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By Sandeep K. Sharma

The U.S. Bureau of Mines has been investigating new techniques to improve the of mineral to recover water lost in the waste slurry, and to produce dewatered solid dewatering s suitable for disposal. As part of this investigation, a study was undertaken to investigate the feasibility of dewatering Alaska placer effluent. Based on the laboratory tests, preliminary field tests were conducted on three placer mines in Alaska. At these mines, the water recovered from the placer effluent (250 to 23,000 NTU) exhibited turbidities of 20 to 240 NTU. In the second year of the project, a large-scale dewatering unit was set up at a mine located in the Livengood district. The feed, at flow rates up to 935 gpm, was mixed with dilute PEO solution in a flexible plastic hose with and without static mixers. Feed to the dewatering unit generally ranged between 300 and 26,500 NTU and required PEO dosages of 0.02 to 0.14 lb per 1,000 gal to produce water from the screen underflow with turbidities of 20 to 50 NTU. During this period, a small unit was also operated at Dow rams of 10 to 25 gpm at sewn sites throughout Alaska, with the effluent from four of the sites being dewatered successfully.

Jan 1, 2010

By J. B. Littlefield

[A rulp has i~c+:r. ilrsi i,nsd Lo O~JPY:L~ e the mid~ol Llf;pin.5cr rll~!-t-.cxny)lin:: apparatus recently c',ov~-lo.pe;t by tL1e '.liro:ul of !dines- For th-is pilryoac, a po?.-iti~rs-nct.i?~. pvrni? t:,.;~t v:i.l.'l. :.-,,- #?,n c-noot'fl ;L flow nc possiY,].c? is dcni?.oYle. Flota.lS:r vnnc\-t:rre 1jl:~l~l: zrt iln~;xtJsY:or (2s thc:; n1lr.t ke tvrned at h ityh spet.d for rT:oot,c, o;?ey,;ltiori., ~nd at hi:,h s~ee(' the c8n:xcity oi' the s-n:r.llest piqt ott:~ir?:zk?e Is too la~-~:c. nir crrn'rle bler! in nt the intn?~, but t,he mm;nt o nor.;: l.o'q7r ir.:,l soon t ire:. the oyernt or]

Jan 1, 1938

By J. B. Littlefield

[A rulp has i~c+:r. ilrsi i,nsd Lo O~JPY:L~ e the mid~ol Llf;pin.5cr rll~!-t-.cxny)lin:: apparatus recently c',ov~-lo.pe;t by tL1e '.liro:ul of !dines- For th-is pilryoac, a po?.-iti~rs-nct.i?~. pvrni? t:,.;~t v:i.l.'l. :.-,,- #?,n c-noot'fl ;L flow nc possiY,].c? is dcni?.oYle. Flota.lS:r vnnc\-t:rre 1jl:~l~l: zrt iln~;xtJsY:or (2s thc:; n1lr.t ke tvrned at h ityh spet.d for rT:oot,c, o;?ey,;ltiori., ~nd at hi:,h s~ee(' the c8n:xcity oi' the s-n:r.llest piqt ott:~ir?:zk?e Is too la~-~:c. nir crrn'rle bler! in nt the intn?~, but t,he mm;nt o nor.;: l.o'q7r ir.:,l soon t ire:. the oyernt or, ]

Jan 1, 1938

By D. K. Deardorff

The hafnium-vanadium phase diagram was constructed within an estimated accuracy of ± 10° C and ± 2 wt pct composition. Alloys for investigation were melted under an atmosphere of purified helium by nonconsumable tungsten-electrode arc melting on a water-cooled copper hearth. Melting points were determined by optical pyrometer, and the remaining phase relationships were investigated by metallography, thermal analysis, and X-ray diffraction. The existence of a face-centered cubic intermetallic compound HfV2 (a = 7.38 A) was confirmed. A eutectic reaction occurred at 20 wt pct vanadium and 1,395° C to yield HfV2 and 8 solid solution. HfV2 melted incongruently by a peritectic reaction at 1,480° C, and the 3 solid solution decomposed eutectoidally at 1,165° C and 6 wt pct vanadium to yield HfV2 and a solid solution. The eutectoid, the eutectic, and the peritectic isotherms extended from 1 to 36.3 wt pct vanadium, from 8 to 36.3 wt pct vanadium, and from 26 to 89.5 wt pct vanadium, respectively. Terminal solid solubilities of hafnium in vanadium at 1,300° C and of vanadium in hafnium at 1,100° C determined to be about 3 and 1 wt pct, respectively.

Jan 1, 1965

By Henry E. Hilliard

The production, use, and emission of vanadium in the United States has been traced for the year 1991. Consumption was 3,300 tons2, exports 1,285 tons, and imports 2,013 tons. About 98% of production was used in metallurgy; the remainder was consumed in chemicals, including catalysts. Total emissions to the environment in 1991 were estimated at about 3,100 tons, including emissions due to the combustion of coal and petroleum products. Emissions resulting from the production of ferrovanadium were 130 tons, and emissions from the production of steel about 6 tons. Dissipative losses, defined as losses that occurred during use or as a result of wear, were estimated to be no more than 3 tons. Disposal losses were estimated to be about 4,600 tons. Most of these losses were steel products that contained 0.1% or less vanadium and mayor may not have been recycled. When these products are recycled by the steel industry, vanadium ends up in the steelmaking slag and does not return to vanadium use cycle. Worldwide emissions due to anthropogenic and natural sources were briefly reviewed. It was concluded that industrial emissions were about three times greater than emissions from natural sources.

Jan 1, 1994

By Ben E. Lindsly

The study of "bottom-hole samples follows in natural sequence the study of samples obtained under high pressures at the well heads of flowing wells. The principal object of this phase of gas-solubility research, started actively in January, 1930, was to gain a more accurate knowledge of the physical and chemical characteristics of the oil-gas mixtures that exist in natural reservoirs.. In possession of actual data regarding the condition of the oil; the quantity of gas liberated from solution upon dimunition of pressure; and the relative volumetric proportions of gas to oil at various pressures throughout the flow string in a well, it should be possible to predict, with a fair degree of accuracy, That physical changes these mixtures would undergo throughout the life of a pool. Such information not only is important in designing flow strings in flowing Tells but is important also in solving problems relating to pumping efficiency and the power required for pumping. Although certain fundamental data were obtained in the study of samples taken at the well head, "bottom-hole" samples are more representative of subsurface mixtures of oil and gas because they are obtained at reservoir temperatures, and before the oil has had the opportunity of intermingling with extraneous gas; that is, gas which either was not in solution originally, or which was liberated from solution at higher pressure, and later became mixed with the original undissolved gas.

Jan 1, 1933

By M. W. Von Bernewitz

The Bureau of Mines receives frequent requests for information on the treatment of mercury ores, but as its own and almost all other publications on mercury are out of print, the Bureau has prepared this circular on the metal for the prospector and operator of small mines and plants. Mercury, commonly though improperly termed ?quicksilver?, is the only common metal that is liquid at ordinary temperatures. Mercury is used in the amalgamation of gold and silver, in power boilers, explosives, friction-less bearings, laboratory apparatus, lamps, medicine, paint, rectifiers, and for ?silvering.? The last mentioned is being superseded by silvering with silver. The use of mercury boilers may increase when they are thoroughly understood, but amalgamation is -being replaced to some extent by the use of corduroy and other collecting mediums, such as jigs and flotation cells.

Jan 1, 1937

By William H. Lesser

A recent survey of pumping plants in the anthracite region of Pennsyl¬vania showed that more than 90 percent of the pumps in use are the horizontal centrifugal types (1).2/ This report on the design and operation of centrifugal pumps should be helpful to engineers of the region who must select pumps that are best suited to particular pumping conditions in anthracite mines. Before a centrifugal mine pumping plant is designed, the special features of the pumps that may be used should be considered, especially when low repair costs and continuous operation during flood periods are prerequisites, and when acid mine water is to be pumped. Two important advantages of a centrifugal pump are that the flow is continuous and that it can be throttled without developing excessive pressure or overloading its driving unit.

Jan 1, 1950

By C. M. Flynn

The solubilities of sideronatrite [Na2Fe(OH)(SO4)2?3H20] and ferrinatrite [Na3Fe(SO4),&apos;3H2O] were determined by the Bureau of Mines in the Na2SO4-Fe2O3-H2SO4-H20 system at 25°, 40°, 60°, and 90° C. The solution compositions investigated ranged from Na+-Fe&apos;+ mol ratios of 0.5 to >100 (Na2SO4 saturation) and H+ -SO4 2-mol ratios of 0 to 1. O. The results are presented in the form of contour plots. The solubilities were determined by seeding supersaturated solutions of known composition with the specified solid phase to precipitate a substantial amount of solid. Water was then added in small portions to the solution until the last portion of the solid dissolved. Equilibration times at 25°, 40°, 60°, and 90° C were 2 days, 1 day, 8 to 16 h, and 2 to 4 h, respectively. The accuracy of the solubility data is estimated to be 1 to 2 pet. Low iron solubilities of <0.36 pct Fe2(SO4)&apos;, or 1 g Fe/kg solution, were obtained in solutions containing at least 8 pet Na2SO4 in the absence of H2SO4 or a total of at least 36 to 38 pet Na2SO4 + H2SO4 at high acidity. The filterability and density of sideronatrite and ferrinatrite in comparison with other iron compounds are reported. These compounds are suitable vehicles for iron removal in Na2SO4-rieh solutions. Additional solubility data on the Na2SO4-H2SO4-H20 system were also obtained.

Jan 1, 1987

By Graham W. Marks

The general positions of the absorption maxima of aqueous solutions of the violet and green isomers of chromic sulfate the visible spectral region have long been known, but, to the knowledge of the writer, no comprehensive studies have ever been made. To gain further knowledge concerning these inorganic complexes and to investigate the possibilities of developing an analytical method for determining the concentrations of the violet and green isomers in a mixture, a more complete investigation was made in the spectral range from 325 to 850 millimicrons.

Jan 1, 1951

By R. V. Ramani

In this the available information friction factors and leakage report, on characteristics are reviewed and summarized. The use of Penn State Mine Ventilation Simulator (Volumes II and III of the Final Report) to analyze the sensitivity of the ventilation system to the changes in leakage and friction factors is discussed with examples. In simple ventilation systems, the results of changes in leakage and friction factors can be easily solved and explained by the laws of air-flow. In complex systems, with fixed quantity branches and multiple sections, the effect of changes in leakage and friction factors cannot be generalized. This study points out the importance of good input data for obtaining reliable information from computer analyses and demonstrates the application of simulators to analyze the effectiveness of ventilation systems. An extensive bibliography on friction factors, leakage characteristics and ventilation economics is included.

Jan 1, 1977

By B. W. Madsen

The Bureau of Mines conducted a large-scale (6.4 t), long-term (2,165 days) test to gain a better understanding of the leaching characteristics of chalcopyritic ores. An ore sample containing 0.77 pct Cu was leached in a fiberglass column by downward percolation of acidified ferric sulfate solutions. Three sets of leaching conditions were investigated: (1) ambient temperature leaching, (2) elevated temperature (50° to 60° C) leaching, and (3) elevated temperature leaching after inoculation with thermophilic bacteria. Leaching at ambient temperature resulted in a copper extraction rate of 0.44 pct per 100 days. Increasing the temperature to 50° to 60° C resulted in decreased activity of natural mesophilic bacteria, and the leaching rate decreased to 0.22 pct per 100 days. The pH was lowered from 2.0 to 1.6, and nutrient solutions that contained thermophilic bacteria were added. This procedure resulted in an increase in the ferric-to-ferrous iron ratio and an increase in the copper leaching rate. However, the increased leaching rate was not sustained, and 120 days after inoculation the bacterial activity declined, the ferrous iron content increased, and the copper leaching rate decreased.

Jan 1, 1983

By George T. Faust

The petrographic microscope plays an important role in the mineral dressing of nonmetallic materials. Petrographers and mineral technologists have evinced an interest in the technique developed, specifically, for mineral-dressing problems. The following dissertation makes the informa¬tion more generally available. ACKNOWLEDGMENTS The authors are indebted to O. C. Ralston, chief engineer, Nonmetals Division, and to Will H. Coghill, supervising engineer of the Southern Experiment Station for a critical reading of the manuscript. They are also indebted to their colleagues for technical information obtained in the course of cooperative work, in particular to J. B. Clemmer for the use of the data on fluorite.

Jan 1, 1940

By K. B. Rojiani

Surface mining activities disturb large tracts of land resulting in the potential for greatly increased downstream sediment loads. The Surface Mining Control and Reclamation Act of 1977 places increased emphasis on the protection of the environment from the adverse effects of surface mining operations. Surface mining activities must be planned to minimize disturbance to the hydrologic balance, erosion and sediment contributions to receiving streams. Sediment ponds must provide a sediment storage volume equal to the accumulated sediment volume from the drainage area as determined by the Universal Soil Loss Equation (USLE) or other empirical methods established by the regulatory authority. It has thus become extremely important for the mining industry to secure more accurate estimates of potential erosion losses and sediment yield. Accurate estimates of sediment yield are required for the planning, design and successful operation of sediment control systems such as detention ponds and other alternative control structures and for evaluating the effectiveness of land management practices. The principal soil loss prediction procedure available for use is the LISLE. The USLE procedure is inadequate for use in predicting soil loss from surface mine regions for a number of reasons. These include: 1. The USLE was developed to estimate average average annual loss from agricultural soils. It cannot predict accurately soil loss for specific storm events. In surface mine regions a major portion of the soil loss occurs during the initial six months to one year of active mining. Accurate estimates of soil loss over short periods are thus required for the design of control structures. 2. The slope length and gradient factors used in the USLE were obtained from data or cropland having slopes ranging

Jan 1, 1983

By Erle C. Donaldson

Bureau of Mines engineers examined the chemical and biological treatment of sewage water designed in one case for reuse and in another for subsurface injection. In the first case discussed, approximately 6 million gallons per day of sewage are treated by the activated sludge process followed by tertiary treatment that includes ion exchange. The renovated water is used in the industrial complex. Liquid industrial waste is sent to a waste disposal facility where it is treated for injection into a deep subsurface formation. In the second case, a community of 3,000 people is using a lagoon sewage treatment system followed by subsurface injection of t- treated effluent. Subsurface disposal is used to avoid growth of algae and weeds in a nearby lake to which the treated effluent was originally discharged. The renovation of municipal water for reuse provides a source of water for industries in a semiarid region and may also provide a source for domestic use in densely populated regions where domestic water requirements have priority over industry needs. In addition both waste treatment systems provide examples of the use of subsurface waste disposal to avoid pollution of surface streams.

Jan 1, 1971

By L. L. Oden

The Bureau of Mines is conducting research to develop methanation catalysts for converting synthesis gas derived from coal to synthetic natural gas. This report describes a method to prepare supported Raney nickel coatings by dipping screen-covered nickel sheet in molten aluminum-nickel alloy. Coatings were formed at 1,050° C that were comparable in thickness, composition, microstructure, and catalytic properties to flame-sprayed commercially pre-pared Raney nickel. A molten salt comprising cryolite-8 wt-pct LiF was employed over the molten metal bath to clean and preheat the substrates, to protect the metal bath from oxidation, and to heattreat the coated specimens. Immediately following heat treatment, specimens were quenched to 700° C in a molten salt bath containing CaC12-34.5 wt-pct NaCl, which also functioned to remove the insoluble occluded fluoride salt.

Jan 1, 1976

By Alan A. Campoli

OD March 20, 1989, a meeting was held at the U.S. Bureau of Mines Pittsburgh Research Center at the request of Senator Pete V. Domenici of New Mexico. The purpose of the meeting was to engender a technical relationship between the National Laboratories and the minerals industry. During the meeting, the Director of the Bureau of Mines, T S Ary, suggested that since the Bureau is the focal point for mining research in the United States, it would be appropriate for the agency to act as the liaison between the National Laboratories and the minerals industry. As the first step in this process, the author was selected to perform a 6-month investigation to better define the proper role of the Bureau in this area. As part of the investigation, the mining and mineral-related technology available at 21 major U.S. Department of Energy (DOE) Research Laboratories was reviewed. It was assumed that the broad range of scientific and technical areas covered DOE research would provide fertile ground for mining-related technologies. It was hoped that the applicability of DOE research to this liaison effort would be indicative of Federal laboratories in general.

Jan 1, 2011

By Timothy J. Rohrbacher

This report presents results from an ongoing U.S. Bureau of Mines study defining domestic coal reserves. Examinations of five 7 ½ -minute central Appalachian quadrangles have been completed to date. Only 26.4%, 5.0%, 6.5%, 8.2%, and 4.2% at the coal resources remaining in the Matewan, Boltsfork, and Hoskinston, KY; Vansant, VA; and Beckley, WV quadrangles, respectively, constitute economically recoverable reserves. An evaluation of the coal mining industry&apos;s impact on the economy of Pike County, KY, wherein the Matewan quadrangle is located, was also completed in order to provide a basic understanding of the influence of coal mining on the local economy. Results show that coal mining is the only major income producing industry in Pike County, accounting for about 46% of the county&apos;s income, and 21% of the total available employment, in the base year 1990. If similar results are found in subsequent investigations, a strong argument can be made that traditional coal producing regions may soon be experiencing resource depletion problems far greater and much sooner than previously thought. This will affect not only the coal industry but, given the obvious dependence of Pike County&apos;s economy on its coal mining industry, the entire social and economic infrastructure of large areas.

Jan 1, 1994

By T. L. Turner, Daniel T. Rogers

As part of a program to investigate technology for the extraction of studied HNO3 alumina from abundant domestic ores , the Bureau of Mines leaching of calcined Georgia kaolinitic clay . In this investigation , iron impurities were removed from the aluminum nitrate pregnant leach liquor by solvent extraction , and the purified liquor was evaporated to prepare a suitably concentrated crystallizer feed liquor . Aluminum nitrate nonahydrate was crystallized from the liquor to separate the aluminum from undesirable trace elements and excess water . Continuous crystallization at 40 ° C in a pilot plant vacuum evaporative unit was performed for 5 days to observe the effects of impurity buildup under minimum bleed- stream conditions . Liquor feed rate was 26 lb/h and AAll (( NNOO33 )) 33..99HH22O0 ((AANNNN)) crystal production rate was 17 lb/h . Fe 203 and Cr203 were not effectively separated from the crystals , and P205 , MgO , and K20 impurities must be removed by recrystallization . Other impurities did not excessively contaminate the crystals . Washing the crystals with water or aqueous HNO3 gave an equivalent increase in crystal purity levels by displacing mother liquor . Theoretical equations , applicable to any continuous evaporative crystallization of developed to produce material balances for engineering ANN , were applications .

Jan 1, 1965

By Ben E. Lindsly

The study of "bottom-hole&apos; samples follow,-is in natural sequence the study of samples3 obtained under high pressures at the well heads of flowing wells. The principal object of this phase of gas-solubility research, started actively in January, 1530, was to gain a more accurate knowledge of the physical and chemical characteristics of the oil-gas mixtures that exist in natural reservoirs. In possession of actual data regarding the condition of the oil; the quantity of gas liberated from solution upon dimunition of pressure; and the relative volumetric proportions of gas to oil at various pressures throughout the flow string in a well, it should be possible to predict, with a fair degree of accuracy, what physical changes these mixtures would undergo throughout the life of a pool. Such information not only is important in designing flow strings in flowing wells but is important also in solving problems relating to pumping efficiency and the power required for pumping. Although certain fundamental rata Mere obtained in the stud of samples taken at the well head, "bottom-hole" samples are more representative of subsurface mixtures of oil and gas because they are obtained at reservoir temperatures, and before the oil has had the opportunity of intermingling with extraneous gas; that is, gas which either was not in solution originally, or which was liberated from solution at some higher pressure, and later became mired with the original undissolved gas.

Jan 1, 1933