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By Amilton Feliciano Castro

In this work, activated carbons (ACs) were prepared using Sewage sludge as starting material. The ACs were pyrolyzed in an inert atmosphere at 550 °C after independent chemical treatment with ZnCl2 or KOH with ratio of 1:1. The materials were used as adsorbents for removal of Cu(II) from aqueous solutions. The adsorbents were characterized using adsorption/desorption nitrogen isotherm, SEM (scanning electron microscopy). The results showed that copper removal could be linked to surface pH and compounds present on the surface of adsorbent. KOH-treated adsorbent has smaller surface area (186 m2 g-1) than ZnCl2-treated adsorbent (192 m2 g-1), however, KOH-treated adsorbent exhibited higher removal of Cu(II). The performance of KOH-treated adsorbent could be attributed to the presence of basic groups on the adsorbent surface. Liu isotherm model gave the best description of the equilibrium data. From the Liu isotherm, the maximum adsorption capacities at 298 K for KOH-treated, ZnCl2-treated and sewage sludge (without inorganic activation) adsorbents are 31.85, 19.79 and 3.513 mg g-1, respectively. The best desorption experiment was obtained using 1.50 mol L-1 of HNO3 as eluent. Recoveries of Cu(II) from Cu(II)-loaded adsorbents are 98.9% (ZnCl2-treated) and 95.5% (KOH-treated.

Aug 17, 2017

By Kai Koosmen, Mehdi Serati, Tengzhou Wang

Spalling and rockburst are unwanted brittle failures at the boundaries of underground excavations that are commonly observed in hard rock and high-stress environments at significant depths, although, spalling has also been observed in comparatively shallow soft rocks. The crack initiation (CI) stress threshold (representing the stress level at which new micro cracks begin to form in an intact rock) is widely used to establish the in-situ spalling strength, and is generally regarded as the lower limit of the long-term rock strength. This study analyses the evolution of CI and other mechanical properties for a high-porosity sandstone with an average UCS of 38 MPa under unconfined cyclic compressive loading. The results indicate that rock properties are variably affected by cyclic loading with; no significant effect on Youngs Modulus; a moderate increase in Poisson’s ratio and fracture angle; a moderate decrease in UCS; and a major reduction in the CI stress threshold. All of these changes were generally amplified by cyclic loading at higher stresses. From the results, it is concluded that rockburst and spalling limit in underground structures may reduce over time if the rock is subject to repetitive cyclic loading, and that the reductions will be greater for higher cyclic stresses. This may be a significant factor in the design and operation of some deep underground structures.

Apr 26, 2022

By M. Lindgren

"Hydrometallurgical processing involves process stages, like leaching, that create harsh environment for stainless steels. High acidity, the presence of chlorides and oxidizing ions combined with relatively high temperature create risk for both uniform and localized corrosion. Advanced electrochemical techniques were employed to study uniform and pitting corrosion of two stainless steel grades 316L and 2205. Results obtained with the linear polarization resistance technique combined with the harmonics distortion analysis, electrochemical noise and coupled multielectrode array systems are compared to the results of conventional electrochemical techniques and immersion tests.INTRODUCTIONHydrometallurgical processing has become favoured in metals production in recent years due to energy costs, leaner ore bodies and environmental factors. Because the hydrometallurgical processing route is flexible, various types of secondary raw materials, like flotation tailings, dusts, sludges and slimes can also be treated in addition to conventional mineral concentrates (Sarveswara Rao & Acharya, 2008).Hydrometallurgical processing relies on aqueous chemistry, usually acids, at temperatures around 100°C for the recovery of metals from ores, concentrates, recycled or residual materials. The processing route can typically be divided into three stages: leaching, solution concentration/purification and metal recovery. The processing environment is aggressive, especially in leaching. High acidity, relatively high temperature together with impurities, like chloride ions, place high demands on the corrosion resistance of construction materials. The dominant corrosion mechanism may be uniform corrosion or localized corrosion depending on the process conditions (Ekman & Torsner, 2010). This complicates the prediction of corrosion rates and, consequently, cost effective material selection.Traditional means to evaluate uniform corrosion resistance of stainless steels are immersion tests and the results are published in the form of iso-corrosion diagrams (Outokumpu Stainless, 2010). For the localized corrosion, namely pitting and crevice corrosion, immersion tests can be used but the duration of the test is rather long because an incubation period takes place prior to the occurrence of the actual localized corrosion damage. Electrochemical techniques, traditionally in the form of cyclic polarization scans, have been employed to assess the susceptibility of a material to pitting corrosion (Papavinasam, 2008). They cannot, however, give any indication of the pitting corrosion rate and lack potential for on-line measurements."

Jan 1, 2012

By A. C. Smith

The U.S. Bureau of Mines evaluated the effectiveness of automatic water sprinkler systems on the suppression of incipient and propagating conveyor belt fires under ventilated conditions. Large-scale experiments were performed at airflows ranging from 1.1 to 4.6 m/s. In incipient fire experiments with 100°C, standard-response sprinklers installed above and between the belts, the sprinklers activated later, the peak heat release rates were larger, and more belting was consumed at the higher airflow. In similar experiments with 74 °C, fast-response sprinklers, the sprinklers activated at the same heat release rate for both high and low airflows, but the peak heat release rate and amount of belting consumed was slightly higher at the lower airflow. In incipient fire experiments with sprinklers located only above the top belt, the heat release rate and amount of belting consumed was larger at the higher airflow. The propagating fire experiments showed that sprinklers located above and between the belts were effective in stopping flame propagation. Peak heat release rates and amount of belting consumed were larger at the higher airflows for both the 74 °C, fast-response and 100 °C, standard-response sprinklers. The sprinklers were equally effective at each airflow.

Jan 1, 2010

By Keith A. Heasley

Historically, the surface subsidence over underground coal mines has been predicted using empirical profile or influence functions which have little or no connection to the actual mechanics of the subsidence. Without a mechanistic basis, establishing the exact site-specific parameters to use in these empirical methods has been problematic. A practical subsidence predictive method based on mechanics has the appealing capability of allowing the determination of site-specific parameters from fundamental properties of the overburden with minimal field calibration work. This paper presents several case studies where a mechanics-based, boundary-element program is used to back-calculate the surface subsidence associated with various panels at several Northern Appalachian coal mines. The program used in this case study is called LAMODEL, and it incorporates a frictionless, laminated overburden into a general purpose displacement-discontinuity code primarily designed for calculating the stresses and displacements in coal mines or other thin scam or vein type deposits. In this paper, the program is used to calculate both the underground convergence and the resulting surface subsidence at five longwall panels and a room-and-pillar section. The fitted subsidence from the model is compared with the field measurements and analyzed. The results from the case studies in this paper demonstrate that the laminated model with calibrated properties can easily provide moderately accurate subsidence predictions and is fairly flexible for fitting measured subsidence. However, additional subsidence predictive case studies arc recommended in order to ultimately evaluate the potential of the laminated overburden model for practical subsidence prediction

Jan 1, 1999

By Jie Zhang, Xi Zhang, Yu Wang, Wei Zhao

The study proposes a novel reagent scheme where adding a small amount of citric acid (CA) significantly improves the depression effect of sodium silicate on calcite and fluorite. The flotation results suggest optimal concentrations for CA and sodium silicate, achieving nearly complete depression of the minerals. Theoretical analysis indicates that CA dissolves calcium ions on the mineral surface, enhancing the adsorption of sodium silicate and preventing collector adsorption.

Mar 27, 2022

By Donald R. Simon

Money... not many subjects are as personal or as emotional. Hessiod said it well in 700 B.C. "Money is life to us wretched mortals". Are you getting paid enough? Does your company reward its top people? Does coal or copper pay more? Production or engineering? How is the synfuels industry going to influence mining salaries? Do high salaries attract and retain the best people? Do modern compensation systems ensure fairness or destroy entrepreneurial spirit? With our tax system and high standard of living why are we so salary conscious? Salary is not only important for what it can purchase but it is also a yardstick, measuring how well we are doing. We all need money to pay the bills and maintain our standard-of-living, but once we reach a certain point the psychological ramifications become more important than the purely practical side. Even necessary payments like the mortgage and the car are a function of our egos. Are our choices of cars and homes based on simple transportation and shelter?

Jan 1, 1980

By R. K. Mishra, A. Kula, X. Jia, M. Niewczas

The mechanical properties of Mg-Gd and Mg-Y solid solutions have been studied under uniaxial tension and compression between 4K and 298K. The results reveal that Mg-Gd alloys exhibit higher strength and ductility under tension and compression attributed to the more effective solid solution strengthening effect and grain boundary strengthening. Profuse twinning has been observed under compression, resulting in a material texture with strong dominance of basal component parallel to compression axis. Under tension, twining is less active and the texture evolution is affected mostly by slip. The alloys exhibit pronounced yield stress asymmetry and significantly different work-hardening behaviour under tension and compression. Increasing of Gd and/or Y concentration leads to the reduction of the tension-compression asymmetry due to the weakening of the recrystallization texture and more balanced twinning and slip activity during plastic deformation. The results suggest that under compression of Mg-Y alloys slip is more active than twinning in comparison to Mg-Gd alloys.

Jan 1, 2015

By Cynara Christ Klippel

A formação de uma escória adequada é essencial para a reação de desfosforação, pois ela deve ser capaz de absorver e reter o fósforo em sua estrutura. Este trabalho tem como objetivo a avaliação do processo de desfosforação de ferro-gusa tomando como base os resultados obtidos na análise química da mistura inicial e escória final, uma vez que as condições finais do metal são determinadas por sua escória. As misturas utilizadas são a base de CaO-FeO e a temperatura de tratamento foi de 1400ºC. Inicialmente o estudo será realizado usando os modelos da literatura e posteriormente com uso de ferramentas de termodinâmica computacional. Será também determinado um modelo para prever a eficiência destas misturas.

Aug 17, 2017

By R. D. Leitch

The work of the United States Bureau of Mines on stream pollution by coal-mine drainage has included a study of seasonal variations in acidity and volume of several streams in Pennsylvania. The acidity of these streams has been determined during the two or three years prior to 1930 and the results may be considered to represent "normal" low water conditions. The summer of 1330, however, was unusually dry and represents what may be termed "extreme low water conditions on these streams. This report is a comparison of the results obtained for extreme low water of 1930 and for other years. The streams investigated were Buffalo Creek in Somerset County, Indian Creek (lower 5 miles) in Westmoreland County, Little Toby Creek in Elk and Jefferson Counties, Daguscohonda Run in Elk County and West Creek in Elk and Cameron Counties. These will be treated separately in the order given. Most of the descriptive matter and physical data pertinent to the streams and drainage basins are taken from published reports of the Pennsylvania State Water Supply Commission, 1917.

Jan 1, 1931

By João Domingos Guimarães de Athayde Junior, Luiz Fernando Andrade de Castro, Willian Facundes, Marlon José dos Anjos Silva

O aumento da demanda por aços com baixos teores de enxofre tem levado algumas indústrias siderúrgicas a estudar formas de otimizar o tratamento de dessulfuração no aço, visando reduzir o consumo de agentes dessulfurantes, o teor de enxofre e o tempo de tratamento no refino secundário. Neste trabalho, foi analisada a evolução do enxofre durante o tratamento de dessulfuração de duas classes de aço no forno panela, nas 30 corridas experimentais utilizou-se uma mistura micropulverizada contendo cal e fluorita. Após avaliação dos resultados e das condições termodinâmicas e cinéticas, foram desenvolvidas equações para cálculo da mistura a ser injetada em função do teor de enxofre inicial e objetivado. O uso da mistura proposta no processo resultou na redução de 1,1 kg/t de mistura micropulverizada, 0,22 kg/t de alumínio, 3,3 kWh/t de energia, 0,034 kg/t de eletrodo e 2 minutos de tratamento.

Oct 1, 2019

By R. F. Linfield

Figure 1-1 shows the basic transmitter design concepts used for the pulse system, the half-wave CW system, and the full-wave CW system. The antenna current waveform is also shown for each transmitter for typical operating frequencies and antennas. The switches shown in Figure 1-i were actually implemented using solid state devices. In all three systems the signaling format may be interrupted to conserve power and thereby extend battery life. Frequency accuracy and stability is achieved using a tuning fork oscillator in the transmitters and tuning fork filters in the receivers for all three systems. This provides the narrow reception bandwidths needed to enhance signal detectability. All three systems also use frequency assignment for identification purposes. The location schemes employed are likewise identical, each being based on detecting the null (signal minimum) of the horizontal magnetic field on the surface. Since these systems are basically similar, the primary purpose is to select the system which gives the maximum signal detectability on the surface from a manpack transmitter operating in the mine. Both the pulse and half-wave C W systems use a d. c. pulse to energize the loop antenna. However, with the pulse system, this pulse duration is short compared to the pulse repetition rate (prf), whereas with the half-wave C W system the pulse duration equals one-half the period of the switching frequency. In the pulse system, energy from the battery is stored in a capacitor so that during the switching interval the internal resistance of the power source can be considered almost negligible. Both transmitters must drive a loop antenna which is a reactive load having inductance, L, and resistance, Ra.

Jan 1, 1973

By Gyan S. Rajhans

"The strategy of fibrous dust sampling is discussed, various sampiing methods are critically reviewed .and their application to coal dust is demonstrated. Fibre counting is described in detail. An attempt is made to explain the basis of determining the threshold limit value of asbestos and other dusts. The paper also discusses such dust control methods as enclosure of the process, effective local exhaust ventilation, segregation, substitution, wet processing and continuous monitoring of the return air for recirculation."

Jan 1, 1970

By C. Bergstrand

"Precipitation of gypsum and the formation of scale may pose a serious challenge in the leaching of several minerals. As an example, precipitated gypsum may form scale in the machines increasing the need for maintenance. Alternatively, it may encapsulate precious elements, i.e. gold and lower the recovery during subsequent leach processes. In this work we explore how different biopolymers modify the rheology of gypsum at three different pH levels at ambient and elevated temperatures. The ability to disperse gypsum vary with temperature, pH and biopolymer. It is also inversely related to the scaling potential. Measurements of the zeta potential as a function of increasing amounts of biopolymer reveals that the magnitude of the zeta potential changes in the presence of biopolymer, and so does the ability to disperse the gypsum suspension. Similar results with hematite will also be discussed. The methodology and results may aid in the selection of additives used in mineral processing applications where scale pose a problem.INTRODUCTION Processing of refractory gold ores normally involve either atmospheric or oxidation under pressure in order to convert sulfides to oxides (Weir, King, & Robinson, 1986; Weir, Robinson, & King, 1986). This conversion facilitates leaching of gold (and silver) in normal CIL processes. During oxidation, sulfides are converted to sulfates. Normally, there is an abundance of calcium ions in the process water, either released from the ore or added as lime to adjust pH for the CIL process. Precipitation of calcium sulfate, or other compounds (calcium carbonate, jarosite, hematite) is a way to remove gangue minerals from the solution entering the CIL circuit (Ji, King, Fleming, & Ferron, 2010). Precipitation may also cause challenges in the process as gold (or other valuable elements) may become encapsulated in gangue. (Beauchamp, Choung, & Xu, 2006). In addition to precipitation, the precipitated gangue minerals may solidify and form scale in the processing equipment. Recently, Lauten and Kluck (2016) found that dispersants used as scale inhibitors to prevent encapsulation of gypsum did not modify the solubility of gypsum. In the utilised model system, similar amounts of gypsum precipitated with and without dispersants. Instead, it was found that the dispersants evaluated as scale inhibitors reduced the yield stress of gypsum suspensions. The reduced yield stress was associated with a reduced tendency for gypsum particles to agglomerate and form scale."

Jan 1, 2017

By Anburaj C., Srinivas A.

Deep excavation with support system is required to construct various part of underground structures like shafts, stations and entry structures etc. These structures have to be constructed using permanent or temporary embedded retaining walls with support system. The selection of a suitable type of retaining wall will depend upon the geological condition present in the particular location, time, cost and available equipment etc. In Bangalore Metro Rail Project, secant pile wall is adopted as the temporary earth retaining system and depth of excavation is about 20 m. It is designed initially based on bottom up construction methodology with 3 level of struts and 3 level of anchors but at later stage due to time and other construction related issues, it is decided to change the configuration to 6 levels of strut. Generally, in deep excavations, all the underground structures should be designed and checked for the critical forces from both permanent stage and construction stages. Since, secant piles are used as temporary retaining wall, only construction stage analysis is carried out to get the governing forces and deformation. In construction stage analysis, soil layers are defined with boundary conditions and the surcharge during construction and surcharge from actual building near the secant pile are considered. This paper discusses the effect of change in the support system from anchors to struts and how these changes in the support system affect the behavior of secant pile and subsequently adjacent buildings present in the influence zone of the excavation. As a result, in changing from anchors to struts, the wall displacement, strut forces and ground movement on the adjacent ground and buildings increases. The increase in deflection, ground movements and strut forces occurs during backfilling sequence of the underground station excavation. During backfilling, struts has to be removed and this imparts higher magnitude in deflection, strut forces and ground movements.

Nov 1, 2022

By H. Mullani

We have in southeast Kansas a variety of soils underneath which are a variety of subsoils compressed into what is commonly called “ hard pan.” These soils are of six types, ranging from a clay to a sandy loam. The surface soil in Cherokee County and Crawford County, of whatever quality or type is, generally speaking, from 6 to 12 inches in depth. The so-called “hard pan” ranges from the native grass roots to a depth of from 2 to 12 feet, and in some places even deeper than that.

Jan 1, 2010

By Michael A. Poling

Ladies and gentlemen, I appreciate this opportunity to be with you, and to share my outlook on the future of Federal coal leasing. I'm told that you wanted the best speaker on this subject in the world. Perhaps it's a reflection of these trying financial times, but I'm glad you finally agreed to settle for the best speaker your budget would afford. I have been asked to give you some insight on the status of Federal coal leasing, and how the budget problems facing the Department will affect the coal program. So I've polished up my crystal ball, and I'll try to give you a peek at the future. Before I do that, however, let me first go back in time - to when this Administration took office in 1981. We had a coal program then, after a hiatus of ten years. But that program was untested and - for reasons well known to all of you - did not work well in practice once we began operating the program. We went back to the drawing board and redesigned the program so that it can do what it is intended to do. We've made the program more predictable. That means that when future lease sales are scheduled, those sales will be reflective and reactive to the need to lease coal. On February 26, Secretary Hodel unveiled a framework for resumption of Federal leasing program activities, ending a more than two-year suspension of regional coal sales. The new program will provide the opportunity to satisfy market demand for acquiring and developing new leases, assure the government of fair market value for its coal reserves, and provide a stable supply of coal for this country's energy needs. The new program grew out of the Department's response to recommendations of the Linowes Commission and the Office of Technology Assessment, coupled with a supplemental environmental study. The Linowes Report, issued in 1984, contained 36 recommendations and three Judgments on leasing levels, tract selection, sale procedures, appraisal methods, key statutory and related factors, and organization and management of the leasing program. Major changes in the new leasing program reflect these concerns. We have developed a definition for captive tracts and devised procedures to appraise their value to the adjacent coal or mine owner. Other steps include a coal lease appraisal guide which describes our appraisal methodology and is available to the public. Improvements have also been made in the gathering of lease assignment information to help in estimating the value of potential lease tracts. To improve market analysis, a three-tiered system will be used to ensure that steps of the lease sale decision process are undertaken in the context of coal supply and demand. Regional Coal Teams will thus have the advantage of long range, regional and tract specific market studies to help them determine whether sufficient demand is expected first to warrant the initiation of activity planning, then to set regional leasing levels, and finally to actually offer specific tracts for lease sale. Sale procedures will also be improved in many ways to encourage competition, improve the chances for receiving adequate bids, and to evaluate whether bids represent fair market value. We made additional modifications to the program in response to the OTA recommendations. Regional Coal Teams have been given a larger role in recommending key decisions concerning the amounts of coal to be studied and the actual selection and scheduling of tracts for lease sale. These recommendations will be accepted unless the Secretary can cite an overriding national interest factor, or a governor's request to modify the recommendations. Smaller, more frequent sales will be held, to better judge market conditions and prevent over- or under-leasing. Public participation guidelines have been written, to document all opportunities for the public to comment at various stages in the planning process. We also decided that resource management plans prepared after the passage of FLPMA in 1976 must be completed, in order for a new round of lease sale planning to begin. The BLM will also beef up its procedures for consulting with affected Federal agencies during the planning process, to assure that the purposes and values of those agencies are considered and factored into land use decisions. To assure consistent use of an adequate data base in coal lease decision-making, Regional Coal Teams will develop standards and guidelines for data adequacy, and document the use of these standards. These procedures will also be applied to the unsuitability criteria screening process. Thus, the new leasing system announced by Secretary Hodel: is fully responsive to recommendations made by the Linowes Commission and the Office of Technology Assessment for improving environmental planning and fair market value procedures; gives the regional coal teams a major say in determining leasing levels, and on the timing,

Jan 1, 1986

By Foluke Salgado de Assis

Este trabalho visa apresentar os resultados obtidos através de ensaios balísticos realizados em sistemas de blindagem multicamada. Seguindo as especificações da norma americana NIJ 0101.06, foram realizados ensaios utilizando munição de calibre 7,62x 51 mm, que possui velocidade acima de 800 m/s. A blindagem multicamada utilizada possui como camada frontal uma pastilha hexagonal cerâmica (alumina dopada com 4% de nióbia), segunda camada de compósito de matriz poliéster reforçada com tecido de juta e como terceira camada uma placa de alumino 5052 H34. A utilização de compósitos poliméricos reforçados com fibras naturais em substituição às fibras de aramida é de grande interesse, pois além de desempenharem a mesma função no sistema de blindagem, possuem um valor de mercado bem menor. Os resultados de profundidade de indentação na plastilina foram satisfatórios visto que atenderam a norma NIJ 0101.06 e utilizando a técnica de microscopia eletrônica de varredura, verificou-se que o compósito poliéster-juta capturou os fragmentos através do mecanismo de incrustação mecânica.

Aug 17, 2017

[In presenting this list of permissible explosives and blasting devices, the Bureau of Mines desires to call attention to pages 17 and 23, outlining the conditions in use under which, and only under which, the explosive or blasting device is permissible. In view of publications recounting trade practice favoring the use of a blasting device without stemming, particular emphasis is placed upon condition 4 on page 17 and condition 2 on page 23. An explosive or a blasting device enumerated in the permissible lists of thin Bureau is not permissible in use unless it is properly confined with clay or other incombustible stemming.]

Jan 1, 1941

By Moacir Alves dos Reis

O objetivo deste trabalho foi criar um projeto de um simulador do sistema de carregamento do Alto Forno 2, voltado para o treinamento de operadores e técnicos em manutenção. O principal objetivo está em produzir uma ferramenta que auxilie no processo de ensino dos operadores e técnicos de forma mais rápida e segura, reduzindo os custos do treinamento e ao mesmo tempo simulando situações de operação, alarmes de processos sem interferência no sistema de carregamento real. São apresentadas as etapas previstas para o desenvolvimento do projeto e as ações já realizadas até o presente momento. O simulador será equipado com equipamentos reais do sistema de carregamento do Alto Forno, sendo apenas simulado as entradas e saídas físicas (I/O) dos equipamentos externos (motores, limites, válvulas, etc.) e utilizará um ambiente virtual modelado a partir do PLC, SDCD e Monitores para que os operadores possam visualizar e simular todos os alarmes deste processo.

Jul 30, 2018