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By J M. Santini, I C. A Streimann

Arsenic is a naturally occurring element in the environment and is toxic to biological systems. Arsenic can exist in the environment in the following redox states, arsenite (+3), arsenate (+5), arsine (-3) and elemental (0) (Oremland and Stolz, 2003). Arsenic is released into the environment by natural and anthropogenic activities such as rock weathering and ore mining, respectively. Such activities result in the release of the soluble inorganic arsenic oxyanions, arsenite and arsenate. The redox state of arsenic in the environment is influenced by a number of factors including, redox potential, pH and microorganisms (Irgolic et al, 1977; Genc-Fuhrman, Tjell and McConchie, 2004). Recently, the ability of microorganisms to influence the cycling of arsenic in the environment has attracted much attention. Microorganisms that can oxidise arsenite and reduce arsenate have been isolated and the mechanisms of arsenic metabolism are currently being investigated. The differences between arsenic resistance and arsenic metabolism are being revealed. The role of microorganisms in the release of arsenic into the environment is of particular importance with arsenic contamination of waters causing the death of millions of people worldwide, due to the consumption of contaminated water (Vasken Aposhian et al, 2003; Islam et al, 2004).

Jan 1, 2004

By P J. Clark, A W. Fisher, R G. Ford

Site characterisation of subsurface contaminant transport is often hampered by a lack of knowledge of site heterogeneity and temporal variations in hydrogeochemistry. The use of a regional-scale data compilation derived from satellite imaging is discussed with respect to directing design of site characterisation to monitor the fate of a Dense Non-Aqueous Phase Liquid (DNAPL) plume in Nevada. Evaluation of the drainage basin contributing to the groundwater flux into the study site was used to re-assess the site conceptual model and re-direct the characterisation effort. The use of highly resolved measurements of subsurface hydrogeochemistry in space and time were employed to identify the predominant biogeochemical processes controlling arsenic transport during discharge of groundwater into a pond at a site in Massachusetts. Direct-push conductivity measurements coupled with vertically-resolved sampling within the pond and adjoining aquifer demonstrated spatial and temporal variations in dissolved arsenic within groundwater and the pond water column and sediment pore water. Spatial variability was observed over the scale of centimetres to metres, and temporal variations were observed over the scales of days (following storm events) to seasons. Microbially-driven redox processes maintained anoxic conditions in groundwater and at the sediment-water interface (iron and sulfate reduction) and exerted both a direct and indirect influence on arsenic solution speciation and partitioning to surface water sediments.

Jan 1, 2004

By Naresh Koirala

The Greater Vancouver Regional District completed installation of a 2.5 Km long, 2400 mm diameter concrete sewer in Delta, British Columbia in 2000. The sewer traverses through area of peat and soft ground. The ground investigation along the sewer alignment consisted of cone penetration tests and auger drilling with standard penetration tests. The gravity sewer is supported on precast, pretensioned spun concrete piles imported from Malaysia which had never been used for a major project in North America. The capacities of the installed piles were tested using pile driving analyzer (PDA) and three static load tests. A total of 46 PDA tests were carried out during pile installation. The paper describes the pile vetting process the owner went through prior to accepting the piles for use in the project and performance of the piles. It compares the pile capacity estimated from the PDA tests with that estimated from soil mechanics methods using data from cone penetration tests and standard penetration tests. The ranges of estimated capacities calculated by different methods are discussed from design capacity selection considerations.

Jan 1, 2004

By L. Munsamy

The bulk of primary mining at the Anglo Coal's Bank Colliery was carried out by drill and blast method, in a bord and pillar layout exploiting the No. 2 Seam. Secondary extraction, top/bottom coaling, also took place using both the drill and blast (D&B) method and continuous miners (CM). Extensive mining in this seam resulted in the risk of sterilising the No. 4 Seam reserves. Therefore, multiseam design guidelines established by Salamon and Oravecz (8) were re-evaluated in light of the low safety factors and the low pillar width to mining height ratios of pillars in the No. 2 Seam. Two and three dimensional (2D & 3D) numerical modelling was carried out to quantify and verify the parameters that influence the multiseam mining. The modelling was conducted primarily in two dimensions (plane strain), with 3D models to confirm the validity of the 2D results. A panel risk assessment flow chart was developed to assess the panels with respect to pillar failure and multiseam mining. This flow chart was extended into the evaluation of risk of surface subsidence using the current rock engineering knowledge. The aim of this risk assessment tool is to assess all underground workings at Anglo Coal collieries simply and rapidly. The identification of high-risk areas would warrant further investigation and possible backfilling to reduce the risk of pillar failures ensuring that reserves in the No. 4 and 5 Seams above are intact.

Jan 1, 2004

By Dennis J. Kemp

Laterite projects are found in the tropical and sub-tropical regions of the world. As a result severe meteorological situations accompany such projects, often in regions of high seismic activity and political uncertainty. Frequently, socio-economic development supported by political interest is a major driver for development, while environmental protection imposes numerous stresses on the project. This paper will review and examine the many social, environmental, technical and financial issues that a mining and extraction process is subject to during development. The options that must be evaluated will be discussed in the context of sustainable development. Issues of project standards and cultural impact through to long-term issues such as greenhouse gasses and climate change will be assessed in redirecting project environmental norms. Although a rationale for sustainable project can be developed many long- term uncertainties around issues remain. Keywords: sustainable development, communities, social issues, standards, energy, waste management, consultation, agreements

Jan 1, 2004

By Y S. M Tabatabaei, R Hosseini Tabata

Application of Acidithiobacillus ferrooxidans bacteria to flotation of Sarcheshmeh low-grade copper sulfide ore was studied. Sarcheshmeh low-grade ore contains pyrite, which causes some problems in the flotation of copper minerals. In this study, A ferrooxidans was used to change the surface chemistry of pyrite and copper sulfide ores and consequently, their flotation behaviour. In the presence of A ferrooxidans and xanthate as a collector, pyrite was depressed whereas chalcopyrite and other sulfide minerals were unaffected. In addition, the pulp pH remained unchanged. It was shown that the surface chemical properties of the bacteria could be manipulated successfully to achieve the desired effects in a flotation process. The results showed that the recovery of pyrite in the presence of the bio-depressant is 50 per cent lower than when no bacteria were present. At the same time the recovery of chalcopyrite remained unchanged.

Jan 1, 2004

By 12670

The Cigar Lake project will develop the world’s second largest high-grade uranium deposit. The Cigar Lake Phase 1 orebody contains approximately 226 million pounds U3O8 at an average grade of 20.7% U3O8. The mine, to be operated by Cameco Corporation, will use a unique water jet boring mining method to cut previously frozen ore. A distinctive ore handling design is required to handle the highgrade ore slurry exiting the mining machines. The ore will be crushed and ground underground, with the ore slurry then pumped to surface. Loaded into purpose-designed containers on tractor-trailer units, the ore slurry will be trucked to Cogema Resources Incorporated’s McClean Lake mill. McClean Lake will leach all of the ore. Forty-three percent of the resulting uranium solution will remain at McClean Lake for processing into yellowcake. The other 57% of the uranium solution will be shipped to Cameco’s Rabbit Lake mill for processing into yellowcake there. Detailed design for the Cigar Lake project is now underway. Barring regulatory or market delays, production could start up as soon as early 2006.

Jan 1, 2004

By H. K. Lin, J. L. Oleson

The purpose of this study is to develop a mathematical model to describe the oxidation of cyanide with SO2as proposed in the Inco process. This research employed a direct method for measuring the change in cyanide concentration with respect to time as effected by varying concentrations of SO2, copper and pH. Developing this model may be applicable in determining optimum conditions in a process well known and used in the mining industry. It was determined that the reaction is first-order with respect to cyanide, SO2and [Cu+2].The reaction order is 0.15, or zeroth order with respect to [H+] at pH range from 8.0 to 9.5.The activation energy, Ea, is 21.6 kJ/mol. The overall rate equation, as determined through this study is: [ ]

Jan 1, 2004

By A. Yoshida, H. Miura, S. Yamaguchi, Y. Oyama

A discussion is given on the ionic equilibria and precipitation reactions in seawater based on thermodynamic analysis, in order to understand the solubility of nutrient salts from dephosphorization slag for marine phytoplankton. Solubility of constituent ions in aqueous solution in equilibrium with solid phases are determined using thermodynamic data. It is proposed that CO2 potential defined as log Pco2 should be considered as an additional parameter to the Eh- pH diagram for the ionic equilibrium of slag components in seawater, since magnesium and calcium carbonate precipitation reactions determine the solubility of ligand ions in nutrient salts, such as phosphates, silicate, and sulfate.

Jan 1, 2004

By Arvindh Gupta

BC Hydro proposed to improve the stability of the existing Seven Mile Dam with 54 corrosion protected, re-stressable anchors comprising 92/0.6? strands each, in phase 2 of the program. Being globally the largest capacity anchors ever build, coupled with extra ordinary specifications, the project was a challenge for the entire post tensioning industry. The paper discusses the challenges associated with the anchor material supply as per specifications, extensive research and development carried out by Con-Tech Systems ltd. to overcome the challenges and contribute in making the project a success. The substance of this article is published in the Aug/Sep issue of ADSC magazine.

Jan 1, 2004

By J Watson

Electronic detonator technology has been under development for the last two decades. Currently, there are a number of systems commercially available with several others still under development, each with its own unique features. This technology can offer a significant advantage to the drill and blast engineer through their ability to initiate an explosive charge at the æplannedÆ time. This new technology has created huge interest within the drill and blast community and also raised their expectations to produce better blasting outcomes. In many cases, specifications (or even expectations) of desired blast results are not properly defined. Interaction between the input variables (rock mass characteristics and blast design) and results (fragmentation, throw, damage, ground vibrations, etc) and their mechanisms, or relationship to one another, are not very well defined or understood. That is why rock blasting is still considered by many as an art rather than science. With one of the few remaining variables (cap scatter) now controllable, todayÆs blaster finally has the ability to apply science to his trade. Even though electronic detonators are available and becoming more commonly used, current field practices are not always conducive to extracting or deriving the maximum benefit from this new technology. In the authorÆs opinion, the following need to be understood to derive and sustain the maximum value: clear definition or specification(s) of desired outcomes from a given blast; impact of different features in an electronic detonator system (precision, accuracy, flexibility, reliability, etc) and their impact on the desired blasting outcomes; interaction of blast design variables (energy, energy distribution, timing, blast geometry) and their impact on desired outcomes; impact of rock mass variability and quality of blast implementation on the desired blasting outcomes; and critical need to utlilise appropriate tools and systems in order to measure and quantify benefits.In the authorÆs opinion a scientific implementation process is the key to derive the benefits. This paper analyses the industryÆs preparedness to derive the benefits from this technology and proposes a scientific methodology to understand, evaluate and sustain the value from this technology.

Jan 1, 2004

Previously, a variety of risk rating systems were used on different mines. However, these were mostly site specific and geology based systems. The purpose of developing a uniform rating system, to be used on all Anglo Coal open cast mines, is to provide an unbiased, standard and quantifiable assessment of the risk from highwall and lowwall failures. This takes into account relative differences in the importance of hazards, as experienced on each mine as a result of different combinations of geotechnical factors and mining conditions. The system is based on critical geotechnical and other parameters that have been identified by mining personnel and rock engineers. The primary advantage of this risk rating system is that all open cast mines in Anglo Coal use an almost identical system, which enables the user to compare their risk to the risk at neighbouring mines and/or other open cast mines. The system can be adjusted to meet local, mine specific requirements. The implementation of this new system (a computer program that automatically calculates the risk) has been made as practical and easy to use as possible. Therefore, this tool can be used by personnel from other mining disciplines not directly related to rock engineering.

Jan 1, 2004

By Mustapha Zergoun

This paper presents the results of load tests to assess the vertical load carrying capacity of concrete expanded base piles, or pressure injected footings, for various projects located near Vancouver, British Columbia, Canada. The site subsurface conditions and load test methods are described for the Vancouver International Airport site and the test results are reviewed under both compression and tension loading conditions. The pile load tests at Vancouver International Airport are compared to load tests at other sites near Vancouver. The pile load test results are reviewed with respect to available methods of estimating the vertical capacity of this type of piles. The effect of ground improvement by densification on the load test results is considered. The limitations of tension load tests on single piles with respect to uplift resistance of pile groups under seismic conditions are pointed out. Recommendations are proposed regarding pile load test methodology to estimate ultimate vertical load carrying capacity of plies for limit state design.

Jan 1, 2004

This paper will review the experiences of both big and small exploration/mining companies (local and foreign investors), including the impediments to exploration and project development in Indonesia since the Contract of Work was first introduced there (1967 Minerals, 1981 Coal). This is seen through the eyes of a person who has been employed in a managerial capacity in large and small concerns, and more recently as an independent consultant. Comment will be made on the political, legislative and social constraints imposed by the presence of a large group of disparate artisans (illegal miners) who now form a significant component of the Indonesian mining industry; the Bre-X debacle; the impact of the recent Regional Autonomy legislation; and changes to the Mining, Forestry and Environmental Acts. An overall view (including statistics) will be presented as to how recent Indonesian developments have affected international confidence in investing in its mineral sector over the past decade and it will be placed in an international competitive context.

Jan 1, 2004

By Houyuan Liu

A new process was developed to recover nickel and cobalt by leaching laterite ore at atmospheric pressure and.95"-105" C. The nickel-containing goethite in limonite was first leached with sulphuric acid to liberate over 90% of nickel, cobalt and iron. The dissolved iron was then precipitated as Ni-free goethite by the additioil of saprolite. The acid released during iron precipitation as goethite was simultaneously used as lixiviant to leach saprolite to recover more nickel. With this process the limonite and saprolite were essentially converted into goethite-, gypsum- and silica- containing tailings. Twenty bench scale tests and two campaigns of pilot plant operation were carried out at BHP Billiton's Newcastle Technology Centre (NTC) from January to August 2002. The overall nickel and cobalt extractions were 81 to 90% and 91 to 100% respectively. The average plant availability was 99%. The advantages of this process over existing processes include high plant availability, high consistency, robustness and simplicity of the operation.

Jan 1, 2004

The current boom being experienced by mining, coupled with a shortage of professionals, will mean those in the industry will have many choices. It may be easy to become carried away and run with the highest bid or the biggest promise. Without planning, however, the ærightÆ opportunity may be missed and there may be some long-term consequences. There are many choices of paths in the industry to suit work preferences, life cycles and to achieve a balanced life. People in mining have changed jobs and companies frequently û which means new leaders need to take greater responsibility in charting their own direction. Career options need to be carefully assessed and aligned to personal values and preferences. Emphasis is given on gaining site experience early on.This paper examines strategies for career planning, which incorporate life cycles, education and what is meant by a balanced lifestyle. Two tools are identified as being helpful in ensuring strategies can be successfully executed. They are ævisioningÆ and æinfluenceÆ.To make the mining industry more attractive, we need more creative solutions around advances in technology and organisation of work. It also needs the input and leadership of new entrants in to the industry to assist in its survival. New leaders are encouraged to voice a vision and effectively influence their companies. New leaders have little authority and need to learn how to effectively influence. We as a mining industry need to listen, be open-minded and give it a go.

Jan 1, 2004

By Blas Melissari, Stavros A. Argyropoulos

"In this paper a computational approach was employed to estimate the melting of solid spheres immersed in different liquid metals and under different convective conditions. The spheres are made from the same material as the liquid metal. The SIMPLER algorithm was implemented using a three-dimensional system in Cartesian co-ordinates. Experimental validation of the dimensionless correlation was carried out in two fluids with vastly different Prandtl numbers. The dimensionless heat transfer coefficient (Nusselt number) is obtained as a function. of the Reynolds and Prandtl number.IntroductionThere is a paucity of dimensionless convective heat transfer correlations applicable to fluids like liquid metals. The existing correlations cover single Prandtl number metals [l] or at most two different Prandtl number metals [2]. A knowledge of heat transfer rates from particles at high flux levels has become increasingly important to the design of energy transfer systems. Melting of solid particles has been studied extensively as it relates to many engineering and environmental applications, such as materials processing, space applications, water resource and energy conversion. When objects are immersed in a fluid with a temperature higher than their melting point, they melt and produce molten material that then mixes with the surrounding fluid. These objects experience not only size variation but also changes in their shape. This observation is more pronounced when the melting occurs in a forced convective flow.Yuge performed pioneering experimental work on the heat transfer from a sphere to air under mixed convection [3]. He suggested procedures for predicting the Nusselt number. Hieber et al [4] studied the spherical system analytically, but their study was limited to flow with small Reynolds numbers. Many researchers studied the melting dynamics of ice spheres in water at different convective regimes. Aziz et al [5] and Hao et al [6] performed measurements of the heat transfer coefficient in the water system by measuring the melting time of ice spheres in forced convection. Hao et al [7] performed visualization studies of ice spheres melting in water under mixed convection regime. All of this groundbreaking work, however, did not involve the use of liquid metals"

Jan 1, 2004

In conjunction with steady increases in production levels, long-wall operators have applied greater quantities of ventilating air to control respirable dust and methane gas. As a result, air velocities greater than 7.6 m/s (1500 fpm) have been measured on longwall faces. Operators have expressed concern over the potential entrainment of respirable dust at these high-velocities, especially during shield advance as dust falls from the shield canopy directly into theair stream. Laboratory tests to simulate dust liberation by shield movement were conducted at the Pittsburgh Research Laboratory of NIOSH in a wind tunnel designed to study dust entrainment in high-velocity airstreams. Dust was introduced into the tunnel to determine dust concentration as it relates to entrainment, dilution, air velocity, and particle adhesion. Airborne dust samples were obtained by iso-kinetic sampling using BGI cyclones to quantify respirable dust concentration at the various air velocities. Laboratory tests were con-ducted at velocities ranging from 2.0 to 10.1 m/s (400 to 2000 fpm),and significant differences in airborne respirable dust levels were measured. This research is being conducted to provide fundamental information on the entrainment characteristics of respirable dust at high air velocities, which will subsequently lead to solutions for shield dust control. A discussion of the test procedures and results are presented.

Jan 1, 2004

Leaving the relatively simple life on a uni student and venturing off in to the outside working world is a big step. There are two paths to follow, the æContikiÆ style graduate program where you pick up your new lease vehicle and set forth on two to three years of planned activities, or can pack everything into one bag, stick a copy of æthe rough guideÆ in your pocket, and set off on your own graduate adventure. I took the path less travelled.The less followed method of developing yourself isnÆt for everybody. Parts of the journey are difficult and sometimes it feels hopeless, but itÆs all a learning experience. Along the way you might not get to all the graduate ætourist stopsÆ like dragline, truck-shovel, or drill and blast. But youÆll see most of them and pick up a lot more of the local culture such as people management, operational knowledge, quality control, and the black arts of project financial management.

Jan 1, 2004

By Roberto Parreiras Tavares, Frederico da Costa Fernandes, Guilherme Antonio Defendi, Vangleik Ferreira da Cruz, Júlio César de Sousa Pena

"Near-net-shape casting is an important area of research in the iron and steel industry today. Among the near-net-shape casting processes, the single-belt caster seems to be the most promising, since it is the only one that can achieve levels of productivity similar to those obtained with conventional continuous casting machines. One of the most important aspects in the single-belt casting is the feeding system used to deliver liquid metal over the belt. This system determines the velocity distribution and the levels of turbulence of the liquid metal and affects the quality of the strips. In the present work, a metal delivery system having a simple geometry was proposed. Using the CFD code CFX 5.6, a mathematical model to simulate three-dimensional turbulent fluid flow and heat transfer in that system has been developed. This model was used to analyze different configurations of the metal delivery system and the free surface shape of the fluid was also determined. A physical model of the feeding system was built and used to validate the predictions of the mathematical model. The fluid flow calculations have been validated by dye injection experiments and laser doppler anemometry. Measurements of the free surface levels have also been performed. These experiments provided supporting evidence for the predictions of the mathematical model.IntroductionTo maintain its competitiveness in the present market, the metallurgical sector, particularly the steelmaking companies, are developing new techniques of production. Some of these new processes are focussed on the strip casting technologies. Among these technologies, the SingleBelt process is considered the most interesting option, reducing the number of rolling steps and, consequently, the final cost of the product, especially the part associated to the energy consumption (fuel and/or electric energy). This process can also reach levels of productivity that can not be matched by other strip casting methods(1). One of the most important aspects concerning these new processes is related to the liquid metal delivery system. This system can have a significant effect on the final quality of the strips, since it determines the velocity distribution and the levels of turbulence of the liquid metal."

Jan 1, 2004