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By E. Aamland

Preparation of high-purity magnesium-yttrium alloys by electroreduction of Y2O3 dissolved in a YF3-LiF bath and the subsequent deposition of yttrium in a molten magnesium cathode was investigated in laboratory-scale apparatus. Parameters such as temperature, current density, and electrolyte density were studied. Electrolysis was conducted in a specially designed MgO diaphragm cell at temperatures ranging from 780° to 970° C. Alloys containing up to 55 weight-percent yttrium were prepared at cathode current efficiencies of 21 to 60 percent. Cell design and operation are described, and some of the limiting conditions pertaining to the method are discussed.

Jan 1, 1973

By H. H. Schrenk, L. B. Berger, Robert L. Beatty

"INTRODUCTION Toxic oxides of nitrogen 5/ are formed or liberated in many industrial process and may constitute a definite hazard to the health of persons exposed to the atmospheres thus produced. Oxides of nitrogen occur in the gases involved in the use of explosives, in the gasoline products of welding operations in the exhaust of internal-combustion engines, in the vicinity of electrical discharges, in the combustion of nitrated materials, and in chemical process involving nitration or the use of nitric acid, Itis evident that oxides of nitrogen may constitute an occupational hazard in many industries, and therefore it is important that those concerned with the control of such hazards be equipped with a technique suitable for the determinations of oxides of nitrogen in the concentrations of,hygienic significance."

Feb 1, 1943

By H. C. Ko

The Bureau of Mines maintains an active program in thermochemistry to provide thermodynamic data for the advancement of mineral science and technology. As part of this effort, the standard enthalpy of formation at 298.15 K, ?Hf°, for 2CdO-CdSO4 was determined by HCI acid solution calorimetry to be -345.69 ±0.61 kcal/mol.

Jan 1, 1983

By R. Hogg, J. M. Mutmansky, E. Kaya

"Characterization of the size, shape, chemical composition, and mineralogical content of mine airborne dusts generally requires a larger mass of dust particles than is typically collected using traditional sampling devices. In this paper, the general design of a passive dust collector is described and the field results are presented. The collector was constructed of galvanized sheet metal duct with a resin-coated honeycomb to provide an elutriation-type system for particle collection. Several versions of the collector were used in the field portions of the research.The dust samples collected from underground coal mines were found to possess angular particle shapes, relatively consistent size distributions, and elemental compositions that showed relatively little variation, at least for the more prevalent elements. In addition, the distributions of particles sizes obtained from the passive dust collector appear to be similar to those of samples collected at the same time in a conventional personal sampler except that the passive device seems to collect a larger quantity of coarse, nonrespirable particles. Conclusions on the suitability of this dust collector for collecting characterization samples are presented. In addition, the potential for using such a dust collection system for supplying dusts for biomedical research is discussed.INTRODUCTIONRecently, a considerable amount of research effort has been directed toward better understanding of the characteristics of the coal dust generated during the mining process. It is generally believed that dust characteristics play a significant role in the development of Coal Workers' Pneumoconiosis (CWP). In order to effectively protect coal workers from coal dust, it is important to understand the properties of dust, the mechanisms of generation and dust-lung reaction. Conducting research on dust characterization, dust control and the biomedical aspects of dust toxicology generally requires a large sample of airborne coal dust. Unfortunately, current dust sampling instruments are not able to meet this demand because only a few milligrams of dust are collected."

Nov 1, 1995

As part of the Bureau of Mines subactivity in secondary resource recovery and to expand the Nation's mineral base, the Tuscaloosa Research Center made characterization and preliminary beneficiation studies of the waste residues from various coal-conversion processes: from pilot plant tests of the Synthane process for coal gasification, the Synthoil process for coal liquefaction, and the solvent-refined coal (SRC) process for sulfur removal from coal. Those coal conversion processes selected for this study were based on the availability of pilot plant samples. Physical, chemical, and mineralogical examinations of the wastes made to determine the mineral content prior to physical beneficiation tests indicated that in addition to significant quantities of carbon, some trace elements offer potential for concentration.

Jan 1, 1980

By R. W. Lewis

The Federal Bureau of Mines Boulder City Metallurgy Research Laboratory conducted experiments in order to develop a spectrochemical method for determining the concentrations of impurities In high-purity tungsten. This report presents a procedure, developed by these experiments, for determining 19 impurities in high-purity tungsten. Metal samples were thermally converted to the oxide, mixed with graphite, which was prepared and mixed with an internal-standard element, and excited in a d.c. arc. Sixteen of the impurity elements were determined with one set of conditions, using germanium as an internal standard. Lanthanum was used as an internal standard in the tests for boron and chromium. Molybdenum required the substitution of sodium chloride for the graphite and the use of copper electrodes. Data on the precision of the method are included in this report. The coefficients of variation vary considerably but average about 15 percent. Higher concentrations of impurities than those investigated may be determined with some modifications of the testing procedure, provided attention is given to the possibility of interelement interferences.

Jan 1, 1961

By J. M. Singer

Flame propagation of lower limit hybrid coal dust-methane-air mixtures in vertical and horizontal flame ducts of 15.2 cm id and 1.8 m length has been investigated to provide information bearing on safety in mines. Fuel concentrations at lower limits of flame propagation and equivalences of coal dust and methane are much higher for continuing flame propagation than for short-span flame propagation in the vicinity of an "overdriving" ignition source. As the energy of the ignition source was increased, the flame speed and the distance of flame propagation from the ignition source increased, whereas the total fuel concentration at the lower limit decreased.

Jan 1, 1968

By R. R. Nothdurft

The internal friction of eight single crystals of magnesium with orienta-tion ranging from 10° to 84° was measured at 33.5 kc and 272° C, and the results were interpreted in terms of the pinned-dislocation model proposed by Granato and Lucke. Results show that the strain-amplitude-dependent decrement varies with orientation in a manner predictable by the G-L model. Different values of strain-amplitude-independent decrement were observed at different orientation angles, but correlation with the theory was not conclusive. Problems and steps for further study are discussed.

Jan 1, 1965

By Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.'s Virginia Pocahontas No. S mine. Methane from the overlying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (l-S/B-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an underground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pet, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

Although alternating-current (a.-c.) power systems and equipment have been used in coal mining for many years, most mines in the United States are powered mainly by direct current (d.-c.). There are several logical reasons for this, but the use of d.-c, equipment is, in most instances, a direct outgrowth of the original practice of using such power for haulage systems. For traction equipment such as the electric trolley locomotive the d.-c. motor has ideal operating characteristics, and thus it has been widely used for haulage locomotive service. The first efforts at electrification of coal mines started with the haulage system and from there branched out to include the many types of electrically powered mining machinery used in the industry today.

Jan 1, 1960

It is now widely accepted that horizontal stress is present nearly everywhere underground. Often it is more severe than the vertical stress. It is a major cause of roof control problems in underground mines. The AHSEM computer program contains two modules to improve mine layouts for control of horizontal stress. For development, the user specifies the orientations of the maximum horizontal stress, the entries, and the crosscuts. Angled crosscuts may be used, and the angles may be different for the right- and left-hand crosscuts. AHSEM then shows the user how the stress condition would vary as the entry and crosscut orientations are changed. The second module is for longwall mining. Severe stress concentrations can make headgate conditions hazardous when the entries are improperly oriented. AHSEM shows whether a particular longwall orientation and extraction sequence places the headgate corner in a stress concentration or in stress relief. It also estimates the magnitude of the stress concentration.

Apr 1, 2003

By Harold E. Heide

The United States is the world's largest consumer of tin and depends entirely upon foreign imports for its major source of supply. Only a small quantity of tin is produced on the North America continent. The advent of the war in Europe in 1939?brought a threat to our foreign sources of supply, and the Congress took steps to forestall shortages of tin and other metals. By authority of the Strategic Minerals Act, passed by Congress in 1939, and subsequent legislation, the Bureau of' Mines ?and Geological Survey conducted investigations of domestic tin deposits. Most of the tin that has been produced in North America came from the Seward Peninsula, Alaska.

Jan 1, 1948

By Donald W. Mitchell, John Nagy, Edwin M. Murphy

To increase safety and productivity in mining , the potential uses and hazards of rigid foam were investigated by the Bureau of Mines Experimental Coal Mine . This research resulted in the development of chemical formulations , spraying equipment , and application procedures that permit safe and effective use of urethane foams for improving mine ventilation , for reducing weathering of mine rock and steel , for constructing seals in fire areas , and for thermal insulation .

Jan 1, 1964

By Donna D. Harbuck

The Bureau of Mines has investigated a process to produce titanium powder directly from titanium salts. If successful, such a process could lower the cost and increase the use of titanium. In this study, K2TiF6, K2TiF3, and TiF3 were reduced with potassium in the temperature range of 650° to 750° C. Under certain conditions, titanium powder 1.6 to 3.3 microns in size was produced. After leaching the product with a 0.1M HCl solution, powder impurities as low as 0.04 pct potassium and 0.28 pct fluorine were obtained. However, oxygen levels of over 1 pct and the frequent formation of insoluble byproducts demonstrate the need for further research to make the powder suitable for powder metallurgy applications.

Jan 1, 2011

By David E. Morse

Burundi, a small central African republic located between Tanzania and Zaire, remained essentially a nation of small family farms in 1978-79 with approximately 95% of the population engaged in subsistance agriculture. Coffee and tea continued as the nation's major export commodities. Mineral exports, small tonnages of cassiterite, wolframite and bastnasite, accounted for an estimated 3% of total exports in 1978 and 2% in 1979, or $2 million2 in both years. Burundi's major mineral imports in 1978-79 were cement, iron and steel, and refined petroleum products. Abnormal weather conditions, a drop in world coffee prices in 1978, and the conflict in neighboring Tanzania and Uganda in late 1978 and early 1979 combined to re-strict economic growth in Burundi during 1978-79. The gross domestic product (GDP) posted a gain of 6.7% in real terms for 1978 and an estimated 2.5% for 1979 which was significantly less than the 13.7% recorded in 1977, a time of high world coffee prices. The manufacturing and construction sectors were hard hit in 1979 by the conflict between Burundi's eastern neighbors because of transport disruptions which made building materials and manufacturing inputs almost unobtainable.

Jan 1, 1981

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By Robert W. Freedman

Vacutainers are used by the Bureau of Mines and the Mining Enforcement and Safety Administration (MESA) for sampling mine air and products of combustion. Tests were conducted on both 10-ml and 30-ml sizes to study shelf life stability during storage, pretreatment of stoppers, and handling of a wider range of compounds. A chamber was constructed to provide convenient, efficient evacuation of the Vacutainers shortly prior to use. Fixed gases and C1 ?C5 hydrocarbons could be stored for 1 week or more after sampling. Where decreases occurred (C02 and C3-C5 hydrocarbons), they were predictable as a function of storage time. An unexplained phenomenon, slow accumulation of CO in evacuated Vacutainers, occurred after a few weeks of storage. The levels were low and time dependent. Attempts to eliminate this behavior by pretreating the stoppers were unsuccessful.

Jan 1, 1976

By W. E. Lamont

Flotation studies of phosphate-bearing waste pond materials, low-grade washer products, and raw ores, all from the Tennessee brown phosphate district, showed that these types of materials could be treated without des liming to recover high-grade phosphate concentrates. The investigation showed that fine grinding before flotation was a requisite for increased recovery of the phosphate values and that the optimum pH conditions were in the range of 10.0 to 10.5 when using anionic collectors. Multiple-cleaning of the rougher phosphate concentrate was required to produce high-grade concentrates. Phosphate recoveries ranged from 60 to 82 percent and were inversely related to the grade of concentrate produced.

Jan 1, 1972

By C. Gary Reiness

A safety glass eyepiece which had been repeatedly exposed to mine environment over a number of years was studied to determine some of its optical properties. In the regions from 385 to 400 mµ and from 625 to 760 mµ, the transmittance was less than the 89 percent required by the American Standard Safety Code for Head, Eye, and Respiratory Protection. From 200 to 320 mµ the relative transmittance of two parts of the eyepiece was found to vary widely, having a maximum of 38 percent difference at 315 mµ. Irradiation of the glass by ultraviolet light caused enhanced absorption in the range from 200 to 1,200 mµ. There was a time-dependent increase of 1016 color centers per cubic centimeter throughout this range after 36.5 hours of irradiation. The rate-of-growth curve for the optical density, at 243.5 mµ and 23° C, was resolved into linear and saturable components, indicating zero order and first order

Jan 1, 1968

By A. D. Garman

This paper presents one of a series of digests of foreign mining legislation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the laws of Bolivia has been prepared from the best available information in Washington, but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State. SYNOPSIS OF LAW All useful substances of the mineral Kingdom belong originally to the State. The soil and subsoil are regarded as two distinct parts, the latter extending indefinitely in depth (Art. 2). The subsoil is under the dominion of the State, which may either abandon it to common use, grant it gratuitously to the owner of the soil, or alienate it, in return for an annual fee, to any individual or association that applies for it. (Art. 1-3.)

Jan 1, 1929