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By Alexander May

This report describes a new method of weighing based upon observing the apparent weight of an object ill two separate pure gases. The method is presented in terms of experimental data which prove its soundness, but does not attempt to show the maximum accuracy possible with this technique. The new method incorporates the underlying principle that the apparent weight of an object is a linear function of the density of the atmosphere in which the object is weighed. The coefficients of this linear function are the true mass and volume of the object. From this functional relationship the true mass and volume of the object may be determined.

Jan 1, 1970

By Clarence Karr

In 1955 the Federal Bureau of Mines established a low-temperature tar laboratory at its new Appalachian Experiment Station in Morgantown, W. Va. The objective of the laboratory is to investigate the yields and chemical and physical properties of tars from low-temperature carbonization of coal, to investigate means of economically upgrading these tars, and to make available to industry and the public essential data for increasing coal utilization through the establishment of a new coal-chemical industry, based on the utilization of low-temperature tars. Because of the obvious economic significance of phenols, as well as the relative ease with which they can be separated and analyzed, initial research has centered mainly around this class of tar constituents. It was realized early that no listing of phenols and their physical properties existed that included enough compounds to be practicable. The purpose of this paper is to make such a compilation available.

Jan 1, 1957

By James J. Snodgrass

The Bureau of Mines designed and constructed a series of calibration models for geophysical borehole logging. A nominal hole diameter of 3 inches was selected as representative of typical core holes drilled for mining and engineering purposes, although additional hole diameters of 2, 5, and 8 inches are provided in one of the models for determination of empirical correction factors for variations in hole diameter. The physical properties of the models were determined by laboratory analyses of drill core samples and evaluated statistically for reliability. This report outlines the location of the models, elements of design and construction, and results of the laboratory tests. The models are available at the Denver Federal Center, Denver, Colo., for use by Government agencies and private industry to calibrate logging equipment for measurements of density, sonic velocity, magnetic susceptibility, and electrical resistivity.

Jan 1, 1976

By P. M. Gruzensky

Several experiments have been carried out in efforts to evaluate qualitatively a variety of electrolytes for refining bismuth. Most extensive work was done with the basic tartrate, hydrochloric acid, and hydrofluosilicic acid electrolytes. Deposits that are smooth and adherent can be obtained from these three electrolytes if low cathode current densities are employed. All three electrolytes were effective in purifying crude bismuth considerably, with additional purification indicated in each instance by a reelectrolysis step. With the basic tartrate electrolyte best results were obtained when the electrolyte was at 40° C, and contained at least 100 grams of bismuth per liter, An apparent disadvantage was depletion of bismuth from this electrolyte, causing the deposits to become spongy and nonadherent.

Jan 1, 1956

By Graham W. Marks

In broadening the utility of spectrochemical methods 9f analysis of ore samples 3,4/ a procedure employ in the total energy method, has been adapted to determination of silver in ores. Silver is the first element in group I of the periodic table to be studied in the Bureau of Mines program. Two silver lines in the spectrum, Ag X\ 3280.683 and 3382.89lR were used in the study, and the problems that had to be overcome were: (1) Influence of extraneous elements on line intensities, (2) preparation of standard curves, and (3) improvement in equipment and technique to increase accuracy. Sodium, potassium, sulfur, selenium, iron, cobalt, and nickel yielded low intensities and hence low results, particularly on the samples high in silver, but addition of 60 percent or more of lime counteracted these effects. One calibration curve must be used for samples low in silver and other for those high in silver. The chocks with fire assaying were close enough for preliminary or exploratory investigations, and the method is much more rapid.

Jan 1, 1948

By George E. Fish

This report describes investigations conducted by the Bureau of Mines from 1957 through 1959 in the Roseland anorthosite-titanium belt of Nelson and Amherst Counties, Va., for the purpose of studying the titanium resources of the area. Three titanium deposits containing much saprolite ore derived from the decomposition of anorthosite and diorite were selected for detailed study Following a reconnaissance of the reported titanium occurrences in the belt. These three deposits occur in or are associated with anorthosite. Most of the occurrences are situated on or near the contact between the anorthosite and the gneissic country rock. The saprolite deposits are as much as 1.5 miles long, 1,000 feet wide, and 100 teat deep and contain significant reserves of titanium-bearing material estimated in excess of 20 million tons. Where it was penetrated by drilling, the unweathered rock beneath the saprolite contains nearly the same titanium values as the saprolite.

Jan 1, 1962

By S. Stephen Uslan

The purpose of the study was to demonstrate the effect of positive reinforcement, specifically, social reinforcement (SR), on the frequency of eye, hand, and back injuries at four experimental salt mines. Injury data was collected from January, 1976, for the prePOMOST period and from the onset of training to September, 1978, for the post-POMOST period. All data was collected on a month-by-month basis. For the training period approximately 100 managers and supervisors from five plants were trained in the use of positive reinforcement for occurrences of "safe behavior." Each supervisor was also provided manuals and other supportive materials. Additionally, following training, all supervisors were provided some coaching experience to keep the knowledge and capabilities gained during training from being extinguished. The analysis showed significant injury reductions in two sites and no injury reductions in the other two. When the injury data was corrected for the additional man hours expended in the postPOMOST period, a third site showed reduction in injuries. Similar findings were shown when the experimental sites were compared to other sites in the industry. The results were interpreted to support the hypothesis that the application of social reinforcement is related to a reduction in injuries.

Jan 1, 1978

By J. B. Rosenbaum

This report presents new findings and consolidates previously published data to provide a single reference containing a concise and comprehensive description of the Bureau's work on electrolytic chromium. Two separate systems for electrolytic-chromium recovery were developed, one designated as the oxidized system the other as the reduced system. The electrowinning of chromium metal follows the dissolution of chromium from the ore or from ferrochrome and its separation from gangue and metallic impurities. Chromite was first solubilized by pressure digestion at slightly elevated temperatures in an oxidized acid solution using Na2Cr2O7 as an oxidizing agent. Later it was found that a sodium-free electrolyte was preferable, using return-cell anolyte containing H2SO4 and Cr03 as the oxidizing agent. Gangue materials were separated from the soluble metallics by filtration; and, after the Cr+3 had been stabilized, the metallic impurities were separated as crystalline ammonium salts by vacuum crystallization.

Jan 1, 1957

By M. L. Wouden

In the late 1970's, the Bureau of Mines began to examine the criteria for reestablishing vegetative cover on coal strip mine spoils near Glenrock, WY. A 9-acre plot, consisting of (1) spoils covered with topsoil, (2) spoils without topsoil, and (3) spoils treated with sewage sludge, was constructed. These plots were seeded with Tegmar intermediate wheatgrass (Agropyron intermedium), Fairway crested wheatgrass (A. cristatum), and Critana thickspike wheatgrass (A. dasystachyum). After 5 yr, the topsoil had about 70 pct plant coverage. Revegetated spoils, without topsoil addition, averaged approximately 30 pct plant coverage, and sewage sludge-treated spoils had about 45 pct plant coverage. Comparison of grass types showed the intermediate wheatgrass produced greater surface coverage.

Jan 1, 1986

By Dennis R. Kasper

This study evaluates selective environmental impacts of two distinct in situ mining techniques. In situ leaching of uranium, porphyry copper and native copper and in situ borehole (slurry) mining of uranium, sandstone, and pebble phosphate ores are the techniques and minerals investigated. The potential impacts onsite in the desert southwest (porphyry copper), Michigan (native copper), Texas and Wyoming (uranium), and Florida and North Carolina (phosphate) are addressed and discussed. The study emphasizes those impacts which are unique to in situ solution leaching and borehole slurry mining. Impacts which are characteristic of all construction projects in the general geographical areas investigated, such as socioeconomic effects on surrounding communities and site-specific impacts, such as rare and endangered species, are beyond the scope of this study. For each of the in situ processes and associated ores investigated, the physical and chemical characteristics of the systems are described, the toxicity of the leaching solutions are presented, and the potential impacts on the environment are developed.

Jan 1, 1979

By S. H. Lorain

This paper is one of a series on mining and milling method and costs being published by the United States Bureau of Mines. The Golden Messenger mine, operated by the United Gold Mines Corporation, is in the York-Confederate Gulch mining region in Luis and Clark County, Mont., 22 miles northeast of the city limits of Helena and about 1 mile north of the town of York. It is the first operation to exploit successfully the low-grade ores of the York-Confederate Gulch area. The unusual vein structure presents some mining problems that have been solved in ail interesting manner.

Jan 1, 1937

By Robert W. McKibbin

The Bureau of Mines conducted laboratory tests to determine the slurry transport and deposition properties of coal waste. A 188.5-ft pipe test loop was constructed with instruments to measure density, flow, and power and discharge, suction, and differential pressures. A 20-ton ample of Western coal waste was crushed and screened to 100 pct minus 1/2 in. Eight loop tests using this graded waste were run at slurry densities ranging from 1.15 (25 wt-pct solids) to 1.46 (60 wt-pct sol-ids) 0 The resultant friction-'pressure gradients ranged from 0,06 to 0.24 ft of water per foot of 4-in standard steel pipe. Particle-size degradation was significant.. In a typical loop test lasting 25 min, the minus 200-mesh fraction increased from 19 pct to 34 pct. Deposition tests showed that without the use of a flocculant, the slurries would not dewater when left to stand for 1 week. With flocculant, additional water was releas2d; however, the settled slurries remained thixotropic. Further testing is necessary to determine their suitability for use as backfill material in active mines.

Jan 1, 1983

By T. W. Johnson

One of the common methods of increasing recovery of oil from partly depleted oil sands is to inject natural gas, air, or air-gas mixtures into the sand, thereby supplying energy to move oil into the well bore. Where natural gas is not available, air or an air-gas mixture is used as the repressuring medium. Air-gas mixtures are obtained from the casing-heads of oil-producing wells in the areas repressured with air or air-gas mixtures and consist usually of varying amounts of the hydrocarbon gases, nitrogen, oxygen, and carbon dioxide. Laboratory experiments have been conducted by the Bureau of Mines to determine the effect of air on crude oils.4/ In these experiments the crude oils were oxidized by the air, and the degree of oxidation depended not only upon the chemical composition of the crude oil but also upon the duration and method of contact between the oil and air, the temperature of the fluids and the concentration of the oxygen. When the crude oils were oxidized the following results and changes in the oils were obtained:

Jan 1, 1937

By T. W. Johnson

One of the common methods of increasing recovery of oil from partly depleted oil sands is to inject natural gas, air, or air-gas mixtures into the sand, thereby supplying energy to move oil. into the well bore. Where natural gas is not available, air or an air-gas mixture is used as the repressuring medium. Air-gas mixtures are obtained from the casingheads of oil-producing wells in the areas repressured with air or air-gas mixtures and consist usually of varying amounts of the hydrocarbon gases, nitrogen, oxygen, and carbon dioxide. Laboratory experiments have been conducted by the Bureau of Mines to determine the effect of air on crude oils.4/ In these experiments the crude oils were oxidized by the air, and the degree of oxidation depended not only upon the chemical composition of the crude oil but also upon the duration and method of contact between the oil and air, the temperature of the fluids and the concentration of the oxygen. When the crude oils were oxidized the following results and changes in the oils were obtained:

Jan 1, 1937

As fulfillment of the requirements of Contract H0387019 for the United States Department of the Interior, Bureau of Mines, a complete field kit, for performing on-site determinations of individual employee Time Weighted Average (TWA) exposures to nitrogen dioxide (NO2) and nitric oxide (NO), has been developed by MDA Scientific, Inc. This report provides background information and experimental data validating the use of this kit with confidence to ? 10 percent accuracy.

Jan 1, 1981

By James C. Barker

In 1981 and 1985-1986, the Bureau of Mines conducted orientation studies of marine placer platinum-group metals (PGM). PGM are derived from the Goodnews Bay ultramafic complex and magnetic surveys show that the complex extends offshore at least four mi. The present seafloor was an emergent foreland as recently as 8000 years ago. High-energy ocean processes are transporting and depositing sediment such that PGM-bearing materials are reworked and later masked by barren littoral drift. Exploration targets include 1) placers formed since present transgression began, and 2) ancient marine and drowned fluvial deposits. Additionally, there is evidence of PGM solution transport and accretion. At least minor values of PGM in Recent lag-type placers and possible submarine strands are concentrated along an offshore scarp incised through glacial deposits into the preglacial surface between Flat Cape and Red Mountain. Other Recent PGM-bearing features include Flat Cape shoal, Chagvan Bay, Salmon River delta, and modern beaches. Ancient placers include possible N-S fluvial systems 2 to 3 mi offshore, a nearshore scarp 50 ft below sea level, and strands adjacent to projected ultramafic bedrock slopes. The existance of ancient placers is dependent on depth of glacial erosion. SEM studies show PGM are principally isoferroplatinum and osmiridium, with minor sperrylite, moncheite, and platiniridium. Gold is a co-product, and concentrates comprise chromite, ilmenite, and magnetite. Beneficiation tests successfully concentrated precious metals from natural blacksand accumulations, but failed to concentrate low-grade lag gravels.

Jan 1, 2011

By Manuel Gomez

This report presents low-temperature tar data from studies by the Bureau of Mines of tars produced in an externally heated (entrained state) pilot-plant-scale retort. Analytical data covering 20 low-temperature tars, derived from the. carbonization of various ranks of foreign and domestic coals, are tabulated. The character of the tar is discussed in relationship to carbonizing conditions and the rank of coal. It is seen that in carbonization techniques that employ entrainment or fluidization of the coal particle, carbonization conditions are secondary to coal rank with respect to tar-oil yields and composition. The influence of distillation conditions on recoverable yields of tar products is presented. The probable yield of commercially important chemical products, based on a ton of pure (moisture- and ash-free) coal, are predicted. INTRODUCTION Low-temperature tars produced by entrainment or fluidized carbonization techniques that employ internally heated reactors represent the most nearly primary tart produced by industrial processes. In brief, such a process involves the application of a heat gradient to the coal particle "boiling" or suspended in a turbulent state in the reactor chamber. Conditions are observed so that the coal particle remains suspended within the reaction zone by a gas stream for a time interval commensurate with maximum tar-oil yield. The heat necessary for the carbonization reaction may be obtained entirely from the hot (preheated) gas stream, or it may be derived partly from the combustion of the volatile products and char by the transport gases, usually air. The volatile material moves out of the carbonizing zone at a rate that approaches the velocity of the transport gas. Carbonizing conditions are ideal when a minimum particle residence time is obtained within the reactor at a given temperature and a maximum yield of condensable volatile matter is released. In industrial practice this objective is a compromise.

Jan 1, 1957

By A. G. Sharkey

THE PURPOSE of this investigation was to develop methods for analyzing coal derivatives and products from the Fischer-Tropsch synthesis. As part of this investigation it was necessary to study the mass spectral characteristics of many classes of compounds. The mass spectra of alcohols, the trimethylsilyl ether derivatives of alcohols, acetal-type compounds, ketones, esters, and naphthenes were correlated with structure, and analytical methods were formulated. A method was devised to determine the ratio of branched to normal hydrocarbons up to CIS in the Fischer-Tropsch product. Low-ionizing-voltage mass spectrometry was combined with type-analyses to analyze tar acids and neutral oils from coal. The necessary sensitivity correlations at low-ionizing voltage were developed, particularly for phenolic compounds. Special analytical techniques were developed for the mass spectral analyses of specific compounds and compound types including (1) oxides of nitrogen, (2) hydrogen sulfide, (3) isomers of butenes and pentenes, and (4) hydrogen deuteride. An investigation was made of the effects of various hydrocarbons and oxygenated compounds on tungsten filaments in the mass spectrometer. The operating characteristics of rhenium filaments under similar conditions were studied. Several improved sample handling techniques were developed, including an automatic manometer and a self-filling micropipet. Studies were made of anomalous and negative peaks in the mass spectra of certain gases.

Jan 1, 1967

By P. M. Sullivan

A physical beneficiation flowsheet was designed by the Bureau of Mines for reclaiming and recycling metal and mineral values contained in municipal incinerator residues, and a continuous processing plant was installed. Residue samples collected from incinerators located in various parts of the country were processed at a rate of 1/2 ton per hour. Continuous screening, shredding, grinding, magnetic separation, and gravity concentration techniques were applied to produce metallic iron concentrates, clean nonferrous metal composites, clean fine glass fractions, and tine carbonaceous ash tailings. Research to develop systems for refining and upgrading the reclaimed metals and glass into marketable products is also underway. From the engineering data developed in the continuous processing plant, evaluations of the capital and operating costs for plants with capacities of 250, 400, 670, and 1,000 tons of dry incinerator residues per day were made. Research on a parallel system to separate and recover the metals, minerals, glass, paper, and plastics from raw, unburned refuse it currently underway, as are studies on the use of air classification to separate the refuse into organic and inorganic fractions.

Jan 1, 1971

By James H. Aase

[This study provides data on the physical and hydrological makeup of the ,t hakes waterway system and forecasts quantities, traffic patterns, and ping cost of prospective bulk mineral commerce projected to be transported it. Factors affecting the shipping cost of iron ore, bituminous coal, imestone were quantified and integrated into a computer program that can d to estimate costs under varying sets of conditions. Combined ship of iron ore, bituminous coal, and limestone in 1995 were estimated at million tons. The cost of operating the U.S. vessel fleet for trans-ng an indicated 80 percent of this traffic tonnage was projected to be $163. 5 million.]

Jan 1, 1970