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By Rob Boom, Yasuyuki Tozaki, Greg Traquair

The objectives of the business case are to examine a proposed metallurgical project and answer fundamental questions about project feasibility, risks, opportunities, and value. A business case fulfills these basic functions: estimates economic value; helps to understand competitiveness; serves as a risk management tool; and serves as a communication tool. A business case evolves with the project life cycle, and supports the gate reviews at the end of each phase of engineering, through to project construction and operations. A business case must be holistic, including all elements of scope that can impinge on project risk and value.

Jan 1, 2015

By S Barrow, D Kent

Controlling the access of equipment, and people, has become more critical over the last few years for improving productivity and to meet safety responsibilities imposed by legislated obligations to have safety management systems. Hence Mine Site Technologies (MST) has spent the last three years completing the development of the tagging system to meet the mining industryÆs requirements, particularly streamlining access control. The basic tagging system tracks active Tags carried by personnel, or attached to vehicles and equipment, within underground zones. These Tags are detected (read) by Beacons placed strategically throughout the mine. As a Tag, or Tags, go past a Beacon they are read and the information transmitted back to the main database PC. This allows the current whereabouts of personnel and equipment to be known, as well as the history of their movements. The objectives of implementing the TRACKER Tagging System at Oaky No 1 Coal Mine were to: maintain a count of personnel inbye a particular point, and can alarm when a pre-set number is reached (eg the limit imposed by availability of SCSRÆs, etc); maintain a count of vehicles (and vehicle type) inbye a point, and can alarm if when a pre-set number is reached (eg when rated diesel units exceeds the limit for the ventilation present in that zone); manage the vehicle fleet, by keeping track of various vehicles underground better control and dispatch management of the equipment is achieved; keep track of equipment, knowing the location of equipment (such as forks, baskets, pumps, fans, etc) where last used or stored will minimise the risk of losing gear and assist in keeping inventory to a minimum; and locate personnel in emergency situations, by placing read Beacons throughout the mine the location of all personnel can be known in real time so that in the event of an emergency, their withdrawal can be monitored.

Jan 1, 2005

By HASSAN E. EL-SHALL, AYMAN A. EL-MIDANY, KERRI-ANN A. HUE

Modifying the hydrophobicity of clay is necessary to accommodate large mycotoxin molecules such as zearalenone (ZEN). In this study, tricaprylmethylammonium (TCMA) chloride and common corn oil were used to modify clay. The results indicate that more than 90 percent of ZEN could be removed using clays modified by TCMA and corn oil at acidic and neutral pH due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clay-forming layers. The removal percentage depends on the pH and amount of clay used. Complete removal can be achieved at acidic pH and small clay amount.

By L. D. Schmidt, H. G. Graham

Several processes for the production of ultra-clean coal for electrode carbon were developed in Germany prior to and during World War II . These processes have been investigated since the end of the war by the British and U. S. Government missions . As the reports of the investigations are not readily available to the public , it is the purpose of this paper to present the information which has been obtained regarding the methods by which ultraclean coal was produced . Almost all the ultra-clean coal was used in the manufacture of electrodes for the production of aluminum and magnesium . Standard raw materials for making these electrodes are pitch coke and petroleum coke , which are nearly ashless . The inclusion of ash in the electrode carbon results in lowered efficiency and impure metal from the reduction process . Petroleum coke and pitch coke were in very short supply in Germany during the war , so that it was necessary to augment the supply with carbon produced from coal . In the emergency , methods were developed to clean coal which had never before been economically feasible . However , a demand for nearly ash-free coal might develop in the United States if a shortage of petroleum coke were to occur at the same time as a strong demand for light metals . Other uses of ultraclean coal are in direct hydrogenation of coal , in production of activated carbon, and for special fuels . Specifications for electrode carbon are rather severe owing to the necessity for producing pure metal . Maximum amounts of impurities allowable in American practice are as follows : Total ash , 1.0 percent ( in finished coke , 0.7 percent ) Silica , 0.08 percent Ca or Na, or their sum , 0.12 percent Sulfur , 2.0 percent Ba , Ni , Cr , Mn , Co , and V are objectionable in very small amounts . The most important process for ultra cleaning of coal in Germany was froth flotation . Froth flotation had been used widely there to process washery -water sludges and to recover coking coal from high - ash fines . Its use was indicated , therefore , when the demand for ultra low-ash coal arose . In two plants the coal cleaned by froth flotation was treated with acid or caustic to lower further the ash content . Another process used on an industrial scale was that of dissolving the coal substance in the middle oil from direct hydrogenation of coal under controlled pressure and temperature . The resulting paste was heated, filtered , and the oil distilled off . The residue was a low-ash organic material that could be carbonized for electrode carbon or could be hydrogenated directly . Several other processes had been developed to the laboratory or pilot - plant stage but had never been used on a commercial scale . These processes included cleaning by centrifugal action , cleaning by electrostatic action , and cleaning by forming a paste with oil in water . The coal-preparation plants at the Carl Alexander mine , Augusta Viktoria mine , and Kőenigin Elisabeth mine are described in Bureau of Mines Information Circular 7389 : " Coal Preparation Practice in Western Germany" , by Thomas . Fraser and M. G. Driessen . Most of the special equipment used at these plants is described in the above publication .

Oct 1, 1948

By Xinghai Lei, Yuqi Shang, Guiming Li, Lu He

There are many factors affecting the stability of open-pit mine slopes, among which slopes with soft interlayers have become an important factor inducing deformation and instability due to their poor mechanical properties. In this paper, for the destabilization of a slope with soft interlayer under rainfall infiltration in an open-pit mine in Zhejiang Province of China during the rainy season, a sudden change of displacement at the monitoring point and the formation of a continuous plastic deformation of the slope are proposed as the criteria for slope destabilization through the establishment of a rainwater seepage-stress coupling model combined with the strength reduction method, and by using COMSOL Multiphysics finite element numerical simulation software to establish a three-dimensional numerical model based on the actual mining slope conditions. The safety principle is introduced through the strength reduction method to analyze the stability of the slope with soft interlayer under the coupling effect of seepage and stress. The safety coefficients of the slope with soft interlayer are calculated by using Numerical methods under the coupling effect of seepage and stress. The influence of rainfall intensity and duration on the stability or safety factor of the slope with soft interlayers was studied through analysis of stress, saturation, displacement, and pore pressure evolution. The mechanism of rainfall affecting slope stability was investigated, and the findings were validated using an engineering case study of a slope with a soft interlayer. The findings show that rainfall intensity is the main factor affecting slope stability in the open-pit mine slope with soft interlayer. The higher the rainfall intensity, the faster the shallow soil forms a saturation zone, whereas soft interlayers speed up the process and endanger slope stability. The slope prevention and control technology of the prestressed anchor cable (rod) framework was proposed based on the slope management construction conditions of the mine, and the effectiveness of the measure was verified through on-site industrial tests. The research findings provide a reference for preventing and controlling slope with soft interlayers in open-pit mines under similar conditions.

Feb 20, 2024

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By A. N. May

"This paper describes the present approach of the Mines Branch to the problem of measuring the stress condition in the interior of rocks surrounding underground openings. An instrument, which will be referred to as a stressmeter, has been developed at the Mines Branch to measure un-directional stress changes in absolute units. There are two modes of operation of this stressmeter. It can be regarded as a fixed instrument, in which case it is installed at the end of a diamond drill hole and left in position to record any subsequent stress changes taking place. Alternatively, three of the stressmeters can be used in conjunction with a trepanning opera-tion to allow the existing stress condition to be determined. The initial laboratory work and subsequent experiences in the field with the stressmeter are described. All the field development work on the stressmeter was made possible through the co-operation of Canadian Refractories Limited, Kilmar, Quebec."

Jan 1, 1960

By D G. Rantucci

Organic carbon is a major ore contaminant at MMG’s Century mine. This carbonaceous matter is associated with shale hosted sphalerite mineralisation. It occurs as elongated lamellae and as inclusions in porous sphalerite aggregates which are fine grained and difficult to liberate from sphalerite. The carbon prefloat circuit was designed to remove the liberated organic carbon in order to mitigate excessive reagent consumption, contamination of the lead and zinc concentrates and poor flotation performance in the primary zinc circuit. The consequence of organic carbon removal is that sphalerite and galena minerals are lost to the prefloat concentrate. A Jameson Cell was installed in late 2005 as a prefloat cleaner cell. Operational experience showed that the cell became capacity limited during periods of high amounts of organic carbon in the feed and was subsequently bypassed.Reactive style operating strategies were implemented to manage the effects of insufficient organic carbon removal by the prefloat circuit but due to the relatively large circuit residence time, upstream changes meant hours before the downstream circuits were stabilised following a disturbance from excess carbon.This paper describes the modifications and testwork undertaken to enable the Jameson Cell to be operated during periods of high organic carbon in the float feed and the implementation of process control initiatives to proactively remove the required prefloat mass from the float feed to eliminate the reactive style operating strategy.The process control modifications centred on dynamically targeting a prefloat mass recovery determined by an equation relating the carbon to zinc ratio to the carbon prefloat mass as a percentage of the float feed. The equation was developed by analysing historical data. These improvements served to optimise the prefloat circuit and consequently stabilise the downstream lead and zinc circuits.

Aug 8, 2011

By R. P. Nicholson

On September 3rd, 1947, the Acadia Coal Company put into operation a central coal preparation plant. This plant was designed to process all coals mined by this Company in the Pictou County coal field. The problem, briefly, was to make a three-way separation of the raw coal fed into the plant. It was desired to remove all stone, metal, and wood from the marketable coal and to produce a splint coal from the raw material which would be suitable for making power. This splint coal product is belted directly to the power plant which is adjacent to the wash plant. To attain this object it was therefore necessary, first, to wash the raw coal, removing all splint, stone, metal, and wood. The stone, metal, wood, and highest-ash splint had then to be removed by a second washing in order to obtain the lower-ash splint for use in the power plant. The plant is on the east side of the Allan colliery, in the town of Stellarton (see accompanying photograph). It is of steel frame construction with wood siding, covered on the exterior with corrugated galvanized iron. Considerable concrete had to be poured for the foundation piers as the plant site is largely 'fill' ground. This necessitated the construction of extremely heavy footings containing a large amount of reinforcing steel. In all, 884 cu. yds. of concrete were poured for the various pits, tanks, and foundations; its average test was about 3,500 lb. per square inch. At the time the plant was constructed, the steel shortage in Canada and the United States was acute and, in order to obtain steel for the structure which is four stories high- an unused part of the Allan bankhead was torn down. Enough steel was obtained from this demolition to fabricate the new plant.

Jan 1, 1948

By Benoit Clermont, Jan Lux

"Magotteaux and Anglo Platinum started a co-operation program with the main aim of establishing the optimum milling configuration measured in terms of throughput, fineness and energy consumption.For this purpose, a fully instrumented pilot milling plant, supplied by Magotteaux (Pty) Ltd, and equipped with a 0.9 x 1.0 m ball mill, was erected at Frank concentrator (Merensky Pt ore). The primary ball mills at Frank concentrator were surveyed in order to set the conditions for the base case. This data was then replicated in the pilot mill under the same configuration. Thereafter, a series of different parameters were varied in order to attempt to optimize the milling system.Some of the grinding parameters that have been studied are:•,Gate versus overflow discharge•,Open versus closed circuit•,Different filling degrees•,Different shell liner profilesOnly grate versus overflow discharge and open versus closed circuit will be discussed in this paper.It should be noted that this paper does not attempt to give a universal solution as to what milling configuration is optimum in all cases. The conclusions apply for this particular case and probably most others, but it would be advisable to consider each case on its own."

Jan 1, 2003

The intention of this paper is to examine the practical and technical aspects associated with the measurement of blasting related phenomena. The emphasis is directed towards the acquisition of quantitative data rather than its theoretical interpretation. The application of advanced technologies will require that many more people involved with blasting become familiar with this topic. Against the many other disciplines where measurement may be beneficial, blasting is peculiar on several counts. 1) It must almost always be carried out in the field, and very often in a production environment. 2) Much consideration must be given for the safety of personnel and equipment. 3) The process is dynamic and seldom repeatable. Because the blast process is so dynamic there is little opportunity for direct examination. For this reason measurements are almost universally made using electronic techniques. In this way the event can be captured faithfully as it occurs and later examined in detail, after the fact. It is obvious that some familiarity with these electronic techniques is a necessary ingredient for successful blast monitoring.

Jan 1, 1990

Abbey, Robert Graham, District Mgr.. The W. W. Sly Mfg. Co., 50 Church St.. New York, N. Y. '21 Abbott, A. N., Mines Supt., Mazapil Copper Co., Ltd Concepcion del Oro, Zac., Mexico. '28 Abbott, Argyle Campbell, Dev. Dept., E. I. du Pont de Nemours & Co., Wilmington, Del. '29 Abbott, Clarence E., V.P., Charge of Raw Materials, Tenn. Coal, Iron & R. R. Co., 1242 Brown-Marx Bldg.. Birmingham, Ala. '04 Abbott, Louis Benjamin, Chief Engr., Elkhorn Div., Consolidation Coal Co., Jenkins, Ky. '16 Abeel, George H., Jr., Cons. Min. Engr Box 427, Santa Monica, Cal. '18 Abel, Albert E., Asst. to Pres., Valley Mould & Iron Corp Hubbard, Ohio. '19 Abel, Raymond L., Asst. Prof., Dept. of Pet. Refin., Univ. of Pittsburgh Pittsburgh. Pa. '28 Abeel, Leo M., Research Engr., Sullivan Concentrator Chapman Camp, B. C., Canada. '31

Jan 1, 1932

By Morgan M. Sears, Mark Morris, Joseph Bright

In an effort to advance the science underlying modern coal pillar stability analysis, researchers at the National Institute for Occupational Safety and Health are currently involved in research aimed at better understanding the impact of an in-seam rock parting on the strength of coal pillars. The purpose of this study is to determine a suitable virtual mining height that could be applied using current pillar stability analysis tools. To accomplish this, the boundary element model LaModel was used to back analyze data collected on pillar performance in a room-and-pillar panel at the Maple Eagle Mine located in Southern West Virginia. In a previous work, data collected from borehole pressure cells (BPCs) and extensometers were taken from three instrumentation sites. Data collected from the back bleeders were used to measure the rear abutment stresses, and data collected from two instrumentation sites in the wraparound bleeder were used to measure the front and side abutment stresses as well as the peak strength and performance of the slabbed leave pillar. The utilization of two nearly identical instrumentation sites in the wrap-around bleeder provided much needed repeatability of the obtained measurements. In this study, the data collected from BPCs at the three instrumentation sites was calibrated to match the Bieniawski pillar stress gradient. To model the measured pillar behavior, the LaModel program was selected due to its capability of being directly comparable to the Analysis of Retreat Mining Pillar Stability (ARMPS) and Analysis of Coal Pillar Stability (ACPS) programs. The model was then calibrated to match the measured abutment extent and abutment stress. Finally, the model was validated by reducing the modeled mining height until the yielding of the slabbed leave pillars in the model matched what was measured in the field. The final calibrated mining heights show that a reduction of the shale parting thickness, not including any clay layers, of 52% is applicable. This research study provides the first known measurement of the ARMPS/ACPS “50% Rule” and its applicability to this panel of the Maple Eagle Mine. This finding provides a proof of concept and could have significant implications for future research.

Feb 1, 2024

By Jack R. Miller

This session has been organized to suggest to you that the development of direct reduction is important to the iron ore mining and coal mining industries. The papers presented this morning will include a discussion of the costs of making direct reduced iron (DRI), the iron ore and coal supplies needed to produce DRI, the financing of direct reduction (DR) projects and, probably most important, the impact of the DR development on the iron ore and coal industries. For starters, this opening presentation offers a brief statement about DR practice and DRI, under the title that should surprise no one: "Direct Reduction: What Is It?" There is always the chance? that a brief statement may become long and complicated. But, by mixing some slides borrowed from Hal Lownie with a larger number of photographs accumulated from other sources, I hope to avoid such pitfalls.

Jan 1, 1978

By David Gatto, Nicolas A. Willig-Friedrich, Jeff A. Segar

"With the increasing demand for electricity, and requirements to generate this power cleanly, more producers are turning towards hydroelectric power. A project in Iowa currently under construction will retrofit an existing Army Corps of Engineers Dam with a hydroelectric generating facility. The design of the intake structure requires the construction of a diaphragm retaining wall. The T-shaped diaphragm wall elements retain an unbalanced fill height up to 21.3 meters (70 feet). The design required a single production element be constructed, tested, and instrumented prior to beginning construction of the rest of the elements. The testing included extensive concrete mix design development, coring, and Cross Hole Sonic Logging. Installed in the other production elements are 10 inclinometers, 4 pressure cells, 4 piezometers, and multiple survey monuments. Some of these instruments require manual readings while most are monitored by an automatic data acquisition system and instantly transferred to a website providing real-time graphical display of the data. This paper will discuss the construction of the diaphragm wall from the contractor’s perspective when working on a site only large enough for two service cranes and a Hydromill excavation unit, without any storage area on the construction pad, describe the testing performed and the quality control procedures employed, and investigate the information gained from the automated instruments providing real time measurement readings.INTRODUCTIONIn 1964 the US Army Corps of Engineers (USACE) constructed a dam by raising the surface grade approximately 34.7 meters (114 feet) above the natural ground line using a combination of fill types. This earthen dam stretched slightly longer than a mile intersecting the flow of the existing Des Moines River. The center of the dam is a concrete spillway consisting of 12 monolith sections. On each end, three of the sections extend 42.6 meters (140 feet) from the spillway to transition from the concrete dam sections to the earthen dam section. Adjacent to these three sections on the East end is where the contractor is actively working, for a private developer under a lease agreement with USACE, on this site to convert it to a Hydroelectric facility licensed for an output of 36.4 megawatts, enough power to meet the needs of about 18,000 homes. To create this, a powerhouse structure, housing two vertical Kaplan turbines is being added to the downstream side of the existing dam. From the power house, two penstock pipes will be cored through the existing concrete monolith sections and connect to the Intake structure on the upstream side of the dam. Protecting and reinforcing the dam adjacent to the intake structure is a new diaphragm wall. This wall is constructed using T-shaped diaphragm elements, acting as a cantilever retaining wall for the intake platform. Figure 1 shows a diagram of the upstream features of the construction."

Jan 1, 2016

By Pedro Jorge Walburga Keglevich de Buzin

A produção siderúrgica em usinas semi-integradas gera vários tipos de resíduos dentre os quais as carepas. No presente trabalho estuda-se o comportamento físicoquímico em altas temperaturas de briquetes autorredutores elaborados com carepa e finos de carvão vegetal produzidos no Rio Grande do Sul, objetivando sua introdução no processo produtivo de aciaria elétrica. Ensaios realizados em laboratório com briquetes industriais confeccionados com estes resíduos demonstraram a potencialidade de utilização destes briquetes autorredutores em processos siderúrgicos via forno elétrico a arco (FEA).

Aug 16, 2017

By William E. Souder

Behavioral accidents are a particular type of accident. They are caused by inappropriate individual behaviors and faulty reactions. Catastrophe theory is a means for mathematically modeling the dynamic processes that underlie behavioral accidents. Based on a comprehensive data base of mining accidents, a computerized catastrophe model has been developed by the Bureau of Mines. This model systematically links individual psychological, group behavioral, and mine environmental variables with other accident causing factors. It answers several longstanding questions about why some normally safe behaving persons may spontaneously engage in unsafe acts that have high risks of serious injury. Field tests with the model indicate that it has three important uses: It can be used as an effective training aid for increasing employee safety consciousness; it can be used as a management laboratory for testing decision alternatives and policies; and it can be used to help design the most effective work teams.

By R. H. Hadfield

Professor ArnolD, of the Sheffield Technical School, who has done so much excellent work in metallurgical research, recently produced, with the aid of aluminum, a sound ingot and bar from the purest known Swedish brand containing 99.8 per cent. of pure iron. Table 1. shows the physical quantities of this metal. TABLE I.— Tests of a Sample of Almost Pure Iron Prepared by Professor Arnold from D. v Ewedish Bar, Containing Before Fusion 0.04 Per Cent. of Carbon. I. II.+ III. Series mark,.. 136 1.371F ...... C, 0.07 0.07 Si, 0.04 0.04 8, 0.02 0.03 ...... Analysis, per cent,. .. P, 0.02 0.015 ...... Mn, 0.06 0.07 Al, 003 ............ Fe, 99.76 99.81 ...... Specific gravity,........... 7.863 ...... Original diameter, inches,. .. 0.564 0.798 0.798 Original area, square inches,. . 0.25 0.50 0.50 Limit of elasticity, tons per square inch,...... 18. 3.8 Breaking-load, tons per square inch,. 21. 23. 14.75 Total elongation, per cent., measured on 2 in.,...... 50. 49.25 61. Total reduction of area, per cent.,. 80. 69.60 61.20 Extension at permanent set, per cent.,...... 0.007 ...... silky and Appearance of fracture,. .. . silky i granular in parts.

Jan 1, 1894

By C. G. Dunn, J. L. Walter

Either (100) (001] or (110) (0011 oriented secondaries, or both, depending on annealing atmosphere and material composition, grew in a matrix of 2-dimensional grains. The growth dependence of secondaries of(hkl) orientation in the iron and 0.6 pct Si-Fe is explained in terms of surface energy driving forces and the dependence of these driving forces on both (hkl) orientation and amount of oxygen at the surace. (100) [001] grains grow when suflicient oxygen is present at the gas-metal interface to make y100 the lowest (hkl) surface energy. When little or no oxygen is present at the gas -metal interface, making Y110 the lowest surface energy, (110) (001 1 grains grow. When Y100 and y110 are approximately equal but lowest among (hkl) surface energies, both (100) (0011 and (110) (0011 grains grow simultaneously. An excess of surface oxygen produces complete grain growth inhibition in high-purity iron; i.e., a 3-dimensional grain structure is retained over long annealing periods. However, a small amount of silicon in the iron reduces the growth inhibiting tendency of oxygen without altering the (hkl) surface energy relationships. Some information on annealing twins is presented. SECONDARY recrystallization in high-purity a iron, cold rolled to strip a few mils thick, was reported recently.' The present paper provides additional information on this subject, also furnishes similar information on both zone-refined iron and a high-purity 0.6 pct Si-Fe alloy, and treats the more important surface phenomena that determine to a large extent whether one or more secondary recrystallization textures will appear during annealing. Previous studies on high-purity 3 pct Si-Fe2,3 have shown the importance of (hkl) and impurity-atom dependent gas-metal surface energies on the formation of secondary recrystallization textures in high-purity material. For example, either (100) or (110) oriented grains may have the lowest surface energy depending on the amount of oxygen at the gas-metal interface, and hence the highest driving force for growth if other growth factors are the same. Another important phenomenon in high-purity material is stabilization of the matrix structure; neither impurities nor a strong matrix texture seem to be necessary when recrystallization and normal grain growth occur, developing a stable two-dimensional type grain structure. The average grain size in such a structure is usually between one and two times the specimen thickness. Consequently, most of the grains have grain boundaries terminating at exposed surfaces, and this results in gas-metal interfaces (or hkl surfaces) as well as

Jan 1, 1962

By W. C. Ellis, M. E. Fine

INTRODUCTION IN the iron-cobalt system there are several property-composition relationships of theoretical importance. The alloys are ferromagnetic exhibiting a maximum saturation at approximately 33 at. pct cobalt;1 the interatomic distances at room temperature show large positive deviations from Vegard's rule;2 and in the region of 50 at. pct cobalt there is an order-disorder transition which has a large effect on other properties. The thermal expansion data for the system have been reported3,4.5,6 only from room temperature to 100°C, and for this temperature range a minimum in coefficient in the region of 50 at. pct cobalt is well established. 3,4,6 This paper reports the expansion properties in the iron-cobalt system for temperatures from 30 to 850°C, shows the correlation with other physical properties, and proposes an explanation for the interrelation. EXPERIMENTAL PROCEDURE The thermal expansivities of iron-cobalt alloys in 10 pct steps in composition were determined from 30 to about 850°C. The major series of alloys was prepared by induction melting from Armco iron and cobalt rondelles with the addition of about 0.6 wt pct manganese. This series was supplemented by three compositions: high purity electrolytic iron, high purity electrolytic cobalt, and an alloy of 52.1 wt pct cobalt prepared from the high purity electrolytic iron and electrolytic cobalt by vacuum-melting. The compositions of both series of alloys are given in Table I. The specimens for measurement were prepared from the cast ingots by first hot-swaging followed in most instances by cold-swaging to 0.180-in. diam rod. Some alloys in the region of 50 pct cobalt, because of inherent cold-brittleness, were swaged hot to the final diameter. The expansion specimens were approximately 2 ½ in. long with flat-ground and polished ends. Before measurement they were annealed in hydrogen for r hr at 900°C. In the apparatus used for the thermal expansivity measurements (Fig I), a modification of that designed by Hidnert and Sweeney,7 the differential expansion between the specimen and vitreous silica was measured by a dial micrometer reading to 0.001 mm. An invar fixture supported the dial gauge, and this fixture, in turn, was connected to a split invar collar which supported the outer silica tube. A pyrex "T" was placed over the outer silica tube and was sealed to the invar collar by Apiezon Q sealing compound. A movable hollow vitreous silica rod which rested on top of the test specimen slid through a flexible rubber diaphragm cemented to the top of the pyrex "T." The specimen rested on a vitreous silica pedestal fused into the outer tube and was kept centered by a silica sleeve. A non-oxidizing atmosphere was obtained by admitting hydrogen into the

Jan 1, 1948