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By J. Drelich

The wetting behavior of liquid polymers at solid surfaces and the adhesion forces involved at polymer-filler interfaces should always be considered in the fabrication of high quality polymer composites, including those made with mineral fillers. Spontaneous polymer spreading over the filler surface is a basic condition in the fabrication of the polymer-mineral composites. In this regard, the wetting and adhesion characteristics of polymer-mineral systems are reviewed in this contribution. It appears that several aspects of wetting phenomena at mineral filler surfaces are not well described in the literature and require further systematic study. Specifically, it is clear from this review that efforts should be made to determine the effects of mineral surface contamination (including surface hydration) on wetting and adhesion phenomena, and to determine the wetting characteristics of molten polymers at mineral filler surfaces. It is expected that any improved fundamental understanding of wetting and adhesion phenomena for the polymer-mineral composites will provide the basis for further technological development.

Jan 1, 1995

By Pengfu Tan

In order to understand and control the formation of dioxins and furans in iron ore sinter plants and to possibly avoid expensive end-of-pipe removal stages, thermodynamic calculations on the stability of PCDD/Fs have been combined with sinter process modeling by means of kinetic simulations and computational fluid dynamics. Three thermodynamic databases of PCDD/Fs, derived using the Group Additivity approach and two computational molecular modeling methods, MNDO and PM3, respectively, combined with the SGTE database have been used to model the PCDDIF formation and the PCDD/F isomer distributions in iron ore sintering. The results show very similar conditions for the PCDD/F formation using the different databases. Concerning the isomer distributions of toxic PCDD/Fs, the calculated data derived from the MNDO method showed optimum agreement with measured values from industrial furnaces. The thermodynamic calculations also proved that the isomer distributions found in combustion processes are equilibrium values, while the concentration ratio of PCDDs and PCDFs in the wind boxes does not represent an equilibrium state. A CFD model of iron ore sintering was developed including the kinetics of 15 relevant chemical reactions with the aim of describing the temperature fields and the gas flow patterns in the sintering bed. On the basis of these information and experimental observations reported in the literature possible pathways for the PCDD/F formation in sinter plants have been identified: PCDD/Fs are formed in the critical temperature region of 250 to 450°C below the combustion zone, are then carried downwards with the gas and condensed close to the bottom of the sinter bed. Transported to the discharge end with the solid mixture, they are again released into the gas phase when the flame front approaches the bottom. PCDD/Fs are also formed in the last wind boxes when the hot off-gases cool down and reach the critical temperature range. Consequently, methods to reduce the dioxin formation reactions are proposed including inhibitor addition to the sinter feed and off-gas quenching.

Jan 1, 2003

By Luis Pommier

In the United States, about one-quarter of the fuel oil and natural gas consumption is associated with power production in utility and industrial boilers and process heat needs in industrial furnaces. Coal has been an attractive candidate for replacement of these premium fuels because of its low cost, but there are penalties associated with the solid fuel form. In many cases pulverized coal is unacceptable as a premium fuel replacement because of the extensive cost of retrofitting an existing boiler designed to burn oil or gas. In the cases of synthetic fuels from coal, research and development still has a long way to go and the costs of research and development are very high. Another option which appears very attractive is the use of solid coal in a liquid fuel form, coal slurry fuels. Occidental Research Corporation (ORC) has been developing coal slurry fuels in conjunction with Island Creek Coal (ICC,) Occidental Petroleum's wholly-owned subsidiary. Both Coal-Oil Mixtures and Coal -Water Mixtures are under development. ICC is a large eastern coal producer, engaged in the production and marketing of bituminous coal, both utility steam and high quality/low volatile metallurgical coals. A sister division, Sheridan Enterprises is engaged in the development of western coals.

Jan 1, 1983

By John Murray, Daniel Ebin, Robert Gould, Yiming Sun, Lizan Gilbert

The Atlanta Plane Train Tunnel West Extension is being constructed at Hartsfield-Jackson Atlanta International Airport using the Sequential Excavation Method (SEM). The tunnel has shallow ground cover and mixed-face conditions and passes underneath the SkyTrain and MARTA stations and airport terminal buildings. It includes a twin tube Bifurcation with a span of over 45 feet and ground cover of 12 feet. A flat roof is being constructed at the Bifurcation to maximize rock cover and minimize surface settlements. This paper focuses on design and construction challenges for the Bifurcation and tunneling beneath the world’s busiest airport, while minimizing impacts to operations.

Dec 1, 2022

By Xiaohong He, Qing Yu, Kaixiang Zhang, Rui Guo, Minghua Lin, Haoyu Miao

With the increasing depth of coal mining, the coal mine shaft traverses’ strata conditions become more and more complex. Shafts are often located in deep thick strata with unstable aquifers, and coal mining requires short-term rapid drainage of aquifers; the additional stress caused by aquifer water drainage is the direct cause of the shaft-lining failure. Over the years, many experts have conducted research on the shaft-lining damage caused by the consolidation and subsidence of the soil layer induced by the long-term drainage of the aquifer. On this basis, this paper conducts an in-depth study of the dynamic change of the pore water pressure of the aquifer in the short-term drainage and its influence on the response of shaft-lining strain and surface subsidence. The result shows that the Mandel effect of pore water pressure around the shaft-lining is obvious at the beginning of drainage, and the pore water pressure suddenly increases; the increase is independent of the drainage rate, which leads to the sudden increase of the shaft-lining strain value unrelated to the drainage rate. The result also shows that with the gradual dissipation of pore water pressure, the increase of shaft-lining strain is positively related to the drainage rate and negatively related to the drainage distance, and the variation trend of horizontal strain is greater than that of vertical strain, which appoints the main cause of shaft-lining damage.

Mar 16, 2023

By C. A. Heiland

IN the third year of war, geophysical oil exploration broke all records to keep pace with the demand for increased reserves. Geophysical prospecting for strategic and other minerals also grew in scope. The trend of geophysical oil exploration throughout the war is indicated in Fig. 1. This figure resembles the one presented in the last annual review issue of M&M (February 1944, p. 62), corrected for data on-operations in the last months of 1943 and extended into 1944. The average number of geophysical oil prospecting crews in the field in 1944 was 451, whereas the total in 1943 was 340. An upward trend in the use of all geophysical methods is clearly evident throughout the year. Seismic operations were 67 per cent, gravimeter surveys 28 per cent, and other methods 5 per cent of the total. Seismic reflection and refraction crews increased 181/2 per cent over the 1943 average, gravimeter operations increased 73 per cent, and other methods gained 92 per cent. The increase in seismic and gravimeter operations, particularly the latter, is probably due to an increased production of equipment and the organization of new service companies. Miscellaneous methods gained largely through a revival of magnetometer work, and an increase in the use of torsion balances and electrical equipment. In comparison with the prewar average of 1941, it is noteworthy that seismic operations increased 58 per cent, gravimeter operations 88 per cent, and miscellaneous other methods gained as much as 283 per cent. Unfortunately the expansion in the number of geophysical crews does not indicate a proportionate increase in efficiency or in areal coverage, as will be brought out later.

Jan 1, 1945

By B. D. Thomas

When the origin and early plans, of Battelle Memorial Institute were described in this journal in October 1929 by R. W. Gillett the first director, the doors of the laboratory had just been opened and the hope of the founder that the institution serve the world by research for industry still existed only as an ideal in the minds of the thirty or so employees who then constituted the staff. Since that time the country has experienced troublous times. A devastating depression plunged the entire world into an unprecedented period of financial and industrial inactivity; and the slow recovery of the late thirties was soon to be overtaken and overwhelmed in the violence of war. Through this time of stress Battelle has continued to grow. The staff has increased to almost 600; buildings and equipment have been added, until now it stands in a place of pre-eminence in the metallurgical and engineering world.

Jan 1, 1944

By C. R. Nisewanger, F. W. Brown

"The velocity of detonation of an explosive is one of its most important properties, because its performance depends markedly on the rate at which it releases its energy. Fortunately, the velocity of detonation is one of the few properties of an explosive that can be measured precisely. However, the velocity of detonation of an explosive may depend on several factors other than its chemical composition, such as density, physical state, degree of confinement, nature of confinement, and magnitude of initiating impulse. Presumably for an explosive of fixed chemical and physical properties there are certain limiting conditions of confinement and initiation under which the explosive will detonate at a maximum constant and uniform velocity. This velocity is its ""ideal"" velocity of detonation. It is obvious, however, that in order to evaluate performance properties of an explosive in all of its applications it may be necessary to measure its velocity of detonation under a number of conditions in which the velocity of detonation is far from the maximum ""ideal"" velocity.. Under certain-conditions the velocity of detonation may even,be,different at different points in the explosive.It is .relatively simple to determine the velocity of detonation of an explosive under a. standard set of conditions if one is free to use large quantities of the explosive and to form it into a convenient shape. Under these circumstances; one can use a thin column of explosive a meter or more in length. The time required for an explosion to travel the length of the column will not be less,of the order a few ten-thousandths of a second and can be readily and accurately measured .by means of the standard spark chronograph or by photographing the explosion with a rotating-drum camera. However in many applications the explosive charge may be of relatively small dimensions arid may not be in a form convenient for making velocity measurements and often may be enclosed in a case or other confining medium. It may be necessary to determine the velocity of detonation over distances of the order of a few centimeters, in which case the time intervals to be measured will be extremely small. For example, the time required for an explosion to traverse 1 centimeter of tetryl is of the order of 1.5 microseconds.Since no satisfactory method of determining time intervals of the order of magnitude of a few microseconds within an explosive charge was available,, at least not for all conditions that might be encountered in practice, it was necessary to develop a special electronic chronoscope which is capable of measuring time intervals as small as a microsecond with a fair degree of accuracy. This report describes the chronoscope and its application to measurements of velocities of detonation in explosives."

Mar 1, 1946

By Robert L. Kranz

The U.S. Bureau of Mines (USBM) has been monitoring and studying seismic activity associated with mining in the Coeur d'Alene silver district of northern Idaho. New statistical methods of studying the stope-scale (1-to l00-m) seismicity at one Idaho silver mine are used in this report (part 1) and its companion (part 2). This report deals with methodology and its limitations. The recent concept of fractals and their seismological use is discussed and applied to mining-induced seismicity. Three types of fractal studies are addressed: spatial analyses (including temporal changes of spatial patterns), temporal analyses, and size analyses. Other statistical measures of mine seismicity are also addressed: event mean location, inter-event distance distribution skewness, temporal coefficient of variation, nearest neighbor and next event statistics, and event location planarity patterns. Each of the methodologies discussed (fractal and nonfractal) is presented using sample data from two stopes in the mine. It is shown that stope-scale, mining-associated microseismicity has a fractal nature. The usefulness of demonstrating fractality (scale invariance) for predictive or descriptive purposes depends on recognition of the factors affecting the calculation of fractal dimensions. Several methodological traps are illustrated that can lead to an incorrect conclusion.

Jan 1, 2010

By D. W. Butner

As a part of the Bureau of Mines program for the discovery and development of critical and essential mineral deposits, the Darwin district, Inyo County, Calif., was chosen for investigation as a possible source of, tungsten ore. Two properties were active in the district at the time. One was producing tungsten concentrate and the other was preparing to produce tungsten concentrate as a byproduct in the milling of lead-zinc ore. The objective of the project set up by the Bureau was to investigate promising areas and to sample, thoroughly those which preliminary inspection indicated contained tungsten ore. Work was begun November 17) 1941, and completed January 19, 1942. In the course of the project, 18 localities were inspected and 9 were sampled. The following pages brief the history, note the location, and outline the physical features and geology of the district. The work performed by the Bureau of Mines is described and supplemented with assay maps.

Jan 1, 1949

By David R. Mitchell

Many of the difficult operating problems of the preparation of coal for market, of sampling coal shipments and in the utilization of coal are caused by segregation in the coal mass. Segregation may be of two kinds: i.e., "size segregation," in which particles of the same size in a mass of coal containing a range of sizes collect together and "density segregation," in which particles of the same density or specific gravity in a mass of particles of varying density gather together. Mechanics of Segregation Size segregation cannot take place with closely sized coal. As the size range increases, the tendency for size segregation increases. Similarly, cleaned coal with particles of approximately the same specific gravity have very little tendency for density segregation. The wider the density range of particles and the more particles of different density, the greater the chances are for density segregation. The following discussion deals primarily with coal of a wide size range as screenings and of wide density differences as uncleaned or run-of-mine screenings. If a mass of coal containing particles of a wide size range is subject to the stream action of a moving current of water, the small particles are transported farther than the coarser. Particles of different density in a stream of moving water are subject to the laws of classification, the heavier settling out first. The familiar sluice box of the gold miner and the action of rivers and other streams in classifying material according to

Jan 1, 1938

By David R. Mitchell

Many of the difficult operating problems of the preparation of coal for market, of sampling coal shipments and in the utilization of coal are caused by segregation in the coal mass. Segregation may be of two kinds: i.e., "size segregation," in which particles of the same size in a mass of coal containing a range of sizes collect together and "density segregation," in which particles of the same density or specific gravity in a mass of particles of varying density gather together. Mechanics of Segregation Size segregation cannot take place with closely sized coal. As the size range increases, the tendency for size segregation increases. Similarly, cleaned coal with particles of approximately the same specific gravity have very little tendency for density segregation. The wider the density range of particles and the more particles of different density, the greater the chances are for density segregation. The following discussion deals primarily with coal of a wide size range as screenings and of wide density differences as uncleaned or run-of-mine screenings. If a mass of coal containing particles of a wide size range is subject to the stream action of a moving current of water, the small particles are transported farther than the coarser. Particles of different density in a stream of moving water are subject to the laws of classification, the heavier settling out first. The familiar sluice box of the gold miner and the action of rivers and other streams in classifying material according to

Jan 1, 1938

By H. F. Weaver

The 17th National First-Aid and Mine Rescue Contest was held in the Kentucky Fair and Exposition Center, Louisville, Ky., October 2, 3, and 4, 1957. The meet was under the auspices of the Federal Bureau of Mines and the Joseph A. Holmes Safety Association, in cooperation with the National Coal Association, United Mine Workers of America, State mining departments, local mining institutes, and coal operators' associations. The Arrangements Committee, as authorized by the General Committee, made all the necessary arrangements for conducting the 1957 contest. Members of the Arrangements Committee were: Harry Gandy, Jr. (chairman), National Coal Association; James B. Benson, Southern Coal Producers' Association; Charles Ferguson, United Mine Workers of America; George C. Trevorrow, Bituminous Coal Operators' Association; and James Westfield, Federal Bureau of Mines.

Jan 1, 1958

By Eduardo de Paula Silveira, Carlos Vinícius Domingos de Carvalho, Roberto Parreiras Tavares, André Afonso Nascimento, Honicássio de Souza Ferreira, Afrânio Márcio Costa

Modelos de transferência de calor possibilitam o conhecimento de espessura da camada solidificada e temperatura da placa, essenciais para alterações no processo visando melhoria de qualidade. Neste estudo foi desenvolvido um modelo pelo método 2½ D, que consiste em acompanhar em toda extensão da máquina uma secção transversal da placa, ajustando as condições de contorno para cada região. Medições de temperaturas superficiais e de espessura da camada de aço solidificada da placa foram utilizadas para validação do modelo. O modelo foi adequado para as condições de contorno e parâmetros da máquina de lingotamento contínuo de placas da Gerdau Ouro Branco visando fornecer subsídios para a melhoria da qualidade superficial e interna das placas.

Oct 1, 2019

By Johne Jesus Mol Peixoto

A complexidade do formato do molde de beam blank aumenta a importância de se compreender o comportamento do fluxo no interior do mesmo. Neste estudo verificou-se a influência da profundidade de imersão e da velocidade de lingotamento sobre as características de fluxo em um molde de beam blank alimentado por duas válvulas tubulares. Os resultados das simulações matemáticas foram coerentes com os resultados do modelamento físico. A velocidade de espalhamento do jato na região do flange é maior que na alma e este fator pode acarretar na solidificação irregular da pele ao longo da seção transversal. A profundidade de penetração do jato variou entre 66cm e 77cm. A intensidade média de flutuação do menisco foi de 0,22mm, sendo a flutuação máxima encontrada de 0,85mm. Com base nos resultados obtidos, os parâmetros de operação sugeridos são: profundidade de imersão igual a 75mm e velocidade de lingotamento máxima de 1m/min.

Aug 17, 2017

By Yi Luo, Jian Yang

Subsurface strata movements and deformations associated with longwall mining operations in underground coal mines could cause various disturbances to subsurface mine structures, ground water bodies, and coalbed methane reservoirs. In order to assess those disturbances correctly and to design effective and efficient mitigation measures, it is necessary to develop an accurate prediction model for subsurface strata movements and deformations. Decades of research have demonstrated that variations of stratification and lithology in the overburden have significant influence on the subsurface strata movements and deformations during ground subsidence process. The key strata theory states that the thick and hard key strata serve as the backbone of the overburden and control the movements of the thin and soft weak strata located above them. From an engineering standpoint, the overburden strata are subdivided into several individual groups by the key strata with each group consisting of a key layer at the bottom and weak layers overlying it. A new subsurface subsidence prediction model considering the key strata effects on subsurface strata movements and deformations has been proposed. In this method, elastic modulus, specific weight, tensile strength, and uniaxial compressive strength (UCS) of each layer are used to identify the key layers and to determine the needed subsurface subsidence parameters. The influence function method, proven to be accurate and versatile for surface subsidence prediction, was employed to predict the subsidence on each of the overburden layers from mining horizon progressively upward to ground surface with the assumption that the predicted subsidence on a given layer serves as the subsidence source for the layer immediately above. The enhanced subsurface subsidence prediction model has been demonstrated with an actual case to show its applicability and improvement.

Jan 25, 2021

By IPMI Educational and Scientific Foundation

It is with great pleasure that we announce the availability of this fourth issue of the IPMI Journal, a publication of the International Precious Metals Educational and Scientific Foundation. This digital peer reviewed publication has been created as a vehicle for the sharing of technical information related to the science and technology of precious metals. Since 1976, the International Precious Metals Institute has championed the exchange of information of critical importance to the precious metals scientific and commercial communities through its various communications vehicles. This has included instructional videos, annual conference symposia, special topic committee meetings, regional seminars, and professional and student achievement awards. Due to the breadth of important topics related to all aspects of precious metals, it has been the vision of the IPMI to provide a publication available to the general public that would become a key source of pertinent topics containing high quality publications by experts in their fields of study. Historically, the IPMI has attracted world renowned experts in many fields (including Nobel Laureates Henry Taube, Ei-ishi Negishi, Robert Grubs, Professor Ben Feringa, and David MacMillan) in the dissemination of discoveries, inventions, and industry proven practices. Such information has a total value greater than the sum of its parts as seemingly unrelated innovations from distinct focus areas can be adapted to solve problems. Because of this important characteristic of information exchange, we have decided to create a digital journal, available to the general public, that will not only communicate state of the art discoveries and sound practices, but will also review historical communications from the IPMI’s archives that have value and use even in today’s environment. On behalf of the members and leaders of the IPMI, we hope you will find value in this new publication.

Dec 1, 2021

To design an apparatus that advances the state of the art in gas content testing equipment. The goal of the design is to incorporate improvements in testing sensitivity/accuracy, durability, and ease of operation over existing equipment. It is also desirable for the new design to successfully perform gas content determinations of multiple chemical species from a rock sample.

Jan 1, 1999

By O. C. Baptist

This report presents results of an investigation undertaken by the Bureau of Mines to determine the clay content of typical petroleum reservoir sands in Wyoming and the effect of clay content on the permeability behavior of the sands. These results should have significance in determining the feasibility of injecting water into the sands for secondary recovery and in estimating the probable damage incurred by these sands if invaded with filtrates from water-base drilling muds. The results of air-, brine-, and water-permeability determinations are given for reservoir sands in three Wyoming fields. The amounts of materials of "fine silt and clay size" (Wentworth scale) in the sands and the types of clay minerals present, as identified by X-ray diffraction methods, are also presented and discussed.

Jan 1, 1955

By James F. Devine

The radial, vertical, and transverse components of particle velocity were recorded by Bureau of Mines investigators along gage arrays extending in one or two directions for 145 to 3,170 feet at five quarries. Of the 39 quarry blasts, 12 were instantaneous blasts, 5 were of the one hole per delay type, using millisecond delayed caps, and 22 were multiple hole per delay type employing millisecond delay detonating fuse connectors. Charge weight per hole ranged from 8 to 1,500 pounds, and the charge weight per delay interval, including the instantaneous blasts, ranged from 25 to 4,620 pounds.

Jan 1, 1966