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By B. K. Parekh, W. M. Goldberger

Sludge obtained during the production of magnesium (Mg) from molten MgCl2 by electrolysis contains entrapped magnesium particles. The sludge containing the magnesium particles is a friable, continuous matrix of frozen salts that may also contain some oxides and impurities. Due to the high reactivity of magnesium metal with water, a dry process was developed to recover magnesium metal from the sludge. The process utilizes mineral-processing unit operations. The steps include selective comminution, screening, attritioning and tabling. Recovery of the high-grade (>90%) metal was in the 70% range. The novel process was also successfully applied to a magnesium-alloy for the recovery of metal from the sludges.

Jan 1, 1997

By Joyce A. Ober

Strontium occurs commonly in nature, averaging 0.034% of all igneous rock; however, only two minerals, celestite and strontianite, contain strontium in sufficient quantities to make its recovery practical, and these minerals are found in sedimentary rocks. Of the two, only celestite has been found to occur in deposits of sufficient size to make development of mining facilities currently attractive. Celestite, the most common strontium mineral, consists primarily of strontium sulfate (SrSO,). Strontianite, the second most common mineral, consists primarily of strontium carbonate (Sr CO3). Strontianite would be the more useful of the two common minerals because strontium is used most commonly in the carbonate form, but few deposits have been discovered that are suitable for development. The physical properties of strontium ores are listed in [Table 1].

Jan 1, 1994

By Chi M. Phan, Anh V. Nguyen, Geoffrey M. Evans, Graeme J. Jameson

Surfactants are used to control the interfacial properties of the gas-liquid and liquid-solid inter- faces inflotation. This paper investigates the dynamic adsorption of surfactants at the gas-liquid intelface. The dynamic adsorption process was modeled by considering the surfactant mass transfer to the gas-liquid interface by dimion and the Langmuir and Frumkin adsorption isotherms. The numerical computation was applied to solve the non-linear governing equations. The dynamic adsorption was measured in tenns of the dynamic surface tension using the pen- dant drop method. The theoretical modek were compared against the experimental data obtained with non-ionic (Dowfroth 250) and ionic (sodium dodecylbenzene sulfate, SDBS) surfactants. The theoretical results agreed well with the erperimental data for SDBS, but not for Dowfrother 250, especially for the initial stage. Reasons for the variation in results are given in the paper.

Jan 1, 2005

By F. W. Petersen

In the precious metal industry, activated carbon is used extensively for the recovery of gold and silver from cyanide solutions, particularly from slimy pulps and unclarified solutions. However, carbon can easily become fouled by inert particles in the pulp, thus decreasing the activity or gold loading of the carbon. This paper attempts to quantify the distribution of fine inert particles in activated carbon. Furthermore, a possible mechanism for the intrusion of fines will be postulated. Precipitated silica and ground silica sand were used to simulate pulp conditions and their loadings on activated carbon were determined by ashing. The kinetics of intrusion of fines into the pores of carbon were relatively fast, and were dependent on the concentration in the pulp. Results indicated that particle size of the solids and zeta potential of the fines influenced the loading of inert species on carbon. Scanning electron microscopy and secondary ion mass spectrometry showed a decrease in solids concentration to the centre of the carbon particle.

Jan 1, 1995

By Shaning Yu, Yosry A. Attia

The purpose of this work was to investigate the feasibility of using column flotation as a floc separation technique. In this study, the ultrafine coal (minus 25 microns) slurries were cleaned by using the Integration of column flotation with selective flocculation. It was found that using column flotation as a floc separation technique during the "cleaning" stage, achieved much better results than that either using column flotation as a rougher separation technique for coal flocs, or using It directly to recover the ultrafine coal from the slurries without adding selective flocculant. Thus, the ultrafine coal slurries were first separated by selective flocculation process to reject a certain amount of the dispersed ultrafine ash minerals, and to aggregate the ultrafine coal particles as flocs. Thus, the entrainment of ultrafine ash minerals Into the coal floc-froth concentrate during flotation could be considerably reduced. Subsequently, the coal flocs were further "cleaned" by column flotation. The experimental results Indicated that this approach was technically feasible and particularly suitable for a slurry containing a large amount of ultrafine particles. The effect of flotation time, and collector dosage on column flotation of coal flocs were also Investigated and reported In this article.

Jan 1, 1988

By Swati Mohanty, G. V. Rao

Sedimentary dolomitic phosphate ores are difficult to treat by flotation, and high-grade phosphate concentrates with high recoveries are difficult to obtain. The literature indicates that the reagents required for beneficiation of such ores are generally dictated by the nature of the gangue. In this paper, the optimum flotation parameters necessary for enhancing the grade and recovery of a typical low-grade dolomitic rock phosphate ore from Jhamarkotra, Rajasthan, are highlighted. The standard design-of-experiment (DOE) technique was used to obtain empirical models for both grade and recovery. The model equations were then used for optimizing the flotation parameters, including pH, percent solids, collector dosage and depressant dosage. Laboratory experiments demonstrated that a phosphate concentrate containing about 36% P205, with a recovery greater than 95%, can be obtained in a single-stage by the reverse flotation of carbonaceous minerals at the optimized conditions. Key words: Phosphate, Flotation, Dolomite

Jan 1, 2003

By B. K. Mishra, R. K. Rajamani, P. Songfack

Primary grinding in SAG mills is gaining more importance with respect to the conventional crushing, rod and ball milling operations. This is due to the reduced operating costs generated by lower steel consumption. However. SAG milling is inherently susceptible to more severe risks and problems since it attempts to combine several stages of the conventional crushing and grinding into a single stage. This paper analyzes the SAG milling operation by predicting the motion of rocks and steel balls. The well-known discrete element method (DEM) is used to calculate the trajectories of individual entities, and their collision with one another. A computer code previously used for studying the motion of grinding media in ball mills is enhanced to handle the interaction between heavy spherical steel balls and light chunks of rocks, usually ellipsoidal in shape. The DEM based software called MILLSOFT can animate the charge motion for different design of liners. A case study of a 9.75-m diameter SAG mill is presented and the effects of lifter bar height and configuration on the overall dynamics of the charge are discussed. Also the effect of spacing between liners on lifting the charge is presented. This new approach has a large potential because it shows in detail the effect of each design or operating parameter on the performance of SAG mills.

Jan 1, 1998

By N. Choi, W. D. Cho

Distribution coefficients of gold and silver between matte and slag during the pyrometallurgical treatment of nickel-copper sulfide concentrates were evaluated as a function of matte and slag compositions in the temperature range of 1,250oC to 1,300oC. It was observed that the composition of the matte phase, including matte grade and copper content in the matte, significantly affected the distribution behavior of gold and silver in the matte-slag system. Both gold and silver preferentially concentrated in the matte phase as the matte grade increased With increasing temperature and copper content in the matte, the distribution coefficients of silver increased, while the gold distribution coefficients decreased. It was also, found that slag additives such as CaO, MgO, and A12O3 caused a significant decrease in the solubility of both gold and silver in silica-saturated iron silicate slag. An activity coefficient of gold in matte was derived from the experimenta1 results.

Jan 1, 1999

Raises are widely constructed underground in hard rock mining for ventilation, material transport or emergency escape. The four major raise excavation methods, Drop Raise, Conventional, Alimak and Raise Bore can be divided into two categories from ground control point of view, one ground support can be installed during excavation, the other not. Excavation method must be chosen carefully to keep the raise wall in stable state during excavation and make sure enough rock stand-up time to install ground support if needed. If rock quality is permitted and there is no strict space limitation, raise bore method which is the only method that ground support can not be installed after the whole excavation is finished should be considered first because it is faster, cheaper, safer and less disturbance to the hosting rock. Support may or may not be needed depends on the purpose of the raise and rock quality. In high quality hosting rocks, if the raise is only for ventilation or material transfer, support may be not needed. If it is for emergency escape or escape and ventilation, which provide or require personnel access, the whole raise must be supported either in high or low quality rock. Based on on site data collection, construction and raise utilization, this paper gave out the rule of thumb how to decide an excavation method. After purpose of the raise, required raise diameter (size) and raise site options being known, geotechnical data collection is the next important step in a raise project.

Jan 1, 2011

By V. Perdikatsis

The aim of this paper is the study of the pollution of soils in greenhouses because of the use of pesticides. The degree of pollution was studied in relation with the mineralogical and pedologic properties of the soil. The study was con-ducted in the region of Kountoura, Palaiochora, situated in the south of the prefecture of Hania/Greece. Several samples of soil, originated from 4 greenhouses were analyzed. 5 pesticides with organic drastic compounds were chosen for analytical determination using GC-MS from 18 which were applied in total during the period of sampling. It was concluded that the adsorption of pesticides in the soil of greenhouses is connected with the percentage of the clay fraction and the content of organic carbon.

Jan 1, 2006

By K. A. Natarajan, M. K. Yelloji Rao

The electrochemistry of sphalerite and chalcopyrite was investigated under both open-circuit and applied potential conditions. Emphasis was placed on the selective dissolution of sphalerite from a mixture of sphalerite-chalcopyrite flotation concentrates as a function of applied potential, acid concentration, pulp density, and time. Morphological studies using a scanning electron microscope (SEM) were also carried out with chemically leached, galvanically leached, and unleached surfaces of sphalerite and chalcopyrite. Selective dissoulution of sphalerite could be achieved if the mixed chalcopyrite-sphalerite concentrate slurry was maintained at a negative applied potential of -0.4V (SCE). Probable mechanisms involved in the selective dissolution of zinc are disscussed.

Jan 1, 1990

By Bruce Johnson

This paper is not written to "break new ground" in computer applications; it is just a treatment of how an operating metal mine utilizes a mainframe computer for planning, analyzing, and reporting on the ventilation and cooling systems. The Unisys mainframe computer at the mine site is used in programs that analyze the ventilation network, keep records on various ventilation installations, calculate the results of measurements and produce reports on ventilation conditions in the working places and on the main air distribution, and plan and analyze the cooling system. All the programs are interactive to terminals. There are a series of data files that are generated by some programs which may be used by other programs. Most of these programs have been developed in-house. The computer is also used as a word processor via a vendor-supplied text editing program to produce memos, letters, and to keep up-to-date lists of equipment used.

Jan 1, 1989

By L. John Minnick

Current developments in using lime and limestone slurries to remove sulfur oxide gases from the stacks of coal- and oil-burning furnaces have established an important need for treatment systems which include adequate disposal of resulting waste materials. The paper briefly outlines the classes of scrubbers which are using lime and limestone and describes the characteristics of the by-product material being produced. Some discussion is also included relating to methods of disposal of the scrubber underflow. Since coal-burning plants also produce fly ash as a waste material, one system developed by the author's company combines this material with the sulfur oxide by-products. The mixture is processed in a manner which converts the waste products into usable materials with acceptable structural and environmental properties. Recent interest in protection of ground waters from heavy-metal leachates has made the fly ash-sulfur oxide system an acceptable means of disposal, because the conversion products have very low permeability and adequately encapsulate soluble salts within the hardened mass. Although only limited information is available on the types and chemical requirements of limestone used in these processes, a few guidelines are presented to indicate the range of materials that can be used with good results.

Jan 1, 1974

By A. A. Peshkov, N. A. Matsko, K. N. Trubetskoy

It is possible to divide the general objectives of a company into two components: maximum expected profits and viability over time. These components are designed to maximize the companies value over time. The evaluation of a project includes both a discounted cash flow (DCF) analysis and a risk analysis. The DCF analysis determines whether the project should be accepted or rejected, and the risk analysis helps to forecast possible deviations from the original estimates. However, the results of both methods do not allow for a quantitative comparison between the main objectives of the venture, and they do not resolve the issue of whether it is advisable to sacrifice immediate profits for future profits. This paper attempts to resolve this issue. The present research was carried out on mining projects with different waste-extraction schedules. Calculations were made using the US Bureau of Mines' usage-of-costs model. Russian experience in open-pit mining is reflected in this paper.

Jan 1, 1996

By T. P. Weldum

INTRODUCTION Cleveland-Cliffs' operations in Michigan have been utilizing fully autogenous grinding for over four decades. This is but one of the key characteristics of the iron ore processing method that was developed for the extremely fine grained, low grade deposits of the region. Liberation size of the hematite and magnetite ranges from about 30 to less than 1 micron. Typical grinding fineness target to achieve silica grade in the concentrate is 80 to 90% passing 25 microns, or a P80 of approximately 20 microns. After primary grinding, the magnetite ore is first upgraded by rougher magnetic separation. It is then ground to final product size, sent through thickener-sizers utilizing selective flocculation, upgraded again by finisher magnetic separation, and then brought to final silica grade by reverse amine flotation. Hematite ore follows essentially the same route, less the magnetic separation stages. Concentrate is filtered and pelletized, along with con- trolled additions of fluxstone, to ready it for shipping. Iron ore pellets on the water of the Great Lakes have a value of approximately 1.5 cents per pound. GRINDING PROCESS DESCRIPTION Details of the Empire magnetite grinding process flowsheet have been presented by Greenwood and Rajala (1992), and more recently by Rose et al. (2002). The Tilden comminution process for either magnetite or hematite is essentially identical, with the exception of some variations in the excess pebble treatment methods (McIvor and

Jan 1, 2004

Open pit optimization and mine design depend upon a realistic estimate of the grade-tonnage dis¬tribution. The estimate should reflect what can be reasonably recovered and processed. The McCoy/Cove operation in central Nevada is a gold and silver mine. Recoverable reserve estimations of gold and silver were made using indicator kriging and the indirect log normal variance correction to construct the grade- tonnage distribution. Optimal pits were generated using this distribution, and the results were compared to the pits generated by ordinary kriging and indicator kriging block mean methods. The results indicate that the proposed method for multimetal recoverable reserve estimation shows an improvement in terms of predicting the recoverable tons and grades. The optimal pits generated from the recoverable resource model are larger than those generated by the ordinary kriging and indicator kriging block mean methods. This model maximizes the overall recovery of the mineral resource.

Jan 1, 1999

By R. Poulin, A. Lamontagne, N. Tassé

This paper presents the results of a laboratory investigation aiming to verify the concept of co-mingling of waste rock with layers of compacted tailings. Overall, co-mingling is expected to delay the onset and reduce the magnitude of acid mine drainage (AMD) production in waste rock. To denionstrate the efficiency of the method proposed, five different column tests have been set-up. Columns were fed with deionized water at the top and drainage waters were collected and analyzed. Bacteria counts were done on the tailings and waste rock after the column tests. Permeability in saturated conditions and capillary parameters were measured for the tailings. The results obtained show that the co-mingling method would be effective in mitigating AMD by maintaining nearly water-saturated conditions in compacted tailings, thus reducing oxygen supply in waste rock by preventing thermal air convection and minimizing oxygen advection and diffusion.

Jan 1, 2000

By S. S. Vasan, K. A. Natarajan, J. M. Modak

The biological removal of calcium from a bauxite ore in the presence of the soil bacterium Paenibacillus polymyxa is demonstrated. A column bioreactor that can be either operated in a fluidized-bed (FB) mode for coarser particles or in a total-recycle-slurry (TRS) mode for finer particles was designed, fabricated and tested for this purpose. For the efficient removal of calcium from the ore to the required levels, leach solution should not be allowed to accumulate in the reactor. Therefore, the solution needs to be drained out periodically. Cascade leaching was found to be more effi¬cient. A direct correlation between pH changes in the leach solution and calcium solubility could be made. More than 85% of the calcium could be removed through cascade leaching.

Jan 1, 2000

By A. L. DeVegt, H. G. Bayer, C. J. Buisman

During the last ten years, Paques Inc. has been engaged in the development and installation of treatment systems to remove sulfur compounds from water and gaseous streams using biotechnological processes. Metal and sulfate can be removed from mine waters in two biological steps. In the first step, sulfate-reducing bacteria converts sulfate to hydrogen sulfide (H2S). The HS reacts with the dissolved metals to form insoluble metal sulfide precipitates. In the second step, sulfide-oxidizing bacteria convert excess H2S to elemental sulfur. The Budelco Zinc Refinery in The Netherlands installed a groundwater treatment system to remove metals and sulfate using the biological steps described above. The system has been operating since May 1992 and has been treating 5,000 m3/d (180 thousand cu ft/day). A pilot plant began operation in November 1995 at Kennecott's Bingham Canyon Utah copper mine to develop processes for metal and sulfate removal from groundwater and for the selective copper recovery from leach water. The principle of the biotechnological methods, the full-scale experience and an overview of the test program at the mine are presented

Jan 1, 1999

By I. Koliabina

In this paper, the results of mathematical modeling of casing pipes decontamination from radio-active new mineral forms directly in boreholes using hydrochloric and hydro-silicic-fluoric acids are presented. Modeling for highly and low radioactive coatings on the walls of casing pipes of Anastasievka oil-and-gas deposit was performed using GEMS software, based on the method of Gibbs energy minimization. Calculations have shown that thorianite and goethite, that are present in low-active crusts, detected in casing pipes uplifted from comparatively low depths, are well dissolved in hydrochloric acid, but radiobarite is almost insoluble. For the same acid concentrations, almost all radiobarite of high-active coatings detected in pipes uplifted from considerable depth is dissolved. To evaluate the possibility of decontamination of pipes from radiobarite of low-active coatings, modeling of crust dissolution under the action of H2SiF6 has been performed. The results have shown that for acid concentrations of more than 13 % almost all Ra and Ba are dissolved while all iron and thorium remains in goethite-thorianite solid solution. For the same acid concentration, almost all radiobarite from high-active coatings is dissolved. Therefore, no reagent allows decontamination of pipes from coatings of both types. It seems that successive or simultaneous use of both reagents (HCl and H2SiF6) in certain ratio is required. To clarify this issue, further experimental and model investigations are necessary. The issue of decontamination of casing pipes from galena that is present in high-active crusts also needs to be clarified.

Jan 1, 2005