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By U. M. J. Boin, W. L. Dalmijn, T. P. R. de Jong

"This paper explores the complex interrelationship between the resource cycle, recycling and metal production as a function of economics, environmental legislation, and product design. It is argued that central to optimising this resource cycle lies the control in particular of physical separation plants by the application of advanced sensor technology and sorting equipment, as well as suitable control and sampling algorithms supported by optimising mass balance models.Metals are produced through a long chain of processes. For primary resources, metals production goes through mining, mineral processing, ore smelting, conversion and refining steps or via low temperature hydrometallurgical processes, or a combination of both pyro- and hydrometallurgical operations. For the recycling of resources, metals are separated and recovered from metal scrap, which plays an increasingly important role in the world. Metals after being produced, either from primary or recycling resources, have to be further refined or manufactured into various types of alloys and finally shaped into different products for the end-users. Since the end-user discards products the contained materials find their way back into the resource cycle as scrap. Therefore, controlling the metallurgical reactors also controls, in a much broader sense, the material quality in the complete metals cycle, from the production phase, to the end-use phase, up to the recycling phase (Reuter et al., 2003). The recycling phase includes separation of materials into saleable intermediate products, which are reintroduced into the production phase as a recycling resource. Therefore, the metallurgical processes in each unit operation in the metals production and processing chain have to be controlled, so as to achieve optimal performance of high product quality, low energy and materials consumption, and low environmental impact."

Jan 1, 2003

By Diego Linhares de Azevedo

Este artigo contém uma pequena introdução à alguns dos protocolos de redes industriais mais populares atualmente, Foundation Fieldbus, Profibus e WirelessHart, apresentando brevemente suas arquiteturas e características, e, então, realizando uma análise comparativa de suas vantagens e desvantagens.

Aug 16, 2017

By Ernest E. Berger

"INTRODUCTIONOne of the outstanding problems in the normetallic industries, and one which involves two of the greatest of these industries, cement and gypsum, is the reaction of Portland cement with calcium sulphate. To all Portland cement clinker there is added in the manufacturing process, a small amount of retarder, as a necessary ingredient of the finished product. This retards the initial set, increases the strength, and adds to the plasticity of the cement so it will have the desired working and setting qualities. The retarder commonly used is gypsum, (CaSOA.2HO), which is the hydrous form calcium sulphate. Calcium sulphate is also available as plaster of Paris (CaSO4 1/2 HC) and anhydrite (CaSO4). The purpose of this inquiry was to determine the form or mixture of forms best adapted for retarder. The problem is complicated by the fact that cement clinker is a complex mixture of calcium silicates and aluminates, and that clinker from different mills, making cement of approximately equal quality, differs considerably in chemical constitution. Thus the same retarder may give very different results with different types of clinker, especially in the percentage of retarder required for the same degree of retardation.It has been known for some time that a small percentage of plaster of Paris will greatly retard the time of set of Portland cement as well as increase its strength and plasticity, but whether gypsum and anhydrite will have a similar effect is as such disputed question. The offects of gypsum have received little consideration in laboratory research because, even though it will not retard a clinker when the two are mixed in the laboratory, as has been noted in some instances, the cement will have a normal set when the two arc mixed in the large tube mill at the plant, so that practically, gypsum seems to be equally as goou as plaster of Paris, and because of the great saving in cost it has been used almost exclusively."

Sep 1, 1925

By Rossana Bezerra de Azevedo Vasconcelos Seabra de Melo

O presente estudo apresenta um método de avaliação de desempenho de operadores nas análises químicas que caracterizam o minério de ferro. São eles: Ferro total (Fe), sílica (SiO2), alumina (Al2O3), manganês (Mn), fósforo (P) e perda por calcinação (PPC). O desempenho é avaliado em termos de precisão e veracidade. Estes dois indicadores primários são combinados num secundário denominado de indicador de “confiabilidade metrológica”. O método foi aplicado nos laboratórios da Mina (no estado do Pará) e do Porto (no estado do Maranhão) de uma empresa mineradora onde foi possível: 1) conhecer o desempenho de cada laboratório assim como conhecer o desempenho de cada operador; 2) identificar os pontos fortes (identificar o procedimento que leva a melhores desempenhos) e oportunidades de melhorias (atuar nas causas, capacitar); 3) equalizar a forma de executar cada uma das tarefas com as melhores práticas identificadas; 4) proporcionar oportunidade de desenvolvimento técnico dos profissionais envolvidos no processo. O desempenho neste indicador tornou-se critério avaliação de aptidão para executar análises.

Aug 2, 2018

By C. Nikolic

A process utilizing ozone for the precipitation of cobalt from nickel sulphate liquors containing ammonium sulphate has been developed. Best results were obtained using nickel carbonate to maintain solution pH at 5.0 to 5.5. Work was performed both in column and stirred-tank reactors. Variables studied included neutralizer type and concentration, NH4+ concentration, temperature, Ni++ and Co++ concentration, per cent O3 in the O2 carrier gas, O3 input rate and agitation. The over-all rate of cobalt rejection increased sharply with increasing agitation and ozone concentration in the gas phase, reflecting relatively slow transfer of ozone from the gas to the liquid phase.

Jan 1, 1978

By Juliana Porto Guimarães

A crescente demanda por aços galvanizados com alta lubricidade tem impulsionado o desenvolvimento de pós-tratamentos que, aplicados sobre a superfície dos revestimentos, reduzem o atrito entre o ferramental e a chapa durante o processo de estampagem de peças críticas na indústria automotiva. Diante disso, a Usiminas desenvolveu, em parceria com a Quaker, a aplicação do pós-tratamento tipo microfosfato denominado Primecoat Z Auto, com a função de melhorar a estampabilidade de aços galvanizados a quente do tipo GI (Zn puro). Nesse estudo foi avaliada a Razão Limite de Estampagem (RLE) de um aço GI destinado a produção de peças críticas, após aplicação desse pós-tratamento em escala de laboratório. Adicionalmente, foram caracterizadas a morfologia e a constituição química do microfosfato, e o desempenho do aço quanto à fosfatização, à pintura automotiva e à resistência a corrosão. Concluiu-se que o filme de pós-tratamento é amorfo, constituído por Zn, P, Al e Mg, promovendo um excelente ganho de lubricidade ao aço GI, sem interferir nos processos subsequentes de fosfatização e de pintura nas montadoras. Além disso, o material apresentou excelente desempenho quanto à resistência à corrosão.

Jul 30, 2018

By James L. Evers

The development of hydraulic mining in the United States has had an uneven record of progress. The shifting of coal extraction from one government agency to another has not provided an environment for a focused national research program. This paper presents an update on hydraulic mining research in the United States. A comparison is made between the development of the technology in this country and the state of the art in other parts of the world.

Jan 1, 1983

By H. G. Hedlund

Tailings in Mining Industry can be handled in different ways. Today tailings disposal is in focus by projecting new plants as well as treating and handling of old Tailings dams.The trend today is to process minerals, detoxify the Tailings and place them as dry surface Deposition or Underground Backfill. This paper will briefly present five different Mining plants in North and Central America, where Tailings have to be dewatered for dry depositing. The Metso-Sala VPA is a filter especially developed for dewatering and drying of Mineral Concentrate and Mineral Tailings. Keywords: tailings disposal, dewatering, drying, mineral tailings

Sep 1, 2012

By Guo Chen, Jin Chen, Jinhui Peng

"In this paper, the methods of life cycle assessment for microwave hot air systems, and the concept of green degree were proposed. Greenness evaluation index, evaluation system and evaluation model of microwave hot air systems were established. Also, life cycle assessment processing based on these ideas was introduced. Analytic hierarchy process and fuzzy decision- making method were utilized to establish and solve the greenness evaluation of assessment model, while the scores of green degree in microwave hot air systems were obtained. The results show that Life cycle assessment can be applied effectively and efficiently to the microwave hot air systems.IntroductionHot air systems are an important industrial operation condition, which is used to provide high temperature air for materials processing. Nowadays, high temperature airs are manufactured by the conventional heating processes, in which some ceramic materials are used as heating materials. However, these processes pollute the environment. Therefore, to explore new method to produce high temperature air with low energy consumption and less environment pollution are necessary.Microwaves are now being used in various technological and scientific fields in order to heat dielectric materials [1]. Microwaves irradiation has been explored in materials processing in recent years [2-3]. The main advantage of using microwave heating is that the treatment time can be considerably reduced, which in many cases represents a reduction in the energy consumption as well. Since there is energy absorption but no heat conduction, the heating is very rapid and highly efficient, resulting in energy savings and the shortened processing time [2, 4]. Compared with conventional heating techniques, the additional advantage of using microwave irradiation is that microwave irradiation achieves both internal and uniform heating [5-7]. In addition, it is more convenient to control the microwave irradiation processing, because of no direct contact between the heating source and heated materials with less equipment size and waste [2, 8-9]. Life cycle assessment is used and accepted methods for the evaluation of the environmental impacts of products or systems [10]. Recently, many appropriate evaluation methods have been developed for life cycle assessment [11-12]. These proposed methods usually are employed for the evaluating product and analyzing results [13]. Among them, the analytic hierarchy process and the fuzzy comprehensive evaluation stand out as a popular method utilized in many fields [14-16]. Analytic hierarchy process and fuzzy comprehensive evaluation are a combination of mathematical and statistical technique that is useful for analyzing the effects of several independent assessment aspects on the system goal without the need of the predetermined relationship between the objective function and the assessment aspects [17-19]."

Jan 1, 2013

By M. Spangler

FirstMiss Gold installed a supervisory control system based on Pavilion Technology's Process Insights neural network software and Oil System's PI data historian. The primary goal of the system was to control the acid preconditioning circuit. However, our first successful control loop was on the limestone feed rate to the neutralization circuit. The information gained by modeling these circuits and the better control provided by the system has resulted in reagent savings of over $80,000 per month.

Jan 1, 1995

By William H. Pelton

The presence of high-grade massive sulphides near York Harbour, Newfoundland has been known since the turn of the century. In the early 1900's a small, massive-sulphide deposit was worked by conventional hand methods and yielded about 100, 000 tons of high grade copper-zinc ore. Since that time, a number of mining companies have held options on the property and an exploration adit was driven along the fourth level of the original mine. Underground drilling revealed several additional massive sulphide lenses in the range of 10, 000 to 60, 000 tons (Fig. 1). The problem facing Long Lac Mineral Exploration Ltd. when they undertook an option on the property in 1969, was to outline any possible extensions to the known sulphide lenses which were outside the reach of underground drills and to search for new ore deposits which might double the known reserves into a feasible project for development. GEOLOGY AND PHYSICAL PROPERTIES: The geology is typical of many massive sulphide deposits within volcanic rocks in the Canadian Shield. The sulphide pods appear to occur along a complex andesite-basalt contact. Identification of the two volcanic types is difficult since they are almost the same colour. The most direct means of identification is by the slight difference in their magnetic susceptibilities. Pyrite, chalcopyrite and sphalerite are the main minerals in the sul¬phide lenses. The ore is massive, differing in density from the host rock by at least 1.0 gm/cc. There is little pyrrhotite or magnetite associated with the sulphides, so there is no appreciable difference in magnetic susceptibility between the sulphides and the basalt. Also, there is no alteration halo around

Jan 1, 1971

By Jr. Watts, B. K. Cantrell, K. L. Bickel, J. F. McDonald

"A field trial was conducted at an underground gold mine to evaluate diesel fuel derived from soybean oil (soy-methyl-esters or “biodiesel”) as an alternative to commercial, low-sulphur, number 2 diesel fuel (D2). A 2.7 m3, 18-ton load-haul-dump (LHD) unit, powered by a naturally aspirated, indirect injection (pre-chamber), 100 kW diesel engine was used as the test vehicle. The LHD was equipped with a diesel oxidation catalyst. The LHD operated satisfactorily on the biodiesel fuel. Operators observed a slight decrease in power and an absence of black smoke.Diesel particulate matter (DPM) concentrations were monitored for a six-week period while the LHD was operated with either the biodiesel fuel or the D2 fuel. DPM concentrations were measured in the mining section’s clean air intake, exhaust and on the LHD. Reduction in DPM emissions was determined from the measured difference in DPM concentrations between the clean air intake and the exhaust. The biodiesel fuel reduced energyspecific DPM emissions approximately 75%, from 3.6 ± 1.8 g/kW-hr to 0.86 ± 0.27 g/kWhr. Time-weighted average DPM exposure, measured near the LHD operator, was reduced from 0.67 ± 0.13 mg/sm3 to 0.28 ± 0.12 mg/sm3, or approximately 58%, when the biodiesel fuel was used. IntroductionDiesel exhaust consists of noxious gases and diesel particulate matter (DPM). Recent attention has focussed on the potential carcinogenicity of DPM and the potential health impact on miners. The National Institute for Occupational Safety and Health (NIOSH) recommended that whole diesel exhaust be regarded as a “potential occupational carcinogen”, and that reductions in workplace exposure would reduce cancer risks (NIOSH, 1988). The International Agency for Research on Cancer (IARC) declared that “diesel engine exhaust is probably carcinogenic to humans” (IARC, 1989)."

Jan 1, 1997

By M. Sadegh Safarzadeh, Erich U. Petersen, Jan D. Miller

"An acid bake-leach process has been identified and applied to an enargite concentrate containing ~67% enargite, ~27% pyrite (FeS2), ~3% chalcopyrite (CuFeS2), ~6% sphalerite (ZnS) and <1% galena (PbS). Sulfuric acid baking of this concentrate resulted in the transformation of the concentrate to S8, As2O3, HFe(SO4)2•4H2O, PbSO4 and Cu0.47Fe0.53SO4•H2O, all of which (except elemental sulfur and PbSO4) dissolved during the water leaching step. More than 87% Cu and 64% As were leached when the concentrate was baked at 200°C over 7 hours with a sulfuric acid-toconcentrate weight ratio of 1.6. Less than 1% As was lost to the gas phase. Upon water leaching, copper and arsenic were released to the solution at a concentration ratio of about 3:1. While enargite is very reactive during the sulfuric acid baking reaction, other minerals present in the concentrate such as pyrite, galena and sphalerite may compete to consume sulfuric acid and be converted into their corresponding sulfates at different concentrations. The purpose of this paper is to present our examination of the effects of sulfuric acid dosage on the extractions of Cu, Fe, and As from an enargite concentrate. In this regard, the concentrate, baked concentrate, and the leach residues are characterized and a conceptual process flowsheet is described for the acid bake-leach process for the treatment of enargite concentrates.IntroductionThe occurrence of enargite (Cu3AsS4) in copper ores and concentrates and the associated high arsenic values in such resources have resulted in a considerable decrease in the demand for such concentrates because they cannot be economically processed using conventional technologies such as smelting and atmospheric leaching (Mihajlovic et al., 2011). The exploitation of such problematic deposits through competitive treatment strategies will be required in the near future in order to satisfy increasing pressure from the copper market. It is expected that the average arsenic grade of copper concentrates will increase from 0.17% in 2008 to 0.22% by 2020 (Mayhew et al., 2011).The acid bake-leach process was identified and selected for further investigation at the University of Utah as a possible process alternative for the treatment of enargite concentrates. In this case, adequate amounts of concentrated sulfuric acid are mixed with the concentrate and heated to the temperature range 150-300°C. Subsequently, the baked material is leached with water/weak acid and the acid bake-leach process has some advantages over conventional sulfuric acid leaching (Prater et al., 1970). During water leaching, metal sulfates are released in solution, after which they can be extracted through well-known hydrometallurgical techniques. While the majority of the work has been done on oxide minerals, there is a limited record of sulfuric acid baking of sulfides."

Jan 1, 2015

By John Rajala

The Otjikoto Gold Mine in the Republic of Namibia is located approximately 300 kilometers north of the capital city of Windhoek. The project features surface mining with a modern gravity/carbon-in-pulp mill for ore treatment and recovery of gold. Initial mill design capacity was 2.5 million tonne per annum but then expanded after 9 months of operation to 3.1 million tonne per annum. The technical steps to establish the Otjikoto mill design from process selection in the due diligence stage, through flowsheet development in the feasibility study followed by detailed engineering design are reviewed in this paper along with mill performance during start-up and in 2019.

Oct 30, 2020

By Göksel Hızlı, Selim Ertürk, Ayşegül Bilen, Raşit Sezer, Cüneyt Arslan

The carbothermic reduction of celestite is the first step in producing many strontium products. The way materials move in the rotary kiln has an essential effect on the carbothermic reduction efficiency as well as the temperature. In this study, the reduction of celestite ore and excess carbon blend in a laboratory-scale rotary kiln was investigated. In the experiments carried out at three different temperatures, the rotational speed and slope of the furnace tube were altered, and their effects on the reaction efficiency were examined. The leachability of the reduced powders and the content of the unburned coke indicated the optimal parameters for the reaction.When the speed was increased to 10 rpm, the powders weremoremobile in the stack and could react more easily with the furnace atmosphere. According to the results, celestite can be reduced by carbon at temperatures of 1000–1200 °C, at rates of between 5% and 75%. The maximumreaction yield (75%) was obtained with a slope of 2° and a rotational speed of 6 rpm at 1100 °C.

May 7, 2020

By Noriyuki Fujii

It is no need to say that exploitation of industrial minerals has a close relation to development of the industries related. In the first stage, a small scale manufactures were initiated in areas producing some main raw material minerals. China and cement manufactures, for example, were established depending on the local occurrence of raw materials such as kaolin and limestone without exception. That is, the industrial development is greatly influenced by the local production of the raw materials in the stage. With the development of industrial technology, various kinds of raw material minerals are explored to meet the demands of industries in the second stage. New materials become indispensable, and low-grade raw material minerals, which were left as useless, are developed as useful materials. In the stage, the development of raw material minerals is accelerated by that of industrial technology related. However, industries mainly rely on domestic production of the min raw material minerals.

Jan 1, 1981

By Rodrigo Afonso Hatwig

Os aços inoxidáveis duplex (DSS) e superduplex (SDSS) são ligas que se caracterizam por apresentar uma microestrutura composta por frações volumétricas similares das fases ferrita e austenita. Dependendo da composição química e do tratamento termomecânico aplicado, a microestrutura dos aços inoxidáveis DSS e SDSS poderá apresentar, além das fases ferrita e austenita, fases intermetálicas deletérias. Neste trabalho, um estudo termodinâmico-computacional foi realizado com o objetivo de acompanhar a evolução das fases de aços superduplex no intervalo de temperaturas entre 300°C e 1.200ºC. Para tanto, fez-se uso do software de simulação termodinâmica FactSage v. 6.4. Os resultados descrevem de forma eficaz as fases principais e secundárias em função da temperatura e composição química.

Aug 8, 2018

By G. Deschênes

Silver minerals are known to have slow leaching rates and low overall extraction and require a high concentration of cyanide and a long retention time to maximize leach extraction. Their response to cyanidation is considered mild to moderately refractory, largely due to complex mineralogical compositions. New research on improving the dissolution of silver minerals in cyanide was performed using high-purity minerals, as well as a high-grade ore sample from the Kupol property, owned 75% by Kinross Gold. The high-purity silver minerals studied in the leach investigations included acanthite, stephanite and pyrargyrite, which were also the predominant silver minerals in the Kupol ore sample. Dissolution of silver from acanthite produced only 37% extraction in 48 hours of leaching with 500 ppm NaCN. Analysis of the leached acanthite surface showed appreciable formation of polysulfide species, which can interfere with silver leaching. Adding lead nitrate into a pretreatment stage increased the acanthite silver extraction to 86.2%. No polysulfide species were formed with the addition of lead nitrate from the surface analysis. Cyanidation of stephanite and pyrargyrite produced very low dissolutions of silver, only 12.6% and 10.4%, respectively, in the absence of lead nitrate. Silver extraction from stephanite improved to 98% by adding lead nitrate directly to the leaching stage, whereas pyrargyrite required a pretreatment with lead nitrate to extract 83.2% Ag. With the addition of lead nitrate, the mineral surfaces had a PbO species and minor amounts of Pb(OH)2 and antimony was oxidized on the stephanite and pyrargyrite surfaces during leaching. There was a much greater concentration of Sb(V) on stephanite relative to pyrargyrite. Therefore, lead forms a redox couple on silver mineral grains and favors the oxidation of silver minerals. The high-grade Kupol sample assayed 22.6 g/t Au and 359.3 g/t Ag following treatment by gravity separation. Gold and silver extractions from the Kupol sample were 94.5% and 82.9%, respectively, using 500 ppm NaCN and 250 g/t lead nitrate. The findings to improve the extraction of silver from the ore sample with lead nitrate addition were congruent with those to improve the extraction of silver from the individual high purity minerals. Pretreatment did not, however, improve gold or silver extraction significantly with the ore sample.

Jan 1, 2011

By S. Acar

"In recent years the gold mining industry has been challenged by declining metal prices as well as having to treat ores that have low grades and are refractory in nature. Many factors must be considered when metallurgical studies are designed to develop process design criteria for these type of ores. These factors are mostly related to the mineralogical and chemical compositions of the ores, the geological setting of the deposit and how the ore/waste will be mined, such as whether openpit or underground, the mine schedule, and the mine fleet type and capacity. The purpose of this paper is to provide an experience-based practical approach to how to select and characterize test samples as well as devise process development metallurgical studies for both oxide and refractory gold ores, and to provide insight into some of the matters that might go wrong during the course of the studies. This paper is intended as both a guide for someone new to the field and also as a reminder for those familiar with the field. IntroductionThe recent decline in ore grades and metal prices have challenged mining companies to reduce capital and operating costs associated with developing new mineral resources. In some cases, metallurgical studies have been sacrificed to prevent cost overruns resulting in inadequate mineralogical, chemical and metallurgical characterization. Consequences have included longer construction schedules, higher initial and working capital, higher operating costs and less than desirable plant performance (Whincup, 2010; Torres, Chaves and Meech, 1999).Mineralogy, geology, mining type and sequence, and the metallurgy of an orebody will determine the process development metallurgical study requirements and eventual process plant design. Therefore, once the geologist has an early indication of a prospective orebody, geologists, metallurgists, mining engineers, and social and environmental responsibility scientists should convene and devise a plan on how to exploit the orebody economically (Lunt, Ritchie and Fleay, 1997).Geologists may find a prospective orebody solely based on grade. However, if the orebody cannot be mined and processed economically, then it is deemed not to be a deposit. An example of this could be a refractory gold deposit, either sulfidic, carbonaceous or siliceous refractory or any combination of those, that may not be mined and processed economically due to reasons such as the physical location of the deposit, depth of the ore lode, or social and environmental concerns. Therefore, an early collaboration between all disciplines must be established.Each orebody may have its own unique mineralogical, geological and chemical characteristics (Guresin et al., 2012). These unique characteristics should be effectively sampled to reduce risks associated with process design and engineering efforts for the process development metallurgical studies. If the sample or samples are not representative of these unique characteristics, then the studies performed will be pointless. The project metallurgist in charge of conducting metallurgical studies should also possess general geology, mineralogy and mine engineering knowledge. Recommended readings are a book on understanding mineral deposits by Misra (2000) and articles on heap leach development by Scheffel (2014a and 2014b)."

Jan 1, 2016

By P. K. Currie, J. V. Walters

Solution mining of magnesium salts (Carnallite and Bischofite) is taking place near Veendam, in the northeast Netherlands. The magnesium salts are used for the production of magnesia sinter, used as a base material for the manufacture of refractory bricks for furnaces. This paper gives, first, an introduction to the operational procedure followed in Veendam, with the emphasis on some of the unique aspects, and then discusses rock-mechanical aspects of the cavity behaviour. The creep behaviour of magnesium salts is described, and Finite Element calculations on cavity stability and potential surface subsidence are discussed.

Jan 1, 1985