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By D. E. Parson, W. A. Morgan

This paper offers a brief review of current literature pertaining to vacuum degassing or vacuum casting of steel as practiced in the U.S.A., Germany and the U.S.S.R. The advantages of vacuum degassing of large forging ingots, heavy section casting, for the conversion of rimming bessemer steels to killed steel and for the production of transformer steels are discussed. Operating pressures, reduction in gas contents and improvements in hydrogen segregation, steel cleanliness and mechanical properties, obtained with the various techniques, are described. The paper includes a description of an experimental vacuum stream-droplet degassing unit and some preliminary results obtained at the Physical Metallurgy Division Research Laboratories Department of Mines and Technical Surveys, Ottawa on laboratory steel melts. Experimental 500 lb direct arc, basic melts have been spray cast into either ingot moulds or dry sand moulds, held inside a vacuum tank. Also 500 lb melts have been

Jan 1, 1961

By A. C. Ackenhell

The geologic environment of Pittsburgh, Pennsylvania is both inviting and challenging to drilled pier installation. The shales and clayey soil zone of the hills are favorable but the alluvial soils of the three major rivers create problems. Beginning in the early 1950's, drilled pier installation continually improved as methods were developed to meet the geologic challenge. Case histories are presented to illustrate the historical development of piers in Pittsburgh. Recent innovations reducing the groundwater problem are illustrated by a case history of a high rise building construction. Load test information for side wall shear on the cylindrical shaft area between the concrete and bedrock continues to be desired but remains generally uneconomical.

Jan 1, 2010

By Jay F. Colinet

Respirable dust exposure has long been known to be a serious health threat to workers in many industries. In coal mining, overexposure to respirable coal mine dust can lead to coal workers? pneumoconiosis (CWP). CWP is a lung disease that can be disabling and fatal in its most severe form. In addition, miners can be exposed to high levels of respirable silica dust, which can cause silicosis, another disabling and/or fatal lung disease. Once contracted, there is no cure for CWP or silicosis. The goal, therefore, is to limit worker exposure to respirable dust to prevent development of these diseases. The passage of the Federal Coal Mine Health and Safety Act of 1969 established respirable dust exposure limits, dust sampling requirements for inspectors and mine operators, a voluntary x-ray surveillance program to identify CWP in underground coal miners, and a benefits program to provide compensation to affected workers and their families. The tremen­dous human and financial costs resulting from CWP and silicosis in the U.S. underground coal mine workforce are shown by the following statistics: ? During 1970?2004, CWP was a direct or contributing cause of 69,377 deaths of U.S. underground coal mine workers. ? During 1980?2005, over $39 billion in CWP benefits were paid to underground coal miners and their families. ? Recent x-ray surveillance data for 2000?2006 show an increase in CWP cases. Nearly 8% of examined underground coal miners with 25 or more years of experience were diagnosed with CWP. ? ?Continuous miner operator? is the most frequently listed occupation on death certificates that record silicosis as the cause of death.

Jan 1, 2010

McArthur River Operation is the world?s largest high grade uranium deposit and is located in Northern Saskatchewan. McArthur River came into production in December 1999 with a number of innovative technologies to allow for mining of a high grade uranium deposit in challenging geotechnical and hydrological conditions. The raisebore mining method has been supplemented by the continued development of a boxhole mining technique to allow for mining of mineralization that cannot be accessed with a drill chamber from above. An innovative freeze wall re-design ? a cathedral freeze wall, was implemented in 2009 to allow for top access of a new orebody in the unconformity area of the Athabasca Sandstone. This paper highlights some of the ongoing improvements to the mining method and the innovative risk mitigation applied to manage the extraction of this challenging orebody.

May 1, 2011

By Carlton E. Brown

Broom and Yant6/ recently described a. microprojection method for determining the particle-size distribution and number concentration of samples of dust collected from the air by such samplers as the Owens jet dust counter) and the thermal precipitator8/ . This method was developed to obviate or reduce the eyestrain consequent to the regular filar-micrometer method9/ and to save time and work. The article stated that work was in progress on a micrcprojection method for counting impinger dust samples; this article describes the method developed. ACKNOWLEDGMENTS The assistance of the personnel of the ventilation Department of the Anaconda Copper Miring Co., Butte, Mont., in developing this method and particularly in suggesting a suitable material to use for the microprojector screen is sincerely appreciated. Much of the work was done in the laboratory of the Anaconda Copper Mining Co. on samples collected in Butte mines during a cooperative study with this Bureau.

Jan 1, 1938

By R. Venugopal, V. K. Saxena, S. K. Tripathy

"This study was carried out to understand the impact of variation in material morphology on the efficacy of microwave pretreatment. Three different types of mineral matter – coal, iron ore and manganese ore – were treated with microwaves at different energy levels, from 180 to 900 W, for different time durations of one to five minutes. The treated samples were subjected to microscopic, milling and liberation studies. Coal is a porous and amorphous material with low dielectric constant, and grinding of the microwave-pretreated coal samples resulted in an 18.18 percent reduction in the 80 percent of passing particle size, or d80, and a 17.1 percent increase in carbon recovery. The microwave-pretreated soft and friable manganese ore samples showed a 47.82 percent reduction in d80 during grinding and higher manganese recovery of 42.46 percent during liberation analysis. The microwave pretreatment and milling of hard and banded iron ore reduced the d80 by 20.83 percent, but no improvement was observed in mineral liberation. Coal showed better results during treatment at lower energy levels of 180 W for one to three minutes, whereas the minerals needed higher energy of 900 W for five minutes. Particle size analysis indicated rapid size reduction up to an energy input of 25 Wh. This effect diminished with increased energy input.IntroductionComminution is an important unit operation in mineral processing plants for the purposes of size reduction and mineral liberation. But most comminution technologies are energy inefficient and only a small amount of energy is consumed in real size reduction, with the rest wasted. High-grade mineral resources have been exploited on a large scale for the last century, and the upgrading of low-grade resources is now required to fulfill the needs of industry. Pretreatment methodologies for comminution will play a crucial role in the upgrading of low-grade mineral resources. Researchers have studied various pretreatment methods to develop an energy-efficient and techno-economically viable solution to improve mineral liberation and product fineness with minimum energy consumption. Most of these studies were focused on the use of chemical additives, thermal, ultrasonic and microwave treatment, and electric disintegration (Klimpel and Austin, 1982; Norgate and Weller, 1994; Gaete-Garreton, Vargas-Hermandez and Velasquez-Lambert, 2000; Wilson et al., 2006; Kumar et al., 2010; Wang, Shi and Manlapig, 2011; Singh et al., 2012)."

Jan 1, 2017

By Bernard Porter

The densities of LiF, NaF, and KF, of binary mixtures of these alkali fluorides, and of binary mixtures of UF4, ThF4, YF3, LaF3, and CeF with each of tie alkali fluorides were measured as functions of the melt composition and temperature. Molar volumes at 1,000° C were calculated for all the mixtures. Binary systems containing LiF exhibited molar volume ideality. Binary fluoride systems containing either NaF or KF as the alkali fluoride exhibit positive deviations from molar volume additivity. However, molar volumes in the NaF-KF system are ideal.

Jan 1, 1966

By L. Barry Phelps

The application of an open-pit Materials Handling Simulator (OPMHS) to analyze mine planning and scheduling problems in large surface mines is discussed. The mine chosen for this application employed a large stripping dragline working in tandem with a shovel-truck haulback system for removing overburden. Large bottom-dump trucks were employed behind a coal loading shovel to transport the exposed coal out of the pit. Specifically, the current operations and the recommendations for short term and long term improvements were simulated on OPMHS. The effects of changing the operating parameters of the equipment on the total system were evaluated. Several alternatives were also studied for the best use of the existing equipment if the current operating parameters could not be improved upon. The results of the application are discussed.

Jan 1, 1978

By R D. Lama, A Misra

One of the major factors restricting an increase in the productivity of a longwall mine is lower productivity obtained in a development panel. There has been a significant improvement in gate road development, particularly in mines requiring high density roof and rib bolting within 2 m of the face. Advance rates have increased from an average of 3 m to 5 m per shift in 1985 up to an average of 5 m to 10 m per shift in 1991. In mines at shallow depths with reasonably good conditions the increase has not been that significant. Advance rates have increased from an average of 7 m to 12 ni per shift in 1985 to an average of 12 m to 15 m per shift in 1991. Compared to the United States' (US) development rates, these are much lower. Extensive research work has been carried out to minimise cutting, wheeling, support setting time, and to optimise pillar length to achieve maximum advance rates. Pillar optimisation is very important in order to expedite adverse rates. This paper investigates various development rate technologies, both present and future, and optimises pillars to improve these dev elupment rates. Pillar optimisation is based upon time and motion studies conducted at mines in the Illawara region of New' South Wales, Australia, and the basic tools of arithmetic.

Jan 9, 1996

By Sandeep Kumar Asarapalli, Sunil Kumar Bisoyi, Bhatu Kumar Pal

Spontaneous heating of coal is one of the major concerns in the coal mining industry. Hundreds of millions of tons of coal are lost each year because of spontaneous heating. If necessary arrangements are made, many fires due to spontaneous heating may be avoided. Therefore, protective measures have become essential to prevent coal from spontaneous combustion. A large amount of coal reserve can be saved by the assessment, suppression, and prediction of spontaneous heating of coal, which also helps in betterment and efficient coal production. The use of chemical retardants can act as inhibitors for the liability of coal toward spontaneous heating by increasing its ignition temperature, thereby, increasing its incubation period. The coal-chemical mixture can be used for whitewashing the exposed coal in galleries as it creates a layer between coal and oxygen in the atmosphere, delaying the oxidation process and ultimately inhibiting the spontaneous heating liability of coal. This work examines the effect of chemicals such as sodium chloride, calcium carbonate, potassium iodide, sodium nitrate, and potassium chloride on the spontaneous heating of a coal sample. Thereby, it suggests a better chemical for inhibiting the liability of coal toward spontaneous heating. The experimentation involves flammability temperature (FT), crossing point temperature (CPT), and differential thermal analysis (DTA). The ignition and oxidation temperatures were found from the above experimental methods for Lingaraj open-cast coal mine samples, with and without adding chemicals. The results are cross-checked and verified through DTA. Correlation analysis was carried out among the results obtained from CPT, DTA, and FT, and better chemical retardants that effectively inhibit coal’s tendency toward spontaneous heating were suggested.

Dec 23, 2023

By Xin Tan

In this paper, two types of low-grade complex zinc oxide ores (sandstone and limestone ores) from Yunnan province, China were investigated. A large number of argillaceous and alkaline gangue makes it infeasible to treat the ores with heap leaching. Although wet metallurgy can be considered, the lower efficiency of liquid-solid separation, the high cost, and low revenue limit this technology to be put into practice in large-scale. In order to solve this problem, a new technology combining mineral processing method with metallurgy technique is studied to process this refractory ore that consists of sandstone ore with 5.84 per centZn and limestone ore with 6.50 per centZn. The results of the tests showed that zinc can effectively be recovered from two types of the ores by using the new technology, and the acid consumption can be remarkably reduced. For sandstone sample, 82.96 per cent Zn was recovered by flotation and final Zn recovery by flotation+ hydro-metallurgy can be up to 78.17 per cent from the ore. In addition, for sandstone, acid consumption can be reduced from 270kg/t by direct acid, leaching to 76.92kg/t by flotation + hydrometallurgy combination. For limestone sample, 85.90 per centZn was recovered by flotation and totally 80.95 per cent Zn can be recovered by new technology which is a combination of mineral processing and metallurgy. Besides, H2SO4 consumption can be reduced from 450kg/t for sandstone originally to113.79kg/t after using new technology. One merit of this new process technology is that the zinc sulfides and oxides can be recovered without desliming in the flotation cells at the different stage and make sure the concentrate products as a good feed for hydrometallurgical technology. This study provided pretty good technical support for tapping low-grade refractory zinc oxide ores. Keywords: low-grade zinc oxide ores, limonite, non-desliming beneficiation, flotation + hydrometallurgy combination

Sep 1, 2012

By Gregory J. Chekan

The Bureau of Mines, in an effort to improve planning and development in coal mining, is investigating strata interactions associated with mining of multiple coalbeds. Two common interactions that occur between adjacent coalbeds are subsidence and pillar load transfer. The study described involves underground observations and measurements conducted at two Pennsylvania mines, each affected by one of these interactions. At the mine affected by subsidence, measurements show that undermining had little effect on upper mine pillar stability, but had a more severe effect on the development and maintenance of entries. Roof-to-floor measurements recorded over four times more convergence in entries developed over gob as compared with entries developed over support pillars in the lower mine. At the mine affected by pillar load transfer, Initial in situ measurements have shown the existence of a pressure arch in the lower workings. Prior research has shown that arch interaction between two adjacent openings can create stress concentrations in the in-nerburden. Underground measurements and results obtained from both mine sites correlate with theoretical and photoelastic multiple-seam models, and eventually these field data will serve to refine model accuracy. Further study of multiple-seam interaction mechanisms will lead to improved mine planning, increased resource conservation, and a safer working environment.

Jan 1, 1986

By MacLean L

In 1975 the Commonwealth Government established import parity pricing for all liquid hydrocarbons discovered after the 16th September, 1975. These discoveries were termed "new oil" to differentiate them from existing discoveries and production. Overnight the price of the product being sought trebled, resulting in greatly enhanced economics by increasing the potential returns on existing prospects and by making smaller plays economically viable. After 18 years of drilling, the offshore Gippsland Basin has attained a moderate level of exploration for a basin of its size. Fifty seven prospects have been drilled within the basin but only a few of these were drilled along the southern and northern margins, while the deep water areas along the eastern margin have remained virtually undrilled following the Hapuku-1 oil discovery. The major hydrocarbon accumulations within the basin are trapped beneath the Latrobe Unconformity surface and exploration has largely concentrated on this single play in areas immediately adjacent to the major producing fields.

Jan 1, 1982

By W. M. Albrecht, W. D. Klopp, R. I. Jaffee, B. G. Koehl

Kinetic studies were made of the reactions of tantalum with oxygen, nitrogen, and air at 400o to 1500°C. The tantalum-oxygen reaction is linear from 500° to 1250°C. The tantalum-nitrogen reaction follows a cubic rate law at 400° to 700°C and a parabolic rate law at 800" to 1475°C. The reaction behavior in air is initially parabolic followed by a transition to linear behavior. In the search for high-temperature materials, considerable interest is being shown in the refractory metal, tantalum. It is the third highest melting metal with a melting point of 2996°C. Also, tantalum has excellent ductility, making it one of the most workable refractory metals. In considering high-temperature applications of tantalum, the oxidation kinetics of the metal must be known. Such information also serves as a basis for the development of corrosion resistant tantalum-base alloys. Therefore, this study was made to investigate the reaction of tantalum with air, nitrogen, and oxygen. LITERATURE Several oxides of tantalum have been reported. The pentoxide, Taz05, is the only oxide of tantalum whose identity has been established. A high-temperature modification, aTa2Os, has been reported by several investigators.1-4 A low-temperature phase, ßTa2O5, undergoes an allotropic transformation at 1320o to 1350oC. 5-8 Four other oxides of tantalum have been reported. The oxides TaO2, TaO, and Ta4O have been reported by schonberg.9 A suboxide Ta2O, was observed by Wasilewski 6. However, the presence of oxides lower than Ta2O5 is questioned by Lagergren and Magneli.7 In oxidation studies, vermilyeal0 and Peterson, et al.,12 reported one possible phase intermediate between Ta and Ta2O5. Only Ta2O5 was formed in the tantalum air reaction, as reported by Michae1.l3 Several studies have been made on the kinetics of the tantalum-oxygen reaction. vermilyeal4 investigated the range 50° to 300°C and found that the rate of growth of a thin adherent oxide film could be described by the Cabrera-Mott theory. Gulbransen and Andrew15,18 studied the reaction kinetics of tantalum in oxygen pressure of 1/10 atm at 250° to 450°C. At all temperatures the reaction followed the parabolic rate law for periods up to two hours. The oxidation behavior in the range 500" to 1000°C was found to be linear at oxygen pressures of 0.2 to 600 psi according to Peterson. et al.l1 At very low pressures (1 x 10-3 to 2 X lo-' mm of Hg) Gebhardt and seghezzi17 reported linear oxidation at 800° to 1500°C. The reaction of tantalum with air is similar to the reaction with oxygen. Studies have been made by Waber, et a1.,12 and Michae1.l3 Two nitrides of tantalum, TaN and Ta2N are known. Their structures have been determined by Brauer and Zapp 18,19 The tantalum-nitrogen reaction kinetics have been investigated by Gulbransen and Andrews. 15, 16 The reaction follows the parabolic rate law at 500° to 850°C at a nitrogen pressure of 1/10 ,atm. At the same temperature, the tantalum-nitrogen reaction is much slower than the tantalum-oxygen reaction. EXPERIMENTAL TECHNIQUES Material— The material used in this study was high-purity, electron-beam-melted tantalum obtained from the Temescal Metallurgical Corp. The hardness of the as received ingot was 76 Vhn. The analysis of the material is given in Table I. Methods—Cylindrical specimens of tantalum approximately 0.9 cm in diam and 0.5 cm in length

Jan 1, 1962

By J. H. Bilbrey

A recording thermobalance ,vas used to determine the rates of oxidation of mol-ten tin over the temperature range 550°-900° C. Oxidation rates were found to vary widely for a given temperature, as previously reported by other investigators. 1 X-ray diffraction data indicated that the probable cause of these variations was the development of preferred orientations in the crystals forming the oxide film. No reasons for the differences in degree of preferred orientation were discovered. For relating the weight of the oxide formed (w) to the time of oxidation (t) an equation of the form wn = kt was found to best represent the experimental data. INTRODUCTION In the course of conducting investigations on the feasibility of using selective oxidation techniques for the purification of various metals in the molten state it was soon discovered that data on the oxidation of molten metals and alloys were very scarce. In contrast to the many hundreds of publications on the oxidation of metals in the solid state there are relatively few articles on the rates of molten-metal oxidation. In view of this scarcity of data, it was decided to institute a series of investigations into the oxidation processes of molten nonferrous metals and alloys with the expectation that the information derived could be put to practical use in developing and improving refining processes based on selective oxidation. This report is the first of a series in which oxidation data for molten nonferrous metals and alloys are presented.

Jan 1, 1955

By Jim V. Rouse

Adverse water-quality impacts of uranium mining and milling activities on both surface- and ground-water resources in the Grants Mineral Belt have recently been documented.1 In some cases, the impacts resulted in violation of existing regulations and license conditions and have endangered public health. Unfortunately, industry-sponsored ground-water monitoring programs do not adequately record the actual impacts of mining and milling on ground-water quality.

Jan 1, 1976

By B. Schulz, T. Leißner, R. G. Merker

"Ores enriched in critical rare earth elements (CREE) keep on being of particular interest. The CREE are Nd, Eu, Tb, Dy, including Y. In conjunction with beneficiation tests on Y-mineral bearing flotation tailings of complicated mineralogy, the Mineral Liberation Analyses (MLA) was used to work out processing characteristics fraction-wise in terms of modal mineralogy, mineral recovery, locking and liberation, and particle size.Size fractions from mechanical sieving (“real fractions”) as well as fractions created virtually by using filters on the MLA-data of the unsieved head material (“virtual fractions”) were investigated comparatively thereby. The ""virtual-sizing-approach"" features a much simpler sample preparation procedure and considerably lower cost if a fraction-wise investigation of a head sample is needed. It can be conveniently applied to intimately locked ores needing a fine grinding to a particle size distribution (PSD) range below 25 microns for instance. However, its practical use is sometimes disputed in terms of the reliability of the results. Results are shown for the main Y-bearing mineral xenotime and selected main gangue minerals of a low grade REE-ore.The influence of sample representativeness, sample preparation and particle counting statistics turned out to be of crucial importance. Given that all preconditions for reliable results are met, locking characteristics, modal mineralogy, and even PSD trends can be read from virtual fractions.The authors encourage processing engineers to use the virtual approach. They propose practical measures to improve the reliability of the MLA results, identify and tackle conflicting results, and mitigate evaluation problems that may arise."

Jan 1, 2016

By Peter K. Strangway

During 1973, a 20,000 net ton (18 100 metric ton) formcoke test was carried out at Inland's 26.5-foot (8.08-meter) hearth diameter on NO. 5 Blast Furnace. The formcoke briquettes were produced from Elko1 coal by FMC at their pilot plant in Kemmerer, Wyoming. The briquettes were shipped to Inland in open railroad cars and most of them were placed in an outside storage field until a sufficient amount was available for the actual blast furnace test. The test consisted of three phases: an initial four-week base period; the actual 33-day formcoke test period; and a final three-week post-test base period. During the formcoke test period, the regular coke skip loads were gradually replaced with skips of formcoke until, after a three-week period, the replacement ratio reached 80%. The furnace operated smoothly and quality hot metal was produced. The burden remained permeable and it was possible to maintain wind rates 9 of over 100,000 scfm (47 Nm3/s) without significant blast pressure increases. Dusting from the formcoke was not a problem either in the stockhouse or in the top gas. The formcoke briquettes maintained their original shape and density as they descended through the furnace. When the 80 percent replacement level had been reached, the inwall temperatures became higher than normal (about 2000 ºF (1090 ºC)) and followed an unusual steady pattern. In addition, the top gas temperature became higher than normal, and the hot metal analyses and temperatures began to fluctuate unacceptably. In general, it is felt that the high inwall temperatures were a result of channeling of the hot furnace gases along the stack walls. This channeling appears to have been promoted by a change in distribution of the burden in the top of the furnace which, undoubtedly, was caused by the increased increments of formcoke. Since it was felt to be unsafe to operate the furnace for an extended period of time with the inwall temperatures at the high level, a decision was made to remove the formcoke from the furnace. When this was done, the inwall temperatures returned to normal. Once the inwall temperatures had returned to normal, the remaining 3,800 net tons (3450 metric tons) of formcoke were used in the furnace at a nominal 40% replacement level for five continuous days. The furnace operated smoothly during this period, and the results were representative of satisfactory furnace operation with partial replacement of regular coke with formcoke. The test was successful in proving that formcoke can replace up to about 50% of the regular coke in a large furnace operating at high wind rates. However, additional work will be required to develop acceptable charging practices for using higher levels of formcoke replacement.

Jan 1, 1977

By Chester L. Arnold, Reinhardt Thiessen, Alexander Lowy

"INTRODUCTION Peat is the accumulated mass of plant materials that remain after partial decay under specific conditions. In the swampy peat bogs dead material which falls on the surface immediately is attacked by fungi and aercbic bacteria. Decay under these conditions is rapid, but of relatively short duration, since the constant addition of new material soon forces the older layers below the water level, in this position, without access to oxygen, the plant constituents are attacked mainly by anaerobic bacteria, and decomposition proceeds slowly. The largest part of peat is contributed by the woody tissues of plants, the chief constituents of which are cellulose and lignin, together with a small proportion of hemicelluloses. During the normal process of biological decay celluloses disappear more rapidly than lignin. The result is a complex substance known as humin, from which the humic acids may be extracted.In 1826, Sprengel 5 found that when decayed plant materials were extracted with alinnli and the resulting black liquid acidified with mineral acid a brown gelatinous precipitate was formed. To this product, which was a brown amorphous powder when dry, he gave the name ""humic acid'. Since that time, chemists have used the name rather loosely to designate products which have been isolated by very diverse means from soils, decayed woods, peat, lignite, and coal. An excellent review of the early work on humic acids was published by Baumann 6 in 1909. This publication aroused the interest of Oden, who then investigated the humic acids. An account of Oden’s work, as a good survey of the literature, is contained in his monograph “Die Huminsauren”. 7"

Nov 1, 1934

Case studies from four western states are used to illustrate the impact of the environmental compliance process on the mining industry. The case studies were not chosen as a statistically significant sample of all mining operations in the western United States but were chosen as representative of operations on both public and private lands and in locations that exhibited varying degrees of involvement by governmental units, non-governmental organizations and the general public. Basically, each case study was chosen because some aspect of their environmental compliance process helped to illustrate an interesting point in the regulatory process. The criteria used to select the case studies were: mines located in different jurisdictional areas, mines located in varying geological areas~ mines located in areas having different historical relationships with mining: and operations that are in production as well as those seeking an operating permit. The variety of such projects should provide the necessary foundation to evaluate the impacts of the environmental compliance process in each location.

Jan 1, 1994