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By J. E. Hoffman, Massimo Maccagni, T. J. Keefe, Marco Olper, O&apos

The research laboratory of B.U.S Engitec has identified and patented a new process for electrolytic production of lead from lead sulphide concentrates with simultaneous production of elementary sulphur. The process occurs in an aqueous solution, at atmospheric pressure, utilizing a solution of ferric fluoroborate in fluoroboric acid as the oxidizing and solubilizing medium for lead sulphide. After the filtration and separation of a residue composed of elementary sulphur and the gangue which accompanied the concentrate, the solution containing lead as fluoroborate and iron reduced to a ferrous state is sent to a diaphragm electrolytic cell where, in the cathode compartment, the lead is deposited in a compact form on the stainless steel permanent blank. The exhaust solution stripped of lead is sent to the anode compartment where the oxidation of ferrous fluoroborate into ferric fluoroboratetakes place, reproducing the oxidizing solution for new leaching. Depending on operating conditions, it is possible to selectively solubilize the lead from the other metal values present in the concentrate. The sulphur produced from the reaction may be separated from the gangue by extraction with solvent or by flotation.

Jan 1, 1993

By M. J. McPherson, P. Mousset-Jones, G. Danko

Ventilation and refrigeration fortune climate modification contributes significantly to the operating costs of a deep hot mine. Mine climate simulation programs can he used to minimize the impact of these costs. There are several computer codes available to assist in this work. Whichever simulation program is used, it is the mine ventilation engineer who must supply the input data. This paper raises and answers the following question, namely, what accuracy is required of the basic input parameters, in order for a certain precision to he obtained in the predicted air temperatures? In the first part of the paper a new approach is described to estimate the dry and wet bulb temperature of the airflow, either in a dry or wet roadway. The calculation procedure allows an arbitrary temperature change with time, using Duhamel's superposition solution. Matrix-vector representation is applied to simplify the computational structure. In the second part of the paper the sensitivities of the dry and wet bulb air temperatures are analyzed, to the changes of the rock thernrophysical properties, the heat transfer coefficient, and the wetness factor.

Jan 1, 1987

By D. A. Peterson

Laboratory testing was completed to determine the effectiveness of a fiberglass cable bolt (FCB) as a cuttable rock support for a continuous, hard-rock mining method. The FCB consists of four Polystal tendons combined in a node/antinode fashion, with polyvinyl chloride (PVC) spacers forming the anti-nodes. The largest ultimate pull-out load achieved by the FCB was 22 t (48,400 lb) at 89% of the tendons' theoretical pullout load. This premature tendon failure is accredited to: • differential stresses within the tendons and • differential tendon displacement. An increase in pull-out resistance for a given embedment length is due to: • increased bond area, • reduced interfacial shear and • "wedge" effect. The critical embedment length was found to be 40% less than for conventional steel cable bolts (SCB) at a 127-mm (5-in.) node spacing. An FCB can have up to a 92% increase in load-carrying capacity over a conventional SCB at equal embedment lengths. The load carrying capacity is equivalent to SCB at a 960-mm (37.8-in.) embedment length. Though the FCB is 7.5% more expensive than the conventional SCB (installed), this cost may be offset by increased performance. FCBs are a potentially viable support alternative for continuous hard-rock mining.

Jan 1, 1993

By Jacek Kolacz, Knut Lyng Sandvik

Fine grinding in an air swept and a grate discharge ball mill working in closed circuit with a forced vortex air classifier has been investigated in continuous laboratory scale. Minerals with different physical properties were ground down to 40, 20, and 10 micron top size. The shape of the product particle size distribution curve was investigated and specific surface (BET) was measured. During production of material with top size of 40 microns in an air swept mill, the capacity was up to 25% higher when compared to a grate discharge mill. This difference dropped to 180A during production of 10 micron top size material. A corresponding decrease in power consumption was observed. An important finding is that by regulation of the air flow rate through the mill, it is possible to achieve products with different specific surfaces and particle size distribution curve steepness. During production of the 10 pm material, the specific surface could be varied in the range 3 to 4.5 m2/g. Such powders could hardly be produced in a grate discharge mill because fine particles coated the grinding media and the lining. On the other hand the internal classification in the air swept mill kept the size distribution of the mill content relatively free of fines. This prevented a similar slowing-down of the air swept grinding process.

Jan 1, 1995

By William H. Dresher

World trade has increased significantly during the last quarter century. However, a new rational for protectionism is emerging which argues for the restriction of trade as a means of preserving and protecting the environment. Fearing lower environmental standards in the Third World, environmentalists are calling for new trade barriers between the developed countries and the developing countries to combat what they see as "eco-dumping." The "greening" of protectionism and the merging of environmental standards into international trade agreements could fundamentally change the world trading system as well as seriously impact the availability of raw materials to provide for the needs of the peoples in both the developing and the developed worlds. This discussion will deal with the agreements and regulations that promise to influence the trans boundary shipment and recycling of scrap metals and wastes containing metals and their projected impact on world trade and metal prices. Emphasis will be placed on the Base1 Convention, whose restrictions concerning trans boundary shipment of scrap metal and metal-containing wastes for recycling took effect on December 31, 1997.

Jan 1, 1998

By J. Drelich, J. D. Miller

The wetting behavior of liquid polymers at solid surfaces and the adhesion forces involved at polymer-filler interfaces should always be considered in the preparation of high-quality polymer composites, including those made with mineral fillers. Spontaneous polymer spreading over the filler surface is a basic condition for the design of polymer-mineral composites. In this regard, the wetting and adhesion characteristics of polymer-mineral systems are reviewed. Based on this review it is clear that several aspects of wetting phenomena at mineral filler surfaces require further systematic study. Specifically, efforts should be made to determine the wetting characteristics of molten polymers at mineral-filler surfaces in greater detail. Also, the effects of mineral-surface contamination (including surface hydration) on wetting and adhesion phenomena need specific investigation. It is expected that an improved fundamental understanding of wetting and adhesion phenomena for polymer-mineral composites will provide the basis for further technological development.

Jan 1, 1996

By Numan Elmas

This paper presents detailed information on the genesis, formation, and industrial utilization of Yaylacik magnesites. Tectonically, the study area is located within the Tavsanli Zone, immediately south of the Izmir-Ankara suture in western Turkey. The geologic setting mainly comprises ophiolitic melangks basics, and ultrabasics associated with very rich magnesite deposits and lacustrine sediments. The ophiolitic unit tectonically overlies the schists and carbonate rocks. The presence of glaucophane and lawsonite indicates a low-temperature/high-pressure metamorphism. The ultra- basic rocks, which exhibit cumulate composition, have been mostly serpentinised and represent the oceanic floor of the Yaylacik ophiolite. Basic intrusives consist of dolerite and diabase, and they show the characteristics of within-plate dolerites. The magnesite occurrences are commonly observed in block, stockwork, lens, and vein forms and were deposited within the serpentinites. In most magnesite samples, secondary quartz/chalcedony formations are observed as fracture fillings due to the highly effective tectonic movements. Field surveys and microscope studies reveal that magnesites had been formed by the metasomatic alteration of serpentinites. Chemical analyses show that, although MgO content of the magnesites varies from 43.41% to 50.48%, Fe203 and CaO are lower than 1%. Silica contents are as high as 5.52% in a few samples. Although Yaylacik magnesites are not suitable for making basic refractory bricks, they are widely used as caustic-calcined magnesite in a variety of applications, including animal food, artificial fertilizer, chemical (acid neutralizer), medical and pharmaceutical, and water treatment.

Jan 1, 1999

By Bruce D. Hulman, Robert .. F. Gorman

Introduction Groundwater resource evaluation has historically required extensive field investigative work, usually at great cost. More recently, the advent of the microcomputer has made difficult aquifer and groundwater evaluations comparatively simple and less expensive. A groundwater model is a numeric solution to a set of equations that calculates the water level in an aquifer or other types of water bearing strata. A computer will execute the solution of the set of equations rapidly and thereby permit evaluation of large amounts of hydrogeologic data rapidly. Computer modeling of groundwater resources is very often used to forecast the effects of multiple uses of a single groundwater resource. Modeling of heavily used aquifers has proven to be beneficial for averting problems arising from competitive use of a groundwater resource. This paper describes the work tasks performed in order to evaluate a large alluvial aquifer and thereby predict the hydrologic impact of additional groundwater withdrawal. Purpose and Scope Neyer, Tiseo & Hindo, Ltd. (NTH) was retained to evaluate the groundwater supply potential of the Missouri River alluvium underlying the Fairfax District in Kansas City, Kansas (Figure 1). The proposed groundwater supply is being considered for industrial use as non-contact process water and a heat exchange medium for plant climate control. The anticipated peak groundwater demand is estimated to exceed 30 million gallons per day (MGD) during the summer months, with an average daily demand of nearly 25 MGD. The proposed groundwater supply was to be developed from 15 large-diameter production wells located at positions that would minimize potential interference.

Jan 1, 1987

By Ted M. Noskiewicz, James A. Ramsay

INTRODUCTION During the various stages of an underground project from inception through design and construction, probably the single factor of most interest and concern is the nature of the ground. The ground conditions more than any other item govern costs and feasibility; and although the methods available for assessing the ground have become increasingly reliable during the past thirty years, it is still very difficult in many cases to predict the behaviour of soil and rock during and after excavation. To help in this ground evaluation process, we have frequently supplemented the boring program with one or more large diameter inspection holes; and during the past eighteen years, seventeen of these holes have been constructed on tunnel projects which we have designed. There are references in the literature to similar inspection holes (1); however, as far as we are aware, no detailed description of them has been published. The behaviour of soil or rock during and after excavation and the effect of ground water on tunneling operations are of vital interest to tunnel designers and contractors. A comprehensive geotechnical investigation is therefore among the early and most important tasks carried out on a tunnel project and the backbone of every geotechnical investigation is the boring program. A series of borings, typically 50 to 100 mm (21 to 4 in) diameter, are drilled from which soil samples or rock core are recovered and the ground water observed.

Jan 1, 1979

By J. Maiti, A. Bhattacherjee

A literature review on quantitative analysis of mine safely studies revealed that numerous investigators explored a wide- range of techniques, including the investigation of bivariate and multivariate statistical models. Although these researchers addressed various issues of accident causation and prevention, they, in general, did not investigate through the use of quantitative models the multivariate relationships of several factors affecting mine safety in a causal framework. In this paper, systems dynamics and structural equation modeling are presented to simultaneously represent and study the effect of policy variables related to accident prevention along with the factors causing accidents and injuries. The application of these models to a group of mines revealed that current training practices at these mines do not appear to alleviate accident occurrences. It is inferred that the use of these quantitative techniques can provide a new direction of research in mine-safety studies.

Jan 1, 2000

By Lawrence F. Rooney

The wide distribution of limestone and dolomite and the decentralization of the depedent industries give the State Geological Survey a major role in the, development of these mineral resources. The amount of geological information necessary for efficient exploration is so large that few companies can afford to do the necessary basic field work or store the data. The state surveys fill these responsibilities and thus might be said to serve as the geological research departments of the limestone and dolomite industry. At the Indiana Geological Survey, the data of most value to limestone producers are in the form of unpublished measured sections, well records, cores, chemical analyses, directories, and geologic maps. Much of this information is published in summary form. The Survey also assists individual members of industry in exploration and evaluation of mineral deposits. In addition, a progressive State Survey provides the geological infor¬mation necessary for the development of new resources which do not appear to justify industry's own preliminary efforts.

Jan 1, 1966

By M. A. Marticorena, R. Stratton-Crawley, C. I. Basilio

Diethylenetriamine (DETA) is a selective depressant for nickeliferous pyrrhotite during pentlandite flotation. Laboratory flotation tests conducted on ore and process samples showed that pyrrhotite rejection is greatly improved by small additions of DETA; however, the effectiveness of this depressant is most noticeable when the mineral sample is oxidized. LIMS and XPS analyses conducted on flotation products and pyrrhotite specimens showed that the difficulty in pyrrhotite rejection arises from inadvertent activation of the mineral by heavy metal ions, such as Ni2+, cu2+ and Ag+, that are present in the process water. In the presence of DETA, however, the mineral is deactivated under oxidizing conditions. The deactivation mechanism may involve oxidation of the activation products, which are likely in the form of heavy metal sulfides, followed by solubilization by DETA. FTIR spectra of pyrrhotite electrodes contacted with DETA showed no trace of the reagent on the surface, substantiating the view that its role is one of complexing agent that enhances the dissolution of activation products under oxidizing conditions. FTIR spectra of pyrrhotite contacted with amyl xanthate solutions showed that both dixanthogen and iron xanthate are formed on the surface, the latter becoming more predominant at higher potentials. In the presence of DETA, however, only a small amount of xanthate is adsorbed on the mineral at potentials (Eh) approximately 200 mV higher than the case without DETA.

Jan 1, 1995

By M. Polat, G. Ahuja, S. Chander, M. S. Klima

A study was conducted to investigate the use of flotation in combination with dense-medium cycloning utilizing ultrafine (-10 um) magnetite, as an integrated process for high-efficiency cleaning of fine coal. The objective was to produce a high-quality (low-ash, low-sulfur) coal, while reducing the amount of non-magnetic material that would need to be removed by magnetic separation. Three dense-medium cyclone tests were performed using different underflow diameters to produce feed material for the flotation separations The use of different underflow configurations caused a variation in the pulp and solids splits, which changed the clean-coal yield and the magnetite-to-coal ratio of the cyclone products, and hence, the composition of the flotation feed. Flotation was used to separate the clean coal and to recover the magnetite contained in the cyclone overflow stream. Any ultrafine refuse material, which may have reported to the cyclone overflow stream, was also removed in this step, further upgrading the product. In addition, flotation was used to improve the overall yield by recovering a middlings fraction from the cyclone underflow stream. It was found that flotation was very effective in separating the coal (or middlings) from the ultrafine magnetite, even under variable feed conditions. Magnetite recoveries approaching 99% were possible using rougher-cleaner separations in a laboratory flotation cell. This paper presents the results from this study.

Jan 1, 1995

By R. J. Pugh

The surface chemical sites on several fillers (quartz, feldspar, calcite and granite) were studied by the adsorption of well defined acid and basic probe molecules (benzoic acid, benzyl alcohol, ethyl benzoate, pyridine and benzyl amine) from cyclohexane. The results provided a wide variation of adsorption data, emphasizing the extensive range of site heterogeneity on the filler surfaces. In addition, it was shown that the acidic probes were strongly adsorbed on all of the minerals, thus indicating that the basic surface sites dominate the acidic ones. Also, through FTIR studies with vapor-phase probes adsorbed on orthoclase, it was possible to identify the nature of specific sites and the type of bonding occurring between the filler surface and the probe molecule. These types of surface analytical techniques could give useful information for predicting the adsorption functional groups on dispersants, dyes, thickeners, etc. and could lead to enhanced interfacial bonding between the filler and the matrix.

Jan 1, 1993

By F. K. Letowski

Leaching of zinc sulphide concentrate by nitric acid which is simultaneously regenerated by oxygen in the reactive froth has been investigated. The reactive froth was formed by a recycled zinc sulphate electrolyte containing nitric acid, a mixture of gaseous 02 and NOx, entrapped in the foam and particles of the zinc concentrate suspended in the foam. In the reactive froth the multiple regeneration of nitric acid proceeded owing to the encapsulated oxygen and amount of nitric acid used can be considerably lower than in the continuous liquid phase. 93 to 97% of zinc was extracted to a solution containing 30 to 409/1 HNO, during 40 to 60 min of leaching in a batch reactor without regeneration of nitric acid. 50 to 100% of the consumed nitric acid was regenerated during continuous leaching in froth carried out in the ‘flotation column’-type reactor at 80 to 90°C and under pressure of 100 to 200kPa. The rate of HNO, regeneration in the froth was proportional to oxygen pressure and inversely proportional to nitric acid concentration in the froth. A two-stage process flowsheet is proposed. In the first, the reduction stage, removal of nitric acid from the leach solution directed to standard purification and electrolysis is carried out by its reduction to nitric oxide using fresh concentrate in the froth. In the second, the oxidation stage, nitric acid is continuously regenerated by oxygen in the froth.

Jan 1, 1995

By J. Scott McDougall, J. Herman P. Eng. Vanderlaag

An underground mine fire can seriously threaten the lives of all personnel in the mine. This fact makes fire emergency planning a high priority in the mining industry. The optimum warning alarm must be fast and able to reach all miners, regardless of their location or work activity. Current means of fire warning are varied, and include such methods as stench, telephones, and word-of-mouth (messengers). Unfortunately, none of these methods are entirely satisfactory. A novel fire warning alarm which enables instantaneous warning of all underground personnel, the Canary Nine Messenger System, has been developed by VLF Magnetic Systems Inc. in conjunction with Noranda Technology Centre and the U.S. Department of the Interior - Bureau of Nines. The warning is sent by an electromagnetic signal which penetrates through mine rock to receivers housed in the battery packs which also power each miner's cap lamp. A loud buzzer in the integrated battery/receiver unit and the flashing of the cap lamp alerts miners to incoming messages. Testing of prototype equipment has demonstrated that the transmitted signal is capable of penetrating through over a mile of mine rock and activating the receiver. This report describes the theoretical basis for through-the-rock ultra-low frequency electromagnetic transmission, and the design of recently available transmitter and receivers.

Jan 1, 1995

By T. L. Heisler

The Cigar Lake project, located in northern Saskatchewan (Figure 1), is one of the world?s largest high grade uranium deposits, with reserves of 150 million kilograms of uranium in a deposit averaging 430 metres below the surface. The Cigar Lake project is being developed by Cigar Lake Mining Corporation (CLMC) which is owned by Cameco Corporation (48.75%), Cogema Canada (36.375%). Idemitsu Uranium Exploration Canada Ltd. (12.875%) and Korea Electric Power (2%). Mining the Cigar Lake orebody is presenting a very real challenge due to the high grade and the ground conditions in and around the orebody. Presently, an underground test of various mining methods is underway.

Jan 1, 1992

By G. S. Brierley, R. D. Drake, J. E. Kelley, J. C. Kellogg

This case study embodies the problems of an underground project under current contracting practices. It will provide a realistic framework for a structured examination of the anatomy of a major complex underground project. Just as it will illustrate the frustrations of the parties to an underground contract, it will also provide a means to examine potential opportunities to provide a better way to develop underground space. Urban Transit Authority (UTA) had planned to expand their heavy rail underground transit system through an extension to an existing line. UTA lacked sufficient funding to guarantee the construction and operation of this planned extension. Venture Partner Associates (VPA) in conjunction with four major department stores entered into an agreement to create a major underground space for a commercial/recreational facility. The concept was to locate the facility adjacent to a planned station and beneath existing aboveground office facilities. This group was known as Commercial Development Corporation (CDC). UTA had reached an agreement with UMTA to provide 20 percent of the line and station costs. UTA then entered into an agreement with CDC to provide the needed additional funding for the station work in return for locating the station adjacent to the planned underground commercial/recreational complex. The agreement called for CDC to contribute 20 percent to the station cost to a maximum of $25 million plus a one percent contribution from commercial/recreational revenues for operating costs.

Jan 1, 1989

By Gemei Yang, Pierre Mousset-Jones, Felipe Calizaya, Malcolm J. McPherson

Laboratory tests on controlled airflow recirculation have shown the development of transient states in response to changes in system prevailing conditions such as those generated by a sudden start-up and stoppage of fans. Researchers in many European countries have developed various models to explain these phenomena. However, these models failed to consider some important factors such as diffusion and dispersion of gas in turbulent flows. For both in-line and cross-cut recirculation, tests have shown that after the start- up of a booster fan, the gas concentration in the system fluctuates, reaching high levels at the initial states and slowly dying out with time. These fluctuations cannot be represented adequately by simple step-wise functions but rather by smooth, albeit complex equations. In this paper, the phenomena are explained by the convection-dispersion theory, and represented by a mathematical model. Based on a few simplifications and applying Fourier's Transform Method to the differential equations of the flow recirculation model, an integral form of gas concentration function was derived. The Simpson Integration Method was used to compute numerical results for two laboratory tests. The paper also discusses the range of the dispersion coefficient to improve the accuracy of the model.

Jan 1, 1989

By V. Roze, M. E. A. Robertson, C. J. Sharland

Current Techniques - Fire Assay Fire assay of gold has been used for several thousand years and is a well known technique to the traditional assayer. Very few assayers wish to use the method but to date there has been no viable alternative. Fire assay is expensive in labour, time, capital and running costs. Workers can be exposed to hazards and uncomfortable working conditions such as lead fumes, heat stress, dust and eye strain. The high capital cost of putting up the building and equipping it, together with running costs which increase annually at a prohibitive rate makes the technique less attractive each year. The main requirement in most assay laboratories is to maximise throughput economically. This is difficult with fire assay as it is impossible to automate. Each sample for analysis is handled by at least 12 people and each person represents a potential source of error. Record keeping and report generation has to be done manually which is both slow and prone to errors. Replacement of staff requires a considerable training period and with a large turnover of personnel this presents yet another problem. The presence of silver and dross in the gold sample affects the accuracy at low gold values. X-ray fluorescent analysis Two methods of XRF instrumentation have been used with limited success. The first type is a laboratory instrument employing L X-rays. Small samples of a few grams, which are not representative,

Jan 1, 1988