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By F. Fraas, H. H. Storch

"In the second paper 4 of this series, data were presented concerning the decomposi¬tion of polyhalite by saturated salt solutions. It was found that uncalcined polyhalite upon leaching with boiling saturated sodium chloride solutions yielded a brine in which the (K2 Mg) /304 ratio was considerably higher than that obtained from the calcined material, and for this reason appeared more suitable for the production of potassium chloride. It was found, in fact, that the leach liquors from uncalcined polyhalite deposited a mixture of KC1 and NaC1 upon evaporation and subsequent cooling, whereas those from calcined polyhalite yielded mixtures which contained not only potassium and sodium chlorides but also large quantities of glaserite, K3Na (S04)2. Hence it was decided to study the evaporation of the uncalcined poly—halite leach liquor and postpone experiments on the calcined polyhalite liquors until such time as a process for further removal of sulphate was developed.A considerable body of equilibrium data is available in the literature on thesystem K+ Mg++ — Na+ Cl—S04 =,— H20 for temperatures up to 83º C. Owing, however, tothe lack of data other than that corresponding to the invariant points and the complete absence of data for temperatures of 100 to 115°C., and owing to the fact that supersaturation phenomena render unsafe the prediction of the behavior of such a system upon evaporation, it was considered essential to obtain the necessary data by actual evaporation and analysis of the brines thus obtained."

Feb 1, 1931

By James E. Mauser

This report deals with the investigation of a continuous process for producing pure zirconium. It covers the construction, operation, and maintenance of the semicontinuous reactor. The report covers a study of test variables, such as reactor temperature and reluctant charge weights, and evaluates the results, such as billet metal hardness, residual billet salt content, and suitability of a purified billet as a consumable electrode for arc melting. The purpose of this project was to develop an inexpensive and continuous process for producing pure zirconium. The process developed, termed the semicontinuous reactor process, produced billets of compacted zirconium sponge. The metal was produced by reducing zirconium tetrachloride with sodium and magnesium beneath molten byproduct salt. Hydraulic rams at each end of a vertical reaction tube compacted the sponge and ejected it as a billet. These billets were purified by heat under vacuum to remove entrapped salt. The goal was to utilize the purified billet directly as a consumable electrode for arc melting.

Jan 1, 1961

By R. C. Hickman

Manganiferous breccia formations on three properties were prospected by the Bureau of Mines from January to November 1954 in Johnson County, Tenn. The prospecting consisted of diamond drilling, trenching, shaft sinking, and crosscutting. The results of the exploratory work show the manganiferous material to be low-grade, with little vertical extension. The manuscript on this report was completed February 1955. LOCATION The prospects are in Johnson County, Tenn. (fig. 1), within a radius of 12 miles from Mountain City. The nearest railroad terminal is Damascus, Va., 14 miles from Mountain City.

Jan 1, 1956

By John E. Hamak

The U.S. Bureau of Mines estimates the identified helium resources of the United States at 630 Bcf as of December 31, 1990. This includes 295 Bcf of demonstrated reserves, 87 Bcf of demonstrated marginal reserves, and 42 Bcf of demonstrated subeconomic resources. The identified resources include 161 Bcf of helium in inferred and marginal reserves and 45 Bcf in inferred subeconomic resources. The identified helium resources contained on Federal lands are approximately 170 Bcf, including 32 Bcf in underground storage in the Cliffside Gasfield near Amarillo, TX. In addition to the identified helium resources, undiscovered helium resources in the United States are estimated at a most likely volume of 103 Bcf, with a maximum volume of 259 Bcf and a minimum volume of 41 Bcf. Also reported are 43 Bcf of helium in nonconventional and low-helium-content natural gases. Current extraction of helium in the United States occurs mostly from natural gases produced from the Hugoton gas area in Kansas, Oklahoma, and Texas, and the Riley Ridge area in southwest Wyoming. Helium extracted from natural gas in the United States in 1990 was 2.5 Bef. If current trends continue, some shortfalls in helium supply may occur in about 5 to 10 years.

Jan 1, 1993

By M. B. Bransford

A calculation procedure was evolved by the Bureau of Mines for determining the heat-transfer characteristics of dilute gas-solid mixtures in an externally heated tube. The procedure accounts for differences in gas and particle velocities and covers a range of particle sizes. Heat transfer coefficients obtained by the calculation procedure are compared with values reported in the literature.

Jan 1, 1970

By Hillary W. St. Clair

This report describes a mathematical procedure for analyzing size distribution data by the method of moments. The method was applied to Andreasen's data on a variety of grinding mill products. It was found that the observed size distributions could be represented by gamma and beta distribution functions over a wide range of sizes. A computer program, written in BASIC, is described for calculating moments, distribution parameters, and the weight fraction in any size range.

Jan 1, 1969

By Christopher D. Risbrudt

In this comprehensive study of the use of wood products in coal mining, a sample of over 220 mines provided data by questionnaire. Wood use per ton of underground coal was found to vary substantially by mining process and region. In the Eastern Coal region, 1.6 board feet of wood was used per ton of coal, wel above the 0.6 board feet usage per ton in the West. The kind of timber used varied also by Region. Hardwood use is about 40 times greater than softwood in the Eastern Region. There, hardwoods are plentiful, relatively cheap and strong. In the West where softwood forests predominate, softwoods were 2-1/2 times more common in mine wood use than hardwoods. Nearly 80 percent of the wood used in underground coal mines is used in cross bars and props. Nearly 54 million cubic feet of wood products were used in coal mining in the sample year 1979; about twice as much going to underground mines as surface mines. Wood requirements for mining were projected to 2030 for a range of three oil price scenarios. Much greater wood use will be required for greater coal output.

Jan 1, 1982

By M. J. Ferrante

Relative enthalpies of CuBr from 298.15 to 1,301 K were measured at the Bureau of Mines to provide thermodynamic data needed for the advancement of mineral technology. The temperatures of transition were measured by differential scanning calorimetry (DSC) and the standard enthalpies of transition[ (IlH~r) by drop calorimetry. The combined results gave reversible transitions at 657 K with llH~r= 1.10 kcal/mol, at 741 K with lm~r == 0.51 kcal/mol, and at 759 K with an enthalpy of fusion (AH~) of 1.22 kcal/moL ] An anomalous increase in heat capacity preceded the first crystal transition at 657 K. Tabulated values are listed for the standard relative enthalpy, heat capacity, entropy, and Gibbs energy function from 298.15 to 1,500 K. Standard relative enthalpies are also given in equation form and combined with thermodynamic data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation.

Jan 1, 1984

By H. L. Gibbs

Many factors contributed to the decision to build a radiochemical laboratory at the Salt Lake City Metallurgy Research Center to investigate the application of radioactive isotopes and chemical compounds in extractive metallurgy. These reasons included the notable success achieved in biological sciences with radioisotopes, the development of reliable instruments and methods for identifying the isotopes and measuring their activities, and the commercial availability of radioisotopes in a variety of forms and known activities. The paramount reason, however, was the realization that better methods were needed for guiding and quantifying research to resolve the complex extractive metallurgy problems under study at the Research Center. This is the first of a series of reports describing the application of radioisotopes and radioactivity techniques in extractive metallurgy. The report includes a discussion of licensing and safety requirements, a general description of the laboratory and the methods used, a definition of the nature and scope of the research program, and a synopsis of the more important problems studied. Subsequent reports will concern radioactive techniques for solving specific problems in mineral dressing, hydrometallurgy, and pyrometallurgy.

Jan 1, 1960

By H. C. George

This report presents a comprehensive tabulation of lifting cost data collected from oil companies in many different fields. These data were collected during the writer's studies of surface equipment and methods of pumping oil wells, in practically all of the important oil fields in the United States and are based on average operating conditions at 57 groups of properties with a total of 4,497 producing wells. Although lifting cost is only a part of the total cost of producing oil, it nevertheless gives a representative cost figure for purposes of comparison.

Jan 1, 1923

By John P. Capp

The feasibility of simultaneously burning several paths through a coalbed to develop a multiple path underground gasification system was investigated by the Bureau of Mines during two experiments, Boreholes were drilled through the overburden and into the coal and arranged in a circle approximately 50 feet from a central borehole. In the first experiment, in an area which had previously been hydraulically fractured,5 air was injected at the center borehole. The coal was ignited at the other boreholes and the fire fronts traveled toward the center, counter to the flow of air, to backward burn paths through the coalbed. Two paths were linked during the first 5 days of operation. The outlets of these two paths were throttled and air pressure was increased to maintain the flow of air, but no other linkages were made. Fourteen days after the two linkages these two paths were opened and gasification was carried on for 10 days, but with only moderate success. In an effort to overcome operating difficulties air was injected at the peripheral boreholes, and the gases were drawn off at the center borehole. Reversed flow operations continued for 12 days and two more paths linked. The heating value of the gas generally was higher than 100 British thermal units per standard cubic foot (B.t.u. per std. c.f.). Because only four of seven paths linked, however, the entire system could not be evaluated with respect to product-gas output and recovery of energy.

Jan 1, 1961

By A. A. Cochran

The objective of the research was to determine the final distribution of cerium additions to steel, their effect on sulfide inclusions, and the usefulness of radiotracer methods in investigating steel problems. Fifty-gram heats of steel were prepared that contained either cerium 141 and nonradioactive sulfur, or sulfur 35 and nonradioactive cerium. These steels were studied by autoradiography, measurements of their surface radioactivities, optical microscopy, and chemical analysis. Samples of the crucibles were analyzed quantitatively for cerium or sulfur by radioactivity counting methods. The addition of cerium to steel melts reduced the size and number of iron sulfide inclusions in the resulting steel. A significant fraction of the sulfur and most of the cerium penetrated into the MgO crucible during the melting operation, The cerium inclusions in steel were identified as cerium sulfide. Radiotracer methods were found to be versatile and highly sensitive.

Jan 1, 1963

By M. P. Ristenbatt, E. K. Holland-Moritz, K. Metzger

A new post-disaster signalling system for the Bureau o Mines, using through-the-earth EM propagation, was successfully field-tested in the Lake Lynn test mine. Successful detection at an estimated input SNR of -30dB was accomplished using a coherent integration time of 4.46 minutes. The transmitted waveform consisted of a repeating pseudonoise maximal length sequence phase modulating a 1950Hz carrier. The receiver used a sliding-window matched filter, optimal for signal known exactly except for phase and starting time, implemented via a special purpose processor. Parallel processing permits adaptive signalling, where the detection (integration) time is determined by the actual input SNR encountered. This field test demonstrates a trapped miner detection system that is about 36dB more sensitive than a current pulsed system. This increased sensitivity permits some desired combination of increased range, shorter detection time, and reduced transmitter power or antenna-size. The combination of pulse-compression-type-signal, coherent integration, parallel-processing, and output peak-detection algorithms permit implemention of an ultra-reliable detection system. The same combination is compatible with digital Pulse Position Modulation and Emitter position location strategies.

Jan 12, 1983

By Robert H. Mattes

The Lake Lynn Laboratory is a multipurpose mining research laboratory operated by the Bureau of Mines and located in Fairchance, Pa, It consists of both surface and underground facilities. The initial focus of the facility, scheduled for full operation in fall 1982, will be on the problems of fires and explosions in mines. The initial experimental explosion was fired on March 3, 1982. The intent of this document is to provide the reader with detailed information on the physical capabilities of the Lake Lynn Laboratory. Subsequent publications will focus on the capabilities of Lake Lynn as compared with those of other similar facilities worldwide, and a comparison of initial explosion test results realized at Lake Lynn and comparable results from the Bruceton Experimental Mines.

Jan 1, 1983

By K. O. Bennington

The thermodynamic properties of aegirine, of composition [(Na0.869Fe30+7362 Fe20+16Mn0.03Ca0.1121)(A10.141Sil 9738)(06)], were experimentally determined at the Bureau of Mines as part of its efforts to advance minerals technology. The standard enthalpy of formation determined by hydrofluoric acid solution calorimetry is AHf298 = -641.12±0.73 kcal/mol. The standard enthalpy of formation from the oxides is AH298 = -37.136±0.509 kcal/mol. Low-temperature heat capacities were determined by adiabatic calorimetry from 19.1 to 304.6 K. The derived standard entropy is S298 = 38.03±0.14 cal/mol?K. The heat capacity was measured over the range 348 to 1,198 K by differential scanning calorimetry. These experimentally determined data were combined with data from the litera¬ture to calculate the Gibbs energies of formation and equilibrium constants of form¬ation over the temperature range of the measurements. Standard enthalpies of forma¬tion are given as functions of temperature. The standard Gibbs energy of formation at 298.15 K is AGf298 = -600.36 kcal/mol.

Jan 1, 1984

By Robert R. Stein

Occupational noise caused by the rock drills used in mining was investigated by the U.S. Bureau of Mines. Using a large reverberation chamber and an automated drill test fixture (ADTF), the sound power levels of mining drills were measured to determine if there are types of drills that are advantageous from a noise production standpoint. Test results show that while there are not large variations among types of drills, there are still some choices that could produce a positive effect on overall noise exposure. It is also shown that lower noise exposures are possible using larger drills because of higher production rates and better operator positioning.

Jan 1, 2010

By D. E. Wolfson

The Bureau of Mines carbonized 35 coal samples from Logan and Mingo Counties) W. Va., at 900° C using the Bureau of Mines-American Gas Association method, and determined yields of products and physical properties of cokes. Twenty samples represented the No.5 Block, Stockton, Chilton, Cedar Grove, Lower Cedar Grove, Alma, No. 2 Gas, and Eagle beds in Logan County, and 15 samples represented the Coalburg, Buffalo Creek, Winifrede, Cedar Grove, Lower Cedar Grove, Alma, and No.2 Gas beds in Mingo County, W. Va, Chemical analyses were determined for all coals. All coals in both counties rank as high-volatile A bituminous. Most of the coals are chemically suitable for metallurgical coals. Coals with accept-able ash and sulfur contents can be used as major constituents in coking blends with higher rank coal to yield coke with satisfactory properties for blast furnace use.

Jan 1, 1967

By J. H. Field

Results of studies by the Federal Bureau of Mines on a pilot-plant scale for removing hydrogen sulfide and carbonyl sulfide from gas mixtures by the hot carbonate system are given in this publication. Gases containing up to 10 pet. hydrogen sulfide and 48 grains carbonyl sulfide per 100 cu.ft. were treated. In most tests carbon dioxide also was present and was removed simultaneously with the sulfur compounds. Because the rate of absorption of hydrogen sulfide is much more rapid than that of carbon dioxide over a wide temperature range, selective removal of hydrogen sulfide occurred in the bottom section of the absorber near the point of gas entry. Hydrogen sulfide was removed to pipeline specifications with carbonate solutions by using split-stream flows in the absorber and regenerator.

Jan 1, 1960

By Gary E. Sherman

To aid the U.S. Army Corps of Engineers In their Resource Development Navigation Study, the U.S. Bureau of Mines (Bureau) examined the potential for mineral development near ten Alaska port sites. This report presents the results for the first three sites: Bethel, Kivalina (Red Dog), and Omalik Lagoon. The mineral deposits near Bethel are primarily gold and mercury; the nearest deposit being 55 mites away. Because of the expense of constructing and maintaining a road over the poorly drained lowlands, the potential of Bethel as a port site in the near-term is considered to be low. The Kivalina site currently serves the Red Dog mine and has the potential to handle material for similar deposits in the area. Results from a lead-zinc mine model indicate that potential for additional mine development exists in the area. Coal is the major deposit type found near the Omalik Lagoon site. Due to environmental constraints, development of a large-scale mine producing coal for export is considered unlikely. A small-scale coal mine model was used to examine the feasibility of producing coal for regional use. This alternative may be feasible but would require conversion of heating/generating equipment in the area.

Jan 1, 2011

By Kenneth M. Earl

In its program of investigation of deposits of strategic minerals, the Bureau of Mines did some development drilling at the Douglas Deposit in an attempt to find an additional source of supply of copper. The deposit, which was opened in 1878, was worked until 1883 and is reported to have produced between 2 and 3 million pounds of copper. Heap-roasting and smelting and later gravity concentration were employed in ore reduction. Old slag dumps and tailing piles from these operations still remain. In 1917, the American Smelting & Refining Co., purchased the mine, and in June 1918 production was started in a 125-ton mill, using both tables and flotation. The mill was closed December 31, 1918, and soon after the milling plant Was dismantled and removed. The mine has remained idle ever since. The deposit occurs in a mineralized zone that follows the schistosity. The principal metallic minerals are pyrite) chalcopyrite, pyrrhotite) arsenopyrite, sphalerite, magnetite) slight chalcocitel and cuprite. To search for additional ore shoots and to prove the known ore shoot at depth, the Bureau of Mines drilled seven holes, which totaled 2,117.4 feet. No additional ore was developed by this work.

Jan 1, 1950