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By B. J. Arnold, F. F. Aplan

"The captive bubble and sessile drop contact angle techniques have been used to evaluate the hydrophobicity of petrographically identified coal macerals. The magnitude of the contact angle on vitrinite is shown to be a function of coal rank ( %C, %0 and % vitrinite reflectance), increasing with increasing rank to a maximum for low volatile bituminous rank coals then decreasing for anthracite. The least data scatter is found when vitrinite reflectance is used as a rank parameter. Contact angles measured or estimated for other discrete macerals, indicate a variation in hydrophobicity based on coal type. These data correlate well with known flotation results. Coal is a heterogeneous mixture of plant remains and associated minerals that have undergone chemical and physical changes by biological and geological processes. These plant remains form coal macerals, discrete organic entities in the coal which have characteristic chemical and physical properties. As the differing chemical nature of each maceral will affect its behaviour in processes such as carbonization the separation of macerals during coal preparation may provide an important asset in coal utilization.Separation of some of the macerals based on specific gravity has been achieved in the laboratory, and by Sun and Cohen , in a study of two Pennsylvania bituminous coal preparation plants. It was indicated that the lighter exinites report almost exclusively to the clean coal while the denser inertinites are concentrated in the higher gravity fractions. The Longwy-Burstlein process6 took advantage of the difference in hardness or friability of the macerals by using impact breakage followed by screening to remove the more friable vitrain,clarain and fusain. The remaining durain, often high in spore content, was then recrushed. The re-mixed fractions produced the optimum size for obtaining the best coke strength for a particular coal.Separation or concentration of rnacerals by froth flotation largely depends on differences in the hydrophobicity of the macerals. Sun and Cohen 5 . indicated an order of decreasing floatability as exinite, vitrinite and inertinite, while a Russian study (as cited by Brown 7 ) showed that vitrains floated more readily than the duller types. More recently, Hirt and Aplan8 showed that 'pseudovitrinite' floats somewhat faster than does vitrinite while fusinite floats very slowly. Olson and A plan found that vitrinite floated easily while substantial quantities of the non-floated coal contained fusinitic material. Burdon noted that vitrinite is more floatable than semifusinite, and Sarker et a/. 11 have shown that vitrinite is selectively concentrated by froth flotation and oil agglomeration. Sun indicated that flotation, based on his calculated floatability index, should decrease in the order clarain, vitrain, fusain and durain; while Horsley and Smith 13 indicated the decrease to be: vitrain, clarain, durain and fusain. These differences can be attributed to the specific coals used in each study and to the individual macerals composing each coal type within a given coal."

Jan 1, 1989

By William O. Vanderburg

Some mines after passing through the prospecting stage and becoming sizable enterprises still adhere to the development program of the prospect, extending their workings without definite plans. In mining operations where definite structural conditions do not exist, a prearranged layout of mine development is not feasible; but where exploration and preliminary development have indicated the extent and probable limits within which the ore is expected, careful planning of development will result in a lowering of mining costs and a consequent increase is profits. A lack of definite plane for laying out mine workings is one of the contributory factors to unnecessarily high costs. Although this paper deals primarily with the influence of level spacing on mining costs, still other phases of mine development, such as the proper spacing of ore chutes and raises, can be analyzed on a cost basis in a similar manner, as shown herein. LEVEL SPACING The problem of establishing a new level or levels in order to exploit steeply dioping ore deposits and prospect the ground at depth recurs at intervals during the active life of mines. Driving levels is largely "dead work" and therefore costly. By the judicious selection of the proper level interval after balancing the opposing factors involved in the problem, a considerable saving in mining costs can be effected. Although much has been written in regard to the various methods employed in ore extraction, mining literature is still incomplete in regard to the factors-influencing level spacing at various mines. Level spacing involves procedures not lending themselves readily to description, and, moreover, it is a phase of mining operations that is apt to escape criticism, because only those in close contact with the operations are equipped with the necessary familiarity with the conditions to pass judgment.

Jan 1, 1932

By W. M. Nabors

As part of a program to promote conservation and efficient utilization of petroleum resources, Bureau of Mines engineers at the Morgantown (W. Va.) Petroleum Research Laboratory are studying secondary oil-recovery projects in the Appalachian region. The increasing demand for petroleum and its products and the increasing cost of exploratory drilling tend to emphasize the importance of improving the recovery of oil from known petroleum reserves. Published reports setting forth the pertinent facts of these operations may help others to profit by the experience. This report presents the results of a study of secondary-recovery methods used in West Virginia by the Piedmont Oil and Gas Co., the Ryan Oil Co., and Water floods , Inc., on their Roane County leases in the Walton and Clover Rush Run pools. The principal oil-producing horizon underlying the area studied is the Big Injun sand, at approximately 2,000 feet. The sand is often referred to as blanket sand because it underlies much of the State and is oil-productive in many localities. Most of the pools in the area were discovered during 1907 to 1910 and were similarly developed and operated.

Jan 1, 1960

By David C. Oyler

The U.S. Bureau of Mines studied the interaction of longwall shield supports and adjacent strata at the Meigs No. 31 Mine in southeastern Ohio. Twenty-three legs of twenty shields at midface were instrumented with pressure transducers and monitored for 11 weeks. During the project, leg setting pressures were reduced twice to determine the effect of setting pressure on shield-strata interaction. No correlation was observed between setting pressure and leg loading rates. The shield loading profiles were consistent with a model in which the roof consists of two zones, a thin immediate roof loading the shields well below the typical setting force and a main roof zone essentially supported by the coal and gob and loading shields through its convergence. This model was used to develop an equation for estimating average loading rates at the site. The only variable of the equation is time, and the equation consists of an exponential term to account for the immediate roof loading and a linear term to account for main roof loading. The equation gave good correlation with average loading rates, but the variation in loading from cycle to cycle was too great for the equation to give good predictions of individual cycle loading rates.

Jan 1, 2010

By H. W. St. Clair

In about 1930, Degussa applied for a patent on a process for the of oxides, carbides, sulfides, and other nonmetallic impurities by filtration in the molter state. The filtering media listed were wire screen, coke, and ceramic materials, and quartz. It was also suggested that filtration might be combined with chemical reaction between the metal and the filter medium or that might be added to the system. No patent was granted on the general scheme, but several years later a patent was granted on a continuous process purification of crude light metals, especially or alkali earth and their alloys. The melt was stirred at 1 temperature at which the impurities (such as oxides and salts) remained solid and the metal was drawn through a filter tube. The impurities collected under the filter and were removed by a screw conveyor. Crude sodium was purified by this process in Degussa's Knapsack plant. During the last war, when the refining of scrap became a very urgent Problem in Germany, experimental investigations were extended to separation of other metals and metallic compounds by filtration. Preliminary experiments seemed to confirm the opinion of Dr. L. Weiss that the principles of wet chemical filtration might be applied to a great extent in the purification of metal and alloys.

Jan 1, 1949

To provide longwall operators with a method to predict methane emissions from panels with increased face width.

Jan 1, 1997

By J. F. Barkley

At the request of several Federal agencies, tests were conducted on a relatively recent type of anthracite -burning equipment named the Anthratube. This device, rated at 130,000 B.t .u. per hour, was designed to burn Pea-size anthracite automatically for steam or hot-water house heating and for domes-tic hot -water supply. ACKNOWLEDGMENTS The helpful cooperation of the Anthracite Institute and the manufacturers of the equipment, Axeman-Anderson Co., Williamsport, Pa., is gratefully acknowledged.

Jan 1, 1953

By T. Kessler

As part of a respirable mine-dust research program at the U.S. Bureau of Mines, spark-source mass spectrometry has been used for the semiquantitative determination of trace elements (200 ppm weight or less) in raw coals. In addition, several minor and major elements have been determined using this technique. Sixty-four elements ranging in concentration from 0.01 to 41,000 ppm weight were determined in one anthracite, two mvb, four lvb, and six hvab raw coal samples. The samples represented 10 coal seams located in Pennsylvania, West Virginia, Virginia, Utah, and Colorado.

Jan 1, 1973

By R. R. Wells, G. M. Potter, A. O. Ipsen

This paper gives results of laboratory and pilot - plant investigations of concentration of western manganese ores during the Bureau of mines manganese-development program initiated in December 1940. The data summarize results obtained from laboratory investigation of concentration of ores from three properties in southeastern Arizona . The high - grade Gray - claims lot B ore , a product of hand sorting , is marketable directly or after sintering treatment . Intermediate - grade lot A selectively mined ore would be marketable after sintering as a plus 35 percent manganese produce , but gravity concentration methods were employed effectively to produce high - grade manganese concentrates with over 80 percent recoveries . Complex association of fine - grained manganese oxides , calcite , and fluorite in a siliceous ground mass limited the recovery of high-grade manganese concentrates obtainable from the low-grade Pyrolusite -group ore . A recovery of 63.7 percent of the manganese was made by flotation in a concentrate that sintered to plus 48 percent manganese grade . The low-grade Davis ore contains iron and manganese oxides too intimately associated to permit production of marketable manganese products . However , good rejection of calcite gangue was obtained by flotation , and the enriched manganese - iron product might have value as a spiegeleisen ore .

Feb 1, 1946

By Sara J. Davenport, Genevieve Morgis, J. J. Forbes

"This circular is part III of a series of papers reviewing the literature on air conditioning in mines, with particular reference to the health, safety, and efficiency of miners.4/ It deals with theoretical and practical methods of conditioning air in mines to correct or alleviate the health hazards described in parts I and II and discusses the results attained by some of the systems now in use in various-parts of the world.The principal conditions to be corrected or alleviated are the chemical qualities of mine air (especially when contaminated with toxic and noxious gases and dusts) and the physical qualities (abnormal mine temperatures and humidities) that emanate from various sources in underground workings. Air motion and barometric pressure are physical qualities also to be considered.From the standpoint of health, knowledge of the composition of the air, or atmosphere, in mines and other underground operations is of prime importance. Suitable control measures or plans of procedure to combat or eliminate the hazards from contaminants must be based upon accurate information obtained by the selection and use of proper methods of sampling and analyzing mine atmospheres (1).5/Conditioning air is one of the most essential factors to be considered in any underground workings, not only from the standpoint of health and safety but also with regard to efficiency and productivity. Without modern air-conditioning, the war's great demand upon the copper mines could hardly have been met, as the mechanical refrigeration cooled off sweltering holes in less than a month, whereas in the past it was standard practice to blow air through the tunnels for 3 years or so until they were cooled.This paper discusses methods of determining the chemical and physical qualities of mine air and their control. Briefly, the following points are presented:"

Oct 1, 1949

By M. M. Fine

The results of tests on oxidized lead ores from two properties are reported in this paper. The investigation was on a small laboratory scale only; no pilot-plant tests were made. One sample, from the Magajupa Mining Co., near Duenweg, No., contained coarsely crystalline and disseminated galena and cerussite, so both tabling and flotation were considered in the beneficiation. By this treatment of an ore containing 11.5 percent lead, a recovery of 79.5 percent of the lead was made in a concentrate containing 73.3 percent lead.

Jan 1, 1948

By G. L. Gates

The Bureau of Mines studied the scales formed in producing wells in the Wilmington field, California. The scales were primarily barium sulfate and resulted from the mixing of injected sea water and formation waters; there was excess sulfate in the injection water and the formation waters contained appreciable barium. After breakthrough, the produced brines were supersaturated with barium sulfate. Laboratory tests indicated that barium sulfate precipitated quickly When the supersaturated brines were agitated with crystals of barium sulfate and fairly rapidly when more sulfate solution was added. Precipitation occurred slowly on standing or under nonturbulent conditions. Both the apparent and equilibrium solubilities of barium sulfate in these brines were determined and compared with equilibrium solubilities in distilled water and sodium chloride solutions.

Jan 1, 1965

By FRANCIS FEEHAN

Safety first is no longer merely a motto ; in some industries and in some parts of the mining industry it is an accomplished fact . In connection with the National Safety Competition of 1928 in which 284 mines and quarries participated , 42 plants were operated without a single lost - time accident . The winning company in the bituminous group had an accident severity rate of 0.053 per thousand man hours of exposure . Excellent safety records of various kinds are becoming more and more frequent , and the indication is that in reality safety is first in many mines and qquuaarrrriieess .. The safety achievements in the Stewart mine of W. J. Rainey , Inc. , are unusual even among mines winning awards in the competition .

Apr 1, 1930

By J. S. Kennedy, R. G. Omeara

Beryllium is a strategic metal of ever-increasing peacetime importance because of the unusual properties of beryllium-copper alloys. These unusual characteristics are the combination of high strength and hardness, high fatigue resistance, and high wear resistance in alloys that have the corrosion resistance of copper. The principal industrial source of beryllium is the mineral beryl, a beryllium-aluminum silicate that occurs in pegmatites associated with quartz, feldspar, mica, and smaller amounts of various accessory minerals. The beryl is usually recovered in processing the pegmatites for the recovery of some of the other mineral constituents. Pegmatite deposits are found in various parts of the United States, but those in the Black Hills of South Dakota are the source of most of domestic production. The beryl marketed from the South Dakota pegmatite deposits occurs as coarse crystals, which are obtained by hand sorting. These pegmatites also contain other valuable minerals.

Jan 1, 1948

By D. S. Burgess

A commercially available Halon 1301 extinguisher has been evaluated as part of an explosion-suppression system for use in coal mines. Studies were made both of the dispersion pattern of the Halon 1301 at an initial pressure of 280 psig, and of the efficacy of this suppressant against 9.5 percent methane-air flames. These flames were quenched successfully only when the suppressant was applied before the fireball diameter exceeded 18 inches.

Jan 1, 1971

By R. R. Sayers

Under compuision of the present urgency to implement the President's promise to make the United States the arsenal for the democracies there is a tendency to demand a relaxation of restrictions on hours of labor and to speed up all industrial processes. The pressure is the more insistent with growing realization of the importance of the time factor in the success- ful prosecution of the war effort and the lack of skilled workers due to (2) operation of the draft, lack of an apprentice system in industry, and loss of skill by workers unemployed for long periods during the depression. With "total" war such as it is today the probabilities are that everyone will be required to exert greater effort (in many instances in activities to which they are unaccustomed) for longer periods than ever before has been necessary. The question arises, "What will be the aftereffects as well as the immediate effects on health, safety, and efficiency?" A review of the literature leaves the impression that this question has not been an- swered completely, especially as regards the ultimate effects. Mechanization, speeding up of industrial processes, mass produc- tion, and the small industrial concerns present many problems to indus- trial medicine. Does the tendency to expect the worker to produce at full speed all the time he is on the job decrease the effectiveness of the shorter working hours and cause undue fatigue, loss of efficiency, and increased accident proneness? The answer is important as this condition is likely to be intensified by the exigencies of the present emergency. According to Viteles (1)3, The increased tension under such conditions of work appears to offset the savings in muscular force made pos- sible by the machine. The tension, the speed, the subject- tion to specialization of work and a rhythm uncontrolled by the individual promote fatigue, characterized by a "decrease in the power to work, a decrease in pleasure taken in work, and a decrease in the enjoyment of the hours spent away from work."' The crowding of workers in temporary structures without proper provision for comfort and health may add greatly to the general fatigue factors already present in many industrial establishments. In 1932 Lockhart (2) stated that the production and maintenance of a healthy, satisfied industrial population is the most urgent necessity, involving problems so serious as to constitute a national task too great economically to be relegated to industrial concerns. If this was true in 1932, it must be doubly so today.

Jun 1, 1942

By S. H. Ash

The Pennsylvania anthracite-mining region is the only one in the world of major magnitude. As the deposits of anthracite in the United States are limited virt113.lly to Pennsylvania, the difficulties of this industry have been commonly considered a State rather than a national problem. However, there is also national interest in the conservation and wise utilization of all fuel resources and in the control of interstate waterways. The anthracite industry is confronted with the very se:;-ious :problem of accumu.lation of water in many of the mines. This problem must be solved soon if progressively higr-er mi~ing costs are to be avoided. The water proble~ cannot be solved by the operating compa,nies without State or Federal aid, or both, owing to the magnitude of the work requir~d, diversity of interests of the coal ana surfa.ce ovmerships, hazard to the whole mining community, and interests affec~ed outside the mining region. The cost of abati~ the ever-increasing_surface seepage to mine workings and of handling this seepage once it }3s occurred is beyond the economic resources of most ope~ating ma.'18.gements. The data in this paper giving the high lights of the water problem and indicating what appears to be a step in the right direction are based upon observations made during the past year that the industry desires and believes it is to the npublic interesttr to keep mine workings free of flood end surface waters.

May 1, 1941

By Van E. Shaw

Three comparatively simple, efficient, and rapid extraction methods for the dissolution of yttrium and rare-earth elements from a euxenite carbonate residue have been developed, using dilute sulfuric acid as the solvent. Extraction processes have resulted in yields of 98+ percent of the total rare-earth elements and yttrium contained in the residue and have given preliminary separation between the cerium-group and the yttrium-group rare-earth elements. Extraction procedures presented are: Procedure 1. -The recovery of total rare-earth elements and yttrium by a cold dilute sulfuric acid leach at a pH of 2.5. Procedure 2. -The recovery of yttrium and yttrium-group rare-earth elements by leaching with dilute sulfuric acid at 125° F. and a pH of 3.0, with subsequent recovery of the cerium-group rare-earth elements by a cold dilute sulfuric acid leach of the residue at a pH of 2.5. Procedure 3. -The recovery of the total rare-earth elements and yttrium by fractional leaching as in procedure 1, followed by boiling the sulfate solution, which precipitates the cerium-group rare-earth elements and leaves the yttrium-group rare-earth elements in solution.

Jan 1, 1959

By F. S. LOTT, I. S. CULVER

The number of petroleum refineries in the United States decreased during 1948 from 390 to 375, continuing the trend to fewer units of larger individual capacity that has persisted since the peak in number of plants was recorded on January 1 , 1936. Large - scale construction of new processing facilities continued through 1948 with a resultant gain in daily crude-oil throughput capacity of installed equipment from 6,034,252 barrels on January 1 , 1948 to 6,438,995 barrels on January 1 , 1949. The capacity of the average refinery to process crude oil therefore increased during 1948 from 15,472 barrels daily to 17,171 . The principal areas of expansion of facilities were the strategic seaboard districts of the Texas and Louisiana Gulf Coast and the East Coast , and the important Indiana , Illinois , Kentucky, etc. , district that supplies markets in the upper Middle West region . These four districts accounted for 79 percent of the total new capacity added in the United States in 1948. The relatively small petroleum- refining industry of the Other Rocky Mountain district experienced a vigorous expansion in 1948 that will continue during 1949 . Capacity building on January 1, 1949 , amounting to 341,500 barrels daily, was 25,750 barrels lower than the comparable total on January 1 , 1948, but was the second highest on record . New construction was heavily concentrated in the Texas Gulf, East Coast , and Indiana -Illinois

Sep 1, 1949

By O. C. Blade

A comparison of certain properties of the commercial aviation gasolines produced in the United States during October 1949, 1950, and 1951 is presented in table 1, the 1951 data being average values from tables 3 through 6 of the present report. Trends in the average values of certain characteristics of these fuels may be seen in figures 1 through 4 which also indicate the minimum and maximum values. As may be observed, with the exception of changes in kinematic viscosities, the properties of commercial aviation gasolines have not varied greatly during recent years. A list of aviation-gasoline survey reports published by the Bureau of Mines is given on page 6. A summary of the average values of the properties on jet fuels is shown in table 2.

Jan 1, 1952