and 35 per cent. Chemically, it differs from the siliceous itabirite due to the relatively high CaO, MgO and, consequently, high LOI contents. Together with supergene ores, fresh itabirites have been included in the ore reserves of the Serra Azul project. We anticipate that all the four types of fresh itabirite will be incorporated as ore in the QF region, causing a huge increase on the iron ore resources of the district, and representing enormous environmental and technological challenges for the local iron ore industry.

Jul 11, 2011

By A. C. Boyle

PaGE I. Introduction.........68 II. Location of the District,....... • 70 .. III. Stratigraphy...........73 Description of the Rocks.......73 Triassic Eruptives (Andesite Flows and Tuffs) ....73 Triassic Sediments (Shales and Slates)..75 Areal Geology ............75 Structure...-.......76 Folds............. 76 Faults..........79 Shear ...........80 Intrusives..........81 Alaskite Dike.........81 Andesitic Intrusion.......82 IV. PetrogRaphy of thE Rock Types......83 Andesite Flows.........84 Tuff 8...........84 Andesite Tuff........84 Rhyolite Tuff.....-.......85 Alaskite-Porphyry.......89 Andesite Dike........91 V. Description of the Mines......92 VI. Metalliferous Deposits ........ 95 Character of the Ores...........97 Mineralogy of the Ores.......97 Metallic Minerals.......97 Microscopic Character of the Ores...98 Secondary Enrichment....... 103 Genesis of the Ores ...........104 VII. The Sulphate Deposits.......109 Gypsum ..... HO Anhydrite......... ,... 110 Barite............ 110 Origin. with special reference to Gypsum....111 VIII. Summary.............. 113 IX. BIblYogRaphY.............114

Jan 1, 1915

By Nagai K, Moriyama K

Toyo smelter has been making s veral efforts to reduce and diversify energy for dealing successfully with such :n:;rgy problems as the first and second oil crises. ::,specially it is one of th:; most important subjects to substitute oil by alternative: energy source, because oil is expensive and unstable with respect to its supply. t _'hercfore i was decided to propel tnC ezhstitution of coal *jr oil. in the first place, the supple- mental fuel oil in the reaction shaft was replaced by oil to coal in 1981, and then th, fuel substitution of pulverized coal was achieved in the steam superheater in 1984. 3y these fuel substitutions about 7u,' of the total fuel energy at 2oyo smelter has been replaced by coal. in this paper the fuel substitu- tions at loyo smelter are described in detail.

Jan 1, 1987

By J. W. Freeman, J. P. Rowe, R. F. Decker

HEAT-to-heat variations in properties of an alloy of constant nominal chemical composition have been a perplexing problem to the metallurgist. These heat-to-heat differences have been especially baffling in high-temperature metallurgy. In order to establish fundamental reasons for these heat-to-heat variations, the National Advisory Committee for Aeronautics has sponsored and financially assisted an extended research program on heat-resistant alloys at the University of Michigan. As part of the program to find the contribution of processing variables, Frey, Freeman, and white' studied effects of heat treating on nickel-base alloys and Ewing and reeman' investigated effects of hot-working practice on N155 alloy. To extend the program to the study of effects of melting practice on high-temperature properties, a 55 Ni-20 Cr-15 Co-4 Mo-3 Ti-3 pct A1 composition was selected for experimentation. The objective of this program was to establish the melting-practice variables which influenced the hot-working characteristics and creep-rupture properties and, at the same time, establish the metallurgical mechanisms for the effects. During the course of the investigation of practices using vacuum melting, it became increasingly evident through chemical analyses supplied by industrial concerns that a major variable was melt reaction with the crucible. This paper is devoted to the results of this phase of the melting-practice study. EXPERIMENTAL PROCEDURES Experimental 10-lb heats were induction melted in the University of Michigan vacuum-melting unit with the melting practices outlined in Table I. Aim analysis for the basic alloy, in wt pct, for all heats was as follows: Cr Co Mo Ti Al 20.0 15.0 4.0 3.1 3.1 Mn Si C Ni 0.12 0.12 0.08-0.15 Bal. Small amounts of boron and zirconium were added to certain heats as listed in Table I. These additions

Jan 1, 1959

By K. J. Miller

A laboratory electrophoresis column was designed to separate pyrite from fine coal by utilizing an observed difference in the electrophoretic mobilities of the two materials in water. The apparatus worked well when tested with synthetic mixtures of coal and pyrite, but some modifications in design and procedure were necessary to provide a sharper separation. After these changes were made, the column was tested with a high-pyritic-sulfur raw coal sample. The column successfully fractionated the sample, removing not only the pyritic refuse, but a siliceous refuse as well. The invest ion demonstrated on a laboratory scale that pyrite and other impurities can be separated from fine coal by electrophoresis.

Jan 1, 1970

By P. L. De Bruyn

[According to the Young equation, SG = SL + Coso, the equilibrium contact angle depends on the values of the three interfacial tensions involved. A solute promotes wetting, i. e. a decrease of contact angle if it decreases.LG and/or YSL or if it increases SG. Dewetting, the important step in flotation is, promoted if the solute increases y and/or SL or decreases. Most solutes used for wetting or dewetting are, positively adsorbed at all interfaces involved and consequently according to the Gibbs equation lower the interfacial tensions. Wetting is therefore expected to occur if LG and SL are more affected by the solute than SG. Dewetting on the other, hand demands a greater decrease of SG than that of SL (and of LG). See P. L. de Bruyn, J. Th. G. Overbeek and B. Schuhmann, Jr., Mining Engineering (1954) P. 519.]

Jan 1, 1960

By J. F. Wolff

During the past 4 or 5 years, much has been added to the detailed geologic knowledge of the Mesabi Range. This has not been in the direction of discovery of any new fundamental facts, but of detailed study, subdivision and correlation of different parts of the whole formation and of individual orebodies. Prior to this time, mining engineers in the district were so engaged with the commercial interests of exploring and developing orebodies that close geologic study and subdivision were done in a few instances only. The demand for refinement of work in .this direction has led 'the engineers of the Oliver Iron Mining Co. to do extensive structural subdivision and correlation in all exploration work during the past 4 years. Such work has become a commercial necessity rather than a scientific refinement, and at the present time is being extended to all parts of the Range. In the summer of 1914, the author of this paper wrote a series of articles on the orebodies and special features of the Mesabi Rangc, which was published in the Engineering and Mining Journal, issues of July 17 to Aug. 7,1915. Since that time studies of subdivision of the iron-formation have been extended considerably. The principal feature of this paper is the presentation of the subdivisions of the iron-formation. To this is added a discussion of the relations of the orebodies to the gentle folding and fracturing of the formation, and special features of the Range. The outline will be as follows : I. General geology. 11. Subdivision of Biwabik iron-formation. 111. Relation of orebodies to folding and fracturing of the iron-formation. IV. Special features. Acknowledgnlent is due to W. J. Olcott, President, and John Uno Sebenius, General Mining Engineer, of the Oliver Iron Mining Co., for permission to use the information presented in this paper.

Jan 1, 1917

By S. Yaw Amponsah, E. Ben-Awuah, P. M. Takouda, P. Eme

Mining production scheduling is the process of determining the sequence of block extraction over a period of time that will yield the maximum net present value for a mining operation. The block extraction sequence needs to occur under certain resource constraints which presents an NP-hard problem that is computationally intractable and complex to solve for large scale problems using exact mathematical models such as Mixed Integer Linear Programming (MILP). In this paper, we used a metaheuristic optimisation model based on a Genetic Algorithm (GA) to solve the production scheduling problem. The problem definition and resource constraints are formulated using a mining specific GA that enforces block extraction precedence and mining capacity constraints through a normalisation method. A case study is implemented with the GA model, and the results and computational time are compared with that of a MILP model with CPLEX solver which is based on a branch-and-cut algorithm.

Sep 1, 2021

By Rusdian F. Kayadoe, Michael B. Hutahaean, Sandi A. Firmanulhaq

Deep Mill Level Zone (DMLZ) mine is located in Papua, Indonesia operated by PT Freeport Indonesia (PTFI) with approximately 1,500m below surface. The ore body extend 1230m width from northwest to southeast by 300–400m length east-west. The mine currently produces at full production of 80,000 tons per day until 2041. Part of the extension of current active production block and mitigation sits 225 m above the production block 1 (PB1) and 2 (PB2A and PB2B) which located in 2590L, named production block#4 (PB4W and PB4E). As the mining continues at PB1N, PB2A, and PB2B, the cave growth vertically and laterally to south perimeter of the footprint affecting the integrity of PB4W/E footprint. Currently, PB1N and PB2N are in active production whilst PB4E development continues from South against PB1N cave, as can be seen in Figure 1. A slight overlapping between PB1E and PB4E intentionally to promote cave connections between the two caves. Despite low stress model in the PB4E near existing caves, the PB4E cave propagation expected by the large strain and will be propagating in tension failure to the PB1E cave. Hence, designing the drill drives edge and first drawbell location as close as possible to the PB1E cave is necessary to guarantee cave connection. Since PB4 footprint development commenced in December 2021, there have been a substantial cave propagation observed from existing downhole monitoring. As the PB4 footprint designed perpendicular to existing DMLZ PB1 cave, adjustment of the development edge design is necessary to reflect the progression the loosening zone propagation to the South. Final life of mine design for extraction, undercut and ventilation level were decided in October 2023 considering latest update cave (fractured/ yielded) boundary. Numerical model of potential rock mass damage also aids the decision to locate the drift edge design. Predicting the cave progression impact is critical to both production at the existing active blocks and development of the new area. The use of cave shape data from year 2021–2023 gives an insight of the cave shape estimation at the end of 2024 when the undercut drift will be developed. This paper presents actual cave growth of active production blocks and its relative vertical progression impact as the result of drawing in order to plan for acceptable rate and provide mitigation once the minimum acceptable rock mass condition and minimum pillar threshold achieved.

Feb 1, 2025

By Ana Clara Petrucelli

A principal ferramenta de controle do processo BOF reside na regulagem do sopro de oxigênio. A análise dos parâmetros de interação entre o sopro e o banho metálico compõe o objetivo deste trabalho. Através de uma análise visual da penetração e fração volumétrica da bacia de descarburação, foi determinada a melhor configuração de sopro entre diferentes combinações de bicos multifuros (3 a 6 furos), distância lança-banho e vazão. Foram feitas previsões sobre a penetração do jato a partir de um balanço de energia a fim de validá-las com o modelo físico. As maiores penetrações foram alcançadas com os bicos de 3 e 4 furos, com a maior vazão e menor distância lança-banho dentre os padrões testados. Todavia, as maiores frações volumétricas da bacia de descarburação foram obtidas com 5 e 6 furos, vazão e distâncias variadas dentre as ensaiadas.

Jul 29, 2018

By David Hughes

The paper covers the utilization of on-line analysis in process control of solvent extraction in nickel leach solvent extraction processes in Finland and Australia and in copper heap-leach and solvent extraction in Chile. The goals of and requirements for controlling the solvent extraction stages of the processes are reviewed. The applications at three plants are compared. The development of the technology used is reviewed and design considerations are discussed. Requirements for on-line control and analyzer performance are compared. A new generation of analyzers and its effect on the set-up process of a project is introduced.

Jan 1, 2003

By D. K. Deardorff, H. Kato

THE transformation temperature of hafnium from hcp to bcc is 1750° + 20 °C in contrast to previously published values by Duwez and fast2 which are believed inaccurate. The Bureau of Mines determined this value by measuring the temperatures at which a sudden decrease was observed in the electrical resistance of hafnium alloys containing up to 18 at. pct Zr, and then extrapolating the temperatures to 0 pct Zr. Duwez1 previously reported a transformation temperature of 1310°C, obtained by use of a rapid-cooling thermal-analysis technique. Later, Fast2 published a much higher value of 1950° 100°C based upon: a) his own determination of 1690°C for the beginning of the transformation range for hafnium containing 5.7 at. pct Zr, and b) his belief that lattice parameters reported3 for Duwez' hafnium indicated i contained 19 at. pct Zr and that the 1310°C value should be associated with that composition. Russell4 subsequently stated that Duwez and Fast probably were reporting their lattice parameters in different units and reassigned a value of 6.0 at. pct Zr to Duwez' hafnium. If this assumption were true, Duwez' hafnium was of approximately the same purity as Fast's, but his transformation value was considerably lower. The reason for this divergence is not known. Fast's value for hafnium containing 5.7 at. pct Zr agrees well with our data. McGeary5 determined a transformation value of 1660°C by metallographic examination of heat-treated specimens, but the zirconium content of his hafnium was not definitely established. The specimens used in this investigation were 1/8-in.-diam rods 6 1/2 in. long, fabricated by hot-swaging bars cut from arc-melted buttons. These buttons were melted from crystal bar hafnium and crystal bar zirconium. The chief impurity in the hafnium

Jan 1, 1960

By Charles G. Kemsley

MR. C. R. WHITTEMORE: It is interesting to note that the mining industry is making increased use of alloy steels for drilling. They will undoubtedly lead to greater footage at lesser cost. Mr. Kemsley states that, for use in hard ground, the shanks are brought to a hardness of 435 to 440 Brinell by heating them to approximately l,800°F. It seems to me that this temperature is excessively high-it is considerably above the critical point of the steel. The only effect of such a high temperature is to lessen considerably the impact resistance of the steel. The possibilities of an oil quench, followed by a tempering draw which does not lessen the hardness of the steel too much but increases its toughness, might well repay further study; also the temperature control, a factor which depends on the composition of the steel. However, service results are undoubtedly the best criterion of practice. MR. KEMSLEY: I would like to point out that the steel is not quenched at 1,800°F. After heating to this temperature, it is laid aside to cool gradually; this high temperature is necessary to produce the required hardness by simple normalizing-cooling in still air. We all know that ideal conditions for hardening steel demand salt baths and furnaces with automatic temperature control, but for most companies the cost of such equipment having sufficient output capacity is prohibitive. The end we are trying to attain is to make good drills at a cost that will be within the means of any mine.

Jan 1, 1942

By Stephen Meyer, Véronique Falmagne, Antti Pyy

Kittilä Mine is a gold mine located in Northern Finland, owned and operated by Agnico Eagle Finland. The mining operation started in 2008 with open pits which were completed in 2012 and production moved to being entirely underground. The mine consists of four separate orebodies, currently producing 2.0 Mt per annum, and requiring over 19 km of development on a yearly basis. The principal mining method is long hole stoping with delayed backfill. Microseismic monitoring was initially tested in the Suuri orebody, in the mining block between the 625 and 500 Levels. A small monitoring system was installed in 2018, after observations of stress-induced damage to the rock mass and in anticipation of future mining at greater depth. The initial goals were to evaluate if useful data could be recorded and test the signal quality of different sensor types. Prior to 2018, ground control related challenges in the Suuri and Roura mining blocks had been mostly related to sill pillar mining and block movements between weak graphitic schist planes. Seismic monitoring in the Suuri deposit proved successful for following the rock mass response to mining and helped support the rationale for early monitoring in the new, deeper mining block in Rimpi at 900 m depth. Preliminary geotechnical characterization and testing of the rock mass showed areas of silicification in the footwall rocks with potentially continuous structural features. Seismic monitoring of the Rimpi area has confirmed the brittle behavior of the rock mass, with strong seismic responses induced by stress changes following blasting being recorded. In addition to this expected behavior, a large magnitude event associated with significant damage in the footwall drive development 90 m above the stoping was experienced. Initial investigation of the rockburst showed two separate damage locations with over 300 tons of displaced rock. The seismic monitoring system recorded this rockburst as a single seismic event with magnitude significantly larger than previously recorded. Additional analyses indicated a possible thrust fault event, triggering two separate strainbursts. Following this event, the ground support system was upgraded in parts of the footwall drives to improve dynamic capacity. Systematic calculation of the source mechanisms for the small footwall events down to Mw-2.5 has revealed potential planar structures in the footwall. Early implementation of microseismic

Apr 26, 2022

By M. Wallin

Millions of tons of sludge from different metallurgical processes are produced worldwide annually, and the environmental impact of landfilling these often hazardous sludges stresses the need to understand their role as valuable resources. The current work explores the potential of producing a saleable low-phosphorous ferromanganese alloy by utilizing sludge from the silicomanganese industry together with an iron source. The aim of the project is to explore the feasibility and practical challenges related to reduction and dissolution of manganese and silicon from the sludge to liquid metal and slag. Parameters such as ratio of input material as well as the effect of adding limestone and coke to the mixture were explored by thermodynamic calculations and adapted experimentally. Results show that a ferromanganese alloy, in fact, can be formed, while silicon and calcium forms a complex slag that captures a significant amount of impurities.