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By I. Farr, P. Quinn, H. Mani

"Difficulties in the flotation of Inca's ultramafic ores at the Thompson Mill are related to the presence of serpentine slimes and some floatable rock minerals. Serpentine slime coatings depress pentlandite recovery while rock flotation decreases concentrate grade. Carboxy methyl cellulose (CMG) has been shown to promote sulphide flotation and to reject floatable rock.To improve ultramafic ore flotation, CMC addition in the rougher stage was studied in a laboratory scale column. Batch tests were conducted in the lab and followed up with continuous testwork at the Thompson mill. At 0.5-1.0 g CMG per kg ore, pentlandite recovery is increased by 5-10% in rougher flotation, pentlandite/rock selectivity is improved and pentlandite/pyrrhotite selectivity is unaffected.IntroductionAt Inca's Manitoba Division, two distinctly different sulphide ores are processed at the Thompson Mill, primarily by froth flotation. The sulfide ores are contained within the Thompson Nickel Belt and currently there are two operating mines, Thompson and Birchtree. Sulphide mineralization in both mines is simple, consisting of pyrrhotite (both monoclinic and hexagonal), pentlandite, and minor chalcopyrite. Both deposits are hosted by metasedimentary and metavolcanic rocks with variable ultramafic rock associations. Ultramafic rocks are mostly serpentinites: magnesium rich rocks composed predominately of serpentine. There is little serpentinite at the Thompson mine, while mineralization at Birchtree is closely associated with significant ultramafic rocks.Excellent recoveries of pentlandite (Pn) and chalcopyrite (Cp) are achieved at the Thompson Mill when processing ore from the Thompson mine. In treating the ultramafic associated Birchtree ore, nickel recoveries are some 6 to 8% below that achieved with Thompson ore. Furthermore, a typical concentrate from Birchtree ore contains more rock and is higher in MgO content. The presence of rock in the concentrate is related to free floatable rock species as well as rock locked with sulfides. The reason for the difference in flotation responses of these two ores has been the subject of on-going re-search."

Jan 1, 1998

By Stephen P. Signer

The U.S. Bureau of Mines is developing an intelligent system for roof' control that uses both an expert system and neural networks to improve the capability of mining engineers to evaluate roof support effectiveness for ground control in coal mines. The expert system com- pares roof support capacities with the support requirements estimated to be necessary to maintain entry stability. It does this by evaluating the results of tests on various types of roof support and establishing the maximum allowable load according to anchorage capacity and yield strength of the support. After the user enters geological information (rock properties, geometry of the opening, in situ stresses, bolt pattern parameters, etc. ), the expert system compares the predicted required loading to the roof support capacity and gives the operator advice on the adequacy of the design and how improvements could be made. A good source of the real-time data necessary to allow the expert system to make decisions will come from a roof bolting machine being developed by the Bureau of Mines. Researchers have collected data from a Western coal mine on drill bit position, penetration rate thrust, torque, and rotation rate. Using this information, two neural net- works were developed to identify different types of strata and features in a mine roof such as rock type, rock compressive strength and joint characteristics. The result is a system that can assist a mining engineer with design information that can be constantly updated as mining progresses.

Jan 1, 1992

Alternative processes for converting coal to liquid products and their stage of development are outlined. The merits of hydrogenationprocesses in general, and the solvent refined coal process in particular, are stressed. Bench scale experimental hydrogenation procedures used by the Australian Coal Industry Research Laboratories Ltd. (ACIRL) to study the liquefaction of Australian coals and correlations between properties of such coals and their conversion to liquid products are described. Factors involved in assessing investment and operating costs for modern hydrogenation based coal refineries of different capacities are described with reference to a recent study undertaken in N.S.W. The significance of coal properties such as yield and yield structure of total liquid products and how they and other factors can influence the economics of the coal refining operations are discussed.

Jan 1, 1977

The transfer of Langmuir-Blodgett (LB) monolayers of collector molecules to the surface of mineral crystals is an excellent method for the study of collector adsorption phenomena and is of particular significance in the understanding and development of improved flotation separations. The fatty acid/fluorite and amine/sylvite potation systems were investigated by the Fourier transform infrared/internal reflection spectroscopy (FT-IR/IRS) examination of transferred LB monolayers of collector molecules at the surfaces of the mineral crystals. The [ir]-A isotherm study of fatty acid and amine, typical anionic and cationic collectors, showed the different packing trends dependent upon the pH and/or type of subphase. This result clearly reflects the effect of pH on compound formation and dissociation of the collector molecules. Identification of the collector adsorption state and confirmation of the validity of the FT-IR/IRS adsorption density equation were included in this research effort. This allowed for a detailed discussion of collector adsorption phenomena. As a result of these experiments, it is possible to relate the hydrophobic character of a surface to the nature of the adsorbed collector structure and thus describe flotation behavior in greater detail. For example, it appears that in the case of oleate/ fluorite the equivalent of an LB monolayer can form spontaneously during adsorption from solution, and this structure is known as a self-assembled monolayer (SAM). Such a state is significantly more hydrophobic than the oleate structure which forms on the calcite surface at an equivalent adsorption density.

Jan 1, 1996

By D. Malhotra

Most primary-molybdenite producers use a selective-flotation process in which molybdenite is floated from the ore while other sulfide and non-sulfide gangue minerals are depressed in the same step (Figure 1). The process was developed at the Climax mill. Reagents used in the rougher-flotation stage include vapor oil (collector), syntex (surfactant), pine oil (frother) and occasionally sodium cyanide and Nokes reagent (depressant). Rougher concentrate is upgraded by cleaner flotation to produce market-grade molybdenite concentrates. Reagents used in the cleaner flotation stage are Dowfroth 250, vapor oil, sodium cyanide and Nokes reagent. The development of the flotation reagent scheme at Climax and the role of the reagents have been well described by Born, et al, (1976) and Malhotra, et al, (1976, 1977a, 1977b, 1977c, 1980). The hydrocarbon collector, vapor oil, accounts for approximately 50 percent of the total molybdenite-flotation reagent cost. Because vapor oil sources are limited, and the cost of vapor oil has increased significantly over the last decade, several studies have been done to evaluate alternate oil-based collectors and/or blends of collectors which would produce similar metallurgical results at a reduced cost, or increase the overall molybdenite recovery at the same cost (Smit and Bhasin, 1983; Hahn, 1969; Smith and Bhappu, 1971). The approach taken in the present study was to evaluate alternate non-oil based collectors and collector systems that are less expensive than vapor oil.

Jan 1, 1985

By J. H. Tylczak, R. Blickensderfer

Impact and abrasion properties of various commercial US grinding halls were evaluated and compared by the Bureau of Mines, US Department of the Interior. Laboratory tests were conducted on balls obtained from eight major US manufacturers. The halls included forged steel, cast steel, and alloyed white cast iron and were subjected to repeated impacts until they broke or until 300,000 impacts were exceeded. Pin abrasion tests also were conducted. The results showed wide differences in impact lives, ranging from a few thousand to over 500,000 impacts. The life of inferior commercial halls was increased five to six times by a laboratory tempering heat treatment. For halls that did not break, the major impact wear mode was spalling and ranged from an average rate of 0.28 to 4.46 mg per impact. The softest halls (steel) had excellent impact resistance but low abrasion resistance. The abrasion resistance of the steel halls generally increased with hardness. The alloyed white cast irons had about twice the abrasion resistance of the steel halls. Users should become aware of the wide variations among commercial halls, and ball manufacturers should be aware that their product can he improved.

Jan 1, 1990

Evaluation of Comminution Circuit Design for Sustainability Using EcoNomicsTM

Sep 13, 2010

By S. Tan

In this paper, several commonly used computer truck dispatching criteria are evaluated. A computer-oriented truck dispatching and production simulator was developed to provide data for comprehensive cross comparison among the dispatching criteria. The definitions, primary considerations, characteristics, and performances of these dispatching criteria were investigated. From the simulation results, it was concluded that, in general, no one criterion can dominate all others. All basic dispatching criteria including minimizing truck waiting time, minimizing shovel waiting time, minimizing truck saturation, maximizing truck momentary productivity, or truck routes optimization provide a local optimal solution. To obtain a direct global optimization solution for this complex stochastic process does not appear to be likely. Therefore, the search for an optimal dispatching criterion that will fit all conditions may not be realistic. However, based on the simulation results of the mine operation, several dispatching criteria which have good potential to increase performance can be selected. It may be necessary to search for the best combination of these truck dispatching criteria for a given situation. For example, a truck flow measurement such as the truck clustering factor at shovels can be used as a switch parameter to change from one criterion to another. The values for the switch parameter at which actions should be taken to change the criterion can be established through simulation programs.

Jan 1, 1992

By R. V. Ramani, S. Tan

In this paper, several commonly used computer truck-dispatching criteria are evaluated. A computer-oriented truck-dispatching and production simulator was developed to provide data for comprehensive cross comparison among the dispatching criteria. The definitions, primary considerations, characteristics and performances of these dispatching criteria were investigated. From the simulation results, it was concluded that, in general, no one criterion can dominate all others. However, several dispatching criteria that have good potential to increase performance can be identified. All basic dispatching criteria, including minimizing truck waiting time, waiting shovel with minimum waiting time, minimizing truck saturation, maximizing truck momentary productivity or optimization of truck routes, provide local optimal solutions. To obtain a direct global optimization solution for this complex stochastic process does not appear to be likely Therefore, the search for an optimal dispatching criterion that will fit all conditions may not be realistic. It may be necessary to search for a hybrid combination of the several truck dispatching criteria that have good potential for a given situation. An approach to selecting such a hybrid dispatching criterion is presented.

Jan 1, 1993

By J. M. Keane, C. K. Chase

Critical to successful dump and heap leaching of copper is an adequate evaluation of applicable parameters. This paper deals with methods to establish optimum conditions for dump and heap leaching copper so that commercial operations can proceed. Discussion is also offered of ore occurrences and preparations for dump or heap leaching.

Jan 1, 1988

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By Sina Mostaghel, M. Guo, E. Klaffenbach

The current paper is focused on evaluating the behavior of copper in a copper production slag and the assessment of metal recovery possibilities. For this reason, thermodynamic calculations were carried out to determine the influence of parameters such as slag composition, temperature and oxygen partial pressure on recovery of non-ferrous elements. It was found that the formation of a solid face centered cubic (fcc) phase, mainly consisting of iron, limits the extent of reduction that can be achieved for an industrial process. However, it could be discovered that solubility of iron in the Cu-rich liquid alloy strongly depends on presence of other elements, particularly arsenic. As part of the results of this study, the solubility of Cu in the slag at onset of fcc phase formation is presented as function of temperature, oxygen partial pressure and concentration of MgO and CaO. It was concluded that lower temperature (1200°C) and higher CaO addition (16 mass-% in this study), would result in the highest achievable copper recovery from slag. INTRODUCTION Copper slag is produced as a by-product of the copper production process. The slag is still containing a high amount of copper and other valuable metals. This demands further treatment of the slag as a secondary source of metals. In addition, the physical/mechanical properties of slag allow its use in several applications such as hydraulic engineering, civil engineering, as an abrasive and many more. These applications help reducing the use of natural resources like rock and sand. By decreasing the content of heavy metals such as Cu, Pb, Zn and As in the slag, its application in abovementioned fields becomes more attractive as the probability of releasing these elements to the environment is further reduced. To develop a pyrometallurgical slag reduction process, it is necessary to understand what describes the end point of the reduction. This point is expected at maximum copper recovery without facing operational challenges. Existing literature provide some information on the effect of different parameters such as temperature or concentration of different slag formers, on solubility of copper and heavy metals in different phases. However, due to complexity of industrial slags, equilibrium experiments and accurate thermodynamic modelling are essential to be able to reliably predict the behavior of different elements in the system and determine the end-point of reduction.

Jan 1, 2019

By J. J. Taute, N. B. du Preez

"A well-performing solvent-extraction circuit is a key part of producing good quality copper cathode. To ensure consistent operation, a good understanding of the circuit’s operation and an ability to rapidly troubleshoot key parameters is required. This paper briefly discusses the modeling of solventextraction circuits. The paper then goes on to discuss the determination of key performance parameters from plant data and comparing these with the circuit models to quantify circuit performance. The identification and troubleshooting of circuit issues is presented with a worked example. INTRODUCTIONA well-performing solvent-extraction (SX) circuit is a key part of producing good quality copper cathode. To ensure a consistent, high-quality operation, a good understanding of the circuit performance is required. Evaluating the performance of an SX circuit is an extensive topic. The objective of this paper is to focus on the evaluation that the metallurgist should be performing on a regular basis using flow and concentration data. This paper does not cover important topics, such as crud management, phase continuity, or organic management. Some basic SX modeling concepts are first be presented. The calculation of the parameters is then presented with a brief discussion and recommended ranges (where applicable). A worked example is used to provide a basis for further discussion on the evaluation of the calculated parameters and use of data collected.BASIC SOLVENT-EXTRACTION MODELING CONCEPTSThis section presents the basic modeling concepts used in SX simulation packages currently available. SX reagent suppliers have invested significant time and effort into collecting data on the performance of their reagents under different conditions. Based on these data, suppliers have developed packages which they normally make available to their clients for free. These are typically used for process design and plant optimization studies. For example, BASF developed ISOCALCTM and CYTEC Industries developed MINCHEM® and MEUMTM.Chemistry of Copper Solvent ExtractionLiquid–liquid extraction involves the selective transfer of a substance between two immiscible liquid phases by controlling the relative solubility in each phase. In the case of copper SX, the exchange is typically achieved by an oxime-based chelating mechanism. In particular, mixtures of aldoxime and ketoxime are normally used in conjunction with modifiers. More detail on this extensive topic can be found in Schlesinger et al. (2011)."

Jan 1, 2015

By A. Hosseini

Full-scale rupture tests were conducted on 508 mm (20 in) diameter API X-60 5.7 mm wall thickness pipes containing either axial semi-elliptical cracks or simulated corrosion defects with equivalent depths ranging from 20 to 60 percent thickness. In the case of the cracks, the failure pressures were predicted with reasonable accuracy when considering a level 3 failure assessment diagram (FAD) procedure based on API 579, as compared to level 2 FAD, since the mechanical properties were known. In both cases, the accuracy improved for shallower cracks. Considering simulated corrosion defects, the RSTRENG approach provided more reliable results on predicting the collapse pressure. For a similar depth and profile, the cracked pipes failed at a lower pressure than those containing simulated corrosion defects of equivalent depth.

Jan 1, 2010

By Paul J. Sabatini, Yazen A. Khasawneh

"A Demag CC1800 crawler crane was partially erected on crane mats adjacent to a seawall when settlements near a corner of the crane mat area were observed to be slightly larger than previously assessed. A ground improvement program including installation of dry soil cement mix (DSM) piers was implemented to improve soil bearing capacity. Due to near-surface obstructions, only 75 percent of the DSM piers were installed to the design depth. Because of the partial installation of the DSM piers, an evaluation of the crane pad stability and the effect of the crane loading on the stability of an adjacent 10-ft high concrete seawall, which was believed to have limited (if any) reserve capacity, was required. A two-dimensional finite element model was developed to evaluate the responses of the partially improved ground and the sea wall to the loads imposed by the crane. Geotechnical site investigation and laboratory testing programs were performed to better define the subsurface conditions near the area where settlements occurred and to provide the required mechanical parameters for the soil constitutive model. Analysis results indicate that total and differential settlements of the crane pad and the increase in load on the seawall were tolerable provided limited excavation and replacement of weak dredged soils outside the DSM area would be implemented.INTRODUCTION & BACKGROUNDA Demag CC1800 was erected on 8 ft × 16 ft crane lattice mats at about 12 ft from an existing seawall. Approximately 3.5 in. of subsidence was observed at one corner of the crane mats, while the crane was partially erected and stationary. The approximate location of the crane mats with respect to the existing seawall when the subsidence occurred is shown on Fig. 1.The seawall consists of a reinforced concrete wall connected by reinforced concrete bents to a composite section of sheet pile wall; the total depth of the seawall is about 29 ft. The bents are spaced at about 20’4” and supported by five piles at each bent location. The composite sheet pile consists of concrete and a sheet pile section with a reinforced concrete wale section. The retaining wall is about 10 ft in height and is supported at three levels. The first support level comprises a 2-½” diameter steel rod near the top of the wall spaced at 40’8” the second and third level supports comprise 1-½” diameter steel rods spaced at about 5’6”. The second level support is inclined at about 10 degrees below horizontal and the third level support is oriented horizontally through the wall footing. A schematic of the seawall section is shown on Fig. 2.A geotechnical site investigation was implemented soon after the subsidence was observed. The program included advancing four borings to a depth ranging from 16 ft below ground surface (bgs) to about 30 ft bgs. In general, the investigation showed sandy material (likely fill that was used behind the retaining wall) from the ground surface in two borings located immediately behind the retaining wall. The other two borings furthest from the retaining wall showed very soft to soft clay (possibly dredged material) from the ground surface to a depth of about 10 ft bgs. Based on this information, the ultimate bearing capacity of the subsoils was estimated to range from 1,200 to 2,000 pounds per square feet (psf). From the anticipated crane loading (weight of the crane and loading lifts), a minimum allowable bearing capacity of about 1,500 psf would be required for safe operation. To achieve the required bearing capacity a ground improvement program was selected and implemented."

Jan 1, 2017

By J M. Marwan, B Tang

Strain-type rockbursts, or strainbursts, are characterised by a localised violent failure. Their cause is attributed primarily to the sudden release of strain energy, which accumulates in a volume of highly stressed rock as a result of mining activities. Examples of such phenomena are crown/sill pillar bursts created in the mining process, pillar crush in room-and-pillar mining, face ejection in drift development headings at depth, and floor bursts associated with deep shaft sinking. The paper describes a simple method for the assessment of crown pillar bursts in steeply dipping ore deposits which are extracted by the overhand cut-and-fill method. The method is based on a theory previously established by the author to help assess the need for a remedial solution such as pillar destress blasting. Basically, the mining-induced energy storage rate (ESR) in the pillar is compared with the critical strain energy to come up with the so-called burst potential index (BPI).

Jan 1, 2001

By Rolf Andreas Lauten, Guy Kluck

"Formation of scales may have important detrimental effects in many mineral processing applications. A well-known problem is the need for frequent maintenance to remove scale from processing equipment. Another challenge may relate to encapsulation of valuable minerals in precipitating scale. In this work, we explore the ability of some crystal growth inhibitors to prevent or lower the degree of scale precipitation. In many situations pregnant leach solutions contains substantial concentrations of calcium, magnesium, sulfate and carbonate in addition to dissolved valuable elements, e.g. gold, copper, zinc. Together with non-dissolved gangue minerals, some slurries may also contain particulate gold, copper etc. During normal processing of the pregnant leach solution it may be exposed to temperature gradients or similar promoting precipitation of various scales. Valuable minerals may become entrapped in precipitates and thus become inaccessible to the lixiviant. Use of a crystal growth inhibitor may lower the degree of encapsulation of valuable elements.Using a simple model system, supersaturated with respect to gypsum, the effect of some crystal growth inhibitors on the prevention of scale is evaluated in terms of amount precipitated gypsum, the particle size of the precipitated gypsum and the carbon gold loading capacity.INTRODUCTIONGold bearing sulfide ores are often roasted or pressure oxidised prior to leaching. The purpose of this unit operation is to prevent loading the leaching circuit with sulfides that consume cyanide. Pressure oxidation or roasting chemically converts the sulfides into sulfates and at the same time, the pH of the slurry ends up in the acidic range. Typically, lime addition is the preferred means to raise the pH to around 10 where gold leaching takes place. Combination of large amounts of calcium ions from the lime with sulfate ions from the ore induces precipitation of gypsum. Compounds like calcium carbonate may also precipitate if carbonate ions are present in the slurry. Depending upon the composition of the ore, compounds like calcium carbonate and other types of scale may also precipitate on gold surfaces on the slurry particles. A layer of scale on top of exposed gold surfaces will prevent dissolution in the cyanidation that takes place during leaching. Naturally, such a precipitation may lower the gold recovery."

Jan 1, 2016

By J. D. Miller, C. L. Lin

Appropriate software and hardware necessary to adapt a x-ray CT analyzer for determination of coal washability has recently been developed and sucessfully tested for well characterized samples under laboratory conditions. Evaluation of the CT-based analyzer under simulated on-line conditions is also presented to verify the on-line capabilities of the newly developed x-ray CT analyzer for the control of coarse coal cleaning circuits. The investigation shows that the data obtained from CT washability analyses compare favorably with experimental sink-float data. Further, image frequency was considered to evaluate the CT-Based coal washability analyzer for simulated on-line conditions. Specifically the number of observations (image spacing) needed for accurate sampling and the total time required to perform the calculations for a representative data set were determined.

Jan 1, 2001

By D. Shin

The gold leaching using cyanide from ore or waste has been almost universally in use [1]. Recently, biological gold bioleaching using cyanide producing bacteria, e.g. Chromobacterium violaceum, Pseudomonas fluorescens, or P. aeruginosa, has been investigated as environmental friendly and cost effective method. Among them, C. violaceum has been reported as effective cyanide producing bacterium on gold leaching [2, 3]. C. violaceum produces cyanide using glycine as a direct precursor and subsequently detoxify the cyanide by ß-cyanoalanine synthase [4]. However, until today only 0.026 ? 16.9 mg/L of cyanide production in YP medium has been reported in the literatures by C. violaceum [4-6]. Comparing with adding cyanide chemical, biogenic cyanide concentration is lower than the cyanide concentration added in traditional cyanidation. Since cyanide also forms complexes with a number of other elements such as iron, nickel, zinc, silver, copper, and platinum, it is very important for gold recovery to investigate the enhancement of biological cyanide production and set optimal experimental condition. Most of early studies on gold bioleaching by C. violaceum have been performed to investigate gold leaching mechanism using gold powder, and recently various resources such as ores, electronic scrap, and printed circuit boards of waste electronics [7]. Few studies have dealt with gold bioleaching from low-grade ore. In this research the feasibility of gold bioleaching by C. violaceum from low-grade ores containing gold was evaluated and fundamental study was performed for further scale-up study. The aim of this study was to improve the potential of gold bioleaching by C. violaceum from gold-containing ore; in particular, enhancement of biological cyanide production.

Jan 1, 2012

By Grady B. V O, Cavell K. J, Ault A. R, Newman O. M G, Malcolm J. McPhersqn

Cyclic voltammetry (CV) has been evaluated as a technique for monitoring the quality of an industrial zinc sulphate electrolyte. The basis of the method involves measuring a change in the polarisation of the zinc nucleation reaction at an aluminium surface and relating this to the impurity content and/or the overall quality of the electrolyte. Specifically, the technique aims to be able to indicate and quantify detrimental synergism between impurity elements, something which traditional analytical techniques are incapable of providing. The technique has found some success with regard to monitoring glue additions in a range of metal electrolytes. It has been found that investigations by a number of workers over the past 15 years have produced variable and often misleading results due to the inadvertent use of commercial purity aluminium working electrodes. It has been shown that impurity elements in the working electrode can give rise to a range of responses that are not obtained when pure aluminium is used and that the response is variable due to the lack of surface homogeneity of commercial purity aluminium electrodes. Furthermore, it was demonstrated that previous detection limits reported in the literature were based on the presence of additional peaks in the cathodic scan and not polarisation effects. The results of this study have shown that when a pure aluminium working electrode was used, the method was incapable of detecting any change in polarisation for an electrolyte containing three common impurities (Co, Ni and Ge), at concentrations that would significantly reduce optimum electrolytic performance. A range of methods was tried to sensitise the technique, including raising the temperature and acidity, and adding antimony in order to induce some synergism. In all cases the polarisation response was unchanged. Consequently, apart from the commercialised application for monitoring additions of antimony and levelling agents such as glue, CV has very limited application as an electrolyte screening technique.

Jan 1, 1993