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By Y. Qin, X. Fu, T. Qi, H. Tang

"The FASTMELT ® process was developed as an alternative to blast furnace ironmaking; in this process, high-quality molten iron is produced using direct reduction followed by high-temperature slag/metal separation. In this study, iron recovery and phosphorus removal from oolitic highphosphorus haematite using the FASTMELT® process was investigated. The performance of two reducing agents, coal and wood char, was compared. Direct reduction experiments indicated that with optimized reductant addition, the ore-char and ore-coal briquettes attained metallization values of 82% and 78%, respectively, and residual carbon contents of 0.24 and 2.35%, respectively. The slag/metal separation experiments revealed that molten iron containing 0.41% phosphorus and 0.021% silicon (by mass) was produced from optimally reduced ore-char briquettes, and molten iron containing 0.78% phosphorus and 0.91% silicon from optimally reduced ore–coal briquettes. The study indicates that carbonaceous materials with high CO2 reactivity are suitable for use in the FASTMELT ® process for phosphorus removal and iron recovery from oolitic high-phosphorus haematite. IntroductionIn China, the general depletion of iron-rich mineral reserves has led to many efforts to exploit low-grade and refractory ironcontaining resources for ironmaking (Liu et al., 2014). The efficient utilization of the highphosphorus oolitic haematite resources in central China has received considerable attention. The available resources of this material total approximately 3.0 billion tons. The oolitic units in the ore exhibit an onionlike structure with phosphorus-containing gangue layers of 2–10 µm thickness. The best concentrate produced from these resources contains approximately 50% iron (Fe) and 0.8–1.2% phosphorus (P) (by mass) (Ai, Yu, and Wei, 2009; Song et al., 2013; Wu, Wen, and Cen, 2011). Further removal of phosphorus from these ores using conventional beneficiation methods is not possible."

Jan 1, 2017

By R. W. O. Kersten

"The aim was to investigate stable pillar design procedures currently in use on chrome and platinum mines, subject them to a critical appraisal, and review some of the alternatives proposed in the literature. It is concluded that these pillar design methodologies suffer from drawbacks that can be detrimental to the mining industry and that an improvement is essential.It was decided that the increased availability of analytical models and failure criteria could be exploited to update the empirical to an analytical/empirical method. The proposed methodology adopted FLAC2D simulations using the Hoek-Brown failure criterion to calculate full stress-deformation curves for typical pillars. The mine stiffness concept was introduced to determine the pillar load, integrating the influence of the pillar and strata stiffness and mining geometry.The proposed methodology was calibrated by comparing experimental and predicted deformations and failure depth of pillars in one hard-rock mine. The conclusion was that the methodology is an improvement over the one currently in use. An improved factor of safety is given by the intersection point of curves for the stiffness of the system and the pillar strength. IntroductionThe paper describes part of the findings of a PhD thesis (Kersten, 2016) on an alternative stable pillar design methodology. This publication contains sufficient information to implement the method for further interpretation and testing. A detailed comparison of measured and predicted data is dealt with in the thesis, and the results show that there is promise in the methodology.The design of stable pillars in mining is of fundamental importance, not only in the Bushveld Complex mines but throughout the mining industry. Wherever mining occurs, pillars are formed at some stage and it is essential to predict their behaviour, i.e. whether they will burst, yield, or remain stable. Although of crucial importance, pillar design still suffers from major shortcomings and weaknesses."

May 1, 2019

By M. Seerane, R. Machaka, P. Ndlangamandla

"Metal injection moulding (MIM) is a near-net-shaping powder metallurgy technique suitable for the cost-effective mass production of small and complex components. In this paper, the effects of the metal powder particle size on the final properties of 17-4 PH stainless steel are reported. Three different particle sizes (d50 33.0, 7.91 and 4.04 µm) were used to prepare the injectable MIM feedstocks using a CSIR-developed wax-based binder system at a fixed solids loading of 60 vol.%. The distribution slope parameter and the rheological flow index behaviour were used to predict the flowability of the feedstocks. The effects of the particle size on MIM products were established. The results are discussed in terms of the subsequent microstructural and mechanical properties of MIM 17-4 PH stainless steel against the established MPIF Standard 35. IntroductionMetal injection moulding (MIM) is a near-netshape manufacturing process established as an alternative to produce complex small-tomedium shaped components that were previously fabricated by conventional methods at higher costs (Attia and Alcock, 2011; Todd and Sidambe, 2013).Although recent advances in micromanufacturing (mainly machining and electrodeposition-based) have enabled the fabrication of complex micro-size geometries directly into miniaturized parts, these processes are generally neither routine nor easily accessible at present (Attia and Alcock, 2011).Typically, the MIM process consists of four steps: mixing, injection moulding, debinding and sintering. Mixing involves blending of the desired metal powder composition with carefully selected multicomponent organic binders at the right proportion. This mixture, which is called feedstock, is then injected into a mould of a required shape to form a ‘green part’. Debinding is the removal of the binders by chemical, thermal, or catalytic means while maintaining the shape of the part. Finally, the debound part is sintered to a full or near-full density part (Sotomayor, Varez and Levenfeld, 2010). The MIM process is essentially a combination of plastic injection moulding with conventional powder metallurgy technologies."

Jan 1, 2016

By S. Mohanta, B. C. Melkap

"SynopsisDry beneficiation of coal by air dense medium fluidized bed is an emerging trend. It is widely believed that the particle size of the medium has a significant effect on the separation efficiency. This investigation demonstrates that medium particle size has a major effect on separation efficiency. Experimental results show that different size fractions of the same feed respond differently to the same size fraction of medium solids. Furthermore, a particular size fraction of feed coal responds differently with different size fractions of medium solids. The Ep values and overall metallurgical performance parameters, obtained from experimental results, clearly indicate the superior performance of an air dense medium fluidized bed separator when using –150+106 µm magnetite powder as the fluidizing medium. These observations reinforce the importance of sizing the medium particle size for the air dense medium fluidized bed.IntroductionIn an air dense medium fluidized bed (ADMFB), a fluidizing bed of a particular density is created by suspending solid particles in an upward air flow. A feed containing coal particles of different densities is introduced into this fluidizing bed. The particles with relative density less than the bed density float on the top of the bed, while particles denser than the bed density sink through it. Since there is a general correlation between ash content and density of coal particles, it is possible to remove ash-forming impurities from a raw coal to the required level by regulating the density of the fluidizing bed. Recently, the ADMFB process has received significant attention world-wide for its specific advantages of low operating cost and less restrictive for small capacities (Luo and Chen, 2001; Houwelingen and de Jong, 2004; Dwari and Hanumantha Rao, 2007; Sahu et al., 2009; Mohanta et al., 2012). This process is not recognized as a well-established industrial practice because of the availability of efficient wet processing technology. However, with the revival of interest in dry beneficiation of coal in general, and ADMFB in particular, there is a concerted effort to improve the efficiency of the ADMFB process, and successive improvements have made the process a competitive and viable option for beneficiating coal."

Jan 1, 2015

By S. Blancher, A. Perroton, H Smith, T. Nzima, T. Wallmach, V. Dieudonné

Chromite beneficiation is generally performed by crushing and density separation using spirals. At the Dwarsrivier Chrome mine spiral efficiencies seam to vary, the reason for which is not evident. This sometimes results in the production of low-grade products, which are sold at relatively low prices. This paper represents a Qemscan® study that investigated mineralogical reasons for these variations. Variations in liberation of chromite particles as well as variations in chromite compositions were investigated. The results showed that the so-called low grade chromite product can be improved to become a high grade chromite product by means of a refinement in mineral processing. A detailed Qemscan® database (SIP file) was developed to account for variations in chromite chemistries. It can be shown that chemical variations with respect to Cr, Al, Mg and Fe in chromite particles reporting to the scavenger tails are larger than in the high grade product. A combination of these chemical variations together with a decrease in liberation of chromite particles in the scavenger tails can potentially help to recover more chromite particles from this specific process stream.

Sep 1, 2021

By M. Z. Naghadehi, F. F. Nasategay, J. Sattarvand, R. Battulwar, E. E. Gohari

After the recent increase in catastrophic failures of tailings dams such as the Burmadinho, Brazil failure in 2019, the mining industry has actively engaged in the stabilisation of tailings dams. Most of the tailings storage facility (TSF) guidelines suggest a laborious action that can be facilitated through imaging by unmanned aerial vehicles (UAVs). Although UAVs are not unknown to most mining operations, automated rill detection through aerial image processing is a new concept. This study utilises images from sites in the U.S. and employs semantic segmentation with a UNet architecture to detect location and size of these rills. The developed model can be used as a tool for monitoring surface erosion of TSFs.

Sep 1, 2021

By K. Cole, D. Mesa, P. R. Brito-Parada, M. R. van Heerden

Turbulence in stirred tank flotation vessels determines the bulk transport of particles and has an important role in particle-bubble collisions necessary for attachment. Positron emission particle tracking (PEPT) produces quantitative measurements of the kinematic motion of different particle classes inside flotation vessels. This paper presents flow profiles of the vessel, residence time distributions, flow profiles through the mesh and macroturbulent kinetic energy distributions as experienced by valuable (hydrophobic) mineral particles in a laboratory scale flotation vessel. The results highlight the impact of the rotor-stator design and a retrofit mesh modification at the upper part of the vessel which improve recovery by decreasing turbulence in the quiescent zone and at the interface. Keywords: Flotation machines, turbulence, PEPT

Jan 1, 2020

By J. D. Zhou, F. Yang, X. G. Bi

"In this investigation, the phosphorus distribution ratios in the CaF2 system and B2O3 system dephosphorization slags for high-phosphorus hot metal pretreatment were measured by an indirect method under laboratory conditions. Firstly, the phosphorus distribution ratio between liquid slag and solid iron was measured, and then the phosphorus distribution ratio between liquid slag and hot metal was calculated. Phosphorus capacity was calculated in terms of the composition and optical basicity of the slag. Dephosphorization slag was also studied by scanning electron microscopy, energy dispersive analysis, and X-ray diffraction analysis. The experimental results show that the phosphorus capacity of the B2O3 slag system is much greater than that of the CaF2 system. It is demonstrated thatB2O3 can completely replace CaF2 as fluxing agent for high-phosphorus hot metal pretreatment. With CaF2 as fluxing agent, the phosphorus capacity increases with increasing CaO content in the slag, but the phosphorus distribution ratio decreases. B2O3, when used as fluxing agent, can react with high melting point phases such as 2CaO·SiO2 and 3CaO·P2O5 in the slag to form new phases with low melting points such as 11CaO·B2O3.4SiO2, 2CaO·B2O3.SiO2, and Ca9.93(P5.84B0.16O24) (B0.67O1.79), thereby acting as a fluxing agent. When the ratio of w(B2O3)/w(CaO) is 0.16, the phosphorus distribution ratio reaches its maximum value, that is, the dephosphorization ability of the slag is at its maximum. IntroductionAs international iron ore prices continue to rise, the development of China's steel industry is facing a lot of pressure. Against this background, development and utilization of domestic high-phosphorus iron ore resources is particularly important. When highphosphorus iron ore is used in ironmaking, the phosphorus content in the hot metal can reach 0.35% or more, and the hot metal must be pretreated. For hot metal with 0.08–0.10% dissolved phosphorus, the traditional hot metal dephosphorization pretreatment technologies are relatively mature. However, when using these methods to dephosphorize hot metal containing 0.35% P or more, the amount of dephosphorization slag can reach 100–150 kg per ton of hot metal. Furthermore, the traditional dephosphorization methods require the addition of large amounts of CaF2 as fluxing agent, and this results in high fluoride levels in the dephosphorization slag. The fluorine in the slag can partially dissolve in water and thereby causes high fluoride concentration in the water and soil. Once the fluoride is absorbed by humans or animals, it can result in toxic effects on the central nervous system and myocardium. In addition, fluoride can accumulate in the environment, and thereby pose a health risk to animals and humans through the food chain (Li, 2007; Liu, Wang, and Dong, 2011, Diao, 2013). The objective of this research is to replace CaF2 with B2O3 as fluxing agent while achieving the expected goals of hot metal pretreatment."

Jan 1, 2016

By N. Duda, P. Śliwiński, P. Stefaniak, B. Jachnik

Ventilation and air-conditioning are some of the most energy-consuming processes in deep underground mining. Additionally, the energy consumption of these processes systematically increases along with the expansion of the mine. Therefore, proper energy efficiency assessment and consumption forecasts of these systems are particularly important in modern mines for ongoing tracking and planning of the likely costs. In the article, a short-term prediction model for surface air–conditioning stations is described. This model takes into account dependencies that were identified, based on the data from the supervisory control and data acquisition (SCADA) systems. These dependencies between the response value and the external conditions are then incorporated into the model. This way, for example, the ambient temperature or the total number of specific days of the week (with sometimes significantly lower or higher than the weekly average energy consumption levels) are included. Taking into account these dependencies, and e.g. forecasted average monthly temperatures allow us to include the seasonality of energy consumption in the presented model. In the article, a sample energy efficiency analysis of the A/C system based on an example of the KGHM Polish Copper Polkowice-Sieroszowice mine is performed. The results of the solution proposed in the article are then evaluated, and compared to the currently functioning, more basic forecasting methods. However, given the general nature of the dependencies used in the model, similar solutions could be used in other case studies.

Sep 1, 2021

By J. D. T. Steyl, G. B. Grobbelaar

Two examples are presented to show how first-principles – physical-dynamic, here termed behavioural modelling, is used to build digital twins of unit processes or plant sections. A digital twin equips the metallurgist, engineer, or manager with a powerful tool to conduct model-based design, solve process problems and improve operations. It is particularly relevant in the metallurgical industry where plant behaviour is highly integrated, rates respond to particle dynamics in complicated ways and mineral flows across flowsheet boundaries are variable. The two examples used to illustrate the behavioural modelling methodology are 1) a flotation column unit block and 2) a multi-compartment pressure oxidation (POX) autoclave. It simultaneously accounts for the causality of material and heat flow, takes care of mineral particle dynamics, physical and chemical reaction rates, the plant control system behaviour and operating heuristics. The basic modelling building blocks are briefly reviewed to show how the behavioural modelling attributes constrain the mass and heat flow dynamics to physically realistic values. This is the key aspect that allows project value to be created with minimal input data. Behavioural modelling is especially valuable where the process dynamics are poorly understood or controlled, where data-driven models fail to cope with complex and highly integrated plant behaviour, where quality data is lacking or limited funds are available to generate the data required to fill all the knowledge gaps. The paper uses the flotation column example to show how behavioural modelling and simulation can be used to optimise plant performance, while the multi-compartment POX autoclave model shows how it can be used to diagnose process problems. It also provides a solid basis to add a data-driven component – in other words, it makes a strong case for a hybrid first-principle– data-driven approach to solve process problems, especially where microscopic-level understanding is poor. Keywords: Digital twin, behavioural modelling, simulation, flotation column, pressure oxidation

Jan 1, 2020

By G. E. Blight

Several aspects of the behaviour and properties of backfills consisting of cemented cyclone underflow tailings are illustrated by means of examples, and guidelines are given on the optimization of the performance of cemented fills. The stretch characteristics of the geofabric used to contain freshly placed backfill are described, as well as the relationship between these characteristics and the forces acting on retaining barricades. The properties required to achieve a self-supporting, stable free face in cemented backfill are explored, and a graphic relationship between stable height and shear strength is presented and compared with that for uncemented (classified) tailings. After a description of the characteristics of Witwatersrand quartzite gold-tailings backfill and commonly used cements, the process of drainage and air entry into backfill is outlined. Following this, the early-age gain in strength and the shear-strength characteristics, as well as the compressibility characteristics of cemented backfill, are described. Two phenomena that are potentially damaging to cemented backfill are seismic effects (or blasting acceleration) and the closure that takes place during the curing of cement. Investigations show that neither of these phenomena is actually significantly deleterious to gold-tailings backfill: liquefaction does not Occur as a result of seismicity, and hydration of cemented fill is not significantly impeded by closure.

Jan 1, 1996

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

By Z. L. Xue, J. L. Li, X. Y. Wang

"In low-carbon energy-efficient basic oxygen furnace (BOF) steelmaking processes, limestone partly or completely replaces the active lime. The effects of limestone calcination temperature (1200–1500°C) and time (5–15 minutes) on lime reactivity and CaO grain size were investigated. The reactivity was evaluated by titration with hydrochloric acid, and the CaO grain size was analysed using scanning electron microscopy. The results revealed that for calcination temperatures higher than 1300°C, the reactivity reached a maximum and then decreased . The higher the temperature, the earlier the peak of reactivity appears. The CaO grains grow with increasing temperature and time, which leads to the decrease of reactivity. Notably, the effects of temperature on CaO grain size and reactivity are more marked than that of time. To obtain active lime calcined at ultra-high temperature by flash heating, the calcination conditions should be 1300–1400°C for 10–15 minutes, or 1400–1500°C for 8–10 minutes. IntroductionLime is one of the most important slag-making materials for dephosphorization and desulphurization in the basic oxygen furnace (BOF) steelmaking process. The reactivity of lime is a measure of its capability to take part in slag-making. Lime having a reactivity of more than 300.0 mL (4 N HCl), determined by hydrochloric acid titration is generally referred to as active lime (Rusjan et al., 2007; Zeman, 2008). At present, the active lime used for BOF processes comes primarily from a kiln or shaft kiln, where limestone is preheated at 700– 900°C, and then calcined at 1050–1200°C (Drenhaus et al., 2010; Oates, 2007)."

Jan 1, 2016

By J. Bal, V. D. Dao, W. Li

"SynopsisThis study proposes a methodology for evaluating the risk of coal bumps in multiple-seam longwall mining. Both the stress field and the total energy release (TER) during retreat were evaluated in the specified case involving multiple-seam mining using the LaModel program. The results of numerical simulations indicated that both the peak vertical stresses on the panel edges and the peak TERs in the outby longwalls increased significantly as the horizontal offsets were reduced from 60 m to zero. With the comprehensive consideration of the stress field and TERs, a conservative offset of 60 m was ultimately adopted when developing the gateroads of the lower panel in the field. The field measurements indicated that coal bumps were avoided completely by employing the proposed design, and the maximum roof-to-floor and rib-to-rib convergences of the tailgate during retreat were only 360 mm and 576 mm, respectively.IntroductionCoal bumps – sudden, violent bursts of coal – pose a serious threat to the safe excavation of coal. Their occurrence depends on the properties of the surrounding rocks, stress field, and dynamic disturbance. The complexity of the mechanism of coal bumps is further enhanced in multiple-seam mining due to seam interaction. Multiple-seam mining is most frequently found in the coalfields in eastern China, such as Xuzhou, Xinwen, Zaozhuang, and Huainan. In the past, due to issues of availability, economics, and ignorance of the potential risk in multipleseam mining, coal seams in such conditions were mined without proper planning to account for seam interaction. Fortunately, studies published over the past three decades have raised awareness of the problems associated with multiple-seam mining, and indicated that the ground control issues induced by multiple-seam mining can be avoided and/or minimized with proper planning.A number of technical studies pertaining to the design of multiple-seam mines have been published. These studies can be divided into two groups based on their methodologies of design: empirical (Chekan and Listak, 1993; Haycocks and Zhou, 1990, Matetic et al.; 1987a, 1987b) and numerical approaches (Li et al., 2000; Maleki, 2007; Mark, 2007; Peng, 2007; Zipf, 2005). The majority of the extant studies on the interaction mechanisms in multiple-seam mining have focused on the load transfer during operation, resulting in the proposal of the pressure bulb theory (Forrest et al., 1987; Haycocks and Karmis, 1983; Peng, 2008; Peng and Chandra, 1980) and pressure arch theory (Holland, 1973; Oram and Ponder, 1997) to guide multiple-seam mine design. However, neither, of these theories can be used to evaluate the potential for coal bumps."

Jan 1, 2015

By B. k. Kenzhaliyev, M. A. Naimanbayev, Zh. A. Baltabekova, N. G. Lokhova

In research various desorbents were used to desorb the following rare-earth metals from Purosorb 140 cation exchanger, i.e. ammonium chloride; ammonium sulfate; a mixture of nitric acid and ammonium nitrate; a mixture of hydrochloric acid and ammonium chloride; a mixture of sulfuric acid and ammonium sulfate. It was established that a solution containing 30 g/dm3 of H2SO4 + 300 g/dm3 of (NH4) 2SO4 is the most optimal desorbing solution to desorb REMs from macroporous Purosorb 140 cation exchanger impregnated with rare-earth metals from industrial dihydrate wet-process phosphoric acid. It was established that the residual REM content in the cation exchanger decreased from 0.89 to 0.10 wt. % with an increase in the ammonium sulfate concentration from 10 to 400 g/dm3. Technological desorption regimes for rare-earth metals from cation exchanger were developed. The optimal conditions were determined to desorb rare-earth metals from the Purosorb 140 cation exchanger, particularly temperature 25°C; L:S ratio = (0.8 ÷ 1.1):1; duration = 1.0-1.5 hours. Keywords: Rare elements, sorption, cation exchangers, wet-process phosphoric acid, desorption

Jan 1, 2020

By L Dyer, G. J. Wilkie, P. Walters, B Tadesse, L. Keeney

Grade Engineering® is a term trademarked by the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE) and includes five key levers for upgrading ores and rejecting waste prior to expensive downstream comminution and mineral processing. These five levers include natural deportment, induced deportment, bulk sorting, particle sorting and gravity separation. Over the past ten years, CRC ORE has progressed a range of technologies that exploit these levers from laboratory proof of concept through to large scale demonstration and validation. This paper details the work carried out by CRC ORE and Curtin University for assessing the amenability of an ore for its natural deportment and particle sorting attributes in an Integrated Screening and Particle Sorting (ISPS) Grade Engineering® process. ISPS is seen as a preferred method for Grade Engineering® as compared to individually operated unit operations as the benefits of each can be complementary. Furthermore, it is suggested that integrating the two levers has two important impacts: 1. Firstly, there is a risk that isolated particle sorting test results will be misinterpreted as being representative of the full sample without considering the mass balance impact of high-grade material that might have been lost in the fines fraction. This fine fraction will not be detected through the particle sorter. 2. Secondly, and potentially of more valuable impact, is that the opportunity may exist to upgrade the feed first through determining if there is a concentration of high grade to the fine (or coarse) fraction which can be separated through screening. Undertaking screening in the preparation stage of the particle sorting process will enable analysis and separation of the fine or coarse fractions of a rock mass. The result of this study provides the mining industry with an independent framework for undertaking an Order of Magnitude (ISPS) Grade Engineering® assessment on a range of constituent ore types. Keywords: Grade engineering, particle sorting, grade by size fractionation

Jan 1, 2020

By I. C. R. Gilchrist

A principal requirement in the design of a backfill transportation pipeline is the accurate prediction of the values of key slurry flow parameters. Input variables, such as particle size and solids concentration, are usually determined by the load-bearing requirements of the placed fill. It is therefore necessary to identify the optimum conditions of transport for a particular combination of input variables. This paper critically reviews the methods available to predict the values of flow parameters in slurry pipeline systems in the light of experimental data generated at a test facility. Particular reference is made to rod milled waste and deslimed tailings transport systems and, in the case of the former, it is shown that both pumping and load-bearing requirements can be optimized.

Jan 1, 1988

By T. M. Louw, L. Auret, S. M. Bradshaw, F. F. Noelle

Modern industrial processes undergo frequent process state shifts due to changes in demand, feedstock or maintenance operations. Multimodal continuous process monitoring is therefore required for effective plant operation. Steady state analysis is a key component in effective multimodal monitoring. Various issues still remain in determining the starting and ending times of transition states. High dimensionality of process data is a characteristic that makes it difficult to select variables to consider when conducting steady state analysis. In order to address these problems, steady state detection on the principal component space is proposed. First, data undergoes principle component analysis to reduce dimensionality, then existing multivariate steady state detection algorithms are applied on the principle component scores. A novel algorithm, threshold PCA-SSD, is proposed and compared to an existing technique for steady state detection. The algorithms are investigated on high dimensional synthetic data Keywords: Multimode process, steady state detection, principle component analysis

Jan 1, 2020

By J. Petersen, A. E. Lewis, J. Chivavava

Rare earth elements (REEs) have special properties that prompted their extensive use in high-tech applications. The demand for REE has, therefore, increased over the past years, resulting in the supply risk of the materials. Extraction from non-conventional low-grade ores, like easy-to-mine ion adsorption clays (IACs), by hydrometallurgical methods is being explored to supplement the supply of REEs. The extraction of REEs from low tenor IAC leach solutions requires enrichment using cost-effective methods such as precipitation. Therefore, the aim of this study was to understand the recovery of REEs from IAC leach solutions using various reagents for precipitation. In the first part of the study, recoveries of REEs from IAC leach solutions through direct precipitation using H2C2O4 and NH4HCO3, as well as antisolvent crystallization using C2H5OH, were predicted via thermodynamic modelling using OLI Stream Analyzer. Verification experiments were then conducted through the use of an agitated reactor. Simulation results showed that high yields of REEs were possible using each of the reagents, but large quantities of C2H5OH were required. Experimental results confirmed the high yields predicted from simulations. Precipitation with H2C2O4 was found to selectively recover REEs while rejecting Al. However, utilization of NH4HCO3 and C2H5OH resulted in the co-precipitation of Al. Furthermore, the yield of Y from antisolvent crystallization was significantly lower than the theoretical value. The product recovered from antisolvent crystallization consisted of well faceted, large crystalline particles, which filtered faster than the fine, amorphous REE carbonates recovered using NH4HCO3. REE oxalates were crystalline, larger than the REE carbonates and, overall, showed the highest filtration rate.

Dec 11, 2024

By S. C. Maji, U. S. Chattopadyay, S. Chaudhuri, T. Gouri Charan

India is devoid of coking coal resources, which is a vital raw material for coke making. As a result it has to import about 80% coking coal for steel making. Indian National Steel Policy, 2017 has envisaged crude steel production around 300 million tonnes Mt) by the year 2030-31 and forecasts coking coal demand of 161 Mtpa (million tonnes per annum). One way of improving the indigenous resources is to study the performance of existing washeries and to improve the clean coal recovery by adopting suitable technology. A study was carried out, mainly to focus on the fine coal circuit of an existing coking coal washery, to generate the desired quality of clean coal. The operating coking coal washery being studied is presently feeding coal from nine different sources with varying feed ash contents. The coal fines varied in ash content ranging from 19.5% - 43.6%. For treating the coal fines, the washery has operated a spiral for the past few years. Performance studies were carried out, and it was found that the spiral is not efficient in recovering the cleans. Detailed investigations were carried out on the coal fines using flotation techniques, and it was found that to achieve a low ash clean coal, the froth flotation is a much better beneficiation option than a spiral, The studies showed that the recovery of clean coal through a spiral is 67.7% at ash content of 27.0%, while flotation tests showed a recovery of 68.1% at 16.5% ash content. Keywords: Coking coal washery, near gravity material, spiral washer, froth flotation

Jan 1, 2020