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By J. Duby

"A description is given of a series of tests performed to determine the comparative effects which dynamic and static straining, in compression, have on the physical strength properties of mild steel and an aluminum alloy. The dynamic deformation was imposed during the passage of single stress pulses of about 100 micro-second duration. These pulses were recorded with strain gauges mounted near both ends of the specimen. The resulting records were analysed using a simple wave theory; there from the dynamic stress-strain curves for the respective metals were deter-mined and were then compared with the static stress-strain relation. The respective hardnesses of the metals after deformation are evaluates by means of static stress-strain curves in compression. The micro-structures of the metals before and after deformation are also shown. It is observed that dynamic de-formation considerably modifies the rate of strain hardening. This modified hardening appears to be persistent. The observed differences in physical strength properties and micro-structures are discussed in the light of the accepted dislocation theory for metals."

Jan 1, 1960

By German Zambrana

The solution of the problem of beneficiation of cassiterite from its primary ore deposits is of fundamental importance to Bolivia. The process today involves a gravimetric treatment of the ore followed by sulphide flotation. During the last year, a cassiterite flotation stage has been added in several plants to treat the slime tailings. Although cassiterite flotation is already economical for the slime tailings and the mechanism of the process are understood, it is felt that further research could improve the results. In the past, considerable amount of research and test ark has been performed to select appropriate collectors to improve recovery, to increa¬se the grade of tin in the concentrate, to minimize the effect of metallic ions like Ca+2, Fe+2 and Fe+3 which prevent flotation, and to increase the pH of the pulp which now it can not be higher than 3.0. It has been reported that the halogen salts (1) like NaCl exhibit special surface affinity for cassiterite but none for quartz. These effect seems to be favourable for the selective flotation of cassiterite from silica minerals. In view of these preliminary results it was decided to follow the research accordingly: OBJECTIVES The objectives of the present investigation are: 1. 0 evaluate the influence of NaCl salts in quartz and cassiterite flotation.

Jan 1, 1971

By Muhammad Hashim Rasa, Ali Aras

Recovering valuable metals from tailings not only provides a source of income but also helps conserve natural resources, thus reducing the environmental impact of mining activities. This study aimed to recover cobalt using tailings of the Küre flotation plant, which were determined to contain 0.17% Co. Flotation tests were conducted on samples taken from the tailings to investigate the effects of pH and pH conditioning time, as well as types and amounts of depressant, collector, and frother on the grade and recovery of Co in rougher flotation tests. Optimal flotation conditions were determined to be pH 6, a pH conditioning time of 7 min, and dosages of 50 g/t, 100 g/t, and 20 g/t of sodium hexametaphosphate, X-231, and DF250, respectively. According to the rougher flotation test results, a concentrate with a Co grade of 0.46% and a Co recovery of 84.15% was obtained. In the concentrate obtained using cleaner flotation tests, the Co grade increased to 0.49% and Co recovery increased to 90.56%. These results show that froth flotation, carried out with the appropriate reagents, is a successful method for recovering Co by enriching the flotation plant tailings.

May 17, 2023

By William H. Mount

Since the late 19405, St. Joe has operated rubber-tired, trackless mining equipment underground in its Southeast Missouri Lead Belt operations. At first, the trackless equipment was operated in conjunction with rail haulage equipment in the room-and-pillar operations, but was to later replace rail haulage completely. The first pieces of equipment to travel on pneumatic rubber tires were short-haul shuttle cars of 12-ton capacity hauling rock from the heading to the mainline railroad. Early-model drill jumbos were the next pieces of production equipment to be carried on rubber, along with mobile slusher ramps. Mobile diesel equipment, in the form of conventional rear-dump trucks, made its appearance underground in the early 1950s, introducing the era of relatively high-speed mobile equipment as compared to the electrically powered shuttle cars. Haulage distances for rubber-tired vehicles were no longer dictated by trolley lines and trailing cables and tires were subjected to increasingly severe applications. St. Joe's first completely trackless mine, the Hayden Creek Mine, was opened in 1952, employing rubber-tired drill jumbos, electric shuttle cars, and for the first time, an articulated diesel truck consisting of the tractor unit of a conventional earthmoving scraper and a rear-dump rock wagon. Those machines rolled on the first true earthmover tires to be used underground by St. Joe. The articulated truck concept proved to be very successful, and constitutes an In- creasing portion of the underground haulage today.

Jan 1, 1975

By E. E. AGGER, Arthur Notman

THE proposal has been made in a bill introduced into Congress at the last session by Representative Jones of Michigan that an import duty of 6 c. per lb. shall be placed on copper. This action is urged after eighty years of prosperity for the industry in this country; during most of which copper has been on the free list, and during all of which a tariff would have been without real effect. To comprehend the general situation upon which this action would be imposed, we must refer to the past history of the industry and its trends at the present time. The following table supplies us with a picture of the physical growth of the industry in this country and its relation to that of the world as a whole down to Jan. 1, 1921:

Jan 1, 1925

By Reza Kamali, Mohsen Bashiri, Hadi Fanisalek

"Half of the input energy to aluminum reduction cell will be lost as waste heat which could be studied for possible recovery. Since price of energy is increasing and the main production cost in primary aluminum industry is energy, so waste heat recovery consideration will be interesting. One of the possible choices for recovering is from aluminum exhaust gases that needs minimum modifications for reduction cell and has no influence on cell heat balance which is vital for the operation. By using heat exchangers with in-line and staggered tube arrangements which placed before fume treatment plant (FTP) we will be able to recover enough amount of heat. The main challenging problem which is necessary to overcome will be the heat exchanger material and its design because of corrosive and dusty exhaust gases from potroom. In this paper, a desalination system with six effects of evaporator is proposed for producing distilled water by using recovered heat from hot exhaust gases. The calculated amount of produced distilled water is around 27,000 / in this specific suggested desalination plant. The suggested desalination plant is based on Hormozgan Aluminum Company data (Hormozal) in Bandar Abbas, Iran which is constructed by the Persian Gulf.IntroductionWaste heat losses arise both from equipment inefficiencies and from thermodynamic limitations on processes. The exact quantity of industrial waste heat is poorly quantified, but various studies have estimated that as much as 20 to 50% of industrial energy consumption is ultimately discharged as waste heat [1]. In order to achieve a final decision for establishing the waste heat recovery plant in any type of industry, a strong feasibility study is mandatory. Also, we need to remember that the possible amounts of energy and suggested process plant for recovery have to be investigated before starting any feasibility study. This kind of study which is important to be finished before moving to feasibility step is mainly a theoretical study, and was done for the Hormozgan Aluminum Company (Hormozal). In addition to the exhaust gases from the potroom, the exhaust gases from anode baking plant appear to have a better potential for waste heat recovery compared to potroom exhaust gases. The average temperature of exhaust gases from anode baking kiln is 120°C higher than the exhaust gases temperature in the potroom. This needs further investigation in a different study, because this study is just focusing on potroom exhaust gases."

Jan 1, 2011

By V. A. Chanturiya

The results study the minerals oxidation were obtained by us during the methods of microscopic, FT-IR spectroscopic, XRD and chemical analyses of sulphides in tailings of copper-nickel wastes in Kola peninsula. Sulphide minerals begin to oxidize already at the stage of stockpiling and initial stages of storing. The proportion of non-ferrous metals and magnesium oxide increases with time, calcium partially precipitating in the form of gypsum. Comparison of heavy metal contents in pore solutions in cur-rent and stale copper-nickel ore concentration tailings has revealed a significant difference in practically all the parameters. The lower metal contents in current tailing pore solutions (by 5~30 times) are probably due to the presence of float reagent residues blocking oxidation. Much lower concentrations of magnesium and calcium can be accounted for by the difference in kinetics: the rate of sulphide oxidation at this stage is much higher than that of solution interaction with non-metallic minerals as the result of which the solid phase ? solution equilibrium is not achieved. It is generally believed worldwide that it the mining wastes with acidic pore solutions that pose the greatest hazard for the environment. Our findings suggest that although the solution pH in all the samples is higher than 7.8, the contain heavy metal concentrations by far exceeding permissible values. The direct determination of the total and silicate Ni contents in the tailings from current production and in storage tailings has shown that both sulphide and silicate Ni forms occur in tailings. However, the role of silicate Ni is much larger in the storage tailings. The average silicate Ni content accounts for 10% of the bulk Ni content in the current tailings and it increases to 40% in the storage tailings. Thus, the storage tailings are marked not only by sulphide oxidation and the removal of water-soluble sulfates, but also by the interaction of sulfates with the silicate matrix. Although complete equilibrium is not achieved even within 30 yr under polar-region conditions, the major part of the Ni in fine-grained fractions passes into silicate form. The probability of Ni transition to the silicate form directly correlates with the dispersion of the material and the amount of chemically reactive serpentine and hydrochlorite. The migration of Ni as sulfates and its precipitation by chemically active silicates distorts the distribution of this component in the coarse- and fine-grained fractions that are typical of tailings from the current production of copper-nickel ores. On the one hand, the variation of the mode of Ni occurrence in storage tailings lowers the value of technogenic raw materials as a source of this metal.

Jan 1, 2014

By Fabiana da Silva Santos

Neste trabalho foram estudados os efeitos da laminação a frio com baixo percentual de redução e a cinética de recristalização em um aço médio carbono e alto manganês. O aço em estudo foi laminado a frio com percentual de redução de 10%, seguido de um tratamento térmico de recozimento nas temperaturas de 650 e 700°C, em tempos de 10, 15, 20, 25 e 30 minutos. A caracterização microestrutural e avaliação da fração recristalizada foram avaliadas por microscopia óptica e a dureza Vickers (avaliada em um macrodurômetro e um microdurômetro). De acordo com os resultados pode-se observar um efeito combinado de recristalização e crescimento de grão em função da microestrutura parcialmente encruada pelo baixo percentual de redução imposto, que se acentua com aumento do tempo e da temperatura de encharque.

Aug 16, 2017

By Bosco Poon, Kim Chan, Luis Raúl Castañeda, Geoff McKay

"Driven steel tubular piles of up to 2 m diameter have been used to support abutments and piers of a bridge over Nambucca River and floodplain. The bridge was designed by Arup-Aurecon Design Joint Venture (Lead Designers) with GHD leading the geotechnical design assessment in conjunction with Acciona Ferrovial Joint Venture (AFJV – Principal Contractor). Piles were to be driven through alluvium and founded on foliated Phyllite bedrock. The large diameter piles posed significant challenges on bearing capacity assessment and pile acceptance criteria, especially for anisotropic rock strength. Prior to pile driving, boreholes were drilled at each pile location, accompanied with a suite of rock index and UCS testing. AFJV and GHD oversaw geotechnical construction verification. All production piles were monitored with a Pile-Driving-Analyser to manage driving stresses and pile termination. Wave matching CAPWAP analyses were performed on 40% of the piles at the end-ofdrive, or restrike, to satisfy specification requirements and limit over-driving. This paper presents discussions on the design and construction of the driven piles with findings from the extensive dynamic pile data obtained. Based on the shaft resistance distribution and toe resistance obtained from CAPWAP analysis, the mobilised pile shaft frictions fs of the soil / rock materials, as well as the end bearing fb of the founding Phyllite bedrock, are examined. The impact of the rock fabric foliation angle on the m obilised fb, and the relationship between rock strength and the mobilised fs are outlined.INTRODUCTIONThe Bridge over Nambucca River consists of a single bridge structure, comprising single substructures and separate superstructures. The 850 m long bridge facilitates the crossing of the Northbound and Southbound carriageways of the Pacific Highway Upgrade over Nambucca River, with central median barriers, separated by a horizontal clearance of 50 mm. The bridge is required to span over the Nambucca River, which is a navigational channel, and over the adjacent floodplains, including two local access roads and the existing Pacific Highway. The bridge superstructure consists of 21 simply supported spans, each comprises four 2.25 m deep precast post-tensioned U-Girders, with two girders across the width of each carriageway. The spans of girders vary from eleven spans of 39.5m and ten spans of 41.5 m. The floodplain section of the bridge was founded on up to 2m diameter steel tubular piles, designed to be driven through alluvial sediments and weak rock to nominal refusal on sound rock. Dynamic load testing using wave matching CAPWAP (CAse Pile Wave Analysis Program) analyses in conjunction with PDA (Pile Driving Analyser) were used to verify the pile integrity and mobilised capacity. This paper discusses geotechnical aspects associated with design and construction of driven piles. The methodology developed for construction to verify pile capacity and to meet acceptance criteria is outlined. Based on the shaft resistance distribution and toe resistance obtained from CAPWAP analysis, the mobilised pile shaft friction, fs of the soil / rock materials, as well as the end bearing, fb of the founding Phyllite bedrock, are examined. The impact of the rock fabric foliation angle on the mobilised fb, and the relationship between rock strength and the mobilised fs are outlined."

Jan 1, 1900

By N. Duru, C. Nesbitt

During the cyanide leaching process, gold and silver ores that come from the transition zones, which typically contains low levels of sulfide, may produce one or more of the following reduced sulfur species: sulfide ( HS−), polysulfides ( Sn 2−), thiocyanate ( SCN−), thiosulfate ( S2O3 2−), trithionate ( S3O6 2−), tetrathionate ( S4O6 2−), pentathionate ( S5O6 2−), hexathionate ( S6O6 2−). The actual speciation of the reduced sulfur species in the circuits will primarily depend on the redox potential, pH, cyanide levels, and existing sulfur species in recycled process water, as well as the presence of other reactive metal species. The development of an accurate analytical method for sulfur species in cyanide leaching units of gold ores where sulfur speciation occurs has an important role in explaining the metal recovery deviations. This study presents the speciation of sulfur species and the development of ion chromatography method to analyze reduced sulfur species thiocyanate ( SCN−), thiosulfate ( S2O3 2−), trithionate ( S3O6 2−), tetrathionate ( S4O6 2−) in cyanide leaching circuits for gold ores. The method developed has resulted in precise quantification of target sulfur species in leach solutions. Method development and validation results were illustrated on analytical graphs containing each species’ peak number, retention time (min), type, width (min), area (mAU*s), height (mAU), and area distribution (%) of the peak.

Mar 2, 2024

By James P. McGee

Preliminary calculations show an economic advantage in using nuclear energy to supply the endothermic heat required for gasifying coal. It should be noted that the various assumptions used in preparing these calculations must undergo further evaluation through additional engineering design and research. The proposed system for gasification is the indirect process cycle with helium heated in a nuclear reactor and passed through an exchanger-type gasifier for the reaction of coal and steam to form CO (carbon monoxide) and H2 (hydrogen gas).

Jan 1, 1960

By Caibin Wu, Ali Lei, Ningning Liao, Jingsheng Ye

"The particle size distribution characteristics of ground product can influence the quality of the classification overflow and the next beneficiation indexes in an ore concentrator. Usually, the size distribution of ground product is considered to be determined by that of new ball mill feed. However, based on large amounts of data from industrial grinding circuit surveys, this paper has clearly shown that the size distribution of ground product should be determined by the size characteristics from classification underflow unless the circulating load was small, because the new feed is an important component and occupy a dominant position of mixed ore from belt feed and classification underflow. On the other hand, the correlation coefficient of the size distribution between ground product and classification underflow can be more than 0.99 when the relevance principle and its method are used. Meanwhile, their P80 value also keeps a synchronous correlation. The greater the capacity of classification underflow is, the higher the correlation of size distribution between the ground product and the mixed feed is. Furthermore, the correlation coefficient of the size distribution between ground product and classification overflow which is from primary or secondary can be 0.96. It is another discovery that the correlation coefficient is related to the type of classifier. The coefficient of size distribution of overflow and underflow from hydrocyclone is superior to that of spiral classifier, which can explain the reason why the hydrocyclone is widely used to replace the spiral classifier in concentrator.INTRODUCTION It is well knows that ball mill circuits closed with cyclones or spiral classifier such as a primary grinding circuit, a secondary grinding circuit and SAB mill have become an industry standard. Which grinding process employed will be determined by the P80 value of ground products. When the primary closed circuit ball mill or SAB that it is different throughout between the two processes was employed, a grinding fineness with -200mesh under 68% will be available. However, the secondary grinding circuit with the fineness of -200mesh above 80% can be conducted. Of course, the grinding fineness is determined by the grain size characteristics of the mineral."

Jan 1, 2018

By Albert L. Toenges, Henry E. Dekay, James N. Scudder

Support of the immediate roof in coal mines is essential for their safe operation, and timbers are the most common means of support. Their effectiveness depends upon their resistance to decay. The theory has been advanced by some mine operators that rock dust, which is applied to ccal-mine workings to prevent propagation of explosions, accelerates the decay of mine timbers. As the results of part 1 of this study were inconclusive, the study was continued. Its principal objectives are: 1. To determine the effect of rock dusting upon decay of mine timber. 2. To compare the extent of decay of timbers in two mines in which underground conditions are similar. 3. To determine the loss in strength of the timbers after exposure to mine atmosphere. The studies were carried on in the Crucible mine of the Crucible Fuel Co. where the first part of this study was made, and in the Isabella mine of the Weirton Coal Co. The mines are on the Monongehela River and are adjacent.

May 1, 1943

By R. J. Pugh

In addition to directly analyzing the surfaces of minerals using high vacuum instrumentation methods, some important surface properties of mineral fillers can be determined indirectly by using reactive chemical probe molecules. This technique enables the strength and the number of the surface reactive sites to evaluation and this type of information is useful in predicting interfacial behaviour of minerals. One method of classifying these surface sites is by using Lewis acid/base theory and this type of approach could enable one to predict the adsorption of functional groups in dispersants, thickeners, pigments, etc. Also the adhesion of polymer matrices to the filler surface may be improved.

Jan 1, 1992

By Rhulani F. Maluleke, Francis W. Petersen, John H. Marsh, Johann de T. Steyl, Allan Nesbitt

"Pressure leaching of chalcopyrite and nickeliferrous pyrrotite at temperatures between 105 and 200 ºC has been proposed as a potentially viable route for the extraction of mineral elements from sulphide concentrates. In general, these concentrates contain iron, and the economic success of the processes is partially dependent on the choice of the environmentally acceptable iron-removal technique. One of the most widely used methods for the removal of iron from sulphate liquors is precipitation as hematite, goethite, or jarosite. The nature of the iron precipitate formed dictates downstream dewatering and residue treatment and disposal options. However, a better understanding of iron precipitation under the defined process conditions would consequently be of benefit in process design and optimisation.This study investigated the precipitation of iron in the autoclave at temperatures between 105 and 200 ºC. The effects of temperature, acid concentration, iron concentration, and the presence of other metal cations on the nature and composition of the precipitates were determined."

Jan 1, 2003

By A. Noble

"A supply of sustainably sourced rare earth elements (REEs) is critical for several high-tech industries, renewable energy technologies, and defense applications. Recent studies have shown that REEs exist in coal and coal combustion byproducts at elevated concentrations and in quantities that could meet domestic demand. Despite these promising findings, declines in rare earth prices, volatile commodity markets, and challenging geo-metallurgical conditions have jeopardized this potentially valuable REE resource. While the dilute REE concentrations inherently necessitate low-cost separation technologies, the ultimately operating cost threshold for economic extraction must be based on commodity price projections and market demand. In this paper, the micro-pricing principle is used to develop a rigorous economic model assessing the inherent value of REEs in coal materials. This model is based upon basket pricing of individual elemental oxides, and elemental distributions of coal samples from various basins. These results may be used to assess the economic viability of potential REE concentration and refining technologies INTRODUCTION Recent efforts by US Department of Energy (DOE) and the National Energy Technology Laboratory (NETL) have suggested that rare earth elements (REEs) may exist in coal and coal byproducts at concentrations suitable for economic extraction and processing. While the knowledge of REE occurrence in coal material dates back over 50 years, recent supply restrictions and material criticality considerations have prompted a national interest to establish a sustainable domestic supply of REEs. REEs are not “rare” in the sense of crustal abundance; however, few natural processes lead to concentrated ore deposits. As a result, the elevated concentrations found in coal material may provide a potentially promising resource for these materials. While the term “rare earths” is often used to describe a singular concept, the 15 rare earth elements actually have varying and sometimes contrasting scarcity and cost profiles. Various authors have proposed classification systems to provide information on REE criticality (e.g. Seredin and Dai, 2012, Zhang et al., 2015). The most straightforward classification is provided on the basis of geochemistry with designations for “light”, “medium” and “heavy” rare earths. Light rare earths (those to the left of the periodic table: Ce, Pr, Nd, and Sm) tend to be more common and less valuable when compared to their medium (Eu, Gd, Tb, Dy, and Y) and heavy (Ho, Er, Tm, Yb, and Lu) counterparts. While light rare earths are often found in traditional ore deposits at economic concentrations, the heavier rare earths are almost exclusively found as ion-absorbed clays (Seredin and Dai, 2012)."

Jan 1, 2016

By E. C. Harder, E. W. Greig

Bauxite is known mainly as the ore from which aluminum is smelted but it has large use also in the manufacture of artificial abrasives and in the production of a number of useful chemicals as well as of aluminous cement "ciment fondu." An important and growing use is in the manufacture of refractory products. Composition Dana and earlier mineralogists gave the mineral formula of bauxite as A1203.21120 and the composition as A1202, 73.9 pct; H2O, 26.1 pct. A specific mineral of this composition has, however, never been identified by either microscopic, chemical or X ray examination, and therefore it is concluded that bauxite is a rock consisting of one or more aluminum minerals together with impurities. The term is now used synonymously with aluminum ore and it embraces gibbsite (hydrargillite or alpha trihydrate), A1203. 3H20 (A1203, 65.4 pct; H2O, 34.6 pct); boehmite (alpha monohydrate), A1203•H20 (A1202, 85 pct; H2O, 15 pct) ; diaspore (beta monohydrate), A1203•H20 (A1203, 85 pct; H2O, 15 pct), and mixtures in various proportions of any two of them. Bauxite of the Mediterranean region in Europe is predominantly boehmite, as in France and Istria, subordinately a mixture of gibbsite and boehmite, as in Dalmatia, or of boehmite (or gibbsite) and diaspore, as in Greece. The bauxite of North and South America, tropical Africa, Asia, and Australasia consists largely of gibbsite, but boehmite in appreciable amount occurs in many places. Corundum (A1202) is not included un¬der bauxite, although gradations from bauxite to emery or corundum exist. All bauxite, irrespective of the aluminum minerals composing it, contains certain impurities in variable amount, including silica in the form of clay minerals (kaolinite, halloy site, and others) or quartz, iron oxide (as hematite or goethite), titania (as leucoxene or rutile), iron sulfide (as pyrite or marcasite), iron carbonate (siderite), and calcium carbonate (as calcite); the last three mentioned in minor amount and of local occurrence only. Bauxite belongs to a group of partly consolidated materials called laterites, formed by surface weathering. This group includes also impure siliceous, ferruginous, and phosphatic bauxite and siliceous and aluminous iron ores and manganese ores and nickel and chrome laterites. Phosphorus and manganese minerals locally form important impurities in bauxite deposits. Properties Gibbsite is white or light shades of gray, cream or pink. Its hardness is 2.5 to 3.5; specific gravity, 2.3 to 2.4; crystal system, monoclinic, crystals tabular parallel to 001, often fibrous, concretionary, stalactitic; luster, vitreous to pearly; generally translucent; cleavage, parallel to 001; disassociation temperature, approximately 300°C. Boehmite, a relatively new and important mineral described by J. Boehm15 in 1925, confirmed and named by J. de Lapparen64 in 1930, has some properties not yet definitely determined. It occurs in grayish, brownish, and reddish shades. Its hardness is between that of gibbsite and diaspore; specific gravity, 3.01 to

Jan 1, 1960

By R. E. Cumings

The Bureau of Mines made electrorefining tests in inert-atmosphere, molten salt cells to develop methods for the preparation of high-purity molybdenum. Seven of the electrolytes investigated were suitable for the preparation of refined metal. The electrolytes were composed of molybdenum chloride in alkali chlorides or mixtures of alkali and alkaline-earth chlorides. An electrolyte composed of potassium chloride and potassium hexachloro-molybdate was selected for a larger scale, more detailed study on the basis of its ease of preparation, its ability to retain the molybdenum salt, and the type of deposits obtained. High-purity molybdenum in the 99.99-percent-purity range was successfully prepared as dense plate up to 80 mils thick and as dendritic crystals. The temperature of electrolysis and the current density were major factors in determining whether plate or dendritic crystals of molybdenum were obtained.

Jan 1, 1966

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) spin trapping experiments have been carried out to investigate the mechanism of sulfite oxidation em¬ploying 5,5-dimethyl-l-pyrroline-1-oxide (DMPO) as a spin trap. The results show that sulfite autoxidation, catalyzed by Mn(II), involves not only the SO-3 radicals but also the •OH radicals. An addition of H2 02 to the sulfite aqueous medium significantly increases the •OH radical formation. This result provides new clues to the chemical mechanism of the sulfite oxidation and the sulfite toxicity.INTRODUCTIONStudies of the oxidation of the sulfite (SO 2-/3) ions under various conditions are of high current interest because excessive exposure to sulfite is toxic and the origin of this toxicity seems to involve sulfite oxidative pathways [1]. An important fact is that human exposure to sulfite is on the increase [1,2]. Some of the increase in the sulfite exposure is linked to the fact that SO2 is a major air pollutant [2] and in aqueous media SO2 exists in equilibrium with SO2-/3. In addition, beverages and foods are common sources of sulfite intake. For example, sulfite is used extensively in the wine industry as an inhibitor of yeasts and bacteria and is present in finished wines in concentrations up to 6 mM [1]. Sulfite is also often added to dehydrated fruits, vegetables and soups, as well as fruit juices and beer [1,3,4]. Because of these, the mean daily intake of sulfite from diet (in the United States) has been estimated to be between 0.0014 and 0.14 mM/kg body weight [1]. At such high levels, sulfite exposure can have toxic effects, such as the induction of an acute asthmatic state [5,6]. Sulfite also appears to have adverse genetic effects [7] and can act as a mutagen or comutagen [8] and a cocarcinogen [5,7-9]."

Jan 1, 1990